@article{AnishchenkoNikolaevKurths2006, author = {Anishchenko, Vadim S. and Nikolaev, S and Kurths, J{\"u}rgen}, title = {Winding number locking on a two-dimensional torus : synchronization of quasiperiodic motions}, issn = {1539-3755}, doi = {10.1103/Physreve.73.056202}, year = {2006}, abstract = {We propose a new autonomous dynamical system of dimension N=4 that demonstrates the regime of stable two- frequency motions and period-doubling bifurcations of a two-dimensional torus. It is shown that the period-doubling bifurcation of the two-dimensional torus is not followed by the resonance phenomenon, and the two-dimensional ergodic torus undergoes a period-doubling bifurcation. The interaction of two generators is also analyzed. The phenomenon of external and mutual synchronization of two-frequency oscillations is observed, for which winding number locking on a two- dimensional torus takes place}, language = {en} } @phdthesis{Maraun2006, author = {Maraun, Douglas}, title = {What can we learn from climate data? : Methods for fluctuation, time/scale and phase analysis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-9047}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Since Galileo Galilei invented the first thermometer, researchers have tried to understand the complex dynamics of ocean and atmosphere by means of scientific methods. They observe nature and formulate theories about the climate system. Since some decades powerful computers are capable to simulate the past and future evolution of climate. Time series analysis tries to link the observed data to the computer models: Using statistical methods, one estimates characteristic properties of the underlying climatological processes that in turn can enter the models. The quality of an estimation is evaluated by means of error bars and significance testing. On the one hand, such a test should be capable to detect interesting features, i.e. be sensitive. On the other hand, it should be robust and sort out false positive results, i.e. be specific. This thesis mainly aims to contribute to methodological questions of time series analysis with a focus on sensitivity and specificity and to apply the investigated methods to recent climatological problems. First, the inference of long-range correlations by means of Detrended Fluctuation Analysis (DFA) is studied. It is argued that power-law scaling of the fluctuation function and thus long-memory may not be assumed a priori but have to be established. This requires to investigate the local slopes of the fluctuation function. The variability characteristic for stochastic processes is accounted for by calculating empirical confidence regions. The comparison of a long-memory with a short-memory model shows that the inference of long-range correlations from a finite amount of data by means of DFA is not specific. When aiming to infer short memory by means of DFA, a local slope larger than \$\alpha=0.5\$ for large scales does not necessarily imply long-memory. Also, a finite scaling of the autocorrelation function is shifted to larger scales in the fluctuation function. It turns out that long-range correlations cannot be concluded unambiguously from the DFA results for the Prague temperature data set. In the second part of the thesis, an equivalence class of nonstationary Gaussian stochastic processes is defined in the wavelet domain. These processes are characterized by means of wavelet multipliers and exhibit well defined time dependent spectral properties; they allow one to generate realizations of any nonstationary Gaussian process. The dependency of the realizations on the wavelets used for the generation is studied, bias and variance of the wavelet sample spectrum are calculated. To overcome the difficulties of multiple testing, an areawise significance test is developed and compared to the conventional pointwise test in terms of sensitivity and specificity. Applications to Climatological and Hydrological questions are presented. The thesis at hand mainly aims to contribute to methodological questions of time series analysis and to apply the investigated methods to recent climatological problems. In the last part, the coupling between El Nino/Southern Oscillation (ENSO) and the Indian Monsoon on inter-annual time scales is studied by means of Hilbert transformation and a curvature defined phase. This method allows one to investigate the relation of two oscillating systems with respect to their phases, independently of their amplitudes. The performance of the technique is evaluated using a toy model. From the data, distinct epochs are identified, especially two intervals of phase coherence, 1886-1908 and 1964-1980, confirming earlier findings from a new point of view. A significance test of high specificity corroborates these results. Also so far unknown periods of coupling invisible to linear methods are detected. These findings suggest that the decreasing correlation during the last decades might be partly inherent to the ENSO/Monsoon system. Finally, a possible interpretation of how volcanic radiative forcing could cause the coupling is outlined.}, subject = {Spektralanalyse }, language = {en} } @article{MittalPorcasWucknitzetal.2006, author = {Mittal, Rupal and Porcas, Richard and Wucknitz, Olaf and Biggs, Andy D. and Browne, Ian W. A.}, title = {VLBI phase-reference observations of the gravitational lens JVAS B0218+357}, doi = {10.1051/0004-6361:20054012}, year = {2006}, abstract = {We present the results of phase-referenced VLBA+Effelsberg observations at five frequencies of the double-image gravitational lens WAS B0218+357, made to establish the precise registration of the A and B lensed image positions. The motivation behind these observations is to investigate the anomalous variation of the image flux-density ratio (A[B) with frequency - this ratio changes by almost a factor of two over a frequency range from 1.65 GHz to 15.35 GHz. We investigate whether frequency dependent image positions, combined with a magnification gradient across the image field, could give rise to the anomaly. Our observations confirm the variation of image flux-density ratio with frequency. The results from Our phase-reference astrometry, taken together with the lens mass model of Wucknitz et al. (2004, MNRAS, 349, 14), show that shifts of the image peaks and centroids are too small to account for the observed frequency- dependent ratio}, language = {en} } @article{GandhimathiRajasekarKurths2006, author = {Gandhimathi, V. M. and Rajasekar, S. and Kurths, J{\"u}rgen}, title = {Vibrational and stochastic resonances in two coupled overdamped anharmonic oscillators}, series = {Modern physics letters : A, Particles and fields, gravitation, cosmology, nuclear physics}, volume = {360}, journal = {Modern physics letters : A, Particles and fields, gravitation, cosmology, nuclear physics}, number = {2}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0375-9601}, doi = {10.1016/j.physleta.2006.08.051}, pages = {279 -- 286}, year = {2006}, abstract = {We study the overdamped version of two coupled anharmonic oscillators under the influence of both low- and high-frequency forces respectively and a Gaussian noise term added to one of the two state variables of the system. The dynamics of the system is first studied in the presence of both forces separately without noise. In the presence of only one of the forces, no resonance behaviour is observed, however, hysteresis happens there. Then the influence of the high-frequency force in the presence of a low-frequency, i.e. biharmonic forcing, is studied. Vibrational resonance is found to occur when the amplitude of the high-frequency force is varied. The resonance curve resembles a stochastic resonance-like curve. It is maximum at the value of g at which the orbit lies in one well during one half of the drive cycle of the low-frequency force and in the other for the remaining half cycle. Vibrational resonance is characterized using the response amplitude and mean residence time. We show the occurrence of stochastic resonance behaviour in the overdamped system by replacing the high-frequency force by Gaussian noise. Similarities and differences between both types of resonance are presented. (c) 2006 Elsevier B.V. All rights reserved.}, language = {en} } @article{GerhardFariaOliveiraJretal.2006, author = {Gerhard, Reimund and Faria, Roberto M. and Oliveira Jr., O. N. and Giacometti, Jose A.}, title = {Useful effects of space charge and dipole polarization: Recent developments in polymer electrets and organic semiconductors (Editorial)}, issn = {1070-9878}, doi = {10.1109/TDEI.2006.247817}, year = {2006}, language = {en} } @article{BaptistaPereiraKurths2006, author = {Baptista, Murilo da Silva and Pereira, Tiago and Kurths, J{\"u}rgen}, title = {Upper bounds in phase synchronous weak coherent chaotic attractors}, issn = {0167-2789}, doi = {10.1016/j.physd.2006.02.007}, year = {2006}, abstract = {An approach is presented for coupled chaotic systems with weak coherent motion, from which we estimate the upper bound value for the absolute phase difference in phase synchronous states. This approach shows that synchronicity in phase implies synchronicity in the time of events, a characteristic explored to derive an equation to detect phase synchronization, based on the absolute difference between the time of these events. We demonstrate the potential use of this approach for the phase coherent and the funnel attractor of the Rossler system, as well as for the spiking/bursting Rulkov map.}, language = {en} } @article{DiezTauerSchulz2006, author = {Diez, Isabel and Tauer, Klaus and Schulz, Burkhard}, title = {Unusual polymer dispersions-polypyrrole suspensions made of rings, frames, and platelets}, series = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft}, volume = {284}, journal = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft}, publisher = {Springer}, address = {New York}, issn = {0303-402X}, doi = {10.1007/s00396-006-1521-8}, pages = {1431 -- 1442}, year = {2006}, abstract = {Experimental results show that the polymerization of pyrrole in the presence of beta-naphthalenesulfonic acid and different fluorosurfactants like perfluorooctanesulfonic acid, perfluorooctyldiethanolamide, and ammonium perfluorooctanoate leads to polypyrrole with special morphologies, such as rings or disks and rectangular frames or plates. The formation of these unusually shaped particles of polymer dispersions is explained by the chemical and colloidal peculiarities of the oxidative pyrrole polymerization with ammonium peroxodisulfate in aqueous medium.}, language = {en} } @article{ZhouMotterKurths2006, author = {Zhou, Changsong and Motter, Adilson E. and Kurths, J{\"u}rgen}, title = {Universality in the synchronization of weighted random networks}, doi = {10.1103/Physrevlett.96.034101}, year = {2006}, abstract = {Realistic networks display not only a complex topological structure, but also a heterogeneous distribution of weights in the connection strengths. Here we study synchronization in weighted complex networks and show that the synchronizability of random networks with a large minimum degree is determined by two leading parameters: the mean degree and the heterogeneity of the distribution of node's intensity, where the intensity of a node, defined as the total strength of input connections, is a natural combination of topology and weights. Our results provide a possibility for the control of synchronization in complex networks by the manipulation of a few parameters}, language = {en} } @misc{ThielRomanoKurthsetal.2006, author = {Thiel, Marco and Romano, Maria Carmen and Kurths, J{\"u}rgen and Rolfs, Martin}, title = {Twin Surrogates to Test for Complex Synchronisation}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-57231}, year = {2006}, abstract = {We present an approach to generate (multivariate) twin surrogates (TS) based on recurrence properties. This technique generates surrogates which correspond to an independent copy of the underlying system, i. e. they induce a trajectory of the underlying system starting at different initial conditions. We show that these surrogates are well suited to test for complex synchronisation and exemplify this for the paradigmatic system of R¨ossler oscillators. The proposed test enables to assess the statistical relevance of a synchronisation analysis from passive experiments which are typical in natural systems.}, language = {en} } @article{EvansDeviMaketal.2006, author = {Evans, Nicholas R. and Devi, Lekshmi Sudha and Mak, Chris S. K. and Watkins, Scott E. and Pascu, Sofia I. and K{\"o}hler, Anna and Friend, Richard H. and Williams, Charlotte K. and Holmes, Andrew B.}, title = {Triplet energy back transfer in conjugated polymers with pendant phosphorescent iridium complexes}, issn = {0002-7863}, doi = {10.1021/Ja0584267}, year = {2006}, abstract = {The nature of Dexter triplet energy transfer between bonded systems of a red phosphorescent iridium complex 13 and a conjugated polymer, polyfluorene, has been investigated in electrophosphorescent organic light-emitting diodes. Red- emitting phosphorescent iridium complexes based on the [Ir(btp)2(acac)]fragment (where btp is 2-(2 '- benzo[b]thienyl)pyridinato and acac is acetylacetonate) have been attached either directly (spacerless) or through a - (CH2)(8)-chain (octamethylene-tethered) at the 9-position of a 9-octylfluorene host. The resulting dibromo- functionalized spacerless (8) or octamethylene-tethered (12) fluorene monomers were chain extended by Suzuki polycondensations using the bis(boronate)-terminated fluorene macromonomers 16 in the presence of end-capping chlorobenzene solvent to produce the statistical spacerless (17) and octamethylene-tethered ( 18) copolymers containing an even dispersion of the pendant phosphorescent fragments. The spacerless monomer 12 adopts a face-to-face conformation with a separation of only 3.6 angstrom between the iridium complex and fluorenyl group, as shown by X-ray analysis of a single crystal, and this facilitates intramolecular triplet energy transfer in the spacerless copolymers 17. The photo- and electroluminescence efficiencies of the octamethylene-tethered copolymers 18 are double those of the spacerless copolymers 17, and this is consistent with suppression of the back transfer of triplets from the red phosphorescent iridium complex to the polyfluorene backbone in 18. The incorporation of a -(CH2)(8)- chain between the polymer host and phosphorescent guest is thus an important design principle for achieving higher efficiencies in those electrophosphorescent organic light-emitting diodes for which the triplet energy levels of the host and guest are similar}, language = {en} } @article{WesselSchirdewan2006, author = {Wessel, Niels and Schirdewan, Alexander}, title = {Toward a prediction of sudden death in propofol-related infusion syndrome}, year = {2006}, language = {en} } @article{MontbrioPazoSchmidt2006, author = {Montbrio, Ernest and Pazo, Diego and Schmidt, J{\"u}rgen}, title = {Time delay in the Kuramoto model with bimodal frequency distribution}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {74}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {APS}, address = {College Park}, issn = {1539-3755}, doi = {10.1103/PhysRevE.74.056201}, pages = {5}, year = {2006}, abstract = {We investigate the effects of a time-delayed all-to-all coupling scheme in a large population of oscillators with natural frequencies following a bimodal distribution. The regions of parameter space corresponding to synchronized and incoherent solutions are obtained both numerically and analytically for particular frequency distributions. In particular, we find that bimodality introduces a new time scale that results in a quasiperiodic disposition of the regions of incoherence.}, language = {en} } @article{OstermeyerMudgeVeitchetal.2006, author = {Ostermeyer, Martin and Mudge, Damien and Veitch, Peter John and Munch, Jesper}, title = {Thermally induced birefringence in Nd : YAG slab lasers}, doi = {10.1364/AO.45.005368}, year = {2006}, abstract = {We study thermally induced birefringence in crystalline Nd:YAG zigzag slab lasers and the associated depolarization losses. The optimum crystallographic orientation of the zigzag slab within the Nd:YAG boule and photoelastic effects in crystalline Nd:YAG slabs are briefly discussed. The depolarization is evaluated using the temperature and stress distributions, calculated using a finite element model, for realistically pumped and cooled slabs of finite dimensions. Jones matrices are then used to calculate the depolarization of the zigzag laser mode. We compare the predictions with measurements of depolarization, and suggest useful criteria for the design of the gain media for such lasers.}, language = {en} } @article{FloresSuarezMellingerWegeneretal.2006, author = {Flores Su{\´a}rez, Rosaura and Mellinger, Axel and Wegener, Michael and Wirges, Werner and Gerhard, Reimund and Singh, Rajeev}, title = {Thermal-pulse tomography of polarization distributions in a cylindrical geometry}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {13}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {5}, publisher = {IEEE}, address = {Piscataway}, issn = {1070-9878}, doi = {10.1109/TDEI.2006.258210}, pages = {1030 -- 1035}, year = {2006}, abstract = {Fast, three-dimensional polarization mapping in piezoelectric sensor cables was performed by means of the novel thermal-pulse tomography (TPT) technique with a lateral resolution of 200 mum. The active piezoelectric cable material (a copolymer of polyvinylidene fluoride with trifluoroethylene) was electrically poled with a point-to-cable corona discharge. A focused laser was employed to heat the opaque outer electrode, and the short-circuit current generated by the thermal pulse was used to obtain 3D polarization maps via the scale transformation method. The article describes the TPT technique as a fast non-destructive option for studying cylindrical geometries.}, language = {en} } @article{MellingerWegenerWirgesetal.2006, author = {Mellinger, Axel and Wegener, Michael and Wirges, Werner and Mallepally, Rajendar Reddy and Gerhard, Reimund}, title = {Thermal and temporal stability of ferroelectret films made from cellular polypropylene/air composites}, year = {2006}, abstract = {Ferroelectrets are thin films of polymer foams, exhibiting piezoelectric properties after electrical charging. Ferroelectret foams usually consist of a cellular polymer structure filled with air. Polymer-air composites are elastically soft due to their high air content as well as due to the size and shape of the polymer walls. Their elastically soft composite structure is one essential key for the working principle of ferroelectrets, besides the permanent trapping of electric charges inside the polymer voids. The elastic properties allow large deformations of the electrically charged voids. However, the composite structure can also possibly limit the stability and consequently the range of applications because of, e. g., penetration of gas and liquids accompanied by discharge phenomena or because of a mechanical pre-load which may be required during the application. Here, we discuss various stability aspects related to the piezoelectric properties of polypropylene ferroelectrets. Near and below room temperature, the piezoelectric effect and the stability of the trapped charges are practically independent from humidity during long-time storage in a humid atmosphere or water, or from operating conditions, such as continuous mechanical excitation. Thermal treatment of cellular polypropylene above -10 degrees C leads to a softening of the voided structure which is apparent from the decreasing values of the elastic modulus. This decrease results in an increase of the piezoelectric activity. Heating above 60 degrees C, however, leads to a decrease in piezoelectricity}, language = {en} } @article{MellingerWegenerWirgesetal.2006, author = {Mellinger, Axel and Wegener, Michael and Wirges, Werner and Mallepally, Rajendar Reddy and Gerhard, Reimund}, title = {Thermal and temporal stability of ferroelectret films made from cellular polypropylene/air composites}, year = {2006}, language = {en} } @article{AndrianovSaalfrank2006, author = {Andrianov, Ivan and Saalfrank, Peter}, title = {Theoretical study of vibration-phonon coupling of H adsorbed on a Si(100) surface}, issn = {0021-9606}, doi = {10.1063/1.2161191}, year = {2006}, abstract = {In this paper a perturbation-theory study of vibrational lifetimes for the bending and stretching modes of hydrogen adsorbed on a Si(100) surface is presented. The hydrogen-silicon interaction is treated with a semiempirical bond-order potential. Calculations are performed for H-Si clusters of different sizes. The finite lifetime is due to vibration-phonon coupling, which is assumed to be linear or bilinear in the phonon and nonlinear in the H-Si stretching and bending modes. Lifetimes and vibrational transition rates are evaluated with one- and two-phonon processes taken into account. Temperature effects are also discussed. In agreement with the experiment and previous theoretical treatment it is found that the H-Si (upsilon(s)=1) stretching vibration decays on a nanosecond timescale, whereas for the H-Si (upsilon(b)=1) bending mode a picosecond decay is predicted. For higher-excited vibrations, simple scaling laws are found if the excitation energies are not too large. The relaxation mechanisms for the excited H-Si stretching and the H-Si bending modes are analyzed in detail.}, language = {en} } @article{CharronCironeNegrettietal.2006, author = {Charron, Eric and Cirone, M. A. and Negretti, Antonio and Schmiedmayer, J{\"o}rg and Calarco, Tommaso}, title = {Theoretical analysis of a realistic atom-chip quantum gate}, issn = {1050-2947}, year = {2006}, abstract = {We present a detailed, realistic analysis of the implementation of a proposal for a quantum phase gate based on atomic vibrational states, specializing it to neutral rubidium atoms on atom chips. We show how to create a double-well potential with static currents on the atom chips, using for all relevant parameters values that are achieved with present technology. The potential barrier between the two wells can be modified by varying the currents in order to realize a quantum phase gate for qubit states encoded in the atomic external degree of freedom. The gate performance is analyzed through numerical simulations; the operation time is similar to 10 ms with a performance fidelity above 99.9\%. For storage of the state between the operations the qubit state can be transferred efficiently via Raman transitions to two hyperfine states, where its decoherence is strongly inhibited. In addition we discuss the limits imposed by the proximity of the surface to the gate fidelity.}, language = {en} } @article{LeitererLeitenbergerEmmerlingetal.2006, author = {Leiterer, York and Leitenberger, Wolfram and Emmerling, Franziska and Th{\"u}nemann, Andreas F. and Panne, Ulrich}, title = {The use of an acoustic levitator to follow crystallization in small droplets by energydispersive X-ray diffraction}, issn = {0021-8898}, doi = {10.1107/S0021889806024915}, year = {2006}, language = {en} } @phdthesis{Dominis2006, author = {Dominis, Dijana}, title = {The role of binary stars in searches for extrasolar planets by microlensing and astrometry}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-10814}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {When Galactic microlensing events of stars are observed, one usually measures a symmetric light curve corresponding to a single lens, or an asymmetric light curve, often with caustic crossings, in the case of a binary lens system. In principle, the fraction of binary stars at a certain separation range can be estimated based on the number of measured microlensing events. However, a binary system may produce a light curve which can be fitted well as a single lens light curve, in particullary if the data sampling is poor and the errorbars are large. We investigate what fraction of microlensing events produced by binary stars for different separations may be well fitted by and hence misinterpreted as single lens events for various observational conditions. We find that this fraction strongly depends on the separation of the binary components, reaching its minimum at between 0.6 and 1.0 Einstein radius, where it is still of the order of 5\% The Einstein radius is corresponding to few A.U. for typical Galactic microlensing scenarios. The rate for misinterpretation is higher for short microlensing events lasting up to few months and events with smaller maximum amplification. For fixed separation it increases for binaries with more extreme mass ratios. Problem of degeneracy in photometric light curve solution between binary lens and binary source microlensing events was studied on simulated data, and data observed by the PLANET collaboration. The fitting code BISCO using the PIKAIA genetic algorithm optimizing routine was written for optimizing binary-source microlensing light curves observed at different sites, in I, R and V photometric bands. Tests on simulated microlensing light curves show that BISCO is successful in finding the solution to a binary-source event in a very wide parameter space. Flux ratio method is suggested in this work for breaking degeneracy between binary-lens and binary-source photometric light curves. Models show that only a few additional data points in photometric V band, together with a full light curve in I band, will enable breaking the degeneracy. Very good data quality and dense data sampling, combined with accurate binary lens and binary source modeling, yielded the discovery of the lowest-mass planet discovered outside of the Solar System so far, OGLE-2005-BLG-390Lb, having only 5.5 Earth masses. This was the first observed microlensing event in which the degeneracy between a planetary binary-lens and an extreme flux ratio binary-source model has been successfully broken. For events OGLE-2003-BLG-222 and OGLE-2004-BLG-347, the degeneracy was encountered despite of very dense data sampling. From light curve modeling and stellar evolution theory, there was a slight preference to explain OGLE-2003-BLG-222 as a binary source event, and OGLE-2004-BLG-347 as a binary lens event. However, without spectra, this degeneracy cannot be fully broken. No planet was found so far around a white dwarf, though it is believed that Jovian planets should survive the late stages of stellar evolution, and that white dwarfs will retain planetary systems in wide orbits. We want to perform high precision astrometric observations of nearby white dwarfs in wide binary systems with red dwarfs in order to find planets around white dwarfs. We selected a sample of observing targets (WD-RD binary systems, not published yet), which can possibly have planets around the WD component, and modeled synthetic astrometric orbits which can be observed for these targets using existing and future astrometric facilities. Modeling was performed for the astrometric accuracy of 0.01, 0.1, and 1.0 mas, separation between WD and planet of 3 and 5 A.U., binary system separation of 30 A.U., planet masses of 10 Earth masses, 1 and 10 Jupiter masses, WD mass of 0.5M and 1.0 Solar masses, and distances to the system of 10, 20 and 30 pc. It was found that the PRIMA facility at the VLTI will be able to detect planets around white dwarfs once it is operating, by measuring the astrometric wobble of the WD due to a planet companion, down to 1 Jupiter mass. We show for the simulated observations that it is possible to model the orbits and find the parameters describing the potential planetary systems.}, subject = {Mikrogravitationslinseneffekt}, language = {en} } @article{AlbersSpahn2006, author = {Albers, Nicole and Spahn, Frank}, title = {The influence of particle adhesion on the stability of agglomerates in Saturn's rings}, issn = {0019-1035}, doi = {10.1016/j.icarus.2005.10.011}, year = {2006}, abstract = {In planetary rings, binary collisions and mutual gravity are the predominant particle interactions. Based on a viscoelastic contact model we implement the concept of static adhesion. We discuss the collision dynamics and obtain a threshold velocity for restitution or agglomeration to occur. The latter takes place within a range of a few cm s(-1) for icy grains at low temperatures. The stability of such two-body agglomerates bound by adhesion and gravity in a tidal environment is discussed and applied to the saturnian system. A maximal agglomerate size for a given orbit location is obtained. In this way we are able to resolve the borderline of the zone where agglomerates can exist as a function of the agglomerate size and thus gain an alternative to the classical Roche limit. An increasing ring grain size with distance to Saturn as observed by the VIMS-experiment on board the Cassini spacecraft can be found by our estimates and implications for the saturnian system will be addressed.}, language = {en} } @article{HamannGraefenerLiermann2006, author = {Hamann, Wolf-Rainer and Graefener, G. and Liermann, A.}, title = {The galactic WN stars - Spectral analyses with line-blanketed model atmospheres versus stellar evolution models with and without rotation}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {457}, journal = {Astronomy and astrophysics : an international weekly journal}, number = {3}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361:20065052}, pages = {1015 -- 1031}, year = {2006}, abstract = {Context. Very massive stars pass through the Wolf-Rayet (WR) stage before they finally explode. Details of their evolution have not yet been safely established, and their physics are not well understood. Their spectral analysis requires adequate model atmospheres, which have been developed step by step during the past decades and account in their recent version for line blanketing by the millions of lines from iron and iron-group elements. However, only very few WN stars have been re-analyzed by means of line-blanketed models yet. Aims. The quantitative spectral analysis of a large sample of Galactic WN stars with the most advanced generation of model atmospheres should provide an empirical basis for various studies about the origin, evolution, and physics of the Wolf-Rayet stars and their powerful winds. Methods. We analyze a large sample of Galactic WN stars by means of the Potsdam Wolf-Rayet (PoWR) model atmospheres, which account for iron line blanketing and clumping. The results are compared with a synthetic population, generated from the Geneva tracks for massive star evolution. Results. We obtain a homogeneous set of stellar and atmospheric parameters for the GalacticWN stars, partly revising earlier results. Conclusions. Comparing the results of our spectral analyses of the Galactic WN stars with the predictions of the Geneva evolutionary calculations, we conclude that there is rough qualitative agreement. However, the quantitative discrepancies are still severe, and there is no preference for the tracks that account for the effects of rotation. It seems that the evolution of massive stars is still not satisfactorily understood.}, language = {en} } @article{ZhangHayerAlSutietal.2006, author = {Zhang, Ning and Hayer, Anna and Al-Suti, Mohammed K. and Al-Belushi, Rayya A. and Khan, Muhammad S. and K{\"o}hler, Anna}, title = {The effect of delocalization on the exchange energy in meta- and para-linked Pt-containing carbazole polymers and monomers}, doi = {10.1063/1.2200351}, year = {2006}, abstract = {A series of novel platinum-containing carbazole monomers and polymers was synthesized and fully characterized by UV-VIS absorption, luminescence, and photoinduced absorption studies. In these compounds, a carbazole unit is incorporated into the main chain via either a para- or a meta-linkage. We discuss the effects of linkage and polymerization on the energy levels of S-1, T-1, and T-n. The S-1-T-1 splitting observed for the meta-linked monomer (0.4 eV) is only half of that in the para-linked monomer (0.8 eV). Upon polymerization, the exchange energy in the para- linked compound reduces, yet still remains larger than in the meta-linked polymer. We attribute the difference in exchange energy to the difference in wave function overlap between electron and hole in these compounds. (c) 2006 American Institute of Physics}, language = {en} } @article{KuzanyanPipinSeehafer2006, author = {Kuzanyan, Kirill M. and Pipin, Valerij V. and Seehafer, Norbert}, title = {The alpha effect and the observed twist and current helicity of solar magnetic fields}, issn = {0038-0938}, doi = {10.1007/s11207-006-1636-6}, year = {2006}, abstract = {We present a straightforward comparison of model calculations for the alpha-effect, helicities, and magnetic field line twist in the solar convection zone with magnetic field observations at atmospheric levels. The model calculations are carried out in a mixing-length approximation for the turbulence with a profile of the solar internal rotation rate obtained from helioseismic inversions. The magnetic field data consist of photospheric vector magnetograms of 422 active regions for which spatially-averaged values of the force-free twist parameter and of the current helicity density are calculated, which are then used to determine latitudinal profiles of these quantities. The comparison of the model calculations with the observations suggests that the observed twist and helicity are generated in the bulk of the convection zone, rather than in a layer close to the bottom. This supports two-layer dynamo models where the large-scale toroidal field is generated by differential rotation in a thin layer at the bottom while the alpha-effect is operating in the bulk of the convection zone. Our previous observational finding was that the moduli of the twist factor and of the current helicity density increase rather steeply from zero at the equator towards higher latitudes and attain a certain saturation at about 12 - 15 degrees. In our dynamo model with algebraic nonlinearity, the increase continues, however, to higher latitudes and is more gradual. This could be due to the neglect of the coupling between small-scale and large-scale current and magnetic helicities and of the latitudinal drift of the activity belts in the model}, language = {en} } @article{AkpoWeberReiche2006, author = {Akpo, Claudia and Weber, Edwin and Reiche, J{\"u}rgen}, title = {Synthesis, Langmuir and Langmuir-Blodgett film behaviour of new dendritic amphiphiles}, series = {New journal of chemistry}, volume = {30}, journal = {New journal of chemistry}, publisher = {RSC}, address = {Cambridge}, issn = {1144-0546}, doi = {10.1039/b609645j}, pages = {1820 -- 1833}, year = {2006}, abstract = {New amphiphilic compounds 1-9 that feature a construction with dendronized hydrophilic and hydrophobic segment groups connected to a specific aromatic or aliphatic spacer unit have been synthesized, following a modular building block strategy. The hydrophilic dendrons are typically branched elements with peripheral carboxylic groups, unlike the hydrophobic dendrons that contain peripheral alkyl chains as part of respective amide functions. The hydrophilic dendrons are in different generations of branching, while the hydrophobic dendrons are all in the first generation of branching (three terminal branching), but differ in the length of the alkyl chains, thus giving rise to designed structure and amphiphilic properties in the new compounds. The resulting surfactants are capable of forming well-defined Langmuir films of remarkable stability when spread from a solution onto an aqueous subphase. Nevertheless, specific packing behaviour and orientation of the amphiphilic molecules were found, depending on the molecular structure, as determined using analysis of the surface pressure-area (pi-A) isotherms. Langmuir-Blodgett transfer of the first monolayer from a pure water subphase to a clean silicon wafer proved possible for the amphiphiles of peripheral alkyl chain length C-12, while the amphiphiles with the longer alkyl chains failed, possibly due to the more rigid monolayers they form, impeding the transfer.}, language = {en} } @phdthesis{Kucklaender2006, author = {Kuckl{\"a}nder, Nina}, title = {Synchronization via correlated noise and automatic control in ecological systems}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-10826}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = { Subject of this work is the possibility to synchronize nonlinear systems via correlated noise and automatic control. The thesis is divided into two parts. The first part is motivated by field studies on feral sheep populations on two islands of the St. Kilda archipelago, which revealed strong correlations due to environmental noise. For a linear system the population correlation equals the noise correlation (Moran effect). But there exists no systematic examination of the properties of nonlinear maps under the influence of correlated noise. Therefore, in the first part of this thesis the noise-induced correlation of logistic maps is systematically examined. For small noise intensities it can be shown analytically that the correlation of quadratic maps in the fixed-point regime is always smaller than or equal to the noise correlation. In the period-2 regime a Markov model explains qualitatively the main dynamical characteristics. Furthermore, two different mechanisms are introduced which lead to a higher correlation of the systems than the environmental correlation. The new effect of "correlation resonance" is described, i. e. the correlation yields a maximum depending on the noise intensity. In the second part of the thesis an automatic control method is presented which synchronizes different systems in a robust way. This method is inspired by phase-locked loops and is based on a feedback loop with a differential control scheme, which allows to change the phases of the controlled systems. The effectiveness of the approach is demonstrated for controlled phase synchronization of regular oscillators and foodweb models.}, subject = {Markov-Prozess}, language = {en} } @article{MeucciSalvadoriIvanchenkoetal.2006, author = {Meucci, Riccardo and Salvadori, Francesco and Ivanchenko, Mikhail V. and Al Naimee, Kais and Zhou, Chansong and Arecchi, Fortunato Tito and Boccaletti, Stefano and Kurths, J{\"u}rgen}, title = {Synchronization of spontaneous bursting in a CO2 laser}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {74}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.74.066207}, pages = {6}, year = {2006}, abstract = {We present experimental and numerical evidence of synchronization of burst events in two different modulated CO2 lasers. Bursts appear randomly in each laser as trains of large amplitude spikes intercalated by a small amplitude chaotic regime. Experimental data and model show the frequency locking of bursts in a suitable interval of coupling strength. We explain the mechanism of this phenomenon and demonstrate the inhibitory properties of the implemented coupling.}, language = {en} } @article{AbelBergweilerGerhard2006, author = {Abel, Markus and Bergweiler, Steffen and Gerhard, Reimund}, title = {Synchronization of organ pipes : experimental observations and modeling}, issn = {0001-4966}, doi = {10.1121/1.217044}, year = {2006}, abstract = {We report measurements on the synchronization properties of organ pipes. First, we investigate influence of an external acoustical signal from a loudspeaker on the sound of an organ pipe. Second, the mutual influence of two pipes with different pitch is analyzed. In analogy to the externally driven, or mutually coupled self-sustained oscillators, one observes a frequency locking, which can be explained by synchronization theory. Further, we measure the dependence of the frequency of the signals emitted by two mutually detuned pipes with varying distance between the pipes. The spectrum shows a broad '' hump '' structure, not found for coupled oscillators. This indicates a complex coupling of the two organ pipes leading to nonlinear beat phenomena.}, language = {en} } @article{LiSunKurths2006, author = {Li, Changpin and Sun, Weigang and Kurths, J{\"u}rgen}, title = {Synchronization of complex dynamical networks with time delays}, issn = {0378-4371}, doi = {10.1016/j.physa.2005.07.007}, year = {2006}, abstract = {In the present paper, two kinds of dynamical complex networks are considered. The first is that elements of every node have different time delays but all nodes in Such networks have the same time-delay vector. The second is that different nodes have different time-delay vectors, and the elements of each node also have different time delays. Corresponding synchronization theorems are established. Numerical examples show the efficiency of the derived theorems.}, language = {en} } @article{BoccalettiHwangChavezetal.2006, author = {Boccaletti, Stefano and Hwang, Dong-Uk and Chavez, Mario and Amann, Andreas and Kurths, J{\"u}rgen and Pecora, Louis M.}, title = {Synchronization in dynamical networks : evolution along commutative graphs}, issn = {1539-3755}, doi = {10.1103/Physreve.74.016102}, year = {2006}, abstract = {Starting from an initial wiring of connections, we show that the synchronizability of a network can be significantly improved by evolving the graph along a time dependent connectivity matrix. We consider the case of connectivity matrices that commute at all times, and compare several approaches to engineer the corresponding commutative graphs. In particular, we show that synchronization in a dynamical network can be achieved even in the case in which each individual commutative graphs does not give rise to synchronized behavior}, language = {en} } @article{KurthsRomanoThieletal.2006, author = {Kurths, J{\"u}rgen and Romano, Maria Carmen and Thiel, Marco and Osipov, Grigory V. and Ivanchenko, Mikhail V. and Kiss, Istvan Z. and Hudson, John L.}, title = {Synchronization analysis of coupled noncoherent oscillators}, issn = {0924-090X}, doi = {10.1007/s11071-006-1957-x}, year = {2006}, abstract = {We present two different approaches to detect and quantify phase synchronization in the case of coupled non- phase coherent oscillators. The first one is based on the general idea of curvature of an arbitrary curve. The second one is based on recurrences of the trajectory in phase space. We illustrate both methods in the paradigmatic example of the Rossler system in the funnel regime. We show that the second method is applicable even in the case of noisy data. Furthermore, we extend the second approach to the application of chains of coupled systems, which allows us to detect easily clusters of synchronized oscillators. In order to illustrate the applicability of this approach, we show the results of the algorithm applied to experimental data from a population of 64 electrochemical oscillators}, language = {en} } @article{EmmerlingOrgzallRecketal.2006, author = {Emmerling, Franziska and Orgzall, Ingo and Reck, G{\"u}nter and Schulz, Burkhard W. and Stockhause, Sabine and Schulz, Burkhard}, title = {Structures of substituted di-aryl-1, 3,4-oxadiazole derivatives: 2,5-bis(pyridyl)- and 2,5-bis(aminophenyl)-substitution}, series = {Journal of molecular structure}, volume = {800}, journal = {Journal of molecular structure}, number = {1-3}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0022-2860}, doi = {10.1016/j.molstruc.2006.03.076}, pages = {74 -- 84}, year = {2006}, abstract = {Crystal structures of four different di-aryl-1,3,4-oxadiazole compounds (aryl = 2-pyridyl-, 3-pyridyl-, 2-aminophenyl-, 3-aminophenyl-) are determined. Crystallization of di(2-pyridyl)-1,3,4-oxadiazole yielded monoclinic and triclinic polymorphs. The structures are characterized by the occurrence of pi-pi interactions. Additionally, in case of the aminophenyl compounds intra- as well as intermolecular hydrogen bonds are found that influence the packing motif as well. Since these molecules are often used as ligands in metal-organic complexes similarities and differences of the molecular conformation between the molecules in the pure crystals and that of the ligands in the complexes are discussed. (c) 2006 Elsevier B.V. All rights reserved.}, language = {en} } @article{SteuerGrossSelbigetal.2006, author = {Steuer, Ralf and Gross, Thilo and Selbig, Joachim and Blasius, Bernd}, title = {Structural kinetic modeling of metabolic networks}, series = {Proceedings of the National Academy of Sciences of the United States of America}, volume = {103}, journal = {Proceedings of the National Academy of Sciences of the United States of America}, number = {32}, publisher = {National Academy of Sciences}, address = {Washington}, issn = {0027-8424}, doi = {10.1073/pnas.0600013103}, pages = {11868 -- 11873}, year = {2006}, abstract = {To develop and investigate detailed mathematical models of metabolic processes is one of the primary challenges in systems biology. However, despite considerable advance in the topological analysis of metabolic networks, kinetic modeling is still often severely hampered by inadequate knowledge of the enzyme-kinetic rate laws and their associated parameter values. Here we propose a method that aims to give a quantitative account of the dynamical capabilities of a metabolic system, without requiring any explicit information about the functional form of the rate equations. Our approach is based on constructing a local linear model at each point in parameter space, such that each element of the model is either directly experimentally accessible or amenable to a straightforward biochemical interpretation. This ensemble of local linear models, encompassing all possible explicit kinetic models, then allows for a statistical exploration of the comprehensive parameter space. The method is exemplified on two paradigmatic metabolic systems: the glycolytic pathway of yeast and a realistic-scale representation of the photosynthetic Calvin cycle.}, language = {en} } @article{FrancoOrgzallRegensteinetal.2006, author = {Franco, Olga and Orgzall, Ingo and Regenstein, Wolfgang and Schulz, Burkhard}, title = {Structural and spectroscopical study of a 2,5-diphenyl-1,3,4-oxadiazole polymorph under compression}, issn = {0953-8984}, doi = {10.1088/0953-8984/18/4/029}, year = {2006}, abstract = {The x-ray pattern and the Raman and luminescence spectra of crystalline 2,5-diphenyl-1,3,4-oxadiazole in one of its polymorphic forms (DPO II) have been investigated under pressure up to 5 GPa. The behaviour of the lattice parameters under compression was determined and it was found that the Murnaghan equation of state provides a good description of the volume-pressure relationship of DPO II. The values for the bulk modulus and its pressure derivative are K-0 = 8.6 GPa and K-0' = 7.2. The analysis of the Raman spectrum under compression clearly shows the pressure- induced shift of the Raman modes to higher frequencies. The mode Gruneisen parameters for the lattice modes were determined. Additionally, it was found that the emission spectrum of DPO II moves to lower energies and that the luminescence intensity decreases when pressure is applied}, language = {en} } @article{GaedkeKamjunke2006, author = {Gaedke, Ursula and Kamjunke, Norbert}, title = {Structural and functional properties of low- and high-diversity planktonic food webs}, issn = {0142-7873}, doi = {10.1093/plankt/fb1003}, year = {2006}, abstract = {To test the consequences of decreased diversity and exclusion of keystone species, we compared the planktonic food webs in two acidic (pH <= 3), species-poor mining lakes with those in two species-rich, neutral lakes. The ratio of heterotrophic to autotrophic biomass (HIA) was similar in acidic and neutral lakes with comparable productivity. However, food webs in both acidic lakes were largely restricted to two trophic levels in contrast to the four levels found in neutral lakes. This restriction in food chain length was attributed to the absence of efficient secondary consumers, rather than to productivity or lake size which resulted in unusually low predator-prey weight ratios, with small top predators hardly exceeding their pry in size. In contrast to the neutral lakes, plankton biomass size spectra of acidic lakes were discontinuous due to a lack of major functional groups. The unique size-dependence of feeding modes in pelagic food webs, with bacteria in the smallest size classes followed by autotrophs, herbivores and carnivores, was maintained for bacteria but the other feeding modes strongly overlapped in size. Thus, their characteristic succession along the size gradient was roughly preserved under extreme conditions but the flow of energy along the size gradient was truncated in the acidic lakes. For most but not all attributes studied, differences were larger between acidic and neutral lakes than between neutral lakes of different trophic state}, language = {en} } @article{ZemanovaZhouKurths2006, author = {Zemanova, Lucia and Zhou, Changsong and Kurths, J{\"u}rgen}, title = {Structural and functional clusters of complex brain networks}, series = {Physica, D, Nonlinear phenomena}, volume = {224}, journal = {Physica, D, Nonlinear phenomena}, number = {1-2}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0167-2789}, doi = {10.1016/j.physd.2006.09.008}, pages = {202 -- 212}, year = {2006}, abstract = {Recent research using the complex network approach has revealed a rich and complicated network topology in the cortical connectivity of mammalian brains. It is of importance to understand the implications of such complex network structures in the functional organization of the brain activities. Here we study this problem from the viewpoint of dynamical complex networks. We investigate synchronization dynamics on the corticocortical network of the cat by modeling each node (cortical area) of the network with a sub-network of interacting excitable neurons. We find that the network displays clustered synchronization behavior, and the dynamical clusters coincide with the topological community structures observed in the anatomical network. Our results provide insights into the relationship between the global organization and the functional specialization of the brain cortex.}, language = {en} } @phdthesis{Kierfeld2006, author = {Kierfeld, Jan}, title = {Strings and Filaments: From Vortices to Biopolymers}, address = {Potsdam}, pages = {204 S. : graph. Darst.}, year = {2006}, language = {en} } @book{FreudeKuznetsovPikovskij2006, author = {Freude, Ulrike and Kuznetsov, Sergey P. and Pikovskij, Arkadij}, title = {Strange nonchaotic attractors : dynamics between order and chaos in Quasiperiodically Forced Systems}, publisher = {World Scientific}, address = {Singapore}, isbn = {981-256633-3}, pages = {350 S.}, year = {2006}, language = {en} } @article{MakuchBrilliantovSremcevicetal.2006, author = {Makuch, Martin and Brilliantov, Nikolai V. and Sremcevic, Miodrag and Spahn, Frank and Krivov, Alexander V.}, title = {Stochastic circumplanetary dynamics of rotating non-spherical dust particles}, series = {Planetary and space science}, volume = {54}, journal = {Planetary and space science}, number = {9-10}, publisher = {Elsevier}, address = {Oxford}, issn = {0032-0633}, doi = {10.1016/j.pss.2006.05.006}, pages = {855 -- 870}, year = {2006}, abstract = {We develop a model of stochastic radiation pressure for rotating non-spherical particles and apply the model to circumplanetary dynamics of dust grains. The stochastic properties of the radiation pressure are related to the ensemble-averaged characteristics of the rotating particles, which are given in terms of the rotational time-correlation function of a grain. We investigate the model analytically and show that an ensemble of particle trajectories demonstrates a diffusion-like behaviour. The analytical results are compared with numerical simulations, performed for the motion of the dusty ejecta from Deimos in orbit around Mars. We find that the theoretical predictions are in a good agreement with the simulation results. The agreement however deteriorates at later time, when the impact of non-linear terms, neglected in the analytic approach, becomes significant. Our results indicate that the stochastic modulation of the radiation pressure can play an important role in the circumplanetary dynamics of dust and may in case of some dusty systems noticeably alter an optical depth. (c) 2006 Elsevier Ltd. All rights reserved.}, language = {en} } @phdthesis{Ott2006, author = {Ott, Christian David}, title = {Stellar iron core collapse in {3+1} general relativity and the gravitational wave signature of core-collapse supernovae}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-12986}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {I perform and analyse the first ever calculations of rotating stellar iron core collapse in {3+1} general relativity that start out with presupernova models from stellar evolutionary calculations and include a microphysical finite-temperature nuclear equation of state, an approximate scheme for electron capture during collapse and neutrino pressure effects. Based on the results of these calculations, I obtain the to-date most realistic estimates for the gravitational wave signal from collapse, bounce and the early postbounce phase of core collapse supernovae. I supplement my {3+1} GR hydrodynamic simulations with 2D Newtonian neutrino radiation-hydrodynamic supernova calculations focussing on (1) the late postbounce gravitational wave emission owing to convective overturn, anisotropic neutrino emission and protoneutron star pulsations, and (2) on the gravitational wave signature of accretion-induced collapse of white dwarfs to neutron stars.}, language = {en} } @article{ThielRomanoKurths2006, author = {Thiel, Marco and Romano, Maria Carmen and Kurths, J{\"u}rgen}, title = {Spurious structures in recurrence plots induced by embedding}, doi = {10.1007/s11071-006-2010-9}, year = {2006}, abstract = {In this paper we show that delay embedding produces spurious structures in a recurrence plot (RP) that are not present in the real attractor. We analyze typical sets of simulated data, such as white noise and data from the chaotic Rossler system to show the relevance of this effect. In the second part of the paper we show that the second order Renyi entropy and the correlation dimension are dynamical invariants that can be estimated from Recurrence Plots with arbitrary embedding dimension and delay}, language = {en} } @article{TirokGaedke2006, author = {Tirok, Katrin and Gaedke, Ursula}, title = {Spring weather determines the relative importance of ciliates, rotifers and crustaceans for the initiation of the clear-water phase in a large, deep lake}, year = {2006}, abstract = {Clear-water phase (CWP) is an important event in seasonal plankton succession. We examined the influence of all herbivorous zooplankton on its initiation under different weather and climatic conditions using up to 19 years of observations from the large, deep Lake Constance (Europe) and estimates of relative clearance rates. A CWP occurred regularly, even if daphnid biomass was still very low. CWP was attributed to strong grazing either by a daphnid- dominated zooplankton community or by a diverse assemblage consisting of micro- and meso-zooplankton. Both types of zooplankton communities occurred with approximately the same frequency. The timing of the CWP was unrelated to the North Atlantic Oscillation (NAO) but correlated with the wind-dependent intensity of deep vertical mixing 3 months earlier, during early spring. Less mixing enabled early growth of phytoplankton, ciliates and rotifers despite low temperatures, which prevented daphnid development at this time. This resulted in enhanced grazing of ciliates and rotifers, which increased the importance of phytoplankton less edible for most ciliates, rotifers and daphnids. Ciliates clearly dominated the grazing pressure on phytoplankton throughout spring, maintaining high biomasses together with the phytoplankton for up to 2 months. A CWP was observed when herbivores grazing on larger phytoplankton developed in addition to ciliates}, language = {en} } @inproceedings{HainzlScherbaumZoeller2006, author = {Hainzl, Sebastian and Scherbaum, Frank and Z{\"o}ller, Gert}, title = {Spatiotemporal earthquake patterns}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7267}, year = {2006}, abstract = {Interdisziplin{\"a}res Zentrum f{\"u}r Musterdynamik und Angewandte Fernerkundung Workshop vom 9. - 10. Februar 2006}, language = {en} } @article{VasconcelosLopesVianaetal.2006, author = {Vasconcelos, D. B. and Lopes, S. R. and Viana, R. L. and Kurths, J{\"u}rgen}, title = {Spatial recurrence plots}, doi = {10.1103/Physreve.73.056207}, year = {2006}, abstract = {We propose an extension of the recurrence plot concept to perform quantitative analyzes of roughness and disorder of spatial patterns at a fixed time. We introduce spatial recurrence plots (SRPs) as a graphical representation of the pointwise correlation matrix, in terms of a two-dimensional spatial return plot. This technique is applied to the study of complex patterns generated by coupled map lattices, which are characterized by measures of complexity based on SRPs. We show that the complexity measures we propose for SRPs provide a systematic way of investigating the distribution of spatially coherent structures, such as synchronization domains, in lattice profiles. This approach has potential for many more applications, e.g., in surface roughness analyzes}, language = {en} } @article{ZenBilgeGalbrechtetal.2006, author = {Zen, Achmad and Bilge, Askin and Galbrecht, Frank and Alle, Ronald and Meerholz, Klaus and Grenzer, J{\"o}rg and Neher, Dieter and Scherf, Ullrich and Farrell, Tony}, title = {Solution processable organic field-effect transistors utilizing an alpha,alpha '-dihexylpentathiophene- based swivel cruciform}, doi = {10.1021/Ja0573357}, year = {2006}, language = {en} } @phdthesis{Brunnemann2006, author = {Brunnemann, Johannes}, title = {Singularities of Classical Relativity within the Framework of Loop Quantum Gravity}, address = {Potsdam}, pages = {180 S.}, year = {2006}, language = {en} } @article{HennebergPietschPanzneretal.2006, author = {Henneberg, Oliver and Pietsch, Ullrich and Panzner, Tobias and Geue, Thomas and Finkelstein, Kenneth D.}, title = {Simultaneous X-ray and visible light diffraction for the investigation of surface relief and density grating formation in azobenzene containing polymer films}, issn = {1542-1406}, doi = {10.1080/15421400500383345}, year = {2006}, abstract = {The development of surface relief and density patterns in azobenzene polymer films was studied by diffraction at two different wavelengths. We used x-ray diffraction of synchrotron radiation at 0.124 nm in combination with visible light diffraction at a wavelength of 633 nm. In contrast to visible light scattering x-ray diffraction allows the separation of a surface relief and a density grating contribution due to the different functional dependence of the scattering power. Additionally, the x-ray probe is most sensitive for the onset of the surface grating formation}, language = {en} } @article{ZouThielRomanoetal.2006, author = {Zou, Yong and Thiel, M. and Romano, Maria Carmen and Kurths, J{\"u}rgen and Bi, Q.}, title = {Shrimp structure and associated dynamics in parametrically excited oscillators}, series = {International journal of bifurcation and chaos : in applied sciences and engineering}, volume = {16}, journal = {International journal of bifurcation and chaos : in applied sciences and engineering}, number = {12}, publisher = {World Scientific Publ. Co}, address = {Singapore}, issn = {0218-1274}, doi = {10.1142/S0218127406016987}, pages = {3567 -- 3579}, year = {2006}, abstract = {We investigate the bifurcation structures in a two-dimensional parameter space (PS) of a parametrically excited system with two degrees of freedom both analytically and numerically. By means of the Renyi entropy of second order K-2, which is estimated from recurrence plots, we uncover that regions of chaotic behavior are intermingled with many complex periodic windows, such as shrimp structures in the PS. A detailed numerical analysis shows that, the stable solutions lose stability either via period doubling, or via intermittency when the parameters leave these shrimps in different directions, indicating different bifurcation properties of the boundaries. The shrimps of different sizes offer promising ways to control the dynamics of such a complex system.}, language = {en} } @article{MedranoTBaptistaCaldas2006, author = {Medrano-T., R. O. and Baptista, Murilo da Silva and Caldas, Ibere Luiz}, title = {Shilnikov homoclinic orbit bifurcations in the Chua's circuit}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {16}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {4}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.2401060}, pages = {9}, year = {2006}, abstract = {We analytically describe the complex scenario of homoclinic bifurcations in the Chua's circuit. We obtain a general scaling law that gives the ratio between bifurcation parameters of different nearby homoclinic orbits. As an application of this theoretical approach, we estimate the number of higher order subsidiary homoclinic orbits that appear between two consecutive lower order subsidiary orbits. Our analytical finds might be valid for a large class of dynamical systems and are numerically confirmed in the parameter space of the Chua's circuit. Shilnikov homoclinic orbits are trajectories that depart from a fixed saddle-focus point, with specific eigenvalues, and return to it after an infinite amount of time (that is also true to time reversal evolution). That results in an orbit that is unstable and has an infinite period. These two main characteristics contribute in the hardness for its observation in a dynamical system as well as in nature. However, its presence reveals fundamental characteristics of the system involved, as the existence of unstable periodic orbits embedded in a chaotic set. Once the unstable periodic orbits give invariants quantities of this set,1 the Shilnikov homoclinic orbits are also related to the characteristics of the chaotic set. Their connection with the fundamental dynamical properties is verified in a wide variety of systems. A series of numerical and experimental investigations reveal how Shilnikov homoclinic orbits, in the vicinity of a chaotic attractor, determine its dynamical and topological properties.4 Thus, the Shilnikov orbits are related to the returning time of the trajectory of a CO2 laser,5 also to the topology of a glow-discharge system.6 Moreover, some class of spiking neurons are modeled by chaos governed by such orbits,7,8 and their presence are connected to the intermittence present in rabbit arteries.9 These orbits are shown to be behind the mechanism of noise-induced phenomena,10 and they are also responsible for the dynamics of an electrochemical oscillator.11 In this work, we contribute to the understanding of how Shilnikov homoclinic orbits appear on the parameter space of systems as the ones above mentioned, by showing that these orbits are not only distributed following an universal rule but also exist for large parameter variations. We then confirm our previsions in the Chua's circuit system}, language = {en} } @article{WinterhalderSchelterKurthsetal.2006, author = {Winterhalder, Matthias and Schelter, B and Kurths, J{\"u}rgen and Schulze-Borthage, A and Timmer, Jens}, title = {Sensitivity and specificity of coherence and phase synchronization analysis}, doi = {10.1016/j.physleta.2006.03.018}, year = {2006}, abstract = {In this Letter, we show that coherence and phase synchronization analysis are sensitive but not specific in detecting the correct class of underlying dynamics. We propose procedures to increase specificity and demonstrate the power of the approach by application to paradigmatic dynamic model systems. (c) 2006 Elsevier B.V. All rights reserved}, language = {en} } @article{KofodPaajanenBauer2006, author = {Kofod, Guggi and Paajanen, Mika and Bauer, Siegfried}, title = {Self-organized minimum-energy structures for dielectric elastomer actuators}, issn = {0947-8396}, doi = {10.1007/s00339-006-3680-3}, year = {2006}, language = {en} } @article{LandaUshakovKurths2006, author = {Landa, Polina S. and Ushakov, Vladimir and Kurths, J{\"u}rgen}, title = {Rigorous theory of stochastic resonance in overdamped bistable oscillators for weak signals}, series = {Chaos, solitons \& fractals : applications in science and engineering}, volume = {30}, journal = {Chaos, solitons \& fractals : applications in science and engineering}, number = {3}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0960-0779}, doi = {10.1016/j.chaos.2005.08.116}, pages = {574 -- 578}, year = {2006}, abstract = {The results of the theoretical consideration of stochastic resonance in overdamped bistable oscillators are given. These results are founded not on the model of two states as in [McNamara B, Wiesenfeld K. Theory of stochastic resonance. Phys Rev A 1989;39:4854-69], but on splitting of motion into regular and random and the rigorous solution of the Fokker-Planck equation for the random component. We show that this resonance is caused by a change, under the influence of noise, of the system's effective stiffness and damping factor contained in the equation for the regular component. For a certain value of the noise intensity the effective stiffness is minimal, and this fact causes non-monotonic change of the output signal amplitude as the noise intensity changes. It is important that the location of the minimum and its value depend essentially on the signal frequency.}, language = {en} } @article{FruebingKremmerGerhardetal.2006, author = {Fr{\"u}bing, Peter and Kremmer, Alexander and Gerhard, Reimund and Spanoudaki, Anna and Pissis, Polycarpos}, title = {Relaxation processes at the glass transition in polyamide 11: From rigidity to viscoelasticity}, series = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, volume = {125}, journal = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, number = {12}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-9606}, doi = {10.1063/1.2360266}, pages = {8}, year = {2006}, abstract = {Relaxation processes associated with the glass transition in nonferroelectric and ferroelectric polyamide (PA) 11 are investigated by means of differential scanning calorimetry, dynamic mechanical analysis, and dielectric relaxation spectroscopy (DRS) in order to obtain information about the molecular mobility within the amorphous phase. In particular, the effects of melt quenching, cold drawing, and annealing just below the melting region are studied with respect to potential possibilities and limitations for improving the piezoelectric and pyroelectric properties of PA 11. A relaxation map is obtained from DRS that shows especially the crossover region where the cooperative alpha relaxation and the local beta relaxation merge into a single high-temperature process. No fundamental difference between quenched, cold-drawn, and annealed films is found, though in the cold-drawn (ferroelectric) film the alpha relaxation is suppressed and slowed down, but it is at least partly recovered by subsequent annealing. It is concluded that there exists an amorphous phase in all structures, even in the cold-drawn film. The amorphous phase can be more rigid or more viscoelastic depending on preparation. Cold drawing not only leads to crystallization in a ferroelectric form but also to higher rigidity of the remaining amorphous phase. Annealing just below the melting region after cold drawing causes a stronger phase separation between the crystalline phase and a more viscoelastic amorphous phase.}, language = {en} } @article{FruebingKremmerGerhardetal.2006, author = {Fr{\"u}bing, Peter and Kremmer, Alexander and Gerhard, Reimund and Spannoudaki, Anna and Pissis, Polycarpos}, title = {Relaxation processes at the glass transition in polyamide 11 : From rigidity to viscoelasticity}, issn = {0021-9606}, doi = {10.1063/1.2360266}, year = {2006}, language = {en} } @article{AssmannThielRomanoetal.2006, author = {Assmann, Birte and Thiel, Marco and Romano, Maria Carmen and Niemitz, Carsten}, title = {Recurrence plot analyses suggest a novel reference system involved in newborn spontaneous movements}, series = {Behavior research methods : a journal of the Psychonomic Society}, volume = {38}, journal = {Behavior research methods : a journal of the Psychonomic Society}, number = {3}, publisher = {Springer}, address = {New York}, issn = {1554-351X}, doi = {10.3758/BF03192793}, pages = {400 -- 406}, year = {2006}, abstract = {The movements of newborns have been thoroughly studied in terms of reflexes, muscle synergies, leg coordination, and target-directed arm/hand movements. Since these approaches have concentrated mainly on separate accomplishments, there has remained a clear need for more integrated investigations. Here, we report an inquiry in which we explicitly concentrated on taking such a perspective and, additionally, were guided by the methodological concept of home base behavior, which Ilan Golard developed for studies of exploratory behavior in animals. Methods from nonlinear dynamics, such as symbolic dynamics and recurrence plot analyses of kinematic data received from audiovisual newborn recordings, yielded new insights into the spatial and temporal organization of limb movements. In the framework of home base behavior, our approach uncovered a novel reference system of spontaneous newborn movements.}, language = {en} } @article{CarminatiGreffetHenkeletal.2006, author = {Carminati, R{\´e}mi and Greffet, Jean-Jacques and Henkel, Carsten and Vigoureux, Jean-Marie}, title = {Radiative and non-radiative decay of a single molecule close to a metallic nanoparticle}, issn = {0030-4018}, doi = {10.1016/j.optcom.2005.12.009}, year = {2006}, abstract = {We study the spontaneous emission of a single emitter close to a metallic nanoparticle, with the aim to clarify the distance dependence of the radiative and non-radiative decay rates. We derive analytical formulas based on a dipole- dipole model, and show that the nonradiative decay rate follows a R-6 dependence at short distance, where R is the distance between the emitter and the center of the nanoparticle, as in Forster's energy transfer. The distance dependence of the radiative decay rate is more subtle. It is chiefly dominated by a R-3 dependence, a R-6 dependence being visible at plasmon resonance. The latter is a consequence of radiative damping in the effective dipole polarizability of the nanoparticle. The different distance behavior of the radiative and non-radiative decay rates implies that the apparent quantum yield always vanishes at short distance. Moreover, non-radiative decay is strongly enhanced when the emitter radiates at the plasmon-resonance frequency of the nanoparticle.}, language = {en} } @phdthesis{Cramer2006, author = {Cramer, Marcus}, title = {Quasi-free systems on general lattices : criticality, entanglement-area laws, and single-copy entanglement}, address = {Potsdam}, pages = {99 S. : graph. Darst.}, year = {2006}, language = {en} } @article{SaalfrankNestAndrianovetal.2006, author = {Saalfrank, Peter and Nest, Mathias and Andrianov, Igor V. and Klamroth, Tillmann and Kroner, Dominic and Beyvers, Stephanie}, title = {Quantum dynamics of laser-induced desorption from metal and semiconductor surfaces, and related phenomena}, volume = {18}, number = {30}, publisher = {IOP Publ.}, address = {Bristol}, issn = {1361-648X}, doi = {10.1088/0953-8984/18/30/S05}, pages = {S1425 -- S1459}, year = {2006}, abstract = {Recent progress towards a quantum theory of laser-induced desorption and related phenomena is reviewed, for specific examples. These comprise the photodesorption of NO from Pt(111), the scanning tunnelling microscope and laser- induced desorption and switching of H at Si(100), and the electron stimulated desorption and dissociation of CO at Ru(0001). The theoretical methods used for nuclear dynamics range from open-system density matrix theory over nonadiabatically coupled multi-state models to electron-nuclear wavepackets. Also, aspects of time-dependent spectroscopy to probe ultrafast nonadiabatic processes at surfaces will be considered for the example of two-photon photoemission of solvated electrons in ice layers on Cu(111)}, language = {en} } @article{Nest2006, author = {Nest, Mathias}, title = {Quantum carpets and correlated dynamics of several fermions}, doi = {10.1103/Physreva.73.023613}, year = {2006}, abstract = {We study theoretically the coherent and correlated motion of many fermions inside an infinite square well potential. We will look at electrons and He-3 atoms, which behave very differently not only because of their masses, but also because of their different interaction potential. Also, the level of theory and the role of approximations in the solution of the time-dependent Schrodinger equation will be discussed}, language = {en} } @phdthesis{Schmeja2006, author = {Schmeja, Stefan}, title = {Properties of turbulent star-forming clusters : models versus observations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7364}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Stars are born in turbulent molecular clouds that fragment and collapse under the influence of their own gravity, forming a cluster of hundred or more stars. The star formation process is controlled by the interplay between supersonic turbulence and gravity. In this work, the properties of stellar clusters created by numerical simulations of gravoturbulent fragmentation are compared to those from observations. This includes the analysis of properties of individual protostars as well as statistical properties of the entire cluster. It is demonstrated that protostellar mass accretion is a highly dynamical and time-variant process. The peak accretion rate is reached shortly after the formation of the protostellar core. It is about one order of magnitude higher than the constant accretion rate predicted by the collapse of a classical singular isothermal sphere, in agreement with the observations. For a more reasonable comparison, the model accretion rates are converted to the observables bolometric temperature, bolometric luminosity, and envelope mass. The accretion rates from the simulations are used as input for an evolutionary scheme. The resulting distribution in the Tbol-Lbol-Menv parameter space is then compared to observational data by means of a 3D Kolmogorov-Smirnov test. The highest probability found that the distributions of model tracks and observational data points are drawn from the same population is 70\%. The ratios of objects belonging to different evolutionary classes in observed star-forming clusters are compared to the temporal evolution of the gravoturbulent models in order to estimate the evolutionary stage of a cluster. While it is difficult to estimate absolute ages, the realtive numbers of young stars reveal the evolutionary status of a cluster with respect to other clusters. The sequence shows Serpens as the youngest and IC 348 as the most evolved of the investigated clusters. Finally the structures of young star clusters are investigated by applying different statistical methods like the normalised mean correlation length and the minimum spanning tree technique and by a newly defined measure for the cluster elongation. The clustering parameters of the model clusters correspond in many cases well to those from observed ones. The temporal evolution of the clustering parameters shows that the star cluster builds up from several subclusters and evolves to a more centrally concentrated cluster, while the cluster expands slower than new stars are formed.}, subject = {Sternentstehung}, language = {en} } @article{WegenerWirgesTiersch2006, author = {Wegener, Michael and Wirges, Werner and Tiersch, Brigitte}, title = {Porous polytetrafluoroethylene (PTFE) electret films : porosity and time dependent charging behaviour of the free surface}, doi = {10.1007/s10934-006-9015-0}, year = {2006}, abstract = {Electrically charged porous polytetrafluoroethylene (PTFE) films are often discussed as active layers for electromechanical transducers. Here, the electric charging behavior of open-porous PTFE films with different porosities is investigated. Optimized electric charging of porous PTFE films is determined by variation of charging parameters such as electric fields and charging times. Maximum surface potentials are depending on the porosity of the PTFE films. Suitable charging leads to high surface potentials observed on non-stretched or slightly stretched porous PTFE films. Further increase of charging fields yields decreasing values of the surface potential accompanied with an increase of conductivity.}, language = {en} } @article{GarnierLaschewskyStorsberg2006, author = {Garnier, Sebastien and Laschewsky, Andr{\´e} and Storsberg, J}, title = {Polymeric surfactants : novel agents with exceptional properties}, issn = {0932-3414}, year = {2006}, abstract = {This article presents recent progress in the field of polymeric surfactants made of permanently amphiphilic block copolymers or of stimulus-sensitive ones. We highlight key points in the design of amphiphilic macromolecules, to yield polymer surfactants with tailor-made properties, as well as recently developed and still challenging application fields for this new class of surfactants. The efficiency boosting of amphiphilic block copolymers as co-surfactants in microemulsions is discussed, as are surface modification by polymer surfactants, and stabilization of dispersions. Moreover, the use of block copolymers in nanosciences is presented, for instance as a tool for nanomaterial fabrication, or for biomedical and cosmetic applications in bio-nanotechnology. Finally, self-assembly and applications of some newly developed "exotic" amphiphilic block copolymer structures as new surface-active materials will be highlighted}, language = {en} } @article{LuszczynskaDobruchowskaGlowackietal.2006, author = {Luszczynska, Beata and Dobruchowska, Ewa and Glowacki, Ireneusz and Ulanski, Jacek and Jaiser, Frank and Yang, Xiaohui and Neher, Dieter and Danel, Andrzej}, title = {Poly(N-vinylcarbazole) doped with a pyrazoloquinoline dye : a deep blue light-emitting composite for light- emitting diode applications}, issn = {0021-8979}, doi = {10.1063/1.2162268}, year = {2006}, abstract = {We investigated the spectral properties of light-emitting diodes based on a deep blue-emitting pyrazoloquinoline dye doped into a poly(N-vinylcarbazole)-based matrix. Even though the electroluminescence (EL) of the host is redshifted and broadened with respect to the emission of the dye, the EL spectrum becomes fully dominated by the dye emission at concentrations of ca. 2 wt \%. This is attributed to a competition of exciplex formation on the matrix and exciton formation on the dye.}, language = {en} } @article{WegenerKuenstlerGerhard2006, author = {Wegener, Michael and K{\"u}nstler, Wolfgang and Gerhard, Reimund}, title = {Poling behavior and optical absorption of partially dehydrofluorinated and uniaxially stretched polyvinylidene fluoride}, doi = {10.1080/00150190600694761}, year = {2006}, abstract = {Polyvinylidene fluoride was dissolved together with solid sodium hydroxide as catalyst in a dimethylsulfoxide/ acetone mixture and moderately dehydrofluorinated. The dehydrofluorination leads to a partial degradation of the fluorohydrocarbons, and in particular to main-chain scission and to formation of carbon double or triple bonds. This enhances the absorption at UV-vis frequencies. The degradation process also generates a large amount of excess charges in the polymer, which influence the electrical polarization behavior of the dehydrofluorinated polymer. Uniaxial stretching of moderately dehydrofluorinated polyvinylidene fluoride leads to films in a polar phase. Dipole polarization in the degraded and stretched films is demonstrated by means of switching experiments}, language = {en} } @article{SpahnSchmidt2006, author = {Spahn, Frank and Schmidt, J{\"u}rgen}, title = {Planetary science : Saturn's bared mini-moons}, doi = {10.1038/440614a}, year = {2006}, language = {en} } @article{BassoAquinoAltafimetal.2006, author = {Basso, Heitor Cury and Aquino, C. V. and Altafim, Ruy Alberto Pisani and Altafim, Ruy Alberto Pisani and Gerhard, Reimund}, title = {Piezoelectricity of a single bubble formed by two oppositely charged Teflon-FEP films}, isbn = {1-4244-0547-5}, year = {2006}, language = {en} } @article{AltafimBassoAltafimetal.2006, author = {Altafim, Ruy Alberto Pisani and Basso, Heitor Cury and Altafim, Ruy Alberto Pisani and Lima, L. and de Aquino, C. V. and Goncalves Neto, Luiz and Gerhard, Reimund}, title = {Piezoelectrets from thermo-formed bubble structures of fluoropolymer-electret films}, issn = {1070-9878}, doi = {10.1109/TDEI.2006.247822}, year = {2006}, abstract = {The acetone extracts of the root bark and stem bark of Erythrina sacleuxii showed antiplasmodial activities against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum. Chromatographic separation of the acetone extract of the root bark afforded a new isoflavone, 7-hydroxy-4 -methoxy-3'- prenylisoflavone (trivial name 5-deoxy-3' - prenylbiochanin A) along with known isoflavonoids as the antiplasmodial principles. Flavonoids and isoflavonoids isolated from the stem bark of E. sucleuxii were also tested and showed antiplasmodial activities. The structures were determined on the basis of spectroscopic evidence.}, language = {en} } @misc{GruendePaterShowalteretal.2006, author = {Gr{\"u}n, Eberhard and de Pater, Imke and Showalter, Mark and Spahn, Frank and Srama, Ralf}, title = {Physics of dusty rings: History and perspective}, series = {Planetary and space science}, volume = {54}, journal = {Planetary and space science}, number = {9-10}, publisher = {Elsevier}, address = {Oxford}, issn = {0032-0633}, doi = {10.1016/j.pss.2006.05.005}, pages = {837 -- 843}, year = {2006}, language = {en} } @article{LitwinskiTannertJesorkaetal.2006, author = {Litwinski, Christian and Tannert, Sebastian and Jesorka, Aldo and Katterle, Martin and Roder, Beate}, title = {Photophysical properties of gallium hydroxyl tetratolylporphyrin and 13(2)-demethoxycarbonyl-(gallium hydroxyl)- methyl-pheophorbide alpha}, issn = {0009-2614}, doi = {10.1016/j.cplett.2005.10.131}, year = {2006}, abstract = {Two metal tetrapyrroles containing gallium, gallium hydroxyl tetratolylporphyrin and 13(2)-demethoxycarbonyl- (gallium hydroxyl)methyl pheophorbide a (Ga-(OH)-chlorin), were synthesized from their respective free bases using Ga(III)-acetylacetonate in a phenol melt. Their photophysical properties were investigated and the quantum yields of different monomolecular deactivation processes were determined. For Ga-(OH)-porphyrin S-2-fluorescence was observed and quantified. In contrast. for Ga-(OH)-chlorin no S-2-fluorescence was observed. Both compounds should be useful as efficient photosensitizers in photodynamic therapy.}, language = {en} } @article{MehdaouiKroenerPykavyetal.2006, author = {Mehdaoui, Imed and Kr{\"o}ner, Dominik and Pykavy, Mikhail and Freund, H.-J. and Kl{\"u}ner, Thorsten}, title = {Photo-induced desorption of NO from NiO(100): calculation of the four-dimensional potential energy surfaces and systematic wave packet studies}, doi = {10.1039/B512778e}, year = {2006}, abstract = {The velocity distributions of the laser-induced desorption of NO molecules from an epitaxially grown film of NiO(100) on Ni(100) have been studied [ Mull et al., J. Chem. Phys., 1992, 96, 7108]. A pronounced bimodality of velocity distributions has been found, where the NO molecules desorbing with higher velocities exhibit a coupling to the rotational quantum states J. In this article we present simulations of state resolved velocity distributions on a full ab initio level. As a basis for this quantum mechanical treatment a 4D potential energy surface (PES) was constructed for the electronic ground and a representative excited state, using a NiO5Mg1318+ cluster. The PESs of the electronic ground and an excited state were calculated at the CASPT2 and the configuration interaction (CI) level of theory, respectively. Multi-dimensional quantum wave packet simulations on these two surfaces were performed for different sets of degrees of freedom. Our key finding is that at least a 3D wave packet simulation, in which the desorption coordinate Z, polar angle theta and lateral coordinate X are included, is necessary to allow the simulation of experimental velocity distributions. Analysis of the wave packet dynamics demonstrates that essentially the lateral coordinate, which was neglected in previous studies [Kluner et al., Phys. Rev. Lett. 1998, 80, 5208], is responsible for the experimentally observed bimodality. An extensive analysis shows that the bimodality is due to a bifurcation of the wave packet on the excited state PES, where the motion of the molecule parallel to the surface plays a decisive role}, language = {en} } @article{IlnytskyiSaphiannikovaNeher2006, author = {Ilnytskyi, Jaroslav and Saphiannikova, Marina and Neher, Dieter}, title = {Photo-induced deformations in azobenzene-containing side-chain polymers : molecular dynamics study}, issn = {1607-324X}, year = {2006}, abstract = {We perform molecular dynamics simulations of azobenzene containing side-chain liquid crystalline polymer subject to an external model field that mimicks the reorientations of the azobenzenes upon irradiation with polarized light. The smectic phase of the polymer is studied with the field applied parallel to the nematic director, forcing the trans isomers to reorient perpendicularly to the field (the direction of which can be assosiated with the light polarization). The coupling between the reorientation of azobenzenes and mechanical deformation of the sample is found to depend on the field strength. In a weak field the original smectic order is melted gradually with no apparent change in the simulation box shape, whereas in a strong field two regimes are observed. During the first one a rapid melting of the liquid crystalline order is accompanied by the contraction of the polymer along the field direction (the effect similar to the one observed experimentally in azopenzene containing elastomers). During the slower second regime, the smectic layers are rebuilt to accomodate the preferential direction of chromophores perperdicular to the field.}, language = {en} } @article{PikovskijRosenau2006, author = {Pikovskij, Arkadij and Rosenau, Philip}, title = {Phase compactons}, doi = {10.1016/j.physd.2006.04.015}, year = {2006}, abstract = {We study the phase dynamics of a chain of autonomous, self-sustained, dispersively coupled oscillators. In the quasicontinuum limit the basic discrete model reduces to a Korteveg-de Vries-like equation, but with a nonlinear dispersion. The system supports compactons - solitary waves with a compact support - and kovatons - compact formations of glued together kink-antikink pairs that propagate with a unique speed, but may assume an arbitrary width. We demonstrate that lattice solitary waves, though not exactly compact, have tails which decay at a superexponential rate. They are robust and collide nearly elastically and together with wave sources are the building blocks of the dynamics that emerges from typical initial conditions. In finite lattices, after a long time, the dynamics becomes chaotic. Numerical studies of the complex Ginzburg-Landau lattice show that the non-dispersive coupling causes a damping and deceleration, or growth and acceleration, of compactons. A simple perturbation method is applied to study these effects. (c) 2006 Elsevier B.V. All rights reserved}, language = {en} } @article{SchelterWinterhalderDahlhausetal.2006, author = {Schelter, Bj{\"o}rn and Winterhalder, Matthias and Dahlhaus, Rainer and Kurths, J{\"u}rgen and Timmer, Jens}, title = {Partial phase synchronization for multivariate synchronizing systems}, doi = {10.1103/Physrevlett.96.208103}, year = {2006}, abstract = {Graphical models applying partial coherence to multivariate time series are a powerful tool to distinguish direct and indirect interdependencies in multivariate linear systems. We carry over the concept of graphical models and partialization analysis to phase signals of nonlinear synchronizing systems. This procedure leads to the partial phase synchronization index which generalizes a bivariate phase synchronization index to the multivariate case and reveals the coupling structure in multivariate synchronizing systems by differentiating direct and indirect interactions. This ensures that no false positive conclusions are drawn concerning the interaction structure in multivariate synchronizing systems. By application to the paradigmatic model of a coupled chaotic Roessler system, the power of the partial phase synchronization index is demonstrated}, language = {en} } @article{ZaikinKurths2006, author = {Zaikin, Alexey and Kurths, J{\"u}rgen}, title = {Optimal length transportation hypothesis to model proteasome product size distribution}, series = {Journal of biological physics : emphasizing physical principles in biological research ; an international journal for the formulation and application of mathematical models in the biological sciences}, volume = {32}, journal = {Journal of biological physics : emphasizing physical principles in biological research ; an international journal for the formulation and application of mathematical models in the biological sciences}, number = {3-4}, publisher = {Springer}, address = {Dordrecht}, issn = {0092-0606}, doi = {10.1007/s10867-006-9014-z}, pages = {231 -- 243}, year = {2006}, abstract = {This paper discusses translocation features of the 20S proteasome in order to explain typical proteasome length distributions. We assume that the protein transport depends significantly on the fragment length with some optimal length which is transported most efficiently. By means of a simple one-channel model, we show that this hypothesis can explain both the one- and the three-peak length distributions found in experiments. A possible mechanism of such translocation is provided by so-called fluctuation-driven transport.}, language = {en} } @article{Klamroth2006, author = {Klamroth, Tillmann}, title = {Optimal control of ultrafast laser driven many-electron dynamics in a polyatomic molecule: N-methyl-6-quinolone}, issn = {0021-9606}, doi = {10.1063/1.2185633}, year = {2006}, abstract = {We report time-dependent configuration interaction singles calculations for the ultrafast laser driven many- electron dynamics in a polyatomic molecule, N-methyl-6-quinolone. We employ optimal control theory to achieve a nearly state-selective excitation from the S-0 to the S-1 state, on a time scale of a few (approximate to 6) femtoseconds. The optimal control scheme is shown to correct for effects opposing a state-selective transition, such as multiphoton transitions and other, nonlinear phenomena, which are induced by the ultrashort and intense laser fields. In contrast, simple two-level pi pulses are not effective in state-selective excitations when very short pulses are used. Also, the dependence of multiphoton and nonlinear effects on the number of states included in the dynamical simulations is investigated.}, language = {en} } @article{BeyversOhtsukiSaalfrank2006, author = {Beyvers, Stephanie and Ohtsuki, Y and Saalfrank, Peter}, title = {Optimal control in a dissipative system : vibrational excitation of CO/Cu(100) by IR pulses}, issn = {0021-9606}, doi = {10.1063/1.2206593}, year = {2006}, abstract = {The question as to whether state-selective population of molecular vibrational levels by shaped infrared laser pulses is possible in a condensed phase environment is of central importance for such diverse fields as time-resolved spectroscopy, quantum computing, or "vibrationally mediated chemistry." This question is addressed here for a model system, representing carbon monoxide adsorbed on a Cu(100) surface. Three of the six vibrational modes are considered explicitly, namely, the CO stretch vibration, the CO-surface vibration, and a frustrated translation. Optimized infrared pulses for state-selective excitation of "bright" and "dark" vibrational levels are designed by optimal control theory in the framework of a Markovian open-system density matrix approach, with energy flow to substrate electrons and phonons, phase relaxation, and finite temperature accounted for. The pulses are analyzed by their Husimi "quasiprobability" distribution in time-energy space.}, language = {en} } @phdthesis{Albers2006, author = {Albers, Nicole}, title = {On the relevance of adhesion : applications to Saturn's rings}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-10848}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Since their discovery in 1610 by Galileo Galilei, Saturn's rings continue to fascinate both experts and amateurs. Countless numbers of icy grains in almost Keplerian orbits reveal a wealth of structures such as ringlets, voids and gaps, wakes and waves, and many more. Grains are found to increase in size with increasing radial distance to Saturn. Recently discovered "propeller" structures in the Cassini spacecraft data, provide evidence for the existence of embedded moonlets. In the wake of these findings, the discussion resumes about origin and evolution of planetary rings, and growth processes in tidal environments. In this thesis, a contact model for binary adhesive, viscoelastic collisions is developed that accounts for agglomeration as well as restitution. Collisional outcomes are crucially determined by the impact speed and masses of the collision partners and yield a maximal impact velocity at which agglomeration still occurs. Based on the latter, a self-consistent kinetic concept is proposed. The model considers all possible collisional outcomes as there are coagulation, restitution, and fragmentation. Emphasizing the evolution of the mass spectrum and furthermore concentrating on coagulation alone, a coagulation equation, including a restricted sticking probability is derived. The otherwise phenomenological Smoluchowski equation is reproduced from basic principles and denotes a limit case to the derived coagulation equation. Qualitative and quantitative analysis of the relevance of adhesion to force-free granular gases and to those under the influence of Keplerian shear is investigated. Capture probability, agglomerate stability, and the mass spectrum evolution are investigated in the context of adhesive interactions. A size dependent radial limit distance from the central planet is obtained refining the Roche criterion. Furthermore, capture probability in the presence of adhesion is generally different compared to the case of pure gravitational capture. In contrast to a Smoluchowski-type evolution of the mass spectrum, numerical simulations of the obtained coagulation equation revealed, that a transition from smaller grains to larger bodies cannot occur via a collisional cascade alone. For parameters used in this study, effective growth ceases at an average size of centimeters.}, subject = {Saturn}, language = {en} } @phdthesis{Giesel2006, author = {Giesel, Kristina}, title = {On the consistency of loop quantum gravitiy with general relativity}, address = {Potsdam}, pages = {203 S. : graph. Darst.}, year = {2006}, language = {en} } @phdthesis{Knopf2006, author = {Knopf, Brigitte}, title = {On intrinsic uncertainties in earth system modelling}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-10949}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Uncertainties are pervasive in the Earth System modelling. This is not just due to a lack of knowledge about physical processes but has its seeds in intrinsic, i.e. inevitable and irreducible, uncertainties concerning the process of modelling as well. Therefore, it is indispensable to quantify uncertainty in order to determine, which are robust results under this inherent uncertainty. The central goal of this thesis is to explore how uncertainties map on the properties of interest such as phase space topology and qualitative dynamics of the system. We will address several types of uncertainty and apply methods of dynamical systems theory on a trendsetting field of climate research, i.e. the Indian monsoon. For the systematic analysis concerning the different facets of uncertainty, a box model of the Indian monsoon is investigated, which shows a saddle node bifurcation against those parameters that influence the heat budget of the system and that goes along with a regime shift from a wet to a dry summer monsoon. As some of these parameters are crucially influenced by anthropogenic perturbations, the question is whether the occurrence of this bifurcation is robust against uncertainties in parameters and in the number of considered processes and secondly, whether the bifurcation can be reached under climate change. Results indicate, for example, the robustness of the bifurcation point against all considered parameter uncertainties. The possibility of reaching the critical point under climate change seems rather improbable. A novel method is applied for the analysis of the occurrence and the position of the bifurcation point in the monsoon model against parameter uncertainties. This method combines two standard approaches: a bifurcation analysis with multi-parameter ensemble simulations. As a model-independent and therefore universal procedure, this method allows investigating the uncertainty referring to a bifurcation in a high dimensional parameter space in many other models. With the monsoon model the uncertainty about the external influence of El Ni{\~n}o / Southern Oscillation (ENSO) is determined. There is evidence that ENSO influences the variability of the Indian monsoon, but the underlying physical mechanism is discussed controversially. As a contribution to the debate three different hypotheses are tested of how ENSO and the Indian summer monsoon are linked. In this thesis the coupling through the trade winds is identified as key in linking these two key climate constituents. On the basis of this physical mechanism the observed monsoon rainfall data can be reproduced to a great extent. Moreover, this mechanism can be identified in two general circulation models (GCMs) for the present day situation and for future projections under climate change. Furthermore, uncertainties in the process of coupling models are investigated, where the focus is on a comparison of forced dynamics as opposed to fully coupled dynamics. The former describes a particular type of coupling, where the dynamics from one sub-module is substituted by data. Intrinsic uncertainties and constraints are identified that prevent the consistency of a forced model with its fully coupled counterpart. Qualitative discrepancies between the two modelling approaches are highlighted, which lead to an overestimation of predictability and produce artificial predictability in the forced system. The results suggest that bistability and intermittent predictability, when found in a forced model set-up, should always be cross-validated with alternative coupling designs before being taken for granted. All in this, this thesis contributes to the fundamental issue of dealing with uncertainties the climate modelling community is confronted with. Although some uncertainties allow for including them in the interpretation of the model results, intrinsic uncertainties could be identified, which are inevitable within a certain modelling paradigm and are provoked by the specific modelling approach.}, subject = {Unsicherheit}, language = {en} } @article{JaroszSignerskiBrehmer2006, author = {Jarosz, Grazyna and Signerski, Ryszard and Brehmer, Ludwig}, title = {On dielectric spectra of thin copper phthalocyanine films}, issn = {0040-6090}, doi = {10.1016/j.tsf.2006.02.035}, year = {2006}, abstract = {The work presents low signal dielectric spectra of gold/copper phthalocyanine/magnesium and gold/copper phthalocyanine/gold sandwich systems in the 25 Hz-1 MHz frequency range. The performed analysis enables us to distinguish the electrode resistance and the lattice polarization from processes related with electric transport, such as charge carrier relaxation at space charge region of a barrier and charge carrier injection in dielectric response.}, language = {en} } @article{BridgesReich2006, author = {Bridges, Thomas J. and Reich, Sebastian}, title = {Numerical methods for Hamiltonian PDEs}, issn = {0305-4470}, doi = {10.1088/0305-4470/39/19/S02}, year = {2006}, abstract = {The paper provides an introduction and survey of conservative discretization methods for Hamiltonian partial differential equations. The emphasis is on variational, symplectic and multi-symplectic methods. The derivation of methods as well as some of their fundamental geometric properties are discussed. Basic principles are illustrated by means of examples from wave and fluid dynamics}, language = {en} } @article{SaarimaekiPaajanenSavijaervietal.2006, author = {Saarim{\"a}ki, Eetta and Paajanen, Mika and Savij{\"a}rvi, Ann-Mari and Minkkinen, Hannu and Wegener, Michael and Voronina, Olena and Schulze, Robert and Wirges, Werner and Gerhard, Reimund}, title = {Novel heat durable electromechanical film : processing for electromechanical and electret applications}, year = {2006}, abstract = {New ferroelectrets were developed on the basis of foams from cyclo-olefin polymers and copolymers. The results obtained on the cyclo-olefin polymer foam demonstrate a significant improvement of the service temperature for ferroelectret transducer materials. Suitable compounding and preparation led to cyclo-olefin ferroelectrets with an electromechanical activity of around 15 pC/N, which is thermally stable at least up to 110 degrees C. The properties in sensor and actuator applications are strongly dependent on the processing parameters related to film-making, sensor and actuator preparation, gas content and electric charging. The processing window for the film stretching was very narrow compared to the earlier developed polypropylene ferroelectrets. The film porosity, softness and thus the electromechanical activity are adjusted by gas-diffusion expansion. The activity of the electromechanically operating sensors and actuators was increased by stacking several layers of cellular cyclo-olefin film. For applications such as flat loudspeakers, the foamed films are tuned by tensioning them on a support frame. Correct tensioning was essential also for reducing the distortion levels.}, language = {en} } @article{FeldmeierNikutta2006, author = {Feldmeier, Achim and Nikutta, Robert}, title = {Nonlocal radiative coupling in non monotonic stellar winds (Research note)}, issn = {0004-6361}, doi = {10.1051/0004-6361:20053380}, year = {2006}, abstract = {There is strong observational evidence of shocks and clumping in radiation-driven stellar winds from hot, luminous stars. The resulting non nous monotonic velocity law allows for radiative coupling between distant locations, which is so far not accounted for in hydrodynamic wind simulations. In the present paper, we determine the Sobolev source function and radiative line force in the presence of radiative coupling in spherically symmetric flows, extending the geometry-free formalism of Rybicki \& Hummer (1978, ApJ, 219, 654) to the case of three-point coupling, which can result from, e. g., corotating interaction regions, wind shocks, or mass overloading. For a simple model of an overloaded wind, we find that, surprisingly, the flow decelerates at all radii above a certain height when nonlocal radiative coupling is accounted for. We discuss whether radiation-driven winds might in general not be able to re- accelerate after a non monotonicity has occurred in the velocity law}, language = {en} } @article{AbelStojkovicBreuer2006, author = {Abel, Markus and Stojkovic, Dragan and Breuer, Michael}, title = {Nonlinear stochastic estimation of wall models for LES}, issn = {0142-727X}, doi = {10.1016/j.heatfluidflow.2005.10.011}, year = {2006}, abstract = {A key technology for large eddy simulation (LES) of complex flows is an appropriate wall modeling strategy. In this paper we apply for the first time a fully nonparametric procedure for the estimation of generalized additive models (GAM) by conditional statistics. As a database, we use DNS and wall-resolved LES data of plane channel flow for Reynolds numbers, Re = 2800, 4000 (DNS) and 10,935, 22,776 (LES). The statistical method applied is a quantitative tool for the identification of important model terms, allowing for an identification of some of the near-wall physics. The results are given as nonparametric functions which cannot be attained by other methods. We investigated a generalized model which includes Schumann's and Piomelli et al.'s model. A strong influence of the pressure gradient in the viscous sublayer is found; for larger wall distances the spanwise pressure gradient even dominates the tau(w,zy). component. The first a posteriori LES results are given.}, language = {en} } @article{GlattBuschKaiseretal.2006, author = {Glatt, Erik and Busch, Hauke and Kaiser, Friedemann and Zaikin, Alexei A.}, title = {Noise-memory induced excitability and pattern formation in oscillatory neural models}, issn = {1539-3755}, doi = {10.1103/Physreve.73.026216}, year = {2006}, abstract = {We report a noise-memory induced phase transition in an array of oscillatory neural systems, which leads to the suppression of synchronous oscillations and restoration of excitable dynamics. This phenomenon is caused by the systematic contributions of temporally correlated parametric noise, i.e., possessing a memory, which stabilizes a deterministically unstable fixed point. Changing the noise correlation time, a reentrant phase transition to noise- induced excitability is observed in a globally coupled array. Since noise-induced excitability implies the restoration of the ability to transmit information, associated spatiotemporal patterns are observed afterwards. Furthermore, an analytic approach to predict the systematic effects of exponentially correlated noise is presented and its results are compared with the simulations}, language = {en} } @article{MechauSaphiannikovaNeher2006, author = {Mechau, Norman and Saphiannikova, Marina and Neher, Dieter}, title = {Molecular tracer diffusion in thin azobenzene polymer layers}, series = {Applied physics letters}, volume = {89}, journal = {Applied physics letters}, number = {25}, publisher = {Elsevier}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.2405853}, pages = {3}, year = {2006}, abstract = {Translational diffusion of fluorescent tracer molecules in azobenzene polymer layers is studied at different temperatures and under illumination using the method of fluorescence recovery after photobleaching. Diffusion is clearly observed in the dark above the glass transition temperature, while homogeneous illumination at 488 nm and 100 mW/cm(2) does not cause any detectable diffusion of the dye molecules within azobenzene layers. This implies that the viscosity of azobenzene layers remains nearly unchanged under illumination with visible light in the absence of internal or external forces. (c) 2006 American Institute of Physics.}, language = {en} } @phdthesis{NarayananNair2006, author = {Narayanan Nair, Arun Kumar}, title = {Molecular dynamics simulations of polyelectrolyte brushes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7005}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {This thesis studies strong, completely charged polyelectrolyte brushes. Extensive molecular dynamics simulations are performed on different polyelectrolyte brush systems using local compute servers and massively parallel supercomputers. The full Coulomb interaction of charged monomers, counterions, and salt ions is treated explicitly. The polymer chains are anchored by one of their ends to a uncharged planar surface. The chains are treated under good solvent conditions. Monovalent salt ions (1:1 type) are modelled same as counterions. The studies concentrate on three different brush systems at constant temperature and moderate Coulomb interaction strength (Bjerrum length equal to bond length): The first system consists of a single polyelectrolyte brush anchored with varying grafting density to a plane. Results show that chains are extended up to about 2/3 of their contour length. The brush thickness slightly grows with increasing anchoring density. This slight dependence of the brush height on grafting density is in contrast to the well known scaling result for the osmotic brush regime. That is why the result obtained by simulations has stimulated further development of theory as well as new experimental investigations on polyelectrolyte brushes. This observation can be understood on a semi-quantitative level using a simple scaling model that incorporates excluded volume effects in a free-volume formulation where an effective cross section is assigned to the polymer chain from where couterions are excluded. The resulting regime is called nonlinear osmotic brush regime. Recently this regime was also obtained in experiments. The second system studied consists of polyelectrolyte brushes with added salt in the nonlinear osmotic regime. Varying salt is an important parameter to tune the structure and properties of polyelectrolytes. Further motivation is due to a theoretical scaling prediction by Pincus for the salt dependence of brush thickness. In the high salt limit (salt concentration much larger than counterion concentration) the brush height is predicted to decrease with increasing external salt, but with a relatively weak power law showing an exponent -1/3. There is some experimental and theoretical work that confirms this prediction, but there are other results that are in contradiction. In such a situation simulations are performed to validate the theoretical prediction. The simulation result shows that brush thickness decreases with added salt, and indeed is in quite good agreement with the scaling prediction by Pincus. The relation between buffer concentration and the effective ion strength inside the brush at varying salt concentration is of interest both from theoretical as well as experimental point of view. The simulation result shows that mobile ions (counterions as well as salt) distribute nonhomogeneously inside and outside of the brush. To explain the relation between the internal ion concentration with the buffer concentration a Donnan equilibrium approach is employed. Modifying the Donnan approach by taking into account the self-volume of polyelectrolyte chains as indicated above, the simulation result can be explained using the same effective cross section for the polymer chains. The extended Donnan equilibrium relation represents a interesting theoretical prediction that should be checked by experimental data. The third system consist of two interacting polyelectrolyte brushes that are grafted to two parallel surfaces. The interactions between brushes are important, for instance, in stabilization of dispersions against flocculation. In the simulations pressure is evaluated as a function of separation D between the two grafting planes. The pressure behavior shows different regimes for decreasing separation. This behavior is in qualitative agreement with experimental data. At relatively weak compression the pressure behavior obtained in the simulation agrees with a 1/D power law predicted by scaling theory. Beyond that the present study could supply new insight for understanding the interaction between polyelectrolyte brushes.}, subject = {Molekulardynamik}, language = {en} } @phdthesis{Maulbetsch2006, author = {Maulbetsch, Christian}, title = {Modeling galaxy formation in different environments}, address = {Potsdam}, pages = {IV, 138 S. : graph. Darst.}, year = {2006}, language = {en} } @phdthesis{Fery2006, author = {Fery, Andreas}, title = {Micro-Mechanics and Adhesion of Artifical Capsules From Method-development to Unterstanding Structure-property relations}, address = {Potsdam}, pages = {46 S. : graph. Darst.}, year = {2006}, language = {en} } @article{VarykhalovGudatAdamchuketal.2006, author = {Varykhalov, Andrei and Gudat, Wolfgang and Adamchuk, V. K. and Rader, Oliver}, title = {Magic numbers in two-dimensional self-organization of C-60 molecules}, doi = {10.1103/Physrevb.73.241404}, year = {2006}, abstract = {Employing the chemically passive carbon reconstruction W(110)/C-R(15x3) as substrate for deposition of C-60 molecules, we have discovered by scanning tunneling microscopy two-dimensional self-assembly of fullerenes into uniform molecular nanoclusters with "magic" numbers. Our photoemission measurements determine van der Waals forces as the dominating interaction in this self-organizing two-dimensional molecular gas. Based on this, a theoretical determination of the cluster structures in the framework of the Girifalco model gives perfect agreement with the experiment}, language = {en} } @article{DonnerSeehaferSanjuanetal.2006, author = {Donner, Reik Volker and Seehafer, Norbert and Sanjuan, Miguel Angel Fernandez and Feudel, Fred}, title = {Low-dimensional dynamo modelling and symmetry-breaking bifurcations}, series = {Physica. D, Nonlinear phenomena}, volume = {223}, journal = {Physica. D, Nonlinear phenomena}, number = {2}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0167-2789}, doi = {10.1016/j.physd.2006.08.022}, pages = {151 -- 162}, year = {2006}, abstract = {Motivated by the successful Karlsruhe dynamo experiment, a relatively low-dimensional dynamo model is proposed. It is based on a strong truncation of the magnetohydrodynamic (MHD) equations with an external forcing of the Roberts type and the requirement that the model system satisfies the symmetries of the full MHD system, so that the first symmetry-breaking bifurcations can be captured. The backbone of the Roberts dynamo is formed by the Roberts flow, a helical mean magnetic field and another part of the magnetic field coupled to these two by triadic mode interactions. A minimum truncation model (MTM) containing only these energetically dominating primary mode triads is fully equivalent to the widely used first-order smoothing approximation. However, it is shown that this approach works only in the limit of small wave numbers of the excited magnetic field or small magnetic Reynolds numbers (\$Rm ll 1\$). To obtain dynamo action under more general conditions, secondary mode}, language = {en} } @article{ZuritaSanchezHenkel2006, author = {Zurita-S{\´a}nchez, Jorge R. and Henkel, Carsten}, title = {Lossy electrical transmission lines: Thermal fluctuations and quantization}, issn = {1050-2947}, doi = {10.1103/Physreva.73.063825}, year = {2006}, abstract = {We present a theoretical framework for the analysis of the statistical properties of thermal fluctuations on a lossy transmission line. A quantization scheme of the electrical signals in the transmission line is formulated. We discuss two applications in detail. Noise spectra at finite temperature for voltage and current are shown to deviate significantly from the Johnson-Nyquist limit, and they depend on the position on the transmission line. We analyze the spontaneous emission, at low temperature, of a Rydberg atom and its resonant enhancement due to vacuum fluctuations in a capacitively coupled transmission line. The theory can also be applied to study the performance of microscale and nanoscale devices, including high-resolution sensors and quantum information processors}, language = {en} } @phdthesis{Zakrevskyy2006, author = {Zakrevskyy, Yuriy}, title = {Liquid crystallinity and alignment of ionic self-assembly complexes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-10048}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {In this work the first observation of new type of liquid crystals is presented. This is ionic self-assembly (ISA) liquid crystals formed by introduction of oppositely charged ions between different low molecular tectonic units. As practically all conventional liquid crystals consist of rigid core and alkyl chains the attention is focused to the simplest case where oppositely charged ions are placed between a rigid core and alkyl tails. The aim of this work is to investigate and understand liquid crystalline and alignment properties of these materials. It was found that ionic interactions within complexes play the main role. Presence of these interactions restricts transition to isotropic phase. In addition, these interactions hold the system (like network) allowing crystallization into a single domain from aligned LC state. Alignment of these simple ISA complexes was spontaneous on a glass substrate. In order to show potentials for application perylenediimide and azobenzene containing ISA complexes have been investigated for correlations between phase behavior and their alignment properties. The best results of macroscopic alignment of perylenediimide-based ISA complexes have been obtained by zone-casting method. In the aligned films the columns of the complex align perpendicular to the phase-transition front. The obtained anisotropy (DR = 18) is thermally stable. The investigated photosensitive (azobenzene-based) ISA complexes show formation of columnar LC phases. It was demonstrated that photo alignment of such complexes was very effective (DR = 50 has been obtained). It was shown that photo-reorientation in the photosensitive ISA complexes is cooperative process. The size of domains has direct influence on efficiency of the photo-reorientation process. In the case of small domains the photo-alignment is the most effective. Under irradiation with linearly polarized light domains reorient in the plane of the film leading to macroscopic alignment of columns parallel to the light polarization and joining of small domains into big ones. Finally, the additional distinguishable properties of the ISA liquid crystalline complexes should be noted: (I) the complexes do not solve in water but readily solve in organic solvents; (II) the complexes have good film-forming properties when cast or spin-coated from organic solvent; (III) alignment of the complexes depends on their structure and secondary interactions between tectonic units.}, subject = {Fl{\"u}ssigkristall}, language = {en} } @article{BubeNetoDonneretal.2006, author = {Bube, Kevin and Neto, Camilo Rodrigues and Donner, Reik Volker and Schwarz, Udo and Feudel, Ulrike}, title = {Linear and nonlinear characterization of surfaces from a laser beam melt ablation process}, issn = {0022-3727}, doi = {10.1088/0022-3727/39/7/011}, year = {2006}, abstract = {We apply linear and nonlinear methods to study the properties of surfaces generated by a laser beam melt ablation process. As a result we present a characterization and ordering of the surfaces depending on the adjusted process parameters. Our findings give some insight into the performance of two widely applied multifractal analysis methods-the detrended fluctuation analysis and the wavelet transform modulus maxima method-on short real world data}, language = {en} } @article{RaabWesselSchirdewanetal.2006, author = {Raab, Corinna and Wessel, Niels and Schirdewan, Alexander and Kurths, J{\"u}rgen}, title = {Large-scale dimension densities for heart rate variability analysis}, issn = {1539-3755}, doi = {10.1103/Physreve.73.041907}, year = {2006}, abstract = {In this work, we reanalyze the heart rate variability (HRV) data from the 2002 Computers in Cardiology (CiC) Challenge using the concept of large-scale dimension densities and additionally apply this technique to data of healthy persons and of patients with cardiac diseases. The large-scale dimension density (LASDID) is estimated from the time series using a normalized Grassberger-Procaccia algorithm, which leads to a suitable correction of systematic errors produced by boundary effects in the rather large scales of a system. This way, it is possible to analyze rather short, nonstationary, and unfiltered data, such as HRV. Moreover, this method allows us to analyze short parts of the data and to look for differences between day and night. The circadian changes in the dimension density enable us to distinguish almost completely between real data and computer-generated data from the CiC 2002 challenge using only one parameter. In the second part we analyzed the data of 15 patients with atrial fibrillation (AF), 15 patients with congestive heart failure (CHF), 15 elderly healthy subjects (EH), as well as 18 young and healthy persons (YH). With our method we are able to separate completely the AF (rho(mu)(ls)=0.97 +/- 0.02) group from the others and, especially during daytime, the CHF patients show significant differences from the young and elderly healthy volunteers (CHF, 0.65 +/- 0.13; EH, 0.54 +/- 0.05; YH, 0.57 +/- 0.05; p < 0.05 for both comparisons). Moreover, for the CHF patients we find no circadian changes in rho(mu)(ls) (day, 0.65 +/- 0.13; night, 0.66 +/- 0.12; n.s.) in contrast to healthy controls (day, 0.54 +/- 0.05; night, 0.61 +/- 0.05; p=0.002). Correlation analysis showed no statistical significant relation between standard HRV and circadian LASDID, demonstrating a possibly independent application of our method for clinical risk stratification}, language = {en} } @article{HeinmuellerPetitjeanLedouxetal.2006, author = {Heinm{\"u}ller, Janine and Petitjean, Patrick and Ledoux, Cedric and Caucci, Sara and Srianand, Raghunathan}, title = {Kinematics and star formation activity in the z(abs)=2.03954 damped Lyman-alpha system towards PKS 0458-020}, issn = {0004-6361}, doi = {10.1051/0004-6361:20053910}, year = {2006}, abstract = {We present UVES observations of the log N(H I) = 21.7 damped Lyman-alpha system at z(abs) = 2.03954 towards the quasar PKS 0458-020. Hi Lyman-alpha emission is detected in the center of the damped Lyman-alpha absorption trough. Metallicities are derived for Mg II, Si II, P II, Cr II, Mn II, Fe II and Zn II and are found to be -1.21 +/- 0.12, - 1.28 +/- 0.20, -1.54 +/- 0.11, -1.66 +/- 0.10, -2.05 +/- 0.11, -1.87 +/- 0.11, -1.22 +/- 0.10, respectively, relative to solar. The depletion factor is therefore of the order of [Zn/Fe] = 0.65. We observe metal absorption lines to be blueshifted compared to the Lyman-alpha emission up to a maximum of similar to 100 and 200 km s(-1) for low and high- ionization species respectively. This can be interpreted either as the consequence of rotation in a large (similar to 7 kpc) disk or as the imprint of a galactic wind. The star formation rate (SFR) derived from the Lyman-alpha emission, 1.6 M-circle dot yr(-1), is compared with that estimated from the observed C II* absorption. No molecular hydrogen is detected in our data, yielding a molecular fraction log f < -6.52. This absence of H-2 can be explained as the consequence of a high ambient UV flux which is one order of magnitude larger than the radiation field in the ISM of our Galaxy and originates in the observed emitting region}, language = {en} } @article{SiefertPeinke2006, author = {Siefert, Malte and Peinke, J}, title = {Joint multi-scale statistics of longitudinal and transversal increments in small-scale wake turbulence}, doi = {10.1080/14685240600677673}, year = {2006}, abstract = {We analyse the relationship of longitudinal and transversal increment statistics measured in isotropic small- scale turbulence. This is done by means of the theory of Markov processes leading to a phenomenological Fokker - Planck equation for the two increments from which a generalized K arm an equation is derived. We discuss in detail the analysis and show that the estimated equation can describe the statistics of the turbulent cascade. A remarkable result is that the main differences between longitudinal and transversal increments can be explained by a simple rescaling symmetry, namely the cascade speed of the transverse increments is 1.5 times faster than that of the longitudinal increments. Small differences can be found in the skewness and in a higher order intermittency term. The rescaling symmetry is compatible with the Kolmogorov constants and the K arm an equation and gives new insight into the use of extended self- similarity (ESS) for transverse increments. Based on the results we propose an extended self-similarity for the transverse increments (ESST)}, language = {en} } @phdthesis{Prevot2006, author = {Prevot, Michelle Elizabeth}, title = {Introduction of a thermo-sensitive non-polar species into polyelectrolyte multilayer capsules for drug delivery}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7785}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {The layer-by-layer assembly (LBL) of polyelectrolytes has been extensively studied for the preparation of ultrathin films due to the versatility of the build-up process. The control of the permeability of these layers is particularly important as there are potential drug delivery applications. Multilayered polyelectrolyte microcapsules are also of great interest due to their possible use as microcontainers. This work will present two methods that can be used as employable drug delivery systems, both of which can encapsulate an active molecule and tune the release properties of the active species. Poly-(N-isopropyl acrylamide), (PNIPAM) is known to be a thermo-sensitive polymer that has a Lower Critical Solution Temperature (LCST) around 32oC; above this temperature PNIPAM is insoluble in water and collapses. It is also known that with the addition of salt, the LCST decreases. This work shows Differential Scanning Calorimetry (DSC) and Confocal Laser Scanning Microscopy (CLSM) evidence that the LCST of the PNIPAM can be tuned with salt type and concentration. Microcapsules were used to encapsulate this thermo-sensitive polymer, resulting in a reversible and tunable stimuli- responsive system. The encapsulation of the PNIPAM inside of the capsule was proven with Raman spectroscopy, DSC (bulk LCST measurements), AFM (thickness change), SEM (morphology change) and CLSM (in situ LCST measurement inside of the capsules). The exploitation of the capsules as a microcontainer is advantageous not only because of the protection the capsules give to the active molecules, but also because it facilitates easier transport. The second system investigated demonstrates the ability to reduce the permeability of polyelectrolyte multilayer films by the addition of charged wax particles. The incorporation of this hydrophobic coating leads to a reduced water sensitivity particularly after heating, which melts the wax, forming a barrier layer. This conclusion was proven with Neutron Reflectivity by showing the decreased presence of D2O in planar polyelectrolyte films after annealing creating a barrier layer. The permeability of capsules could also be decreased by the addition of a wax layer. This was proved by the increase in recovery time measured by Florescence Recovery After Photobleaching, (FRAP) measurements. In general two advanced methods, potentially suitable for drug delivery systems, have been proposed. In both cases, if biocompatible elements are used to fabricate the capsule wall, these systems provide a stable method of encapsulating active molecules. Stable encapsulation coupled with the ability to tune the wall thickness gives the ability to control the release profile of the molecule of interest.}, subject = {Mikrokapsel}, language = {en} } @misc{tenFreyhausHuntgeburthWingeretal.2006, author = {ten Freyhaus, Henrik and Huntgeburth, Michael and Winger, Kirstin and B{\"a}umer, Anselm T. and Vantler, Marius and Bekhite, Mohamed M. and Wartenberg, Maria and Sauer, Heinrich and Sparwel, Jan and Rosenkranz, Stephan}, title = {Inhibition of ROS liberation attenuates PDGF-Dependent chemotaxis, but not proliferation in vascular smooth muscle cells - Critical role of Src kinase}, series = {Circulation : an American Heart Association journal}, volume = {114}, journal = {Circulation : an American Heart Association journal}, publisher = {Lippincott Williams \& Wilkins}, address = {Philadelphia}, issn = {0009-7322}, pages = {296 -- 297}, year = {2006}, language = {en} } @article{BaptistaZhouKurths2006, author = {Baptista, Murilo da Silva and Zhou, Changsong and Kurths, J{\"u}rgen}, title = {Information transmission in phase synchronous chaotic arrays}, issn = {0256-307X}, doi = {10.1088/0256-307X/23/3/010}, year = {2006}, abstract = {We show many versatile phase synchronous configurations that emerge in an array of coupled chaotic elements due to the presence of a periodic stimulus. Then, we explain the relevance of these configurations to the understanding of how information about such a. stimulus is transmitted from one side to the other in this array. The stimulus actively creates the ways to be transmitted, by making the chaotic elements to phase synchronize}, language = {en} }