@article{PetitFargesWilkeetal.2001, author = {Petit, Pierre-Emanuel and Farges, Francois and Wilke, Max and Sol{\´e}, V. Armando}, title = {Determination of the iron oxidation state in Earth materials using XANES pre-edge information}, year = {2001}, language = {en} } @article{WilkeFargesPetitetal.2001, author = {Wilke, Max and Farges, Francois and Petit, Pierre-Emanuel and Brown Jr., Gordon E. and Martin, Francois}, title = {Oxidation state and coordination of Fe in minerals : an Fe K XANES spectroscopic study}, year = {2001}, language = {en} } @article{WilkePartzschSchmidtetal.2004, author = {Wilke, Max and Partzsch, G. M. and Schmidt, C. and Farges, Francois}, title = {In-situ study of the iron species in silicate melts}, issn = {0016-7037}, year = {2004}, language = {en} } @article{WilkePartzschFarges2004, author = {Wilke, Max and Partzsch, G. M. and Farges, Francois}, title = {XAFS of iron in silicate melt at high temperature}, issn = {0024-4937}, year = {2004}, language = {en} } @article{FargesDjanarthanydeWispelaereetal.2005, author = {Farges, Francois and Djanarthany, S and de Wispelaere, S and Munoz, Manuel and Magassouba, B and Haddi, A and Wilke, Max and Schmidt, C. and Borchert, Manuela and Trocellier, P and Crichton, W and Simionovici, Alexandre and Petit, Pierre-Emanuel and Mezouar, Mohamed and Etcheverry, M. P. and Pallot-Frossard, I and Bargar, John Reeder and Brown, G. E. and Grolimund, D and Scheidegger, A}, title = {Water in silicate glasses and melts of environmental interest : from volcanoes to cathedrals}, year = {2005}, abstract = {In silicate glasses and melts, water acts according to two main processes. First, it can be dissolved in high temperature/high pressure melts. Second, it constitutes a weathering agent on the glass surface. A number of in-situ x- ray absorption fine structure (XAFS) studies for Fe, Ni, Zr, Th and U show that the more charged cations (Zr, Nb, Mo, Ta, Sn, Th and U) are little affected by the presence of dissolved water in the melt. In contrast, divalent iron and nickel are highly sensitive to the presence of water, which enhance nucleation processes, for example, of phyllosilicates at the angstrom-scale. Such information provides additional constraints on the role of water deep in the Earth, particularly in magmatology. By contrast, the weathering of glass surfaces by water can be studied from a durability perspective. Experimental weathering experiments Of nuclear waste glasses performed in the laboratory show a variety of surface enrichments (carbon, chlorine, alkalis, iron) after exposure to atmospheric fluids and moisture. Mn-, and Fe-surface enrichments of analogous glasses of the XIVth century are related to the formation of Mn and Fe oxy/ hydroxides on the surface. The impact on the glass darkening is considered in terms of urban pollution and mass tourism}, language = {en} } @article{WilkeSchmidtFargesetal.2006, author = {Wilke, Max and Schmidt, Christian and Farges, Francois and Malavergne, Valerie and Gautron, Laurent and Simionovici, Alexandre and Hahn, Matthias and Petit, Pierre-Emanuel}, title = {Structural environment of iron in hydrous aluminosilicate glass and melt-evidence from X-ray absorption spectroscopy}, doi = {10.1016/j.chemgeo.2006.01.017}, year = {2006}, abstract = {The iron speciation in hydrous haplotonalitic and haplogranitic silicate glasses was studied using XAFS spectroscopy and transmission electron microscopy (TEM). Spectral features occurring at the main crest of the XANES at the iron K-edge of hydrous glasses indicate contributions to the spectra by iron-moieties present in a more ordered structural environment than found in the dry glass. These differences are also suggested by analysis of the EXAFS. These effects are not completely suppressed even for those samples that were quenched with a higher cooling rate. Strongest differences to the dry glass are observed for a sample that was quenched slowly through the temperature of glass transformation. Crystals (60 to 1500 nm in size) of magnetite, maghemite and another unidentified phase were observed in this sample by TEM, whereas no crystals were found in samples quenched with regular or high cooling rates. In-situ XANES measurements up to 700 degrees C and 500 MPa were performed to reveal the origin (i.e., during synthesis or quench) of the structural differences for those hydrous glasses that do not display any detectable crystallization. The comparison of XANES spectra collected on Fe2+ in water-saturated haplogranitic melt at 700 degrees C and 500 MPa and on Fe2+ in dry melt at 1150 degrees C shows that the local structural environment of Fe2+ in both systems is similar. This indicates that there is no detectable and direct influence of water on the local structure around iron in this type of melt. Hence, the differences observed between hydrous and dry glasses can only be related to artefacts formed during the quench process. (c) 2006 Elsevier B.V. All rights reserved}, language = {en} } @article{WilkeFargesPartzschetal.2007, author = {Wilke, Max and Farges, Francois and Partzsch, G. M. and Schmidt, C. and Behrens, Harald}, title = {Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy}, year = {2007}, language = {en} } @article{WilkePartzschWelteretal.2007, author = {Wilke, Max and Partzsch, G. M. and Welter, E. and Farges, Francois}, title = {Redox Reaction In Silicate Melts Monitored By Static In-Situ Fe K-edge XANES Up To 1180 C}, year = {2007}, language = {en} } @article{FargesdeWispelaereRossanoetal.2008, author = {Farges, Francois and de Wispelaere, S. and Rossano, Stephanie and Munoz, Manuel and Wilke, Max and Flank, Anne-Marie and Lagarde, Pierre}, title = {Local structures around Si, Al, and Na in hydrated silicate glasses}, year = {2008}, language = {en} }