@misc{SchickEckertPontiusetal.2016, author = {Schick, Daniel and Eckert, Sebastian and Pontius, Niko and Mitzner, Rolf and F{\"o}hlisch, Alexander and Holldack, Karsten and Sorgenfrei, Florian}, title = {Versatile soft X-ray-optical cross-correlator for ultrafast applications}, series = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {1331}, issn = {1866-8372}, doi = {10.25932/publishup-43696}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-436962}, pages = {054304-1 -- 054304-8}, year = {2016}, abstract = {We present an X-ray-optical cross-correlator for the soft (> 150 eV) up to the hard X-ray regime based on a molybdenum-silicon superlattice. The cross-correlation is done by probing intensity and position changes of superlattice Bragg peaks caused by photoexcitation of coherent phonons. This approach is applicable for a wide range of X-ray photon energies as well as for a broad range of excitation wavelengths and requires no external fields or changes of temperature. Moreover, the cross-correlator can be employed on a 10 ps or 100 fs time scale featuring up to 50\% total X-ray reflectivity and transient signal changes of more than 20\%. (C) 2016 Author(s).}, language = {en} } @article{Steinmetz2016, author = {Steinmetz, Matthias}, title = {Die Vermessung des Universums}, series = {Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert}, journal = {Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert}, publisher = {Berlin-Brandenburgische Akademie der Wissenschaften}, address = {Berlin}, isbn = {978-3-939818-67-0}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:b4-opus4-25899}, pages = {197 -- 210}, year = {2016}, language = {de} } @article{ReindlRauchMillerBertolamietal.2016, author = {Reindl, Nicole and Rauch, Thomas and Miller Bertolami, Marcelo Miguel and Todt, Helge Tobias and Werner, K.}, title = {Breaking news from the HST}, series = {Monthly notices of the Royal Astronomical Society}, volume = {464}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnrasl/slw175}, pages = {L51 -- L55}, year = {2016}, abstract = {SAO 244567 is a rare example of a star that allows us to witness stellar evolution in real time. Between 1971 and 1990, it changed from a B-type star into the hot central star of the Stingray Nebula. This observed rapid heating has been a mystery for decades, since it is in strong contradiction with the low mass of the star and canonical post-asymptotic giant branch (AGB) evolution. We speculated that SAO 244567 might have suffered from a late thermal pulse (LTP) and obtained new observations with Hubble Space Telescope (HST)/COS to follow the evolution of the surface properties of SAO 244567 and to verify the LTP hypothesis. Our non-LTE spectral analysis reveals that the star cooled significantly since 2002 and that its envelope is now expanding. Therefore, we conclude that SAO 244567 is currently on its way back towards the AGB, which strongly supports the LTP hypothesis. A comparison with state-of-the-art LTP evolutionary calculations shows that these models cannot fully reproduce the evolution of all surface parameters simultaneously, pointing out possible shortcomings of stellar evolution models. Thereby, SAO 244567 keeps on challenging stellar evolution theory and we highly encourage further investigations.}, language = {en} } @article{ZehbeZaslanskyMochalesetal.2016, author = {Zehbe, Rolf and Zaslansky, Paul and Mochales, Carolina and Mueller, Wolf-Dieter and Fleck, Claudia}, title = {Synchrotron micro tomographic evaluation of multilayered zirconia ceramics-Volumetric effects after indentation}, series = {Journal of the European Ceramic Society}, volume = {36}, journal = {Journal of the European Ceramic Society}, publisher = {Elsevier}, address = {Oxford}, issn = {0955-2219}, doi = {10.1016/j.jeurceramsoc.2015.09.015}, pages = {171 -- 177}, year = {2016}, abstract = {Electrophoretic deposition was used to produce zirconia specimen consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia. In this configuration, the tetragonal stabilized zirconia layers can undergo transformation toughening upon mechanical induced stresses, while the cubic stabilized layers can act as confining element. To understand the volumetric changes due to transformation toughening in these layered materials after indentation, we used an advanced synchrotron-based X-ray mu CT setup and compared the results with surface sensitive methods like Raman spectroscopy, AFM and white light interferometry. The high spatial resolution and the adapted beam energy between the absorption edges of zirconia and yttria allowed discriminating between individual layers due to differences in their yttria content. Furthermore we were able to identify single indents and link volume changes to different physical effects in the different stabilized zirconia parts and visualize the three dimensional volume around only few micrometre sized indents. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{ZehbeMochalesRadziketal.2016, author = {Zehbe, Rolf and Mochales, Carolina and Radzik, Daniela and Mueller, Wolf-Dieter and Fleck, Claudia}, title = {Electrophoretic deposition of multilayered (cubic and tetragonal stabilized) zirconia ceramics for adapted crack deflection}, series = {Journal of the European Ceramic Society}, volume = {36}, journal = {Journal of the European Ceramic Society}, publisher = {Elsevier}, address = {Oxford}, issn = {0955-2219}, doi = {10.1016/j.jeurceramsoc.2015.08.022}, pages = {357 -- 364}, year = {2016}, abstract = {The electrophoretic deposition process was used to produce multi-layered ceramics consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia to make use of their different mechanical behaviour, investigating the possibility to deflect advancing cracks at the interfaces of the different layers. This crack deflection is apparently impacted by a toughening mechanism only found in the tetragonal stabilized zirconia polymorph and is characterized by the stress induced transformation of the metastable tetragonal phase into the monoclinic one, which is accompanied by a volume increase resulting in a closing mechanism for advancing cracks. While improving the electrophoretic deposition process, we investigated the transformation toughening mechanism at the layer interfaces and their effect on crack propagation. Investigations involved a combination of different imaging methods, including light microscopy, white light interferometry, atomic force microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and Raman spectroscopy. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{MengelFeldmannLevermann2016, author = {Mengel, Matthias and Feldmann, Johannes and Levermann, Anders}, title = {Linear sea-level response to abrupt ocean warming of major West Antarctic ice basin}, series = {Nature climate change}, volume = {6}, journal = {Nature climate change}, publisher = {Nature Publ. Group}, address = {London}, issn = {1758-678X}, doi = {10.1038/NCLIMATE2808}, pages = {71 -- +}, year = {2016}, abstract = {Antarctica's contribution to global sea-level rise has recently been increasing1. Whether its ice discharge will become unstable and decouple from anthropogenic forcing2,3,4 or increase linearly with the warming of the surrounding ocean is of fundamental importance5. Under unabated greenhouse-gas emissions, ocean models indicate an abrupt intrusion of warm circumpolar deep water into the cavity below West Antarctica's Filchner-Ronne ice shelf within the next two centuries6,7. The ice basin's retrograde bed slope would allow for an unstable ice-sheet retreat8, but the buttressing of the large ice shelf and the narrow glacier troughs tend to inhibit such instability9,10,11. It is unclear whether future ice loss will be dominated by ice instability or anthropogenic forcing. Here we show in regional and continental-scale ice-sheet simulations, which are capable of resolving unstable grounding-line retreat, that the sea-level response of the Filchner-Ronne ice basin is not dominated by ice instability and follows the strength of the forcing quasi-linearly. We find that the ice loss reduces after each pulse of projected warm water intrusion. The long-term sea-level contribution is approximately proportional to the total shelf-ice melt. Although the local instabilities might dominate the ice loss for weak oceanic warming12, we find that the upper limit of ice discharge from the region is determined by the forcing and not by the marine ice-sheet instability.}, language = {en} } @article{Baushev2016, author = {Baushev, Anton N.}, title = {Can the dark matter annihilation signal be significantly boosted by substructures?}, series = {Journal of cosmology and astroparticle physics}, volume = {30}, journal = {Journal of cosmology and astroparticle physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1475-7516}, doi = {10.1088/1475-7516/2016/01/018}, pages = {12 -- 18}, year = {2016}, abstract = {A very general cosmological consideration suggests that, along with galactic dark matter halos, much smaller dark matter structures may exist. These structures are usually called `clumps', and their mass extends to 10\&\#8722;6 M \&\#8857; or even lower. The clumps should give the main contribution into the signal of dark matter annihilation, provided that they have survived until the present time. Recent observations favor a cored profile for low-mass astrophysical halos. We consider cored clumps and show that they are significantly less firm than the standard NFW ones. In contrast to the standard scenario, the cored clumps should have been completely destroyed inside ~ 20 kpc from the Milky Way center. The dwarf spheroidals should not contain any dark matter clumps. On the other hand, even under the most pessimistic assumption about the clump structure, the clumps should have survived in the Milky Way at a distance exceeding 50 kpc from the center, as well as in low-density cosmic structures. There they significantly boost the dark matter annihilation. We show that at least 70\% of the clumps endured the primordial structure formation should still exist untouched in the present-day Universe.}, language = {en} } @article{KuznetsovTurukinaChernyshovetal.2016, author = {Kuznetsov, Alexander P. and Turukina, Ludmila V. and Chernyshov, Nikolai Yu and Sedova, Yuliya V.}, title = {Oscillations and Synchronization in a System of Three Reactively Coupled Oscillators}, series = {International journal of bifurcation and chaos : in applied sciences and engineering}, volume = {26}, journal = {International journal of bifurcation and chaos : in applied sciences and engineering}, publisher = {World Scientific}, address = {Singapore}, issn = {0218-1274}, doi = {10.1142/S0218127416500103}, pages = {31 -- 39}, year = {2016}, abstract = {We consider a system of three interacting van der Pol oscillators with reactive coupling. Phase equations are derived, using proper order of expansion over the coupling parameter. The dynamics of the system is studied by means of the bifurcation analysis and with the method of Lyapunov exponent charts. Essential and physically meaningful features of the reactive coupling are discussed.}, language = {en} } @article{YadavalliLoebnerPapkeetal.2016, author = {Yadavalli, Nataraja Sekhar and Loebner, Sarah and Papke, Thomas and Sava, Elena and Hurduc, Nicolae and Santer, Svetlana}, title = {A comparative study of photoinduced deformation in azobenzene containing polymer films}, series = {Soft matter}, volume = {12}, journal = {Soft matter}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c6sm00029k}, pages = {2593 -- 2603}, year = {2016}, abstract = {In this paper two groups supporting different views on the mechanism of light induced polymer deformation argue about the respective underlying theoretical conceptions, in order to bring this interesting debate to the attention of the scientific community. The group of Prof. Nicolae Hurduc supports the model claiming that the cyclic isomerization of azobenzenes may cause an athermal transition of the glassy azobenzene containing polymer into a fluid state, the so-called photo-fluidization concept. This concept is quite convenient for an intuitive understanding of the deformation process as an anisotropic flow of the polymer material. The group of Prof. Svetlana Santer supports the re-orientational model where the mass-transport of the polymer material accomplished during polymer deformation is stated to be generated by the light-induced re-orientation of the azobenzene side chains and as a consequence of the polymer backbone that in turn results in local mechanical stress, which is enough to irreversibly deform an azobenzene containing material even in the glassy state. For the debate we chose three polymers differing in the glass transition temperature, 32 degrees C, 87 degrees C and 95 degrees C, representing extreme cases of flexible and rigid materials. Polymer film deformation occurring during irradiation with different interference patterns is recorded using a homemade set-up combining an optical part for the generation of interference patterns and an atomic force microscope for acquiring the kinetics of film deformation. We also demonstrated the unique behaviour of azobenzene containing polymeric films to switch the topography in situ and reversibly by changing the irradiation conditions. We discuss the results of reversible deformation of three polymers induced by irradiation with intensity (IIP) and polarization (PIP) interference patterns, and the light of homogeneous intensity in terms of two approaches: the re-orientational and the photo-fluidization concepts. Both agree in that the formation of opto-mechanically induced stresses is a necessary prerequisite for the process of deformation. Using this argument, the deformation process can be characterized either as a flow or mass transport.}, language = {en} } @misc{TeifCherstvy2016, author = {Teif, Vladimir B. and Cherstvy, Andrey G.}, title = {Chromatin and epigenetics: current biophysical views}, series = {AIMS biophysics}, volume = {3}, journal = {AIMS biophysics}, publisher = {American Institute of Mathematical Sciences}, address = {Springfield}, issn = {2377-9098}, doi = {10.3934/biophy.2016.1.88}, pages = {88 -- 98}, year = {2016}, abstract = {Recent advances in high-throughput sequencing experiments and their theoretical descriptions have determined fast dynamics of the "chromatin and epigenetics" field, with new concepts appearing at high rate. This field includes but is not limited to the study of DNA-protein-RNA interactions, chromatin packing properties at different scales, regulation of gene expression and protein trafficking in the cell nucleus, binding site search in the crowded chromatin environment and modulation of physical interactions by covalent chemical modifications of the binding partners. The current special issue does not pretend for the full coverage of the field, but it rather aims to capture its development and provide a snapshot of the most recent concepts and approaches. Eighteen open-access articles comprising this issue provide a delicate balance between current theoretical and experimental biophysical approaches to uncover chromatin structure and understand epigenetic regulation, allowing free flow of new ideas and preliminary results.}, language = {en} } @article{LiebigSarhanPrietzeletal.2016, author = {Liebig, Ferenc and Sarhan, Radwan Mohamed and Prietzel, Claudia Christina and Reinecke, Antje and Koetz, Joachim}, title = {"Green" gold nanotriangles: synthesis, purification by polyelectrolyte/micelle depletion flocculation and performance in surface-enhanced Raman scattering}, series = {RSC Advances}, volume = {6}, journal = {RSC Advances}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/c6ra04808k}, pages = {33561 -- 33568}, year = {2016}, abstract = {The aim of this study was to develop a one-step synthesis of gold nanotriangles (NTs) in the presence of mixed phospholipid vesicles followed by a separation process to isolate purified NTs. Negatively charged vesicles containing AOT and phospholipids, in the absence and presence of additional reducing agents (polyampholytes, polyanions or low molecular weight compounds), were used as a template phase to form anisotropic gold nanoparticles. Upon addition of the gold chloride solution, the nucleation process is initiated and both types of particles, i.e., isotropic spherical and anisotropic gold nanotriangles, are formed simultaneously. As it was not possible to produce monodisperse nanotriangles with such a one-step procedure, the anisotropic nanoparticles needed to be separated from the spherical ones. Therefore, a new type of separation procedure using combined polyelectrolyte/micelle depletion flocculation was successfully applied. As a result of the different purification steps, a green colored aqueous dispersion was obtained containing highly purified, well-defined negatively charged flat nanocrystals with a platelet thickness of 10 nm and an edge length of about 175 nm. The NTs produce promising results in surface-enhanced Raman scattering.}, language = {en} } @article{SandmannGarzMenzel2016, author = {Sandmann, Michael and Garz, Andreas and Menzel, Ralf}, title = {Physiological response of two different Chlamydomonas reinhardtii strains to light-dark rhythms}, series = {Botany}, volume = {94}, journal = {Botany}, publisher = {NRC Research Press}, address = {Ottawa}, issn = {1916-2790}, doi = {10.1139/cjb-2015-0144}, pages = {53 -- 64}, year = {2016}, abstract = {Cells of a cell-wall deficient line (cw15-type) of Chlamydomonas reinhardtii and of the corresponding wild type were grown during repetitive light-dark cycles. In a direct comparison, both lines showed approximately the same relative biomass increase during light phase but the cw-line produced significantly more, and smaller, daughter cells. Throughout the light period the average cellular starch content, the cellular chlorophyll content, the cellular rate of dark respiration, and the cellular rate of photosynthesis of the cw-line was lower. Despite this, several non-cell volume related parameters like the development of starch content per cell volume were clearly different over time between the strains. Additionally, the chlorophyll-based photosynthesis rates were 2-fold higher in the mutant than in the wild-type cells, and the ratio of chlorophyll a to chlorophyll b as well as the light-saturation index were also consistently higher in the mutant cells. Differences in the starch content were also confirmed by single cell analyses using a sensitive SHG-based microscopy approach. In summary, the cw15-type mutant deviates from its genetic background in the entire cell physiology. Both lines should be used in further studies in comparative systems biology with focus on the detailed relation between cell volume increase, photosynthesis, starch metabolism, and daughter cell productivity.}, language = {en} } @article{FrielerMengelLevermann2016, author = {Frieler, Katja and Mengel, M. and Levermann, Anders}, title = {Delaying future sea-level rise by storing water in Antarctica}, series = {Earth system dynamics}, volume = {7}, journal = {Earth system dynamics}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {2190-4979}, doi = {10.5194/esd-7-203-2016}, pages = {203 -- 210}, year = {2016}, abstract = {Even if greenhouse gas emissions were stopped today, sea level would continue to rise for centuries, with the long-term sea-level commitment of a 2 degrees C warmer world significantly exceeding 2 m. In view of the potential implications for coastal populations and ecosystems worldwide, we investigate, from an ice-dynamic perspective, the possibility of delaying sea-level rise by pumping ocean water onto the surface of the Antarctic ice sheet. We find that due to wave propagation ice is discharged much faster back into the ocean than would be expected from a pure advection with surface velocities. The delay time depends strongly on the distance from the coastline at which the additional mass is placed and less strongly on the rate of sea-level rise that is mitigated. A millennium-scale storage of at least 80\% of the additional ice requires placing it at a distance of at least 700 km from the coastline. The pumping energy required to elevate the potential energy of ocean water to mitigate the currently observed 3 mmyr(-1) will exceed 7\% of the current global primary energy supply. At the same time, the approach offers a comprehensive protection for entire coastlines particularly including regions that cannot be protected by dikes.}, language = {en} } @article{SandevIominKantzetal.2016, author = {Sandev, Trifce and Iomin, Alexander and Kantz, Holger and Metzler, Ralf and Chechkin, Aleksei V.}, title = {Comb Model with Slow and Ultraslow Diffusion}, series = {Mathematical modelling of natural phenomena}, volume = {11}, journal = {Mathematical modelling of natural phenomena}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0973-5348}, doi = {10.1051/mmnp/201611302}, pages = {18 -- 33}, year = {2016}, abstract = {We consider a generalized diffusion equation in two dimensions for modeling diffusion on a comb-like structures. We analyze the probability distribution functions and we derive the mean squared displacement in x and y directions. Different forms of the memory kernels (Dirac delta, power-law, and distributed order) are considered. It is shown that anomalous diffusion may occur along both x and y directions. Ultraslow diffusion and some more general diffusive processes are observed as well. We give the corresponding continuous time random walk model for the considered two dimensional diffusion-like equation on a comb, and we derive the probability distribution functions which subordinate the process governed by this equation to the Wiener process.}, language = {en} } @article{PavlenkoSanderMitzscherlingetal.2016, author = {Pavlenko, Elena S. and Sander, Mathias and Mitzscherling, S. and Pudell, Jan-Etienne and Zamponi, Flavio and Roessle, M. and Bojahr, Andre and Bargheer, Matias}, title = {Azobenzene - functionalized polyelectrolyte nanolayers as ultrafast optoacoustic transducers}, series = {Nanoscale}, volume = {8}, journal = {Nanoscale}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2040-3364}, doi = {10.1039/c6nr01448h}, pages = {13297 -- 13302}, year = {2016}, abstract = {We introduce azobenzene-functionalized polyelectrolyte multilayers as efficient, inexpensive optoacoustic transducers for hyper-sound strain waves in the GHz range. By picosecond transient reflectivity measurements we study the creation of nanoscale strain waves, their reflection from interfaces, damping by scattering from nanoparticles and propagation in soft and hard adjacent materials like polymer layers, quartz and mica. The amplitude of the generated strain epsilon similar to 5 x 10(-4) is calibrated by ultrafast X-ray diffraction.}, language = {en} } @article{HollaenderKossackKolloscheetal.2016, author = {Holl{\"a}nder, Lars and Kossack, Wilhelm and Kollosche, Matthias and Wirges, Werner and Kremer, Friedrich and Gerhard, Reimund}, title = {Influence of the remanent polarisation on the liquid crystal alignment in composite films of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and a cyanobiphenyl-based liquid crystal}, series = {Liquid crystals : an international journal of science and technology}, volume = {43}, journal = {Liquid crystals : an international journal of science and technology}, publisher = {Editions Rodopi BV}, address = {Abingdon}, issn = {0267-8292}, doi = {10.1080/02678292.2016.1185174}, pages = {1514 -- 1521}, year = {2016}, abstract = {Polymer-dispersed liquid crystals (PDLCs) of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and nematic 4-cyano-4\&\#697;-n-hexylbiphenyl (6CB) or 4-cyano-4\&\#697;-n-pentylbiphenyl (5CB) were prepared to study the effect of the remanent polarisation of the polymer on the liquid crystal alignment. We measured the macroscopic alignment of the liquid crystal molecules in the thickness direction by means of Infrared Transition-Moment Orientational Analysis. Electrical poling at 100 V/µm caused an increased order parameter up to 0.15. After subsequent annealing above the nematic-to-isotropic phase-transition temperature, the order parameter was reduced to 0.02. Nevertheless, the order parameter was still higher than for non-poled film indicating a slight orientation in thickness direction. Both values are lower than those expected from model calculations. In agreement with dielectric measurements, we attribute this result to the shielding effect of mobile charge carriers within the liquid crystal inclusions.}, language = {en} } @article{MuenchKipfstuhlFreitagetal.2016, author = {M{\"u}nch, Thomas and Kipfstuhl, Sepp and Freitag, Johannes and Meyer, Hanno and Laepple, Thomas}, title = {Regional climate signal vs. local noise: a two-dimensional view of water isotopes in Antarctic firn at Kohnen Station, Dronning Maud Land}, series = {Climate of the past : an interactive open access journal of the European Geosciences Union}, volume = {12}, journal = {Climate of the past : an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1814-9324}, doi = {10.5194/cp-12-1565-2016}, pages = {1565 -- 1581}, year = {2016}, abstract = {In low-accumulation regions, the reliability of delta O-18-derived temperature signals from ice cores within the Holocene is unclear, primarily due to the small climate changes relative to the intrinsic noise of the isotopic signal. In order to learn about the representativity of single ice cores and to optimise future ice-core-based climate reconstructions, we studied the stable-water isotope composition of firn at Kohnen Station, Dronning Maud Land, Antarctica. Analysing delta O-18 in two 50m long snow trenches allowed us to create an unprecedented, two-dimensional image characterising the isotopic variations from the centimetre to the 100-metre scale. Our results show seasonal layering of the isotopic composition but also high horizontal isotopic variability caused by local stratigraphic noise. Based on the horizontal and vertical structure of the isotopic variations, we derive a statistical noise model which successfully explains the trench data. The model further allows one to determine an upper bound for the reliability of climate reconstructions conducted in our study region at seasonal to annual resolution, depending on the number and the spacing of the cores taken.}, language = {en} } @article{GhoshCherstvyPetrovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Petrov, Eugene P. and Metzler, Ralf}, title = {Interactions of rod-like particles on responsive elastic sheets}, series = {Soft matter}, volume = {12}, journal = {Soft matter}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c6sm01522k}, pages = {7908 -- 7919}, year = {2016}, abstract = {What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed.}, language = {en} } @article{YangGuehrVecchioneetal.2016, author = {Yang, Jie and G{\"u}hr, Markus and Vecchione, Theodore and Robinson, Matthew Scott and Li, Renkai and Hartmann, Nick and Shen, Xiaozhe and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Gaffney, Kelly and Gorkhover, Tais and Hast, Carsten and Jobe, Keith and Makasyuk, Igor and Reid, Alexander and Robinson, Joseph and Vetter, Sharon and Wang, Fenglin and Weathersby, Stephen and Yoneda, Charles and Wang, Xijie and Centurion, Martin}, title = {Femtosecond gas phase electron diffraction with MeV electrons}, series = {Faraday discussions}, volume = {194}, journal = {Faraday discussions}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1359-6640}, doi = {10.1039/c6fd00071a}, pages = {563 -- 581}, year = {2016}, abstract = {We present results on ultrafast gas electron diffraction (UGED) experiments with femtosecond resolution using the MeV electron gun at SLAC National Accelerator Laboratory. UGED is a promising method to investigate molecular dynamics in the gas phase because electron pulses can probe the structure with a high spatial resolution. Until recently, however, it was not possible for UGED to reach the relevant timescale for the motion of the nuclei during a molecular reaction. Using MeV electron pulses has allowed us to overcome the main challenges in reaching femtosecond resolution, namely delivering short electron pulses on a gas target, overcoming the effect of velocity mismatch between pump laser pulses and the probe electron pulses, and maintaining a low timing jitter. At electron kinetic energies above 3 MeV, the velocity mismatch between laser and electron pulses becomes negligible. The relativistic electrons are also less susceptible to temporal broadening due to the Coulomb force. One of the challenges of diffraction with relativistic electrons is that the small de Broglie wavelength results in very small diffraction angles. In this paper we describe the new setup and its characterization, including capturing static diffraction patterns of molecules in the gas phase, finding time-zero with sub-picosecond accuracy and first time-resolved diffraction experiments. The new device can achieve a temporal resolution of 100 fs root-mean-square, and sub-angstrom spatial resolution. The collimation of the beam is sufficient to measure the diffraction pattern, and the transverse coherence is on the order of 2 nm. Currently, the temporal resolution is limited both by the pulse duration of the electron pulse on target and by the timing jitter, while the spatial resolution is limited by the average electron beam current and the signal-to-noise ratio of the detection system. We also discuss plans for improving both the temporal resolution and the spatial resolution.}, language = {en} } @article{GhoshCherstvyGrebenkovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Grebenkov, Denis S. and Metzler, Ralf}, title = {Anomalous, non-Gaussian tracer diffusion in crowded two-dimensional environments}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/1/013027}, pages = {16}, year = {2016}, abstract = {A topic of intense current investigation pursues the question of how the highly crowded environment of biological cells affects the dynamic properties of passively diffusing particles. Motivated by recent experiments we report results of extensive simulations of the motion of a finite sized tracer particle in a heterogeneously crowded environment made up of quenched distributions of monodisperse crowders of varying sizes in finite circular two-dimensional domains. For given spatial distributions of monodisperse crowders we demonstrate how anomalous diffusion with strongly non-Gaussian features arises in this model system. We investigate both biologically relevant situations of particles released either at the surface of an inner domain or at the outer boundary, exhibiting distinctly different features of the observed anomalous diffusion for heterogeneous distributions of crowders. Specifically we reveal an asymmetric spreading of tracers even at moderate crowding. In addition to the mean squared displacement (MSD) and local diffusion exponent we investigate the magnitude and the amplitude scatter of the time averaged MSD of individual tracer trajectories, the non-Gaussianity parameter, and the van Hove correlation function. We also quantify how the average tracer diffusivity varies with the position in the domain with a heterogeneous radial distribution of crowders and examine the behaviour of the survival probability and the dynamics of the tracer survival probability. Inter alia, the systems we investigate are related to the passive transport of lipid molecules and proteins in two-dimensional crowded membranes or the motion in colloidal solutions or emulsions in effectively two-dimensional geometries, as well as inside supercrowded, surface adhered cells.}, language = {en} } @article{GanopolskiWinkelmannSchellnhuber2016, author = {Ganopolski, A. and Winkelmann, Ricarda and Schellnhuber, Hans Joachim}, title = {Critical insolation-CO2 relation for diagnosing past and future glacial inception}, series = {Nature : the international weekly journal of science}, volume = {529}, journal = {Nature : the international weekly journal of science}, publisher = {Nature Publ. Group}, address = {London}, issn = {0028-0836}, doi = {10.1038/nature16494}, pages = {200 -- U159}, year = {2016}, abstract = {The past rapid growth of Northern Hemisphere continental ice sheets, which terminated warm and stable climate periods, is generally attributed to reduced summer insolation in boreal latitudes(1-3). Yet such summer insolation is near to its minimum at present(4), and there are no signs of a new ice age(5). This challenges our understanding of the mechanisms driving glacial cycles and our ability to predict the next glacial inception(6). Here we propose a critical functional relationship between boreal summer insolation and global carbon dioxide (CO2) concentration, which explains the beginning of the past eight glacial cycles and might anticipate future periods of glacial inception. Using an ensemble of simulations generated by an Earth system model of intermediate complexity constrained by palaeoclimatic data, we suggest that glacial inception was narrowly missed before the beginning of the Industrial Revolution. The missed inception can be accounted for by the combined effect of relatively high late-Holocene CO2 concentrations and the low orbital eccentricity of the Earth(7). Additionally, our analysis suggests that even in the absence of human perturbations no substantial build-up of ice sheets would occur within the next several thousand years and that the current interglacial would probably last for another 50,000 years. However, moderate anthropogenic cumulative CO2 emissions of 1,000 to 1,500 gigatonnes of carbon will postpone the next glacial inception by at least 100,000 years(8,9). Our simulations demonstrate that under natural conditions alone the Earth system would be expected to remain in the present delicately balanced interglacial climate state, steering clear of both large-scale glaciation of the Northern Hemisphere and its complete deglaciation, for an unusually long time.}, language = {en} } @article{ArchambaultArcherAuneetal.2016, author = {Archambault, S. and Archer, A. and Aune, T. and Barnacka, Anna and Benbow, W. and Bird, R. and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Ciupik, L. and Collins-Hughes, E. and Connolly, M. P. and Cui, W. and Dickinson, H. J. and Dumm, J. and Eisch, J. D. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Flinders, A. and Fortin, P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Huetten, M. and Hakansson, Nils and Hanna, D. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Khassen, Y. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Millis, J. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Pandel, D. and Park, N. and Pelassa, V. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rousselle, J. and Rulten, C. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Vincent, S. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wilhelm, Alina and Williams, D. A. and Zitzer, B.}, title = {EXCEPTIONALLY BRIGHT TEV FLARES FROM THE BINARY LS I+61 degrees 303}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {817}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.3847/2041-8205/817/1/L7}, pages = {6}, year = {2016}, abstract = {The TeV binary system LS I +61 degrees 303 is known for its regular, non-thermal emission pattern that traces the orbital period of the compact object in its 26.5 day orbit around its B0 Ve star companion. The system typically presents elevated TeV emission around apastron passage with flux levels between 5\% and 15\% of the steady flux from the Crab Nebula (> 300 GeV). In this article, VERITAS observations of LS I + 61 degrees. 303 taken in late 2014 are presented, during which bright TeV flares around apastron at flux levels peaking above 30\% of the Crab Nebula flux were detected. This is the brightest such activity from this source ever seen in the TeV regime. The strong outbursts have rise and fall times of less than a day. The short timescale of the flares, in conjunction with the observation of 10 TeV photons from LS I + 61 degrees 303 during the flares, provides constraints on the properties of the accelerator in the source.}, language = {en} } @article{LeonhardtGerhardtHoeppneretal.2016, author = {Leonhardt, Helmar and Gerhardt, Matthias and Hoeppner, Nadine and Kr{\"u}ger, Kirsten and Tarantola, Marco and Beta, Carsten}, title = {Cell-substrate impedance fluctuations of single amoeboid cells encode cell-shape and adhesion dynamics}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.012414}, pages = {8}, year = {2016}, abstract = {We show systematic electrical impedance measurements of single motile cells on microelectrodes. Wild-type cells and mutant strains were studied that differ in their cell-substrate adhesion strength. We recorded the projected cell area by time-lapse microscopy and observed irregular oscillations of the cell shape. These oscillations were correlated with long-term variations in the impedance signal. Superposed to these long-term trends, we observed fluctuations in the impedance signal. Their magnitude clearly correlated with the adhesion strength, suggesting that strongly adherent cells display more dynamic cell-substrate interactions.}, language = {en} } @article{SchreckPietzschKennedyetal.2016, author = {Schreck, Simon and Pietzsch, Annette and Kennedy, Brian and Sathe, Conny and Miedema, Piter S. and Techert, Simone and Strocov, Vladimir N. and Schmitt, Thorsten and Hennies, Franz and Rubensson, Jan-Erik and F{\"o}hlisch, Alexander}, title = {Ground state potential energy surfaces around selected atoms from resonant inelastic x-ray scattering}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep20054}, pages = {7}, year = {2016}, abstract = {Thermally driven chemistry as well as materials' functionality are determined by the potential energy surface of a systems electronic ground state. This makes the potential energy surface a central and powerful concept in physics, chemistry and materials science. However, direct experimental access to the potential energy surface locally around atomic centers and to its long-range structure are lacking. Here we demonstrate how sub-natural linewidth resonant inelastic soft x-ray scattering at vibrational resolution is utilized to determine ground state potential energy surfaces locally and detect long-range changes of the potentials that are driven by local modifications. We show how the general concept is applicable not only to small isolated molecules such as O2 but also to strongly interacting systems such as the hydrogen bond network in liquid water. The weak perturbation to the potential energy surface through hydrogen bonding is observed as a trend towards softening of the ground state potential around the coordinating atom. The instrumental developments in high resolution resonant inelastic soft x-ray scattering are currently accelerating and will enable broad application of the presented approach. With this multidimensional potential energy surfaces that characterize collective phenomena such as (bio)molecular function or high-temperature superconductivity will become accessible in near future.}, language = {en} } @article{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light-the gravitational field of a laser pulse}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023009}, pages = {16}, year = {2016}, abstract = {The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources.}, language = {en} } @article{KappelArnoldHaus2016, author = {Kappel, David and Arnold, Gabriele and Haus, Rainer}, title = {Multi-spectrum retrieval of Venus IR surface emissivity maps from VIRTIS/VEX nightside measurements at Themis Regio}, series = {Icarus : international journal of solar system studies}, volume = {265}, journal = {Icarus : international journal of solar system studies}, publisher = {Elsevier}, address = {San Diego}, issn = {0019-1035}, doi = {10.1016/j.icarus.2015.10.014}, pages = {42 -- 62}, year = {2016}, abstract = {Renormalized emissivity maps of Themis Regio at the three surface windows are determined from 64 measurement repetitions. Retrieval errors are estimated by a statistical evaluation of maps derived from various disjoint selections of spectra and using different assumptions on the interfering parameters. Double standard deviation errors for the three surface windows amount to 3\%, 8\%, and 4\%, respectively, allowing geologic interpretation. A comparison to results from an earlier error analysis based on synthetic spectra shows that unconsidered time variations of interfering atmospheric parameters are a major error source. Spatial variations of the 1.02 mu m surface emissivity of 20\% that correspond to the difference between unweathered granitic and basaltic rocks would be easily detectable, but such variations are ruled out for the studied target area. Emissivity anomalies of up to 8\% are detected at both 1.02 and 1.18 mu m. At present sensitivity, no anomalies are identified at 1.10 mu m, but anomalies exceeding the determined error level can be excluded. With single standard deviation significance, all three maps show interesting spatial emissivity variations. (C) 2015 Elsevier Inc. All rights reserved.}, language = {en} } @article{GeHeYan2016, author = {Ge, J. X. and He, J. H. and Yan, Huirong}, title = {Effects of turbulent dust grain motion to interstellar chemistry}, series = {Monthly notices of the Royal Astronomical Society}, volume = {455}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stv2560}, pages = {3570 -- 3587}, year = {2016}, abstract = {Theoretical studies have revealed that dust grains are usually moving fast through the turbulent interstellar gas, which could have significant effects upon interstellar chemistry by modifying grain accretion. This effect is investigated in this work on the basis of numerical gas-grain chemical modelling. Major features of the grain motion effect in the typical environment of dark clouds (DC) can be summarized as follows: (1) decrease of gas-phase (both neutral and ionic) abundances and increase of surface abundances by up to 2-3 orders of magnitude; (2) shifts of the existing chemical jumps to earlier evolution ages for gas-phase species and to later ages for surface species by factors of about 10; (3) a few exceptional cases in which some species turn out to be insensitive to this effect and some other species can show opposite behaviours too. These effects usually begin to emerge from a typical DC model age of about 10(5) yr. The grain motion in a typical cold neutral medium (CNM) can help overcome the Coulomb repulsive barrier to enable effective accretion of cations on to positively charged grains. As a result, the grain motion greatly enhances the abundances of some gas-phase and surface species by factors up to 2-6 or more orders of magnitude in the CNM model. The grain motion effect in a typical molecular cloud (MC) is intermediate between that of the DC and CNM models, but with weaker strength. The grain motion is found to be important to consider in chemical simulations of typical interstellar medium.}, language = {en} } @article{PuhlmannHenkelHeueretal.2016, author = {Puhlmann, Dirk and Henkel, Carsten and Heuer, Axel and Pieplow, Gregor and Menzel, Ralf}, title = {Characterization of a remote optical element with bi-photons}, series = {Physica scripta : an international journal for experimental and theoretical physics}, volume = {91}, journal = {Physica scripta : an international journal for experimental and theoretical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0031-8949}, doi = {10.1088/0031-8949/91/2/023006}, pages = {113 -- 114}, year = {2016}, abstract = {We present a simple setup that exploits the interference of entangled photon pairs. 'Signal' photons are sent through a Mach-Zehnder-like interferometer, while 'idlers' are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger-Yelin-Englert inequality between contrast and predictability.}, language = {en} } @misc{Metzler2016, author = {Metzler, Ralf}, title = {PROTEIN PHYSICS Forever ageing}, series = {Nature physics}, volume = {12}, journal = {Nature physics}, publisher = {Nature Publ. Group}, address = {London}, issn = {1745-2473}, doi = {10.1038/nphys3585}, pages = {113 -- 114}, year = {2016}, abstract = {Single-molecule techniques have long given us insight into the motion and interactions of individual molecules. But simulations now show that the dynamics inside single proteins is not as simple as we thought — and that proteins are forever changing.}, language = {en} } @article{SandinSteffenSchoenberneretal.2016, author = {Sandin, C. and Steffen, M. and Schoenberner, D. and R{\"u}hling, Ute}, title = {Hot bubbles of planetary nebulae with hydrogen-deficient winds I. Heat conduction in a chemically stratified plasma}, series = {Frontiers in psychology}, volume = {586}, journal = {Frontiers in psychology}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527357}, pages = {11}, year = {2016}, abstract = {Heat conduction has been found a plausible solution to explain discrepancies between expected and measured temperatures in hot bubbles of planetary nebulae (PNe). While the heat conduction process depends on the chemical composition, to date it has been exclusively studied for pure hydrogen plasmas in PNe. A smaller population of PNe show hydrogen-deficient and helium-and carbon-enriched surfaces surrounded by bubbles of the same composition; considerable differences are expected in physical properties of these objects in comparison to the pure hydrogen case. The aim of this study is to explore how a chemistry-dependent formulation of the heat conduction affects physical properties and how it affects the X-ray emission from PN bubbles of hydrogen-deficient stars. We extend the description of heat conduction in our radiation hydrodynamics code to work with any chemical composition. We then compare the bubble-formation process with a representative PN model using both the new and the old descriptions. We also compare differences in the resulting X-ray temperature and luminosity observables of the two descriptions. The improved equations show that the heat conduction in our representative model of a hydrogen-deficient PN is nearly as efficient with the chemistry-dependent description; a lower value on the diffusion coefficient is compensated by a slightly steeper temperature gradient. The bubble becomes somewhat hotter with the improved equations, but differences are otherwise minute. The observable properties of the bubble in terms of the X-ray temperature and luminosity are seemingly unaffected.}, language = {en} } @article{CioniBekkiGirardietal.2016, author = {Cioni, Maria-Rosa L. and Bekki, Kenji and Girardi, Leo and de Grijs, Richard and Irwin, Mike J. and Ivanov, Valentin D. and Marconi, Marcella and Oliveira, Joana M. and Piatti, Andres E. and Ripepi, Vincenzo and van Loon, Jacco Th.}, title = {XVII. Proper motions of the Small Magellanic Cloud and the Milky Way globular cluster 47 Tucanae}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {586}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527004}, pages = {67 -- 75}, year = {2016}, abstract = {Aims. In this study we use multi-epoch near-infrared observations from the VISTA survey of the Magellanic Cloud system (VMC) to measure the proper motions of different stellar populations in a tile of 1.5 deg2 in size in the direction of the Galactic globular cluster 47 Tuc. We obtain the proper motion of the cluster itself, of the Small Magellanic Cloud (SMC), and of the field Milky Way stars. Methods. Stars of the three main stellar components are selected according to their spatial distributions and their distributions in colour\&\#8722;magnitude diagrams. Their average coordinate displacement is computed from the difference between multiple Ks-band observations for stars as faint as Ks = 19 mag. Proper motions are derived from the slope of the best-fitting line among ten VMC epochs over a time baseline of ~1 yr. Background galaxies are used to calibrate the absolute astrometric reference frame. Results. The resulting absolute proper motion of 47 Tuc is (\&\#956;\&\#945;cos(\&\#948;), \&\#956;\&\#948;) = (+7.26 ± 0.03, \&\#8722;1.25 ± 0.03) mas yr-1. This measurement refers to about 35 000 sources distributed between 10\&\#8242; and 60\&\#8242; from the cluster centre. For the SMC we obtain (\&\#956;\&\#945;cos(\&\#948;), \&\#956;\&\#948;) = (+1.16 ± 0.07, \&\#8722;0.81 ± 0.07) mas yr-1 from about 5250 red clump and red giant branch stars. The absolute proper motion of the Milky Way population in the line of sight (l = 305.9, b = \&\#8722;44.9) of this VISTA tile is (\&\#956;\&\#945;cos(\&\#948;), \&\#956;\&\#948;) = (+10.22 ± 0.14, \&\#8722;1.27 ± 0.12) mas yr-1 and has been calculated from about 4000 sources. Systematic uncertainties associated with the astrometric reference system are 0.18 mas yr-1. Thanks to the proper motion we detect 47 Tuc stars beyond its tidal radius.}, language = {en} } @article{KumphHenkelRabletal.2016, author = {Kumph, Muir and Henkel, Carsten and Rabl, Peter and Brownnutt, Michael and Blatt, Rainer}, title = {Electric-field noise above a thin dielectric layer on metal electrodes}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023020}, pages = {1125 -- 1136}, year = {2016}, abstract = {The electric-field noise above a layered structure composed of a planar metal electrode covered by a thin dielectric is evaluated and it is found that the dielectric film considerably increases the noise level, in proportion to its thickness. Importantly, even a thin (mono) layer of a low-loss dielectric can enhance the noise level by several orders of magnitude compared to the noise above a bare metal. Close to this layered surface, the power spectral density of the electric field varies with the inverse fourth power of the distance to the surface, rather than with the inverse square, as it would above a bare metal surface. Furthermore, compared to a clean metal, where the noise spectrum does not vary with frequency (in the radio-wave and microwave bands), the dielectric layer can generate electricfield noise which scales in inverse proportion to the frequency. For various realistic scenarios, the noise levels predicted from this model are comparable to those observed in trapped-ion experiments. Thus, these findings are of particular importance for the understanding and mitigation of unwanted heating and decoherence in miniaturized ion traps.}, language = {en} } @article{GodecMetzler2016, author = {Godec, Aljaz and Metzler, Ralf}, title = {First passage time distribution in heterogeneity controlled kinetics: going beyond the mean first passage time}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep20349}, pages = {11}, year = {2016}, abstract = {The first passage is a generic concept for quantifying when a random quantity such as the position of a diffusing molecule or the value of a stock crosses a preset threshold (target) for the first time. The last decade saw an enlightening series of new results focusing mostly on the so-called mean and global first passage time (MFPT and GFPT, respectively) of such processes. Here we push the understanding of first passage processes one step further. For a simple heterogeneous system we derive rigorously the complete distribution of first passage times (FPTs). Our results demonstrate that the typical FPT significantly differs from the MFPT, which corresponds to the long time behaviour of the FPT distribution. Conversely, the short time behaviour is shown to correspond to trajectories connecting directly from the initial value to the target. Remarkably, we reveal a previously overlooked third characteristic time scale of the first passage dynamics mirroring brief excursion away from the target.}, language = {en} } @article{ZaksTomov2016, author = {Zaks, Michael A. and Tomov, Petar}, title = {Onset of time dependence in ensembles of excitable elements with global repulsive coupling}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.020201}, pages = {5}, year = {2016}, abstract = {We consider the effect of global repulsive coupling on an ensemble of identical excitable elements. An increase of the coupling strength destabilizes the synchronous equilibrium and replaces it with many attracting oscillatory states, created in the transcritical heteroclinic bifurcation. The period of oscillations is inversely proportional to the distance from the critical parameter value. If the elements interact with the global field via the first Fourier harmonics of their phases, the stable equilibrium is in one step replaced by the attracting continuum of periodic motions.}, language = {en} } @article{SebekToenjesKiss2016, author = {Sebek, Michael and T{\"o}njes, Ralf and Kiss, Istvan Z.}, title = {Complex Rotating Waves and Long Transients in a Ring Network of Electrochemical Oscillators with Sparse Random Cross-Connections}, series = {Physical review letters}, volume = {116}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.116.068701}, pages = {3001 -- 3009}, year = {2016}, abstract = {We perform experiments and phase model simulations with a ring network of oscillatory electrochemical reactions to explore the effect of random connections and nonisochronicity of the interactions on the pattern formation. A few additional links facilitate the emergence of the fully synchronized state. With larger nonisochronicity, complex rotating waves or persistent irregular phase dynamics can derail the convergence to global synchronization. The observed long transients of irregular phase dynamics exemplify the possibility of a sudden onset of hypersynchronous behavior without any external stimulus or network reorganization.}, language = {en} } @misc{BattistonFarmerFlacheetal.2016, author = {Battiston, Stefano and Farmer, J. Doyne and Flache, Andreas and Garlaschelli, Diego and Haldane, Andrew G. and Heesterbeek, Hans and Hommes, Cars and Jaeger, Carlo and May, Robert and Scheffer, Marten}, title = {COMPLEX SYSTEMS Complexity theory and financial regulation}, series = {Science}, volume = {351}, journal = {Science}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {0036-8075}, doi = {10.1126/science.aad0299}, pages = {818 -- 819}, year = {2016}, abstract = {Traditional economic theory could not explain, much less predict, the near collapse of the financial system and its long-lasting effects on the global economy. Since the 2008 crisis, there has been increasing interest in using ideas from complexity theory to make sense of economic and financial markets. Concepts, such as tipping points, networks, contagion, feedback, and resilience have entered the financial and regulatory lexicon, but actual use of complexity models and results remains at an early stage. Recent insights and techniques offer potential for better monitoring and management of highly interconnected economic and financial systems and, thus, may help anticipate and manage future crises.}, language = {en} } @article{AbeysekaraArchambaultArcheretal.2016, author = {Abeysekara, A. U. and Archambault, S. and Archer, A. and Benbow, W. and Bird, R. and Buchovecky, M. and Buckley, J. H. and Byrum, K. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Christiansen, J. L. and Ciupik, L. and Cui, W. and Dickinson, H. J. and Eisch, J. D. and Errando, M. and Falcone, A. and Fegan, D. J. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortin, P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Huetten, M. and Hakansson, Nils and Hanna, D. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Perkins, J. S. and Petrashyk, A. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Ratliff, G. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Vincent, S. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Williams, D. A. and Zitzer, B.}, title = {A SEARCH FOR BRIEF OPTICAL FLASHES ASSOCIATED WITH THE SETI TARGET KIC 8462852}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {818}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.3847/2041-8205/818/2/L33}, pages = {6}, year = {2016}, abstract = {The F-type star KIC. 8462852 has recently been identified as an exceptional target for search for extraterrestrial intelligence (SETI) observations. We describe an analysis methodology for optical SETI, which we have used to analyze nine hours of serendipitous archival observations of KIC. 8462852 made with the VERITAS gamma-ray observatory between 2009 and 2015. No evidence of pulsed optical beacons, above a pulse intensity at the Earth of approximately 1 photon m(-2), is found. We also discuss the potential use of imaging atmospheric Cherenkov telescope arrays in searching for extremely short duration optical transients in general.}, language = {en} } @article{LiuKliemTitovetal.2016, author = {Liu, Rui and Kliem, Bernhard and Titov, Viacheslav S. and Chen, Jun and Wang, Yuming and Wang, Haimin and Liu, Chang and Xu, Yan and Wiegelmann, Thomas}, title = {STRUCTURE, STABILITY, AND EVOLUTION OF MAGNETIC FLUX ROPES FROM THE PERSPECTIVE OF MAGNETIC TWIST}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {818}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/818/2/148}, pages = {22}, year = {2016}, abstract = {We investigate the evolution of NOAA Active Region (AR) 11817 during 2013 August 10-12, when it developed a complex field configuration and produced four confined, followed by two eruptive, flares. These C-and-above flares are all associated with a magnetic flux rope (MFR) located along the major polarity inversion line, where shearing and converging photospheric flows are present. Aided by the nonlinear force-free field modeling, we identify the MFR through mapping magnetic connectivities and computing the twist number \${{ \mathcal T }}_{w}\$ for each individual field line. The MFR is moderately twisted (\$| {{ \mathcal T }}_{w}| \lt 2\$) and has a well-defined boundary of high squashing factor Q. We found that the field line with the extremum \$| {{ \mathcal T }}_{w}| \$ is a reliable proxy of the rope axis, and that the MFR's peak \$| {{ \mathcal T }}_{w}| \$ temporarily increases within half an hour before each flare while it decreases after the flare peak for both confined and eruptive flares. This pre-flare increase in \$| {{ \mathcal T }}_{w}| \$ has little effect on the AR's free magnetic energy or any other parameters derived for the whole region, due to its moderate amount and the MFR's relatively small volume, while its decrease after flares is clearly associated with the stepwise decrease in the whole region's free magnetic energy due to the flare. We suggest that \${{ \mathcal T }}_{w}\$ may serve as a useful parameter in forewarning the onset of eruption, and therefore, the consequent space weather effects. The helical kink instability is identified as the prime candidate onset mechanism for the considered flares.}, language = {en} } @article{ShiEijtSandeepetal.2016, author = {Shi, Wenqin and Eijt, Stephan W. H. and Sandeep, Chandramathi Sukumaran Suchand and Siebbeles, Laurens D. A. and Houtepen, Arjan J. and Kinge, Sachin and Bruck, Ekkes and Barbiellini, Bernardo and Bansil, Arun}, title = {Ligand-surface interactions and surface oxidation of colloidal PbSe quantum dots revealed by thin-film positron annihilation methods}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4942609}, pages = {213 -- 230}, year = {2016}, abstract = {Positron Two Dimensional Angular Correlation of Annihilation Radiation (2D-ACAR) measurements reveal modifications of the electronic structure and composition at the surfaces of PbSe quantum dots (QDs), deposited as thin films, produced by various ligands containing either oxygen or nitrogen atoms. In particular, the 2D--ACAR measurements on thin films of colloidal PbSe QDs capped with oleic acid ligands yield an increased intensity in the electron momentum density (EMD) at high momenta compared to PbSe quantum dots capped with oleylamine. Moreover, the EMD of PbSe QDs is strongly affected by the small ethylenediamine ligands, since these molecules lead to small distances between QDs and favor neck formation between near neighbor QDs, inducing electronic coupling between neighboring QDs. The high sensitivity to the presence of oxygen atoms at the surface can be also exploited to monitor the surface oxidation of PbSe QDs upon exposure to air. Our study clearly demonstrates that positron annihilation spectroscopy applied to thin films can probe surface transformations of colloidal semiconductor QDs embedded in functional layers. (C) 2016 AIP Publishing LLC.}, language = {en} } @article{LenskeWagnerWirthetal.2016, author = {Lenske, Gerlinde and Wagner, Wolfgang and Wirth, Joachim and Thillmann, Hubertina and Cauet, Eva and Liepertz, Sven and Leutner, Detlev}, title = {The importance of pedagogical knowledge for classroom management and for and for students' achievement}, series = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, volume = {19}, journal = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, publisher = {Springer}, address = {Wiesbaden}, issn = {1434-663X}, doi = {10.1007/s11618-015-0659-x}, pages = {211 -- 233}, year = {2016}, abstract = {Im Rahmen der vorliegenden Studie wurde untersucht, ob das p{\"a}dagogisch-psychologische Wissen von Lehrkr{\"a}ften die prozessuale Qualit{\"a}t des Physikunterrichts mit Blick auf die Klassenf{\"u}hrung und den Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler beeinflusst. Das p{\"a}dagogisch-psychologische Professionswissen, konzeptualisiert als ein f{\"a}cher{\"u}bergreifendes, handlungsleitendes Wissen {\"u}ber Strategien und Mittel zur Unterrichtsgestaltung, wurde {\"u}ber einen Paper-Pencil-Test, bestehend aus einer Skala zum deklarativen und einer Skala zum konditional-prozeduralen Wissen erhoben (Lenske et al. 2015). Als ein grundlegendes Merkmal prozessualer Unterrichtsqualit{\"a}t wurde die Klassenf{\"u}hrung anhand von Videoratings zu zwei Messzeitpunkten (zwei Unterrichtsstunden) erfasst. Der Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler wurde {\"u}ber standardisierte Fachwissenstests im Pr{\"a}-Post-Testdesign gemessen. Die Stichprobe umfasst 34 Gymnasiallehrkr{\"a}fte und deren Sch{\"u}lerinnen und Sch{\"u}ler (N = 993). Auf Basis eines Complex-Bootstrap-Mediations-Modells zeigte sich, dass das p{\"a}dagogisch-psychologische Professionswissen {\"u}ber die Klassenf{\"u}hrung vermittelt den Lernzuwachs der Sch{\"u}ler und Sch{\"u}lerinnen positiv beeinflusst. In the present study it was investigated whether the pedagogical knowledge of teachers has an influence on the process quality of physics instruction and on the learning achievement of students as well. Pedagogical knowledge, conceptualized as knowledge about strategies in classroom instruction that is domain-general and relevant for teaching behaviors, was measured using a paper-and-pencil test with two scales: one scale on declarative knowledge, the other on conditional-procedural knowledge (Lenske et al. 2015). As a basic aspect of the process quality of classroom instruction, classroom management was assessed using video ratings of two lessons from each participating teacher. Students' learning achievement was assessed using standardized domain-specific knowledge tests in a pretest-posttest design. The sample included 34 teachers from higher-track secondary schools and their students (N = 993). A complex bootstrapping mediation model shows that teachers' pedagogical knowledge, mediated by their classroom management, has a positive effect on their students' learning achievement.}, language = {de} } @article{ReinhardtKocLeitenbergeretal.2016, author = {Reinhardt, Matthias and Koc, Azize and Leitenberger, Wolfram and Gaal, Peter and Bargheer, Matias}, title = {Optimized spatial overlap in optical pump-X-ray probe experiments with high repetition rate using laser-induced surface distortions}, series = {Journal of synchrotron radiation}, volume = {23}, journal = {Journal of synchrotron radiation}, publisher = {International Union of Crystallography}, address = {Chester}, issn = {1600-5775}, doi = {10.1107/S1600577515024443}, pages = {474 -- 479}, year = {2016}, abstract = {Ultrafast X-ray diffraction experiments require careful adjustment of the spatial overlap between the optical excitation and the X-ray probe pulse. This is especially challenging at high laser repetition rates. Sample distortions caused by the large heat load on the sample and the relatively low optical energy per pulse lead to only tiny signal changes. In consequence, this results in small footprints of the optical excitation on the sample, which turns the adjustment of the overlap difficult. Here a method for reliable overlap adjustment based on reciprocal space mapping of a laser excited thin film is presented.}, language = {en} } @article{EckertMiedemaQuevedoetal.2016, author = {Eckert, Sebastian and Miedema, P. S. and Quevedo, W. and Fondell, Mattis and Beye, Martin and Pietzsch, Annette and Ross, M. and Khalil, M. and F{\"o}hlisch, Alexander}, title = {Molecular structures and protonation state of 2-Mercaptopyridine in aqueous solution}, series = {Chemical physics letters}, volume = {647}, journal = {Chemical physics letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0009-2614}, doi = {10.1016/j.cplett.2016.01.050}, pages = {103 -- 106}, year = {2016}, abstract = {The speciation of 2-Mercaptopyridine in aqueous solution has been investigated with nitrogen 1s Near Edge X-ray Absorption Fine Structure spectroscopy and time dependent Density Functional Theory. The prevalence of distinct species as a function of the solvent basicity is established. No indications of dimerization towards high concentrations are found. The determination of different molecular structures of 2-Mercaptopyridine in aqueous solution is put into the context of proton-transfer in keto-enol and thione-thiol tautomerisms. (C) 2016 The Authors. Published by Elsevier B.V.}, language = {en} } @article{WenzKalkuhlSteckeletal.2016, author = {Wenz, Leonie and Kalkuhl, Matthias and Steckel, Jan Christoph and Creutzig, Felix}, title = {Teleconnected food supply shocks}, series = {Environmental research letters}, volume = {11}, journal = {Environmental research letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1748-9326}, doi = {10.1088/1748-9326/11/3/035007}, pages = {10}, year = {2016}, abstract = {The 2008-2010 food crisis might have been a harbinger of fundamental climate-induced food crises with geopolitical implications. Heat-wave-induced yield losses in Russia and resulting export restrictions led to increases in market prices for wheat across the Middle East, likely contributing to the Arab Spring. With ongoing climate change, temperatures and temperature variability will rise, leading to higher uncertainty in yields for major nutritional crops. Here we investigate which countries are most vulnerable to teleconnected supply-shocks, i.e. where diets strongly rely on the import of wheat, maize, or rice, and where a large share of the population is living in poverty. We find that the Middle East is most sensitive to teleconnected supply shocks in wheat, Central America to supply shocks in maize, and Western Africa to supply shocks in rice. Weighing with poverty levels, Sub-Saharan Africa is most affected. Altogether, a simultaneous 10\% reduction in exports of wheat, rice, and maize would reduce caloric intake of 55 million people living in poverty by about 5\%. Export bans in major producing regions would put up to 200 million people below the poverty line at risk, 90\% of which live in Sub-Saharan Africa. Our results suggest that a region-specific combination of national increases in agricultural productivity and diversification of trade partners and diets can effectively decrease future food security risks.}, language = {en} } @article{WisotzkiBaconBlaizotetal.2016, author = {Wisotzki, Lutz and Bacon, Roland and Blaizot, J. and Brinchmann, Jarle and Herenz, Edmund Christian and Schaye, Joop and Bouche, Nicolas and Cantalupo, Sebastiano and Contini, Thierry and Carollo, C. M. and Caruana, Joseph and Courbot, J. -B. and Emsellem, E. and Kamann, S. and Kerutt, Josephine Victoria and Leclercq, F. and Lilly, S. J. and Patricio, V. and Sandin, C. and Steinmetz, Matthias and Straka, Lorrie A. and Urrutia, Tanya and Verhamme, A. and Weilbacher, Peter Michael and Wendt, Martin}, title = {Extended Lyman alpha haloes around individual high-redshift galaxies revealed by MUSE}, series = {Science}, volume = {587}, journal = {Science}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527384}, pages = {27}, year = {2016}, abstract = {We report the detection of extended Ly alpha emission around individual star-forming galaxies at redshifts z = 3-6 in an ultradeep exposure of the Hubble Deep Field South obtained with MUSE on the ESO-VLT. The data reach a limiting surface brightness (1 sigma) of similar to 1 x 10(-19) erg s(-1) cm(-2) arcsec(-2) in azimuthally averaged radial profiles, an order of magnitude improvement over previous narrowband imaging. Our sample consists of 26 spectroscopically confirmed Ly alpha-emitting, but mostly continuum-faint (m(AB) greater than or similar to 27) galaxies. In most objects the Ly alpha emission is considerably more extended than the UV continuum light. While five of the faintest galaxies in the sample show no significantly detected Ly alpha haloes, the derived upper limits suggest that this is due to insufficient S/N. Ly alpha haloes therefore appear to be ubiquitous even for low-mass (similar to 10(8)-10(9) M-circle dot) star-forming galaxies at z > 3. We decompose the Ly alpha emission of each object into a compact component tracing the UV continuum and an extended halo component, and infer sizes and luminosities of the haloes. The extended Ly alpha emission approximately follows an exponential surface brightness distribution with a scale length of a few kpc. While these haloes are thus quite modest in terms of their absolute sizes, they are larger by a factor of 5-15 than the corresponding rest-frame UV continuum sources as seen by HST. They are also much more extended, by a factor similar to 5, than Ly alpha haloes around low-redshift star-forming galaxies. Between similar to 40\% and greater than or similar to 90\% of the observed Ly alpha flux comes from the extended halo component, with no obvious correlation of this fraction with either the absolute or the relative size of the Ly alpha halo. Our observations provide direct insights into the spatial distribution of at least partly neutral gas residing in the circumgalactic medium of low to intermediate mass galaxies at z > 3.}, language = {en} } @article{PrzybillaFossatiHubrigetal.2016, author = {Przybilla, Norbert and Fossati, Luca and Hubrig, Swetlana and Nieva, M. -F. and Jaervinen, S. P. and Castro, Norberto and Schoeller, M. and Ilyin, Ilya and Butler, Keith and Schneider, F. R. N. and Oskinova, Lida and Morel, T. and Langer, N. and de Koter, A.}, title = {B fields in OB stars (BOB): Detection of a magnetic field in the He-strong star CPD-57 degrees 3509}, series = {Organic letters}, volume = {587}, journal = {Organic letters}, publisher = {EDP Sciences}, address = {Les Ulis}, organization = {BOB Collaboratio}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527646}, pages = {15}, year = {2016}, abstract = {Methods. Spectropolarimetric observations with FORS2 and HARPSpol are analysed using two independent approaches to quantify the magnetic field strength. A high-S/N FLAMES/GIRAFFE spectrum is analysed using a hybrid non-LTE model atmosphere technique. Comparison with stellar evolution models constrains the fundamental parameters of the star. Results. We obtain a firm detection of a surface averaged longitudinal magnetic field with a maximum amplitude of about 1 kG. Assuming a dipolar configuration of the magnetic field, this implies a dipolar field strength larger than 3.3 kG. Moreover, the large amplitude and fast variation (within about 1 day) of the longitudinal magnetic field implies that CPD-57 degrees 3509 is spinning very fast despite its apparently slow projected rotational velocity. The star should be able to support a centrifugal magnetosphere, yet the spectrum shows no sign of magnetically confined material; in particular, emission in H alpha is not observed. Apparently, the wind is either not strong enough for enough material to accumulate in the magnetosphere to become observable or, alternatively, some leakage process leads to loss of material from the magnetosphere. The quantitative spectroscopic analysis of the star yields an effective temperature and a logarithmic surface gravity of 23 750 +/- 250 K and 4.05 +/- 0.10, respectively, and a surface helium fraction of 0.28 +/- 0.02 by number. The surface abundances of C, N, O, Ne, S, and Ar are compatible with the cosmic abundance standard, whereas Mg, Al, Si, and Fe are depleted by about a factor of 2. This abundance pattern can be understood as the consequence of a fractionated stellar wind. CPD-57 degrees 3509 is one of the most evolved He-strong stars known with an independent age constraint due to its cluster membership.}, language = {en} } @misc{BarniskeOskinovaHamann2016, author = {Barniske, Andreas and Oskinova, Lida and Hamann, Wolf-Rainer}, title = {Two extremely luminous WN stars in the Galactic center with circumstellar emission from dust and gas (vol 486, pg 971, 2008)}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {587}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/200809568e}, pages = {1}, year = {2016}, language = {en} } @article{Kuznetsov2016, author = {Kuznetsov, Sergey P.}, title = {Parametric chaos generator operating on a varactor diode with the instability limitation decay mechanism}, series = {Technical Physics}, volume = {61}, journal = {Technical Physics}, publisher = {Pleiades Publ.}, address = {New York}, issn = {1063-7842}, doi = {10.1134/S1063784216030129}, pages = {436 -- 445}, year = {2016}, abstract = {Equations are derived for a parametric chaos generator containing three oscillatory circuits and a variable-capacitance diode (varactor) and are reduced to equations for slow amplitudes of parametrically interacting modes. With allowance for quadratic nonlinearity, the problem is reduced to a system of three first-order differential equations for Pikovsky-Rabinovich-Trakhtengerts real amplitudes with a Lorenz-type attractor. In a more accurate description of nonlinearity of the varactor, the equations for slow amplitudes are complex-valued, which leads to the loss of robustness of chaotic dynamics, which is typical of the Lorenz attractor. The results of numerical calculations (portraits of attractors and Lyapunov exponents) in models with different approximation levels are compared.}, language = {en} } @article{ZehbeKolloscheLardongetal.2016, author = {Zehbe, Kerstin and Kollosche, Matthias and Lardong, Sebastian and Kelling, Alexandra and Schilde, Uwe and Taubert, Andreas}, title = {Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties}, series = {International journal of molecular sciences}, volume = {17}, journal = {International journal of molecular sciences}, publisher = {MDPI}, address = {Basel}, issn = {1422-0067}, doi = {10.3390/ijms17030391}, pages = {16}, year = {2016}, abstract = {Ionogels (IGs) based on poly(methyl methacrylate) (PMMA) and the metal-containing ionic liquids (ILs) bis-1-butyl-3-methlimidazolium tetrachloridocuprate(II), tetrachloride cobaltate(II), and tetrachlorido manganate(II) have been synthesized and their mechanical and electrical properties have been correlated with their microstructure. Unlike many previous examples, the current IGs show a decreasing stability in stress-strain experiments on increasing IL fractions. The conductivities of the current IGs are lower than those observed in similar examples in the literature. Both effects are caused by a two-phase structure with micrometer-sized IL-rich domains homogeneously dispersed an IL-deficient continuous PMMA phase. This study demonstrates that the IL-polymer miscibility and the morphology of the IGs are key parameters to control the (macroscopic) properties of IGs.}, language = {en} } @article{BolotovOsipovPikovskij2016, author = {Bolotov, M. I. and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Marginal chimera state at cross-frequency locking of pulse-coupled neural networks}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.032202}, pages = {6}, year = {2016}, abstract = {We consider two coupled populations of leaky integrate-and-fire neurons. Depending on the coupling strength, mean fields generated by these populations can have incommensurate frequencies or become frequency locked. In the observed 2:1 locking state of the mean fields, individual neurons in one population are asynchronous with the mean fields, while in another population they have the same frequency as the mean field. These synchronous neurons form a chimera state, where part of them build a fully synchronized cluster, while other remain scattered. We explain this chimera as a marginal one, caused by a self-organized neutral dynamics of the effective circle map.}, language = {en} } @misc{Goychuk2016, author = {Goychuk, Igor}, title = {Molecular machines operating on the nanoscale: from classical to quantum}, series = {Beilstein journal of nanotechnology}, volume = {7}, journal = {Beilstein journal of nanotechnology}, publisher = {Beilstein-Institut zur F{\~A}\Prderung der Chemischen Wissenschaften}, address = {Frankfurt, Main}, issn = {2190-4286}, doi = {10.3762/bjnano.7.31}, pages = {328 -- 350}, year = {2016}, abstract = {The main physical features and operating principles of isothermal nanomachines in the microworld, common to both classical and quantum machines, are reviewed. Special attention is paid to the dual, constructive role of dissipation and thermal fluctuations, the fluctuation-dissipation theorem, heat losses and free energy transduction, thermodynamic efficiency, and thermodynamic efficiency at maximum power. Several basic models are considered and discussed to highlight generic physical features. This work examines some common fallacies that continue to plague the literature. In particular, the erroneous beliefs that one should minimize friction and lower the temperature for high performance of Brownian machines, and that the thermodynamic efficiency at maximum power cannot exceed one-half are discussed. The emerging topic of anomalous molecular motors operating subdiffusively but very efficiently in the viscoelastic environment of living cells is also discussed.}, language = {en} } @article{TomovPenaRoqueetal.2016, author = {Tomov, Peter and Pena, Rodrigo F. O. and Roque, Antonio C. and Zaks, Michael A.}, title = {Mechanisms of Self-Sustained Oscillatory States in Hierarchical Modular Networks with Mixtures of Electrophysiological Cell Types}, series = {Frontiers in computational neuroscience / Frontiers Research Foundation}, volume = {10}, journal = {Frontiers in computational neuroscience / Frontiers Research Foundation}, publisher = {Frontiers Research Foundation}, address = {Lausanne}, organization = {HESS Collaboration}, issn = {1662-5188}, doi = {10.3389/fncom.2016.00023}, pages = {476 -- +}, year = {2016}, abstract = {In a network with a mixture of different electrophysiological types of neurons linked by excitatory and inhibitory connections, temporal evolution leads through repeated epochs of intensive global activity separated by intervals with low activity level. This behavior mimics "up" and "down" states, experimentally observed in cortical tissues in absence of external stimuli. We interpret global dynamical features in terms of individual dynamics of the neurons. In particular, we observe that the crucial role both in interruption and in resumption of global activity is played by distributions of the membrane recovery variable within the network. We also demonstrate that the behavior of neurons is more influenced by their presynaptic environment in the network than by their formal types, assigned in accordance with their response to constant current.}, language = {en} } @article{PaulkeStranksKniepertetal.2016, author = {Paulke, Andreas and Stranks, Samuel D. and Kniepert, Juliane and Kurpiers, Jona and Wolff, Christian Michael and Sch{\"o}n, Natalie and Snaith, Henry J. and Brenner, Thomas J. K. and Neher, Dieter}, title = {Charge carrier recombination dynamics in perovskite and polymer solar cells}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4944044}, pages = {252 -- 262}, year = {2016}, abstract = {Time-delayed collection field experiments are applied to planar organometal halide perovskite (CH3NH3PbI3) based solar cells to investigate charge carrier recombination in a fully working solar cell at the nanosecond to microsecond time scale. Recombination of mobile (extractable) charges is shown to follow second-order recombination dynamics for all fluences and time scales tested. Most importantly, the bimolecular recombination coefficient is found to be time-dependent, with an initial value of ca. 10(-9) cm(3)/s and a progressive reduction within the first tens of nanoseconds. Comparison to the prototypical organic bulk heterojunction device PTB7:PC71BM yields important differences with regard to the mechanism and time scale of free carrier recombination. (C) 2016 AIP Publishing LLC.}, language = {en} } @article{AbramowskiAharonianBenkhalietal.2016, author = {Abramowski, Attila and Aharonian, Felix A. and Benkhali, Faical Ait and Akhperjanian, A. G. and Ang{\"u}ner, Ekrem Oǧuzhan and Backes, Michael and Balzer, Arnim and Becherini, Yvonne and Tjus, J. Becker and Berge, David and Bernhard, Sabrina and Bernl{\"o}hr, K. and Birsin, E. and Blackwell, R. and Boettcher, Markus and Boisson, Catherine and Bolmont, J. and Bordas, Pol and Bregeon, Johan and Brun, Francois and Brun, Pierre and Bryan, Mark and Bulik, Tomasz and Carr, John and Casanova, Sabrina and Chakraborty, N. and Chalme-Calvet, R. and Chaves, Ryan C. G. and Chen, Andrew and Chretien, M. and Colafrancesco, Sergio and Cologna, Gabriele and Conrad, Jan and Couturier, C. and Cui, Y. and Davids, I. D. and Degrange, B. and Deil, C. and deWilt, P. and Djannati-Ata, A. and Domainko, W. and Donath, A. and Dubus, G. and Dutson, K. and Dyks, J. and Dyrda, M. and Edwards, T. and Egberts, Kathrin and Eger, P. and Ernenwein, J-P. and Espigat, P. and Farnier, C. and Fegan, S. and Feinstein, F. and Fernandes, M. V. and Fernandez, D. and Fiasson, A. and Fontaine, G. and Foerster, A. and Fuessling, M. and Gabici, S. and Gajdus, M. and Gallant, Y. A. and Garrigoux, T. and Giavitto, G. and Giebels, B. and Glicenstein, J. F. and Gottschall, D. and Goyal, A. and Grondin, M-H. and Grudzinska, M. and Hadasch, D. and Haeffner, S. and Hahn, J. and Hawkes, J. and Heinzelmann, G. and Henri, G. and Hermann, G. and Hervet, O. and Hillert, A. and Hinton, James Anthony and Hofmann, W. and Hofverberg, P. and Hoischen, Clemens and Holler, M. and Horns, D. and Ivascenko, A. and Jacholkowska, A. and Jamrozy, M. and Janiak, M. and Jankowsky, F. and Jung-Richardt, I. and Kastendieck, M. A. and Katarzynski, K. and Katz, U. and Kerszberg, D. and Khelifi, B. and Kieffer, M. and Klepser, S. and Klochkov, D. and Kluzniak, W. and Kolitzus, D. and Komin, Nu. and Kosack, K. and Krakau, S. and Krayzel, F. and Krueger, P. P. and Laffon, H. and Lamanna, G. and Lau, J. and Lefaucheur, J. and Lefranc, V. and Lemiere, A. and Lemoine-Goumard, M. and Lenain, J-P. and Lohse, T. and Lopatin, A. and Lu, C-C. and Lui, R. and Marandon, V. and Marcowith, Alexandre and Mariaud, C. and Marx, R. and Maurin, G. and Maxted, N. and Mayer, M. and Meintjes, P. J. and Menzler, U. and Meyer, M. and Mitchell, A. M. W. and Moderski, R. and Mohamed, M. and Mora, K. and Moulin, Emmanuel and Murach, T. and de Naurois, M. and Niemiec, J. and Oakes, L. and Odaka, H. and Oettl, S. and Ohm, S. and Opitz, B. and Ostrowski, M. and Oya, I. and Panter, M. and Parsons, R. D. and Arribas, M. Paz and Pekeur, N. W. and Pelletier, G. and Petrucci, P-O. and Peyaud, B. and Pita, S. and Poon, H. and Prokoph, H. and Puehlhofer, G. and Punch, M. and Quirrenbach, A. and Raab, S. and Reichardt, I. and Reimer, A. and Reimer, O. and Renaud, M. and de los Reyes, R. and Rieger, F. and Romoli, C. and Rosier-Lees, S. and Rowell, G. and Rudak, B. and Rulten, C. B. and Sahakian, V. and Salek, D. and Sanchez, David M. and Santangelo, A. and Sasaki, M. and Schlickeiser, R. and Schuessler, F. and Schulz, A. and Schwanke, U. and Schwemmer, S. and Seyffert, A. S. and Simoni, R. and Sol, H. and Spanier, F. and Spengler, G. and Spies, F. and Stawarz, L. and Steenkamp, R. and Stegmann, Christian and Stinzing, F. and Stycz, K. and Sushch, Iurii and Tavernet, J-P. and Tavernier, T. and Taylor, A. M. and Terrier, R. and Tluczykont, M. and Trichard, C. and Tuffs, R. and Valerius, K. and van der Walt, J. and van Eldik, C. and van Soelen, B. and Vasileiadis, G. and Veh, J. and Venter, C. and Viana, A. and Vincent, P. and Vink, J. and Voisin, F. and Voelk, H. J. and Vuillaume, T. and Wagner, S. J. and Wagner, P. and Wagner, R. M. and Weidinger, M. and Weitzel, Q. and White, R. and Wierzcholska, A. and Willmann, P. and Woernlein, A. and Wouters, D. and Yang, R. and Zabalza, V. and Zaborov, D. and Zacharias, M. and Zdziarski, A. A. and Zech, Alraune and Zefi, F. and Zywucka, N.}, title = {Acceleration of petaelectronvolt protons in the Galactic Centre}, series = {Nature : the international weekly journal of science}, volume = {531}, journal = {Nature : the international weekly journal of science}, publisher = {Nature Publ. Group}, address = {London}, organization = {HESS Collaboration}, issn = {0028-0836}, doi = {10.1038/nature17147}, pages = {476 -- +}, year = {2016}, abstract = {Galactic cosmic rays reach energies of at least a few petaelectronvolts (of the order of 1015 electronvolts). This implies that our Galaxy contains petaelectronvolt accelerators ('PeVatrons'), but all proposed models of Galactic cosmic-ray accelerators encounter difficulties at exactly these energies. Dozens of Galactic accelerators capable of accelerating particles to energies of tens of teraelectronvolts (of the order of 1013 electronvolts) were inferred from recent \&\#947;-ray observations3. However, none of the currently known accelerators—not even the handful of shell-type supernova remnants commonly believed to supply most Galactic cosmic rays—has shown the characteristic tracers of petaelectronvolt particles, namely, power-law spectra of \&\#947;-rays extending without a cut-off or a spectral break to tens of teraelectronvolts4. Here we report deep \&\#947;-ray observations with arcminute angular resolution of the region surrounding the Galactic Centre, which show the expected tracer of the presence of petaelectronvolt protons within the central 10 parsecs of the Galaxy. We propose that the supermassive black hole Sagittarius A* is linked to this PeVatron. Sagittarius A* went through active phases in the past, as demonstrated by X-ray outbursts5and an outflow from the Galactic Centre6. Although its current rate of particle acceleration is not sufficient to provide a substantial contribution to Galactic cosmic rays, Sagittarius A* could have plausibly been more active over the last 106-107 years, and therefore should be considered as a viable alternative to supernova remnants as a source of petaelectronvolt Galactic cosmic rays.}, language = {en} } @article{KegelesOriti2016, author = {Kegeles, Alexander and Oriti, Daniele}, title = {Generalized conservation laws in non-local field theories}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {49}, journal = {Journal of physics : A, Mathematical and theoretical}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8113/49/13/135401}, pages = {119 -- 134}, year = {2016}, abstract = {We propose a geometrical treatment of symmetries in non-local field theories, where the non-locality is due to a lack of identification of field arguments in the action. We show that the existence of a symmetry of the action leads to a generalized conservation law, in which the usual conserved current acquires an additional non-local correction term, obtaining a generalization of the standard Noether theorem. We illustrate the general formalism by discussing the specific physical example of complex scalar field theory of the type describing the hydrodynamic approximation of Bose-Einstein condensates. We expect our analysis and results to be of particular interest for the group field theory formulation of quantum gravity.}, language = {en} } @article{ClarkShakunMarcottetal.2016, author = {Clark, Peter U. and Shakun, Jeremy D. and Marcott, Shaun A. and Mix, Alan C. and Eby, Michael and Kulp, Scott and Levermann, Anders and Milne, Glenn A. and Pfister, Patrik L. and Santer, Benjamin D. and Schrag, Daniel P. and Solomon, Susan and Stocker, Thomas F. and Strauss, Benjamin H. and Weaver, Andrew J. and Winkelmann, Ricarda and Archer, David and Bard, Edouard and Goldner, Aaron and Lambeck, Kurt and Pierrehumbert, Raymond T. and Plattner, Gian-Kasper}, title = {Consequences of twenty-first-century policy for multi-millennial climate and sea-level change}, series = {Nature climate change}, volume = {6}, journal = {Nature climate change}, publisher = {Nature Publ. Group}, address = {London}, issn = {1758-678X}, doi = {10.1038/NCLIMATE2923}, pages = {360 -- 369}, year = {2016}, abstract = {Most of the policy debate surrounding the actions needed to mitigate and adapt to anthropogenic climate change has been framed by observations of the past 150 years as well as climate and sea-level projections for the twenty-first century. The focus on this 250-year window, however, obscures some of the most profound problems associated with climate change. Here, we argue that the twentieth and twenty-first centuries, a period during which the overwhelming majority of human-caused carbon emissions are likely to occur, need to be placed into a long-term context that includes the past 20 millennia, when the last Ice Age ended and human civilization developed, and the next ten millennia, over which time the projected impacts of anthropogenic climate change will grow and persist. This long-term perspective illustrates that policy decisions made in the next few years to decades will have profound impacts on global climate, ecosystems and human societies - not just for this century, but for the next ten millennia and beyond.}, language = {en} } @article{YangGuehrVecchioneetal.2016, author = {Yang, Jie and G{\"u}hr, Markus and Vecchione, Theodore and Robinson, Matthew Scott and Li, Renkai and Hartmann, Nick and Shen, Xiaozhe and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Gaffney, Kelly and Gorkhover, Tais and Hast, Carsten and Jobe, Keith and Makasyuk, Igor and Reid, Alexander and Robinson, Joseph and Vetter, Sharon and Wang, Fenglin and Weathersby, Stephen and Yoneda, Charles and Centurion, Martin and Wang, Xijie}, title = {Diffractive imaging of a rotational wavepacket in nitrogen molecules with femtosecond megaelectronvolt electron pulses}, series = {Nature Communications}, volume = {7}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/ncomms11232}, pages = {9}, year = {2016}, abstract = {Imaging changes in molecular geometries on their natural femtosecond timescale with sub-Angstrom spatial precision is one of the critical challenges in the chemical sciences, as the nuclear geometry changes determine the molecular reactivity. For photoexcited molecules, the nuclear dynamics determine the photoenergy conversion path and efficiency. Here we report a gas-phase electron diffraction experiment using megaelectronvolt (MeV) electrons, where we captured the rotational wavepacket dynamics of nonadiabatically laser-aligned nitrogen molecules. We achieved a combination of 100 fs root-mean-squared temporal resolution and sub-Angstrom (0.76 angstrom) spatial resolution that makes it possible to resolve the position of the nuclei within the molecule. In addition, the diffraction patterns reveal the angular distribution of the molecules, which changes from prolate (aligned) to oblate (anti-aligned) in 300 fs. Our results demonstrate a significant and promising step towards making atomically resolved movies of molecular reactions.}, language = {en} } @article{NishikawaFrederiksenNordlundetal.2016, author = {Nishikawa, Ken-Ichi and Frederiksen, J. T. and Nordlund, A. and Mizuno, Y. and Hardee, P. E. and Niemiec, J. and Gomez, J. L. and Dutan, I. and Meli, A. and Sol, H. and Pohl, Martin and Hartmann, D. H.}, title = {EVOLUTION OF GLOBAL RELATIVISTIC JETS: COLLIMATIONS AND EXPANSION WITH kKHI AND THE WEIBEL INSTABILITY}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {820}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/820/2/94}, pages = {14}, year = {2016}, abstract = {In the study of relativistic jets one of the key open questions is their interaction with the environment. Here. we study the initial evolution of both electron-proton (e(-) - p(+)) and electron-positron (e(+/-)) relativistic jets, focusing on their lateral interaction with ambient plasma. We follow the evolution of toroidal magnetic fields generated by both the kinetic Kelvin-Helmholtz and Mushroom instabilities. For an e(-) - p(+) jet, the induced magnetic field collimates the jet and electrons are perpendicularly accelerated. As the instabilities saturate and subsequently weaken, the magnetic polarity switches from clockwise to counterclockwise in the middle of the jet. For an e(+/-) jet, we find strong mixing of electrons and positrons with the ambient plasma, resulting in the creation of a bow shock. The merging of current filaments generates density inhomogeneities that. initiate a forward shock. Strong jet-ambient plasma mixing prevents a full development of the jet (on the scale studied), revealing evidence for both jet collimation and particle acceleration in the forming bow shock. Differences in the magnetic field structure generated by e(-) - p(+) and e(+/-) jets may contribute to the polarization properties of the observed emission in AGN jets and gamma-ray bursts.}, language = {en} } @article{BoucheFinleySchroetteretal.2016, author = {Bouche, Nicolas and Finley, H. and Schroetter, I. and Murphy, M. T. and Richter, Philipp and Bacon, Roland and Contini, Thierry and Richard, J. and Wendt, Martin and Kamann, S. and Epinat, Benoit and Cantalupo, Sebastiano and Straka, Lorrie A. and Schaye, Joop and Martin, C. L. and Peroux, C. and Wisotzki, Lutz and Soto, K. and Lilly, S. and Carollo, C. M. and Brinchmann, Jarle and Kollatschny, W.}, title = {POSSIBLE SIGNATURES OF A COLD-FLOW DISK FROM MUSE USING A z similar to 1 GALAXY-QUASAR PAIR TOWARD SDSS J1422-0001}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {820}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/820/2/121}, pages = {1872 -- 1882}, year = {2016}, abstract = {We use a background quasar to detect the presence of circumgalactic gas around a z = 0.91 low-mass star-forming galaxy. Data from the new Multi Unit Spectroscopic Explorer (MUSE) on the Very Large Telescope show that the galaxy has a dust-corrected star formation rate (SFR) of 4.7 +/- 2.0. M-circle dot yr(-1), with no companion down to 0.22 M-circle dot yr(-1) (5 sigma) within 240 h(-1) kpc ("30"). Using a high-resolution spectrum of the background quasar, which is fortuitously aligned with the galaxy major axis (with an azimuth angle alpha of only 15 degrees), we find, in the gas kinematics traced by low-ionization lines, distinct signatures consistent with those expected for a "cold-flow disk" extending at least 12 kpc (3 x R-1/2). We estimate the mass accretion rate M-in to be at least two to three times larger than the SFR, using the geometric constraints from the IFU data and the H (I) column density of log N-H (I)/cm(-2) similar or equal to 20.4 obtained from a Hubble Space Telescope/COS near-UV spectrum. From a detailed analysis of the low-ionization lines (e.g., Zn II, Cr II, Ti II, MnII, Si II), the accreting material appears to be enriched to about 0.4 Z(circle dot) (albeit with large uncertainties: log Z/Z(circle dot) = -0.4 +/- 0.4), which is comparable to the galaxy metallicity (12 + log O/H = 8.7 +/- 0.2), implying a large recycling fraction from past outflows. Blueshifted Mg II and Fe II absorptions in the galaxy spectrum from the MUSE data reveal the presence of an outflow. The Mg II and Fe II absorption line ratios indicate emission infilling due to scattering processes, but the MUSE data do not show any signs of fluorescent Fe II* emission.}, language = {en} } @article{SteinkeOskinovaHamannetal.2016, author = {Steinke, Martin and Oskinova, Lida and Hamann, Wolf-Rainer and Sander, Andreas Alexander Christoph and Liermann, A. and Todt, Helge Tobias}, title = {Analysis of the WN star WR102c, its WR nebula, and the associated cluster of massive stars in the Sickle Nebula}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {588}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527692}, pages = {10}, year = {2016}, abstract = {Context. The massive Wolf-Rayet type star WR102c is located near the Quintuplet Cluster, one of the three massive star clusters in the Galactic centre region. Previous studies indicated that WR102c may have a dusty circumstellar nebula and is among the main ionising sources of the Sickle Nebula associated with the Quintuplet Cluster. Aims. The goals of our study are to derive the stellar parameters of WR102c from the analysis of its spectrum and to investigate its stellar and nebular environment. Methods. We obtained observations with the ESO VLT integral field spectrograph SINFONI in the K-band, extracted the stellar spectra, and analysed them by means of stellar atmosphere models. Results. Our new analysis supersedes the results previously reported for WR102c. We significantly decrease its bolometric luminosity and hydrogen content. We detect four early OB type stars close to WR102c. These stars have radial velocities similar to that of WR102c. We suggest that together with WR102c these stars belong to a distinct star cluster with a total mass of similar to 1000 M-circle dot. We identify a new WR nebula around WR102c in the SINFONI map of the di ff use Br gamma emission and in the HST Pa ff images. The Br gamma line at di ff erent locations is not significantly broadened and similar to the width of nebular emission elsewhere in the H i i region around WR102c. Conclusions. The massive star WR102c located in the Galactic centre region resides in a star cluster containing additional early-type stars. The stellar parameters of WR102c are typical for hydrogen-free WN6 stars. We identify a nebula surrounding WR102c that has a morphology similar to other nebulae around hydrogen-free WR stars, and propose that the formation of this nebula is linked to interaction of the fast stellar wind with the matter ejected at a previous evolutionary stage of WR102c.}, language = {en} } @article{KamannHusserBrinchmannetal.2016, author = {Kamann, S. and Husser, T. -O. and Brinchmann, Jarle and Emsellem, E. and Weilbacher, Peter Michael and Wisotzki, Lutz and Wendt, Martin and Krajnovic, D. and Roth, M. M. and Bacon, Roland and Dreizler, S.}, title = {MUSE crowded field 3D spectroscopy of over 12 000 stars in the globular cluster NGC 6397}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {588}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527065}, pages = {12}, year = {2016}, abstract = {We present a detailed analysis of the kinematics of the Galactic globular cluster NGC 6397 based on more than similar to 18 000 spectra obtained with the novel integral field spectrograph MUSE. While NGC 6397 is often considered a core collapse cluster, our analysis suggests a flattening of the surface brightness profile at the smallest radii. Although it is among the nearest globular clusters, the low velocity dispersion of NGC 6397 of < 5 km s(-1) imposes heavy demands on the quality of the kinematical data. We show that despite its limited spectral resolution, MUSE reaches an accuracy of 1 km s(-1) in the analysis of stellar spectra. We find slight evidence for a rotational component in the cluster and the velocity dispersion profile that we obtain shows a mild central cusp. To investigate the nature of this feature, we calculate spherical Jeans models and compare these models to our kinematical data. This comparison shows that if a constant mass-to-light ratio is assumed, the addition of an intermediate-mass black hole with a mass of 600 M-circle dot brings the model predictions into agreement with our data, and therefore could be at the origin of the velocity dispersion profile. We further investigate cases with varying mass-to-light ratios and find that a compact dark stellar component can also explain our observations. However, such a component would closely resemble the black hole from the constant mass-to-light ratio models as this component must be confined to the central similar to 5 ' of the cluster and must have a similar mass. Independent constraints on the distribution of stellar remnants in the cluster or kinematic measurements at the highest possible spatial resolution should be able to distinguish the two alternatives.}, language = {en} } @article{IvanovCioniBekkietal.2016, author = {Ivanov, Valentin D. and Cioni, Maria-Rosa L. and Bekki, Kenji and de Grijs, Richard and Emerson, Jim and Gibson, Brad K. and Kamath, Devika and van Loon, Jacco Th. and Piatti, Andres E. and For, Bi-Qing}, title = {New quasars behind the Magellanic Clouds. Spectroscopic confirmation of near-infrared selected candidates}, series = {Current biology}, volume = {588}, journal = {Current biology}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527398}, pages = {12}, year = {2016}, abstract = {Context. Quasi-stellar objects (quasars) located behind nearby galaxies provide an excellent absolute reference system for astrometric studies, but they are difficult to identify because of fore-and background contamination. Deep wide-field, high angular resolution surveys spanning the entire area of nearby galaxies are needed to obtain a complete census of such quasars. Aims. We embarked on a program to expand the quasar reference system behind the Large and the Small Magellanic Clouds, the Magellanic Bridge, and the Magellanic Stream that connects the Clouds with the Milky Way. Methods. Hundreds of quasar candidates were selected based on their near-infrared colors and variability properties from the ongoing public ESO VISTA Magellanic Clouds survey. A subset of 49 objects was followed up with optical spectroscopy. Results. We confirmed the quasar nature of 37 objects (34 new identifications): four are low redshift objects, three are probably stars, and the remaining three lack prominent spectral features for a secure classification. The bona fide quasars, identified from their broad emisison lines, are located as follows: 10 behind the LMC, 13 behind the SMC, and 14 behind the Bridge. The quasars span a redshift range from z similar to 0.5 to z similar to 4.1. Conclusions. Upon completion the VMC survey is expected to yield a total of similar to 1500 quasars with Y < 19.32 mag, J < 19.09 mag, and K-s < 18.04 mag.}, language = {en} } @article{HusserKamannDreizleretal.2016, author = {Husser, Tim-Oliver and Kamann, Sebastian and Dreizler, Stefan and Wendt, Martin and Wulff, Nina and Bacon, Roland and Wisotzki, Lutz and Brinchmann, Jarle and Weilbacher, Peter Michael and Roth, Martin M. and Monreal-Ibero, Ana}, title = {MUSE crowded field 3D spectroscopy of over 12 000 stars in the globular cluster NGC 6397 I. The first comprehensive HRD of a globular cluster}, series = {Nucleic acids research}, volume = {588}, journal = {Nucleic acids research}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201526949}, pages = {14}, year = {2016}, abstract = {Aims. We demonstrate the high multiplex advantage of crowded field 3D spectroscopy with the new integral field spectrograph MUSE by means of a spectroscopic analysis of more than 12 000 individual stars in the globular cluster NGC 6397. Methods. The stars are deblended with a point spread function fitting technique, using a photometric reference catalogue from HST as prior, including relative positions and brightnesses. This catalogue is also used for a first analysis of the extracted spectra, followed by an automatic in-depth analysis via a full-spectrum fitting method based on a large grid of PHOENIX spectra. Results. We analysed the largest sample so far available for a single globular cluster of 18 932 spectra from 12 307 stars in NGC 6397. We derived a mean radial velocity of v(rad) = 17.84 +/- 0.07 km s(-1) and a mean metallicity of [Fe/H] = -2.120 +/- 0.002, with the latter seemingly varying with temperature for stars on the red giant branch (RGB). We determine Teff and [Fe/H] from the spectra, and log g from HST photometry. This is the first very comprehensive Hertzsprung-Russell diagram (HRD) for a globular cluster based on the analysis of several thousands of stellar spectra, ranging from the main sequence to the tip of the RGB. Furthermore, two interesting objects were identified; one is a post-AGB star and the other is a possible millisecond-pulsar companion.}, language = {en} } @article{StadtherrCoumouPetoukhovetal.2016, author = {Stadtherr, Lisa and Coumou, Dim and Petoukhov, Vladimir and Petri, Stefan and Rahmstorf, Stefan}, title = {Record Balkan floods of 2014 linked to planetary wave resonance}, series = {Science Advances}, volume = {2}, journal = {Science Advances}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {2375-2548}, doi = {10.1126/sciadv.1501428}, pages = {6}, year = {2016}, abstract = {In May 2014, the Balkans were hit by a Vb-type cyclone that brought disastrous flooding and severe damage to Bosnia and Herzegovina, Serbia, and Croatia. Vb cyclones migrate from the Mediterranean, where they absorb warm and moist air, to the north, often causing flooding in central/eastern Europe. Extreme rainfall events are increasing on a global scale, and both thermodynamic and dynamical mechanisms play a role. Where thermodynamic aspects are generally well understood, there is large uncertainty associated with current and future changes in dynamics. We study the climatic and meteorological factors that influenced the catastrophic flooding in the Balkans, where we focus on large-scale circulation. We show that the Vb cyclone was unusually stationary, bringing extreme rainfall for several consecutive days, and that this situation was likely linked to a quasi-stationary circumglobal Rossby wave train. We provide evidence that this quasi-stationary wave was amplified by wave resonance. Statistical analysis of daily spring rainfall over the Balkan region reveals significant upward trends over 1950-2014, especially in the high quantiles relevant for flooding events. These changes cannot be explained by simple thermodynamic arguments, and we thus argue that dynamical processes likely played a role in increasing flood risks over the Balkans.}, language = {en} } @article{RomitaLadaCioni2016, author = {Romita, Krista and Lada, Elizabeth and Cioni, Maria-Rosa L.}, title = {EMBEDDED CLUSTERS IN THE LARGE MAGELLANIC CLOUD USING THE VISTA MAGELLANIC CLOUDS SURVEY}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {821}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/821/1/51}, pages = {10}, year = {2016}, abstract = {We present initial results of the first large-scale survey of embedded star clusters in molecular clouds in the Large Magellanic Cloud (LMC) using near-infrared imaging from the Visible and Infrared Survey Telescope for Astronomy Magellanic Clouds Survey. We explored a ~1.65 deg2 area of the LMC, which contains the well-known star-forming region 30 Doradus as well as ~14\% of the galaxy's CO clouds, and identified 67 embedded cluster candidates, 45 of which are newly discovered as clusters. We have determined the sizes, luminosities, and masses for these embedded clusters, examined the star formation rates (SFRs) of their corresponding molecular clouds, and made a comparison between the LMC and the Milky Way. Our preliminary results indicate that embedded clusters in the LMC are generally larger, more luminous, and more massive than those in the local Milky Way. We also find that the surface densities of both embedded clusters and molecular clouds is ~3 times higher than in our local environment, the embedded cluster mass surface density is ~40 times higher, the SFR is ~20 times higher, and the star formation efficiency is ~10 times higher. Despite these differences, the SFRs of the LMC molecular clouds are consistent with the SFR scaling law presented in Lada et al. This consistency indicates that while the conditions of embedded cluster formation may vary between environments, the overall process within molecular clouds may be universal.}, language = {en} } @article{LigorioNardiSteyrleuthneretal.2016, author = {Ligorio, G. and Nardi, M. V. and Steyrleuthner, Robert and Ihiawakrim, D. and Crespo-Monteiro, N. and Brinkmann, Martin and Neher, Dieter and Koch, N.}, title = {Metal nanoparticle mediated space charge and its optical control in an organic hole-only device}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4945710}, pages = {5}, year = {2016}, abstract = {We reveal the role of localized space charges in hole-only devices based on an organic semiconductor with embedded metal nanoparticles (MNPs). MNPs act as deep traps for holes and reduce the current density compared to a device without MNPs by a factor of 10(4) due to the build-up of localized space charge. Dynamic MNPs charged neutrality can be realized during operation by electron transfer from excitons created in the organic matrix, enabling light sensing independent of device bias. In contrast to the previous speculations, electrical bistability in such devices was not observed. (C) 2016 AIP Publishing LLC.}, language = {en} } @article{JeonJavanainenMartinezSearaetal.2016, author = {Jeon, Jae-Hyung and Javanainen, Matti and Martinez-Seara, Hector and Metzler, Ralf and Vattulainen, Ilpo}, title = {Protein Crowding in Lipid Bilayers Gives Rise to Non-Gaussian Anomalous Lateral Diffusion of Phospholipids and Proteins}, series = {Physical review : X, Expanding access}, volume = {6}, journal = {Physical review : X, Expanding access}, publisher = {American Physical Society}, address = {College Park}, issn = {2160-3308}, doi = {10.1103/PhysRevX.6.021006}, pages = {17}, year = {2016}, abstract = {Biomembranes are exceptionally crowded with proteins with typical protein-to-lipid ratios being around 1:50 - 1:100. Protein crowding has a decisive role in lateral membrane dynamics as shown by recent experimental and computational studies that have reported anomalous lateral diffusion of phospholipids and membrane proteins in crowded lipid membranes. Based on extensive simulations and stochastic modeling of the simulated trajectories, we here investigate in detail how increasing crowding by membrane proteins reshapes the stochastic characteristics of the anomalous lateral diffusion in lipid membranes. We observe that correlated Gaussian processes of the fractional Langevin equation type, identified as the stochastic mechanism behind lipid motion in noncrowded bilayer, no longer adequately describe the lipid and protein motion in crowded but otherwise identical membranes. It turns out that protein crowding gives rise to a multifractal, non-Gaussian, and spatiotemporally heterogeneous anomalous lateral diffusion on time scales from nanoseconds to, at least, tens of microseconds. Our investigation strongly suggests that the macromolecular complexity and spatiotemporal membrane heterogeneity in cellular membranes play critical roles in determining the stochastic nature of the lateral diffusion and, consequently, the associated dynamic phenomena within membranes. Clarifying the exact stochastic mechanism for various kinds of biological membranes is an important step towards a quantitative understanding of numerous intramembrane dynamic phenomena.}, language = {en} } @misc{BattistonFarmerFlacheetal.2016, author = {Battiston, Stefano and Farmer, Doyne and Flache, Andreas and Garlaschelli, Diego and Haldane, Andy and Heesterbeek, Hans and Hommes, Cars and Jaeger, Carlo and May, Robert and Scheffer, Marten}, title = {Financial complexity: Accounting for fraud Response}, series = {Science}, volume = {352}, journal = {Science}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {0036-8075}, doi = {10.1126/science.352.6283.302}, pages = {302 -- 302}, year = {2016}, language = {en} } @article{HicPradhanRybskietal.2016, author = {Hic, Ceren and Pradhan, Prajal and Rybski, Diego and Kropp, J{\"u}rgen}, title = {Food Surplus and Its Climate Burdens}, series = {Geological Society of America bulletin}, volume = {50}, journal = {Geological Society of America bulletin}, publisher = {American Chemical Society}, address = {Washington}, issn = {0013-936X}, doi = {10.1021/acs.est.5b05088}, pages = {4269 -- 4277}, year = {2016}, abstract = {Avoiding food loss and waste may counteract the increasing food demand and reduce greenhouse gas (GHG) emissions from the agricultural sector. This is crucial because of limited options available to increase food production. In the year 2010, food availability was 20\% higher than was required on a global scale. Thus, a more sustainable food production and adjusted consumption would have positive environmental effects. This study provides a systematic approach to estimate consumer level food waste on a country scale and globally, based on food availability and requirements. The food requirement estimation considers demographic development, body weights, and physical activity levels. Surplus between food availability and requirements of a given country is considered as food waste. The global food requirement changed from 2,300 kcal/cap/day to 2,400 kcal/cap/day during the last 50 years, while food surplus grew from 310 kcal/cap/day to 510 kcal/cap/day. Similarly, GHG emissions related to the food surplus increased from 130 Mt CO2eq/yr to 530 Mt CO2eq/yr, an increase of more than 300\%. Moreover, the global food surplus may increase up to 850 kcal/cap/day, while the total food requirement will increase only by 2\%-20\% by 2050. Consequently, GHG emissions associated with the food waste may also increase tremendously to 1.9-2.5 Gt CO2eq/yr.}, language = {en} } @article{ToalaOskinovaGonzalezGalanetal.2016, author = {Toala, Jes{\´u}s Alberto and Oskinova, Lida and Gonzalez-Galan, Ana and Guerrero, Mart{\´i}n A. and Ignace, R. and Pohl, Martin}, title = {X-RAY OBSERVATIONS OF BOW SHOCKS AROUND RUNAWAY O STARS. THE CASE OF zeta OPH AND BD+43 degrees 3654}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {821}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/821/2/79}, pages = {9}, year = {2016}, abstract = {Non-thermal radiation has been predicted within bow shocks around runaway stars by recent theoretical works. We present X-ray observations toward the runaway stars zeta Oph by Chandra and Suzaku and of BD+43 degrees 3654 by XMM-Newton to search for the presence of non-thermal X-ray emission. We found no evidence of non-thermal emission spatially coincident with the bow shocks; nonetheless, diffuse emission was detected in the vicinity of zeta Oph. After a careful analysis of its spectral characteristics, we conclude that this emission has a thermal nature with a plasma temperature of T approximate to 2 x 10(6) K. The cometary shape of this emission seems to be in line with recent predictions of radiation-hydrodynamic models of runaway stars. The case of BD+43 degrees 3654 is puzzling, as non-thermal emission has been reported in a previous work for this source.}, language = {en} } @article{ArcherBenbowBirdetal.2016, author = {Archer, A. and Benbow, W. and Bird, R. and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Ciupik, L. and Collins-Hughes, E. and Connolly, M. P. and Eisch, J. D. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Flinders, A. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Hakansson, Nils and Hanna, D. and Holder, J. and Humensky, T. B. and Huetten, M. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and McArthur, S. and McCann, A. and Meagher, K. and Millis, J. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Park, N. and Pelassa, V. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Ratliff, G. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rousselle, J. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Vassiliev, V. V. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wilhelm, Alina and Williams, D. A. and Zitzer, B. and Yusef-Zadeh, F.}, title = {TEV GAMMA-RAY OBSERVATIONS OF THE GALACTIC CENTER RIDGE BY VERITAS}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {821}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/821/2/129}, pages = {162 -- 167}, year = {2016}, abstract = {The Galactic Center ridge has been observed extensively in the past by both GeV and TeV gamma-ray instruments revealing a wealth of structure, including a diffuse component and the point sources G0.9+0.1 (a composite supernova remnant) and Sgr A* (believed to be associated with the supermassive black hole located at the center of our Galaxy). Previous very high energy (VHE) gamma-ray observations with the H.E.S.S.. experiment have also detected an extended TeV gamma-ray component along the Galactic plane in the >300 GeV gamma-ray regime. Here we report on observations of the Galactic Center ridge from 2010 to 2014 by the VERITAS telescope array in the >2 TeV energy range. From these observations we (1) provide improved measurements of the differential energy spectrum for Sgr A* in the >2 TeV gamma-ray regime, (2) provide a detection in the >2 TeV gamma-ray emission from the composite SNR G0.9+0.1 and an improved determination of its multi-TeV gamma-ray energy spectrum, and. (3) report on the detection of VER J1746-289, a localized enhancement of >2 TeV gamma-ray emission along the Galactic plane.}, language = {en} } @article{NeherKniepertElimelechetal.2016, author = {Neher, Dieter and Kniepert, Juliane and Elimelech, Arik and Koster, L. Jan Anton}, title = {A New Figure of Merit for Organic Solar Cells with Transport-limited Photocurrents}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep24861}, pages = {E2348 -- E2349}, year = {2016}, abstract = {Compared to their inorganic counterparts, organic semiconductors suffer from relatively low charge carrier mobilities. Therefore, expressions derived for inorganic solar cells to correlate characteristic performance parameters to material properties are prone to fail when applied to organic devices. This is especially true for the classical Shockley-equation commonly used to describe current-voltage (JV)-curves, as it assumes a high electrical conductivity of the charge transporting material. Here, an analytical expression for the JV-curves of organic solar cells is derived based on a previously published analytical model. This expression, bearing a similar functional dependence as the Shockley-equation, delivers a new figure of merit a to express the balance between free charge recombination and extraction in low mobility photoactive materials. This figure of merit is shown to determine critical device parameters such as the apparent series resistance and the fill factor.}, language = {en} } @misc{LevermannPetoukhovScheweetal.2016, author = {Levermann, Anders and Petoukhov, Vladimir and Schewe, Jacob and Schellnhuber, Hans Joachim}, title = {Abrupt monsoon transitions as seen in paleorecords can be explained by moisture-advection feedback}, series = {Proceedings of the National Academy of Sciences of the United States of America}, volume = {113}, journal = {Proceedings of the National Academy of Sciences of the United States of America}, publisher = {National Acad. of Sciences}, address = {Washington}, issn = {0027-8424}, doi = {10.1073/pnas.1603130113}, pages = {E2348 -- E2349}, year = {2016}, language = {en} } @article{StolbovaSurovyatkinaBookhagenetal.2016, author = {Stolbova, Veronika and Surovyatkina, Elena and Bookhagen, Bodo and Kurths, J{\"u}rgen}, title = {Tipping elements of the Indian monsoon: Prediction of onset and withdrawal}, series = {Geophysical research letters}, volume = {43}, journal = {Geophysical research letters}, publisher = {American Geophysical Union}, address = {Washington}, issn = {0094-8276}, doi = {10.1002/2016GL068392}, pages = {3982 -- 3990}, year = {2016}, abstract = {Forecasting the onset and withdrawal of the Indian summer monsoon is crucial for the life and prosperity of more than one billion inhabitants of the Indian subcontinent. However, accurate prediction of monsoon timing remains a challenge, despite numerous efforts. Here we present a method for prediction of monsoon timing based on a critical transition precursor. We identify geographic regions-tipping elements of the monsoon-and use them as observation locations for predicting onset and withdrawal dates. Unlike most predictability methods, our approach does not rely on precipitation analysis but on air temperature and relative humidity, which are well represented both in models and observations. The proposed method allows to predict onset 2 weeks earlier and withdrawal dates 1.5 months earlier than existing methods. In addition, it enables to correctly forecast monsoon duration for some anomalous years, often associated with El Nino-Southern Oscillation.}, language = {en} } @article{ThiemBagheriGrosseSiestrupetal.2016, author = {Thiem, A. and Bagheri, M. and Grosse-Siestrup, C. and Zehbe, Rolf}, title = {Gelatin-poly(lactic-co-glycolic acid) scaffolds with oriented pore channel architecture - From in vitro to in vivo testing}, series = {Vision research : an international journal for functional aspects of vision.}, volume = {62}, journal = {Vision research : an international journal for functional aspects of vision.}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0928-4931}, doi = {10.1016/j.msec.2016.02.019}, pages = {585 -- 595}, year = {2016}, abstract = {A gelatin-poly(lactic-co-glycolic acid), PLGA, composite scaffold, featuring a highly oriented pore channel structure, was developed as a template for articular cartilage regeneration. As a design principle the composite scaffold was optimized to contain only medical grade educts and accordingly no chemical cross linking agents or other toxicological relevant substances or methods were used. Scaffolds were synthesized using a freeze structuring method combined with an electrochemical process followed by freeze-drying. Finally, cross linking was performed using dehydrothermal treatment, which was simultaneously used for sterilization purposes. These composite scaffolds were analyzed in regard to structural and biomechanical properties, and to their degradation behavior. Furthermore, cell culture performance was tested using chondrocytes originated from joint articular cartilage tissue from 6 to 10 months old domestic pigs. Finally, the scaffolds were tested for tissue biocompatibility and their ability for tissue integration in a rat model. The scaffolds showed both excellent functional performance and high biocompatibility in vitro and in vivo. We expect that these gelatin-PLGA scaffolds can effectively support chondrogenesis in vivo demonstrating great potential for the use in cartilage defect treatment. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{SchickLeGuyaderPontiusetal.2016, author = {Schick, Daniel and Le Guyader, Loic and Pontius, Niko and Radu, Ilie and Kachel, Torsten and Mitzner, Rolf and Zeschke, Thomas and Schuessler-Langeheine, Christian and F{\"o}hlisch, Alexander and Holldack, Karsten}, title = {Analysis of the halo background in femtosecond slicing experiments}, series = {Journal of synchrotron radiation}, volume = {23}, journal = {Journal of synchrotron radiation}, publisher = {International Union of Crystallography}, address = {Chester}, issn = {1600-5775}, doi = {10.1107/S160057751600401X}, pages = {700 -- 711}, year = {2016}, abstract = {The slicing facility FemtoSpeX at BESSY II offers unique opportunities to study photo-induced dynamics on femtosecond time scales by means of X-ray magnetic circular dichroism, resonant and non-resonant X-ray diffraction, and X-ray absorption spectroscopy experiments in the soft X-ray regime. Besides femtosecond X-ray pulses, slicing sources inherently also produce a so-called `halo' background with a different time structure, polarization and pointing. Here a detailed experimental characterization of the halo radiation is presented, and a method is demonstrated for its correct and unambiguous removal from femtosecond time-resolved data using a special laser triggering scheme as well as analytical models. Examples are given for time-resolved measurements with corresponding halo correction, and errors of the relevant physical quantities caused by either neglecting or by applying a simplified model to describe this background are estimated.}, language = {en} } @article{BozzoOskinovaFeldmeieretal.2016, author = {Bozzo, Enrico and Oskinova, Lida and Feldmeier, Achim and Falanga, M.}, title = {Clumpy wind accretion in supergiant neutron star high mass X-ray binaries}, series = {BMC neuroscience}, volume = {589}, journal = {BMC neuroscience}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628341}, pages = {369 -- 389}, year = {2016}, abstract = {The accretion of the stellar wind material by a compact object represents the main mechanism powering the X-ray emission in classical supergiant high mass X-ray binaries and supergiant fast X-ray transients. In this work we present the first attempt to simulate the accretion process of a fast and dense massive star wind onto a neutron star, taking into account the effects of the centrifugal and magnetic inhibition of accretion ("gating") due to the spin and magnetic field of the compact object. We made use of a radiative hydrodynamical code to model the nonstationary radiatively driven wind of an O-B supergiant star and then place a neutron star characterized by a fixed magnetic field and spin period at a certain distance from the massive companion. Our calculations follow, as a function of time (on a total timescale of several hours), the transitions of the system through all different accretion regimes that are triggered by the intrinsic variations in the density and velocity of the nonstationary wind. The X-ray luminosity released by the system is computed at each time step by taking into account the relevant physical processes occurring in the different accretion regimes. Synthetic lightcurves are derived and qualitatively compared with those observed from classical supergiant high mass X-ray binaries and supergiant fast X-ray transients. Although a number of simplifications are assumed in these calculations, we show that taking into account the effects of the centrifugal and magnetic inhibition of accretion significantly reduces the average X-ray luminosity expected for any neutron star wind-fed binary. The present model calculations suggest that long spin periods and stronger magnetic fields are favored in order to reproduce the peculiar behavior of supergiant fast X-ray transients in the X-ray domain.}, language = {en} } @article{ZhelavskayaSpasojevicShpritsetal.2016, author = {Zhelavskaya, Irina and Spasojevic, M. and Shprits, Yuri Y. and Kurth, William S.}, title = {Automated determination of electron density from electric field measurements on the Van Allen Probes spacecraft}, series = {Journal of geophysical research : Space physics}, volume = {121}, journal = {Journal of geophysical research : Space physics}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2015JA022132}, pages = {4611 -- 4625}, year = {2016}, abstract = {We present the Neural-network-based Upper hybrid Resonance Determination (NURD) algorithm for automatic inference of the electron number density from plasma wave measurements made on board NASA's Van Allen Probes mission. A feedforward neural network is developed to determine the upper hybrid resonance frequency, fuhr, from electric field measurements, which is then used to calculate the electron number density. In previous missions, the plasma resonance bands were manually identified, and there have been few attempts to do robust, routine automated detections. We describe the design and implementation of the algorithm and perform an initial analysis of the resulting electron number density distribution obtained by applying NURD to 2.5 years of data collected with the Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) instrumentation suite of the Van Allen Probes mission. Densities obtained by NURD are compared to those obtained by another recently developed automated technique and also to an existing empirical plasmasphere and trough density model.}, language = {en} } @article{JaphaZhouKeiletal.2016, author = {Japha, Yonathan and Zhou, Shuyu and Keil, Mark and Folman, Ron and Henkel, Carsten and Vardi, Amichay}, title = {Suppression and enhancement of decoherence in an atomic Josephson junction}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/5/055008}, pages = {22}, year = {2016}, abstract = {We investigate the role of interatomic interactions when a Bose gas, in a double-well potential with a finite tunneling probability (a 'Bose-Josephson junction'), is exposed to external noise. We examine the rate of decoherence of a system initially in its ground state with equal probability amplitudes in both sites. The noise may induce two kinds of effects: firstly, random shifts in the relative phase or number difference between the two wells and secondly, loss of atoms from the trap. The effects of induced phase fluctuations are mitigated by atom-atom interactions and tunneling, such that the dephasing rate may be suppressed by half its single-atom value. Random fluctuations may also be induced in the population difference between the wells, in which case atom-atom interactions considerably enhance the decoherence rate. A similar scenario is predicted for the case of atom loss, even if the loss rates from the two sites are equal. We find that if the initial state is number-squeezed due to interactions, then the loss process induces population fluctuations that reduce the coherence across the junction. We examine the parameters relevant for these effects in a typical atom chip device, using a simple model of the trapping potential, experimental data, and the theory of magnetic field fluctuations near metallic conductors. These results provide a framework for mapping the dynamical range of barriers engineered for specific applications and set the stage for more complex atom circuits ('atomtronics').}, language = {en} } @article{HubrigKholtyginIlyinetal.2016, author = {Hubrig, Swetlana and Kholtygin, A. and Ilyin, Ilya and Sch{\"o}ller, M. and Oskinova, Lida}, title = {THE FIRST SPECTROPOLARIMETRIC MONITORING OF THE PECULIAR O4 Ief SUPERGIANT zeta PUPPIS}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {822}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/822/2/104}, pages = {7}, year = {2016}, abstract = {The origin of the magnetic field in massive O-type stars is still under debate. To model the physical processes responsible for the generation of O star magnetic fields, it is important to understand whether correlations between the presence of a magnetic field and stellar evolutionary state, rotation velocity, kinematical status, and surface composition can be identified. The O4 Ief supergiant zeta Pup is a fast rotator and a runaway star, which may be a product of a past binary interaction, possibly having had an encounter with the cluster Trumper 10 some 2 Myr ago. The currently available observational material suggests that certain observed phenomena in this star may be related to the presence of a magnetic field. We acquired spectropolarimetric observations of zeta Pup with FORS 2 mounted on the 8 m Antu telescope of the Very Large Telescope to investigate if a magnetic field is indeed present in this star. We show that many spectral lines are highly variable and probably vary with the recently detected period of 1.78 day. No magnetic field is detected in zeta Pup, as no magnetic field measurement has a significance level higher than 2.4 sigma. Still, we studied the probability of a single sinusoidal explaining the variation of the longitudinal magnetic field measurements.}, language = {en} } @article{HubrigScholzHamannetal.2016, author = {Hubrig, Swetlana and Scholz, Kathleen and Hamann, Wolf-Rainer and Schoeller, M. and Ignace, R. and Ilyin, Ilya and Gayley, K. G. and Oskinova, Lida}, title = {Searching for a magnetic field in Wolf-Rayet stars using FORS 2 spectropolarimetry}, series = {Monthly notices of the Royal Astronomical Society}, volume = {458}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw558}, pages = {3381 -- 3393}, year = {2016}, abstract = {To investigate if magnetic fields are present in Wolf-Rayet stars, we selected a few stars in the Galaxy and one in the Large Magellanic Cloud (LMC). We acquired low-resolution spectropolarimetric observations with the European Southern Observatory FORS 2 (FOcal Reducer low dispersion Spectrograph) instrument during two different observing runs. During the first run in visitor mode, we observed the LMC Wolf-Rayet star BAT99 7 and the stars WR 6, WR 7, WR 18, and WR 23 in our Galaxy. The second run in service mode was focused on monitoring the star WR 6. Linear polarization was recorded immediately after the observations of circular polarization. During our visitor observing run, the magnetic field for the cyclically variable star WR 6 was measured at a significance level of 3.3 sigma (< B-z > = 258 +/- 78 G). Among the other targets, the highest value for the longitudinal magnetic field, < B-z > = 327 +/- 141 G, was measured in the LMC star BAT99 7. Spectropolarimetric monitoring of the star WR 6 revealed a sinusoidal nature of the < B-z > variations with the known rotation period of 3.77 d, significantly adding to the confidence in the detection. The presence of the rotation-modulated magnetic variability is also indicated in our frequency periodogram. The reported field magnitude suffers from significant systematic uncertainties at the factor of 2 level, in addition to the quoted statistical uncertainties, owing to the theoretical approach used to characterize it. Linear polarization measurements showed no line effect in the stars, apart from WR 6. BAT99 7, WR 7, and WR 23 do not show variability of the linear polarization over two nights.}, language = {en} } @article{ChenPohlBottcheretal.2016, author = {Chen, Xuhui and Pohl, Martin and Bottcher, Markus and Gao, Shan}, title = {Particle diffusion and localized acceleration in inhomogeneous AGN jets - II. Stochastic variation}, series = {Monthly notices of the Royal Astronomical Society}, volume = {458}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw528}, pages = {3260 -- 3271}, year = {2016}, abstract = {We study the stochastic variation of blazar emission under a 2D spatially resolved leptonic jet model we previously developed. Random events of particle acceleration and injection in small zones within the emission region are assumed to be responsible for flux variations. In addition to producing spectral energy distributions that describe the observed flux of Mrk 421, we further analyse the timing properties of the simulated light curves, such as the power spectral density (PSD) at different bands, flux-flux correlations, aswell as the cross-correlation function between X-rays and TeV gamma-rays. We find spectral breaks in the PSD at a time-scale comparable to the dominant characteristic time-scale in the system, which is usually the predefined decay time-scale of an acceleration event. Cooling imposes a delay, and so PSDs taken at lower energy bands in each emission component (synchrotron or inverse Compton) generally break at longer time-scales. The flux-flux correlation between X-rays and TeV gamma-rays can be either quadratic or linear, depending on whether or not there are large variation of the injection into the particle acceleration process. When the relationship is quadratic, the TeV flares lag the X-ray flares, and the optical and GeV flares are large enough to be comparable to the ones in X-ray. When the relationship is linear, the lags are insignificant, and the optical and GeV flares are small.}, language = {en} } @article{KurpiersNeher2016, author = {Kurpiers, Jona and Neher, Dieter}, title = {Dispersive Non-Geminate Recombination in an Amorphous Polymer: Fullerene Blend}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep26832}, pages = {10}, year = {2016}, abstract = {Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer: fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions.}, language = {en} } @article{Beta2016, author = {Beta, Carsten}, title = {To turn or not to turn?}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/5/051003}, pages = {1 -- 17}, year = {2016}, abstract = {Bacteria typically swim in straight runs, interruped by sudden turning events. In particular, some species are limited to a reversal in the swimming direction as the only turning maneuver at their disposal. In a recent article, Grossmann et al (2016 New J. Phys. 18 043009) introduce a theoretical framework to analyze the diffusive properties of active particles following this type of run-and-reverse pattern. Based on a stochastic clock model to mimic the regulatory pathway that triggers reversal events, they show that a run-and-reverse swimmer can optimize its diffusive spreading by tuning the reversal rate according to the level of rotational noise. With their approach, they open up promising new perspectives of how to incorporate the dynamics of intracellular signaling into coarse-grained active particle descriptions.}, language = {en} } @article{KretschmerCoumouDongesetal.2016, author = {Kretschmer, Marlene and Coumou, Dim and Donges, Jonathan Friedemann and Runge, Jakob}, title = {Using Causal Effect Networks to Analyze Different Arctic Drivers of Midlatitude Winter Circulation}, series = {Journal of climate}, volume = {29}, journal = {Journal of climate}, publisher = {American Meteorological Soc.}, address = {Boston}, issn = {0894-8755}, doi = {10.1175/JCLI-D-15-0654.1}, pages = {4069 -- 4081}, year = {2016}, abstract = {In recent years, the Northern Hemisphere midlatitudes have suffered from severe winters like the extreme 2012/13 winter in the eastern United States. These cold spells were linked to a meandering upper-tropospheric jet stream pattern and a negative Arctic Oscillation index (AO). However, the nature of the drivers behind these circulation patterns remains controversial. Various studies have proposed different mechanisms related to changes in the Arctic, most of them related to a reduction in sea ice concentrations or increasing Eurasian snow cover. Here, a novel type of time series analysis, called causal effect networks (CEN), based on graphical models is introduced to assess causal relationships and their time delays between different processes. The effect of different Arctic actors on winter circulation on weekly to monthly time scales is studied, and robust network patterns are found. Barents and Kara sea ice concentrations are detected to be important external drivers of the midlatitude circulation, influencing winter AO via tropospheric mechanisms and through processes involving the stratosphere. Eurasia snow cover is also detected to have a causal effect on sea level pressure in Asia, but its exact role on AO remains unclear. The CEN approach presented in this study overcomes some difficulties in interpreting correlation analyses, complements model experiments for testing hypotheses involving teleconnections, and can be used to assess their validity. The findings confirm that sea ice concentrations in autumn in the Barents and Kara Seas are an important driver of winter circulation in the midlatitudes.}, language = {en} } @article{ParezanovicCordierSpohnetal.2016, author = {Parezanovic, Vladimir and Cordier, Laurent and Spohn, Andreas and Duriez, Thomas and Noack, Bernd R. and Bonnet, Jean-Paul and Segond, Marc and Abel, Markus and Brunton, Steven L.}, title = {Frequency selection by feedback control in a turbulent shear flow}, series = {Journal of fluid mechanics}, volume = {797}, journal = {Journal of fluid mechanics}, publisher = {Cambridge Univ. Press}, address = {New York}, issn = {0022-1120}, doi = {10.1017/jfm.2016.261}, pages = {247 -- 283}, year = {2016}, abstract = {Many previous studies have shown that the turbulent mixing layer under periodic forcing tends to adopt a lock-on state, where the major portion of the fluctuations in the flow are synchronized at the forcing frequency. The goal of this experimental study is to apply closed-loop control in order to provoke the lock-on state, using information from the flow itself. We aim to determine the range of frequencies for which the closed-loop control can establish the lock-on, and what mechanisms are contributing to the selection of a feedback frequency. In order to expand the solution space for optimal closed-loop control laws, we use the genetic programming control (CPC) framework. The best closed-loop control laws obtained by CPC are analysed along with the associated physical mechanisms in the mixing layer flow. The resulting closed-loop control significantly outperforms open-loop forcing in terms of robustness to changes in the free-stream velocities. In addition, the selection of feedback frequencies is not locked to the most amplified local mode, but rather a range of frequencies around it.}, language = {en} } @article{SchimkaSanterMujkicNinnemannetal.2016, author = {Schimka, Selina and Santer, Svetlana and Mujkic-Ninnemann, Nina M. and Bleger, David and Hartmann, Laura and Wehle, Marko and Lipowsky, Reinhard and Santer, Mark}, title = {Photosensitive Peptidomimetic for Light-Controlled, Reversible DNA Compaction}, series = {Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences}, volume = {17}, journal = {Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences}, publisher = {American Chemical Society}, address = {Washington}, issn = {1525-7797}, doi = {10.1021/acs.biomac.6b00052}, pages = {1959 -- 1968}, year = {2016}, abstract = {Light-induced DNA compaction as part of nonviral gene delivery was investigated intensively in the past years, although the bridging between the artificial light switchable compacting.agents and biodompatible light insensitive compacting agents was not achieved until now. In this paper, we report on light-induced compaction and decompaction of DNA molecules in the presence of a new typeof agent, a multivalent cationic peptidomimetic molecule containing a photosensitive Azo-group as a branch (Azo-PM). Az-o-PM is synthesized using a solid-phase procedure during Which anrazoberizene unit is attached as a side chain to an Oligo(arnidoamine) backbone. We shoW, that within a-certain Tange,of concentrations and under illumination with light of appropriate-wavelengths, these cationic Molecules induce reversible DNA compaction/decompaction by photo-isomerization of the incorporated azobenzene unit between a hydrophobic trans- and 4 hydrophilic cis-conformation, as characterized by dynamic light scattering and AFM measurements. In contrast to other molecular Species used for invasive DNA compaction, such as-widely used azobenzene containing cationic surfactant (Azo-TAR, C-4-Azo-OCX-TMAB), the presented peptidomimetic agent appears to lead to different compleication/compaction mechanisms., An investigation of Ato-PM in close proximity to a DNA segment by means of a molecular dynamics simulation sustains a picture in which Azo-PM acts as a multivalent counterion, with its rather large cationic oligo(amidoamine) backbone dominating the interaction with the double helix, fine-tuned or assisted by the presence" andisomerization state of the Azo-moiety. However, due to its peptidomimetic backbone, Azo-PM should be far less toxic than photosensitive surfactants and might represent a starting point for a conscious design of photoswitchable, biocompatible vectors for gene delivery.}, language = {en} } @article{RichterWakkerFechneretal.2016, author = {Richter, Philipp and Wakker, Bart P. and Fechner, Cora and Herenz, Peter and Tepper-Garcia, T. and Fox, Andrew J.}, title = {An HST/COS legacy survey of intervening Si III absorption in the extended gaseous halos of low-redshift galaxies}, series = {Climate : open access journal}, volume = {590}, journal = {Climate : open access journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527038}, pages = {29}, year = {2016}, abstract = {Aims. Doubly ionized silicon (Si III) is a powerful tracer of diffuse ionized gas inside and outside of galaxies. It can be observed in the local Universe in ultraviolet (UV) absorption against bright extragalactic background sources. We here present an extensive study of intervening Si III-selected absorbers and study the properties of the warm circumgalactic medium (CGM) around low-redshift (z <= 0.1) galaxies. Methods. We analyzed the UV absorption spectra of 303 extragalactic background sources, as obtained with the Cosmic Origins Spectrograph (COS) on-board the Hubble Space Telescope (HST). We developed a geometrical model for the absorption-cross section of the CGM around the local galaxy population and compared the observed Si III absorption statistics with predictions provided by the model. We also compared redshifts and positions of the absorbers with those of similar to 64 000 galaxies using archival galaxy-survey data to investigate the relation between intervening Si III absorbers and the CGM. Results. Along a total redshift path of Delta z approximate to 24, we identify 69 intervening Si III systems that all show associated absorption from other low and high ions (e.g., H I, Si II, Si IV, C II, C IV). We derive a bias-corrected number density of dN/dz(Si III) = 2.5 +/- 0.4 for absorbers with column densities log N(Si III) > 12.2, which is similar to 3 times the number density of strong Mg II systems at z = 0. This number density matches the expected cross section of a Si III absorbing CGM around the local galaxy population with a mean covering fraction of < f(c)> = 0.69. For the majority (similar to 60 percent) of the absorbers, we identify possible host galaxies within 300 km s(-1) of the absorbers and derive impact parameters rho < 200 kpc, demonstrating that the spatial distributions of Si III absorbers and galaxies are highly correlated. Conclusions. Our study indicates that the majority of Si III-selected absorbers in our sample trace the CGM of nearby galaxies within their virial radii at a typical covering fraction of similar to 70 percent. We estimate that diffuse gas in the CGM around galaxies, as traced by Si III, contains substantially more (more than twice as much) baryonic mass than their neutral interstellar medium.}, language = {en} } @article{RauchQuinetHoyeretal.2016, author = {Rauch, Thomas and Quinet, P. and Hoyer, D. and Werner, K. and Richter, Philipp and Kruk, J. W. and Demleitner, M.}, title = {VII. New Kr IV - VII oscillator strengths and an improved spectral analysis of the hot, hydrogen-deficient DO-type white dwarf RE 0503-289}, series = {Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants}, volume = {590}, journal = {Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants}, publisher = {EDP Sciences}, address = {Les Ulis}, organization = {VERITAS Collaboration}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628131}, pages = {26}, year = {2016}, abstract = {Context. For the spectral analysis of high-resolution and high signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. New Kr IV-VII oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTE model-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods. We calculated Kr IV-VII oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high S/N ultraviolet (UV) observations of the hot white dwarf RE 0503-289. Results. We reanalyzed the effective temperature and surface gravity and determined T-eff = 70 000 +/- 2000 K and log (g/cm s(-2)) = 7.5 +/- 0.1. We newly identified ten Kr V lines and one Kr vi line in the spectrum of RE 0503-289. We measured a Kr abundance of 3.3 +/- 0.3 (logarithmic mass fraction). We discovered that the interstellar absorption toward RE 0503-289 has a multi-velocity structure within a radial-velocity interval of -40 km s(-1) < upsilon(rad) < +18 km s(-1). Conclusions. Reliable measurements and calculations of atomic data are a prerequisite for state-of-the-art NLTE stellar-atmosphere modeling. Observed Kr V-VII line profiles in the UV spectrum of the white dwarf RE 0503-289 were simultaneously well reproduced with our newly calculated oscillator strengths.}, language = {en} } @article{ArchambaultArcherBenbowetal.2016, author = {Archambault, S. and Archer, A. and Benbow, W. and Bird, R. and Biteau, Jonathan and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cerruti, M. and Chen, Xuhui and Ciupik, L. and Connolly, M. P. and Cui, W. and Eisch, J. D. and Errando, M. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortin, P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Huetten, M. and Hakansson, Nils and Hanna, D. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Moriarty, P. and Mukherjee, R. and Nguyen, T. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Perkins, J. S. and Pichel, A. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rovero, A. C. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Vincent, S. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Williams, D. A. and Zitzer, B. and Fumagalli, M. and Prochaska, J. X.}, title = {UPPER LIMITS FROM FIVE YEARS OF BLAZAR OBSERVATIONS WITH THE VERITAS CHERENKOV TELESCOPES}, series = {The astronomical journal}, volume = {151}, journal = {The astronomical journal}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {0004-6256}, doi = {10.3847/0004-6256/151/6/142}, pages = {19}, year = {2016}, abstract = {Between the beginning of its full-scale scientific operations in 2007 and 2012, the VERITAS Cherenkov telescope array observed more than 130 blazars; of these, 26 were detected as very-high-energy (VHE; E > 100 GeV) gamma-ray sources. In this work, we present the analysis results of a sample of 114 undetected objects. The observations constitute a total live-time of similar to 570 hr. The sample includes several unidentified Fermi-Large Area Telescope (LAT) sources (located at high Galactic latitude) as well as all the sources from the second Fermi-LAT catalog that are contained within the field of view of the VERITAS observations. We have also performed optical spectroscopy measurements in order to estimate the redshift of some of these blazars that do not have spectroscopic distance estimates. We present new optical spectra from the Kast instrument on the Shane telescope at the Lick observatory for 18 blazars included in this work, which allowed for the successful measurement or constraint on the redshift of four of them. For each of the blazars included in our sample, we provide the flux upper limit in the VERITAS energy band. We also study the properties of the significance distributions and we present the result of a stacked analysis of the data set, which shows a 4s excess.}, language = {en} } @article{XueYanChengetal.2016, author = {Xue, Zhike and Yan, Xiaoli and Cheng, Xin and Yang, Liheng and Su, Yingna and Kliem, Bernhard and Zhang, Jun and Liu, Zhong and Bi, Yi and Xiang, Yongyuan and Yang, Kai and Zhao, Li}, title = {Observing the release of twist by magnetic reconnection in a solar filament eruption}, series = {Nature Communications}, volume = {7}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/ncomms11837}, pages = {11}, year = {2016}, abstract = {Magnetic reconnection is a fundamental process of topology change and energy release, taking place in plasmas on the Sun, in space, in astrophysical objects and in the laboratory. However, observational evidence has been relatively rare and typically only partial. Here we present evidence of fast reconnection in a solar filament eruption using high-resolution H-alpha images from the New Vacuum Solar Telescope, supplemented by extreme ultraviolet observations. The reconnection is seen to occur between a set of ambient chromospheric fibrils and the filament itself. This allows for the relaxation of magnetic tension in the filament by an untwisting motion, demonstrating a flux rope structure. The topology change and untwisting are also found through nonlinear force-free field modelling of the active region in combination with magnetohydrodynamic simulation. These results demonstrate a new role for reconnection in solar eruptions: the release of magnetic twist.}, language = {en} } @article{WinklerAbel2016, author = {Winkler, Michael and Abel, Markus}, title = {Optimized setup for two-dimensional convection experiments in thin liquid films}, series = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, volume = {87}, journal = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0034-6748}, doi = {10.1063/1.4950871}, pages = {11}, year = {2016}, abstract = {We present a novel experimental setup to investigate two-dimensional thermal convection in a freestanding thin liquid film. Such films can be produced in a controlled way on the scale of 5-1000 nm. Our primary goal is to investigate convection patterns and the statistics of reversals in Rayleigh-Benard convection with varying aspect ratio. Additionally, questions regarding the physics of liquid films under controlled conditions can be investigated, like surface forces, or stability under varying thermodynamical parameters. The film is suspended in a frame which can be adjusted in height and width to span an aspect ratio range of Gamma = 0.16-10. The top and bottom frame elements can be set to specific temperature within T = 15 degrees C to 55 degrees C. A thickness to area ratio of approximately 108 enables only two-dimensional fluid motion in the time scales relevant for turbulent motion. The chemical composition of the film is well-defined and optimized for film stability and reproducibility and in combination with carefully controlled ambient parameters allows the comparison to existing experimental and numerical data. Published by AIP Publishing.}, language = {en} } @article{WenzLevermann2016, author = {Wenz, Leonie and Levermann, Anders}, title = {Enhanced economic connectivity to foster heat stress-related losses}, series = {Science Advances}, volume = {2}, journal = {Science Advances}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {2375-2548}, doi = {10.1126/sciadv.1501026}, pages = {9}, year = {2016}, abstract = {Assessing global impacts of unexpected meteorological events in an increasingly connected world economy is important for estimating the costs of climate change. We show that since the beginning of the 21st century, the structural evolution of the global supply network has been such as to foster an increase of climate-related production losses. We compute first- and higher-order losses from heat stress-induced reductions in productivity under changing economic and climatic conditions between 1991 and 2011. Since 2001, the economic connectivity has augmented in such a way as to facilitate the cascading of production loss. The influence of this structural change has dominated over the effect of the comparably weak climate warming during this decade. Thus, particularly under future warming, the intensification of international trade has the potential to amplify climate losses if no adaptation measures are taken.}, language = {en} } @article{RipepiMarconiMorettietal.2016, author = {Ripepi, V. and Marconi, M. and Moretti, M. I. and Clementini, Gisella and Cioni, Maria-Rosa L. and de Grijs, R. and Emerson, J. P. and Groenewegen, M. A. T. and Ivanov, V. D. and Piatti, A. E.}, title = {THE VMC SURVEY. XIX. CLASSICAL CEPHEIDS IN THE SMALL MAGELLANIC CLOUD}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, volume = {224}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0067-0049}, doi = {10.3847/0067-0049/224/2/21}, pages = {199 -- 229}, year = {2016}, abstract = {The "VISTA near-infrared YJK(s) survey of the Magellanic Clouds System" (VMC) is collecting deep K-s-band time-series photometry of pulsating variable stars hosted by the two Magellanic Clouds and their connecting Bridge. In this paper, we present Y, J, K-s light curves for a sample of 4172 Small Magellanic Cloud (SMC) Classical Cepheids (CCs). These data, complemented with literature V values, allowed us to construct a variety of period-luminosity (PL), period-luminosity-color (PLC), and period-Wesenheit (PW) relationships, which are valid for Fundamental (F), First Overtone (FO), and Second Overtone (SO) pulsators. The relations involving the V, J, K-s bands are in agreement with their counterparts in the literature. As for the Y band, to our knowledge, we present the first CC PL, PW, and PLC relations ever derived using this filter. We also present the first near-infrared PL, PW, and PLC relations for SO pulsators to date. We used PW(V, K-s) to estimate the relative SMC-LMC distance and, in turn, the absolute distance to the SMC. For the former quantity, we find a value of Delta mu = 0.55. +/- 0.04 mag, which is in rather good agreement with other evaluations based on CCs, but significantly larger than the results obtained from older population II distance indicators. This discrepancy might be due to the different geometric distributions of young and old tracers in both Clouds. As for the absolute distance to the SMC, our best estimates are mu(SMC) = 19.01 +/- 0.05 mag and mu(SMC) = 19.04 +/- 0.06 mag, based on two distance measurements to the LMC which rely on accurate CC and eclipsing Cepheid binary data, respectively.}, language = {en} } @article{KronbergRashevDalyetal.2016, author = {Kronberg, Elena A. and Rashev, M. V. and Daly, P. W. and Shprits, Yuri Y. and Turner, D. L. and Drozdov, Alexander and Dobynde, M. and Kellerman, Adam C. and Fritz, T. A. and Pierrard, V. and Borremans, K. and Klecker, B. and Friedel, R.}, title = {Contamination in electron observations of the silicon detector on board}, series = {Space Weather: The International Journal of Research and Applications}, volume = {14}, journal = {Space Weather: The International Journal of Research and Applications}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1542-7390}, doi = {10.1002/2016SW001369}, pages = {449 -- 462}, year = {2016}, abstract = {Since more than 15 years, the Cluster mission passes through Earth's radiation belts at least once every 2 days for several hours, measuring the electron intensity at energies from 30 to 400 keV. These data have previously been considered not usable due to contamination caused by penetrating energetic particles (protons at >100 keV and electrons at >400 keV). In this study, we assess the level of distortion of energetic electron spectra from the Research with Adaptive Particle Imaging Detector (RAPID)/Imaging Electron Spectrometer (IES) detector, determining the efficiency of its shielding. We base our assessment on the analysis of experimental data and a radiation transport code (Geant4). In simulations, we use the incident particle energy distribution of the AE9/AP9 radiation belt models. We identify the Roederer L values, L\&\#8902;, and energy channels that should be used with caution: at 3\&\#8804;L\&\#8902;\&\#8804;4, all energy channels (40-400 keV) are contaminated by protons (\&\#8771;230 to 630 keV and >600 MeV); at L\&\#8902;\&\#8771;1 and 4-6, the energy channels at 95-400 keV are contaminated by high-energy electrons (>400 keV). Comparison of the data with electron and proton observations from RBSP/MagEIS indicates that the subtraction of proton fluxes at energies \&\#8771; 230-630 keV from the IES electron data adequately removes the proton contamination. We demonstrate the usefulness of the corrected data for scientific applications.}, language = {en} } @article{SchwarzlGodecOshaninetal.2016, author = {Schwarzl, Maria and Godec, Aljaz and Oshanin, Gleb and Metzler, Ralf}, title = {A single predator charging a herd of prey: effects of self volume and predator-prey decision-making}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {49}, journal = {Journal of physics : A, Mathematical and theoretical}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8113/49/22/225601}, pages = {19}, year = {2016}, abstract = {We study the degree of success of a single predator hunting a herd of prey on a two-dimensional square lattice landscape. We explicitly consider the self volume of the prey restraining their dynamics on the lattice. The movement of both predator and prey is chosen to include an intelligent, decision making step based on their respective sighting ranges, the radius in which they can detect the other species (prey cannot recognise each other besides the self volume interaction): after spotting each other the motion of prey and predator turns from a nearest neighbour random walk into directed escape or chase, respectively. We consider a large range of prey densities and sighting ranges and compute the mean first passage time for a predator to catch a prey as well as characterise the effective dynamics of the hunted prey. We find that the prey's sighting range dominates their life expectancy and the predator profits more from a bad eyesight of the prey than from his own good eye sight. We characterise the dynamics in terms of the mean distance between the predator and the nearest prey. It turns out that effectively the dynamics of this distance coordinate can be captured in terms of a simple Ornstein-Uhlenbeck picture. Reducing the many-body problem to a simple two-body problem by imagining predator and nearest prey to be connected by an effective Hookean bond, all features of the model such as prey density and sighting ranges merge into the effective binding constant.}, language = {en} } @article{Pikovskij2016, author = {Pikovskij, Arkadij}, title = {Reconstruction of a neural network from a time series of firing rates}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.062313}, pages = {4}, year = {2016}, abstract = {Randomly coupled neural fields demonstrate irregular variation of firing rates, if the coupling is strong enough, as has been shown by Sompolinsky et al. [Phys. Rev. Lett. 61, 259 (1988)]. We present a method for reconstruction of the coupling matrix from a time series of irregular firing rates. The approach is based on the particular property of the nonlinearity in the coupling, as the latter is determined by a sigmoidal gain function. We demonstrate that for a large enough data set and a small measurement noise, the method gives an accurate estimation of the coupling matrix and of other parameters of the system, including the gain function.}, language = {en} } @article{QiuWirgesGerhard2016, author = {Qiu, Xunlin and Wirges, Werner and Gerhard, Reimund}, title = {Thermal poling of ferroelectrets: How does the gas temperature influence dielectric barrier discharges in cavities?}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4954263}, pages = {1687 -- 1697}, year = {2016}, abstract = {The influence of the temperature in the gas-filled cavities on the charging process of ferroelectret film systems has been studied in hysteresis measurements. The threshold voltage and the effective polarization of the ferroelectrets were determined as functions of the charging temperature TP. With increasing TP, the threshold voltage for triggering dielectric barrier discharges in ferroelectrets decreases. Thus, increasing the temperature facilitates the charging of ferroelectrets. However, a lower threshold voltage reduces the attainable remanent polarization because back discharges occur at lower charge levels, as soon as the charging voltage is turned off. The results are discussed in view of Paschen's law for electrical breakdown, taking into account the respective gas temperature and a simplified model for ferroelectrets. Our results indicate that the thermal poling scheme widely used for conventional ferroelectrics is also useful for electrically charging ferroelectrets. Ferroelectrets (sometimes also called piezoelectrets) are relatively new members of the family of piezo-, pyro-, and ferroelectric materials.1-5 As their name indicates, ferroelectrets are space-charge electrets that show ferroic behavior. They are non-uniform electret materials or materials systems with electrically charged internal cavities. As space-charge electrets, ferroelectrets usually do not contain any molecular dipoles. However, the cavities inside the material can be turned into macroscopic dipoles through a series of micro-plasma discharges at high electric fields, so-called dielectric barrier discharges (DBDs).6-8 The gas inside the cavities is ionized when the internal electric field exceeds the threshold for electrical breakdown, generating charges of both polarities.9 The positive and negative charges travel in opposite directions, and are eventually trapped at the internal top and bottom surfaces of the cavities, respectively. After charging, the cavities may be regarded as macroscopic dipoles that can be switched by reversing the applied voltage. An electric-polarization-vs.-electric-field (P(E)) hysteresis is considered as an essential criterion for ferroelectricity. P(E)-hysteresis curves are usually characterized by the spontaneous polarization, the coercive field, and the remanent polarization. Recently, we have demonstrated P(E)-hysteresis loops on two different types of ferroelectrets, namely, cellular polypropylene ferroelectrets and tubular-channel fluoroethylene-polypropylene copolymer ferroelectrets.10,11 The P(E)-hysteresis loops not only prove the ferroic behavior of ferroelectrets, but also allow us to determine such parameters as the coercive field and the remanent polarization. It is widely accepted that Paschen breakdown is the underlying mechanism for the inception of DBDs in ferroelectrets.12-14 On this basis, the charging behavior and the resulting piezoelectricity of ferroelectrets in different gases at various pressures have been studied.15-17 Paschen's law describes the conditions for electrical breakdown in a gas at a constant temperature (usually room temperature), and it needs to be modified for gas breakdown at other temperatures. The temperature stability of the piezoelectricity in ferroelectrets after charging at elevated temperatures was investigated by several researchers.18-21 Recently, a preliminary report about the effects of the charging temperature on the hysteresis loops in ferroelectrets has been presented.22 In this letter, the influence of the gas temperature on the charging of ferroelectret systems is investigated in more detail by means of quasi-ferroelectric hysteresis-loop measurements. Teflon™ fluoroethylenepropylene (FEP) copolymer samples with tubular channels were prepared via thermal lamination as described previously.23 To this end, two FEP films with a thickness of 50 \&\#956;m each were laminated at 300 ° C around a 100 \&\#956;m thick polytetrafluoroethylene (PTFE) template (total area 35 mm × 45 mm) that contains parallel rectangular openings (area 1.5 mm × 40 mm each). After lamination, the template was removed, which results in an FEP film system with open tubular channels. The samples were metallized on both surfaces with aluminum electrodes of 20 mm diameter. P(E)-hysteresis loops were obtained with a modified Sawyer-Tower (ST) circuit.10,11 A high-voltage (HV) capacitor C1 (3 nF) and a large standard capacitor Cm (1 \&\#956;F) were connected in series with the sample. A bipolar sinusoidal voltage with a frequency of 10 mHz was applied from an HV power supply (FUG HCB 7-6500) controlled by an arbitrary-waveform generator (HP 33120a). The voltage Vout on Cm is measured by means of an electrometer (HP 3458a), and the charge flowing through the circuit is determined as Q(t)=CmVout(t) . The experiments were carried out at isothermal conditions in a Novocontrol® Quatro cryosystem. With the modified ST circuit, Q-V loops have been measured on a tubular-channel FEP ferroelectret system at different temperatures. The sample capacitance of about 34.5 pF is determined by a linear fit of the initial part of the Q-V curve recorded at 20 °C , where the voltage has been raised up from zero on a fresh sample. The hysteresis loops are obtained from the Q-V curves by subtracting the contribution that results from charging of the sample capacitance.10 Figure 1 shows the hysteresis loops of the sample at \&\#8722;100, 0, and +100 ° C, respectively. According to previous theoretical and experimental studies,24,25 the length of each of the horizontal sides of the parallelogram-like hysteresis loops is given by 2Vth where Vth is the threshold voltage. As the charging temperature decreases, the hysteresis loop becomes wider and less high, i.e., the threshold voltage increases, while the polarization at maximum voltage decreases.}, language = {en} } @article{MorettiClementiniMarconietal.2016, author = {Moretti, M. I. and Clementini, Gisella and Marconi, V. Ripepi M. and Rubele, S. and Cioni, Maria-Rosa L. and Muraveva, T. and Groenewegen, M. A. T. and Cross, N. J. G. and Ivanov, V. D. and Piatti, A. E. and de Grijs, R.}, title = {The VMC survey - XX. Identification of new Cepheids in the Small Magellanic Cloud}, series = {Monthly notices of the Royal Astronomical Society}, volume = {459}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw716}, pages = {1687 -- 1697}, year = {2016}, abstract = {We present K-s-band light curves for 299 Cepheids in the Small Magellanic Cloud (SMC) of which 288 are new discoveries that we have identified using multi-epoch near-infrared photometry obtained by the VISTA survey of the Magellanic Clouds system (VMC). The new Cepheids have periods in the range from 0.34 to 9.1 d and cover the magnitude interval 12.9 <= currency sign < K-s > <= currency sign 17.6 mag. Our method was developed using variable stars previously identified by the optical microlensing survey OGLE. We focus on searching new Cepheids in external regions of the SMC for which complete VMC K-s-band observations are available and no comprehensive identification of different types of variable stars from other surveys exists yet.}, language = {en} } @article{RettigDornesThielemannKuehnetal.2016, author = {Rettig, L. and Dornes, C. and Thielemann-Kuehn, Nele and Pontius, N. and Zabel, Hartmut and Schlagel, D. L. and Lograsso, T. A. and Chollet, M. and Robert, A. and Sikorski, M. and Song, S. and Glownia, J. M. and Schuessler-Langeheine, Christian and Johnson, S. L. and Staub, U.}, title = {Itinerant and Localized Magnetization Dynamics in Antiferromagnetic Ho}, series = {Physical review letters}, volume = {116}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.116.257202}, pages = {6382 -- 6389}, year = {2016}, abstract = {Using femtosecond time-resolved resonant magnetic x-ray diffraction at the Ho L-3 absorption edge, we investigate the demagnetization dynamics in antiferromagnetically ordered metallic Ho after femtosecond optical excitation. Tuning the x-ray energy to the electric dipole (E1, 2p -> 5d) or quadrupole (E2, 2p -> 4f) transition allows us to selectively and independently study the spin dynamics of the itinerant 5d and localized 4f electronic subsystems via the suppression of the magnetic (2 1 3-tau) satellite peak. We find demagnetization time scales very similar to ferromagnetic 4f systems, suggesting that the loss of magnetic order occurs via a similar spin-flip process in both cases. The simultaneous demagnetization of both subsystems demonstrates strong intra-atomic 4f-5d exchange coupling. In addition, an ultrafast lattice contraction due to the release of magneto-striction leads to a transient shift of the magnetic satellite peak.}, language = {en} } @article{MuellerNanovaGlaseretal.2016, author = {Mueller, Lars and Nanova, Diana and Glaser, Tobias and Beck, Sebastian and Pucci, Annemarie and Kast, Anne K. and Schroeder, Rasmus R. and Mankel, Eric and Pingel, Patrick and Neher, Dieter and Kowalsky, Wolfgang and Lovrincic, Robert}, title = {Charge-Transfer-Solvent Interaction Predefines Doping Efficiency in p-Doped P3HT Films}, series = {Chemistry of materials : a publication of the American Chemical Society}, volume = {28}, journal = {Chemistry of materials : a publication of the American Chemical Society}, publisher = {American Chemical Society}, address = {Washington}, issn = {0897-4756}, doi = {10.1021/acs.chemmater.6b01629}, pages = {4432 -- 4439}, year = {2016}, abstract = {Efficient electrical doping of organic semiconductors is a necessary prerequisite for the fabrication of high performance organic electronic devices. In this work, we study p-type doping of poly(3-hexylthiophene) (P3HT) with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F(4)TCNQ) spin-cast from two different solvents. Using electron diffraction, we find strong dopant-induced pi-pi-stacking for films from the solvent chloroform, but not from chlorobenzene. This image is confirmed and expanded by the analysis of vibrational features of P3HT and polaron absorptions using optical spectroscopy. Here, a red-shifted polaron absorption is found in doped films from chloroform, caused by a higher conjugation length of the polymer backbone. These differences result in a higher conductivity of films from chloroform. We use optical spectroscopy on the corresponding blend solutions to shed light on the origin of this effect and propose a model to explain why solutions of doped P3HT reveal more aggregation of charged molecules in chlorobenzene, whereas more order is finally observed in dried films from chloroform. Our study emphasizes the importance of solvent parameters exceeding the bare solubility of pure dopant and host material for the preparation of highly conductive doped films.}, language = {en} }