@article{ChenSavateevPronkinetal.2017, author = {Chen, Zupeng and Savateev, Aleksandr and Pronkin, Sergey and Papaefthimiou, Vasiliki and Wolff, Christian Michael and Willinger, Marc Georg and Willinger, Elena and Neher, Dieter and Antonietti, Markus and Dontsova, Dariya}, title = {"The Easier the Better" Preparation of Efficient Photocatalysts-Metastable Poly(heptazine imide) Salts}, series = {Advanced materials}, volume = {29}, journal = {Advanced materials}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0935-9648}, doi = {10.1002/adma.201700555}, pages = {21800 -- 21806}, year = {2017}, abstract = {Cost-efficient, visible-light-driven hydrogen production from water is an attractive potential source of clean, sustainable fuel. Here, it is shown that thermal solid state reactions of traditional carbon nitride precursors (cyanamide, melamine) with NaCl, KCl, or CsCl are a cheap and straightforward way to prepare poly(heptazine imide) alkali metal salts, whose thermodynamic stability decreases upon the increase of the metal atom size. The chemical structure of the prepared salts is confirmed by the results of X-ray photoelectron and infrared spectroscopies, powder X-ray diffraction and electron microscopy studies, and, in the case of sodium poly(heptazine imide), additionally by atomic pair distribution function analysis and 2D powder X-ray diffraction pattern simulations. In contrast, reactions with LiCl yield thermodynamically stable poly(triazine imides). Owing to the metastability and high structural order, the obtained heptazine imide salts are found to be highly active photo-catalysts in Rhodamine B and 4-chlorophenol degradation, and Pt-assisted sacrificial water reduction reactions under visible light irradiation. The measured hydrogen evolution rates are up to four times higher than those provided by a benchmark photocatalyst, mesoporous graphitic carbon nitride. Moreover, the products are able to photocatalytically reduce water with considerable reaction rates, even when glycerol is used as a sacrificial hole scavenger.}, language = {en} } @article{SeilerSremcevicSeissetal.2017, author = {Seiler, Martin and Sremcevic, Miodrag and Seiss, Martin and Hoffmann, Holger and Spahn, Frank}, title = {A Librational Model for the Propeller Bleriot in the Saturnian Ring System}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {840}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.3847/2041-8213/aa6d73}, pages = {6}, year = {2017}, language = {en} } @article{AbeysekaraArchambaultArcheretal.2017, author = {Abeysekara, A. U. and Archambault, S. and Archer, A. and Benbow, Wystan and Bird, Ralph and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cerruti, M. and Chen, X. and Ciupik, L. and Cui, W. and Dickinson, H. J. and Eisch, J. D. and Errando, M. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Hutten, M. and Hakansson, N. and Hanna, D. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Moriarty, P. and Mukherjee, R. and Nguyen, T. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Pelassa, V. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wilhelm, Alina and Williams, D. A. and Fegan, S. and Giebels, B. and Horan, D. and Berdyugin, A. and Kuan, J. and Lindfors, E. and Nilsson, K. and Oksanen, A. and Prokoph, H. and Reinthal, R. and Takalo, L. and Zefi, F.}, title = {A Luminous and Isolated Gamma-Ray Flare from the Blazar B2 1215+30}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {836}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration;Fermi-LAT Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/836/2/205}, pages = {6}, year = {2017}, abstract = {B2 1215+30 is a BL-Lac-type blazar that was first detected at TeV energies by the MAGIC atmospheric Cherenkov telescopes and subsequently confirmed by the Very Energetic Radiation Imaging Telescope Array System (VERITAS) observatory with data collected between 2009 and 2012. In 2014 February 08, VERITAS detected a large-amplitude flare from B2. 1215+30 during routine monitoring observations of the blazar 1ES. 1218+304, located in the same field of view. The TeV flux reached 2.4 times the Crab Nebula flux with a variability timescale of <3.6 hr. Multiwavelength observations with Fermi-LAT, Swift, and the Tuorla Observatory revealed a correlated high GeV flux state and no significant optical counterpart to the flare, with a spectral energy distribution where the gamma-ray luminosity exceeds the synchrotron luminosity. When interpreted in the framework of a onezone leptonic model, the observed emission implies a high degree of beaming, with Doppler factor delta > 10, and an electron population with spectral index p < 2.3.}, language = {en} } @article{VieyroRomeroBoschRamonetal.2017, author = {Vieyro, Florencia L. and Romero, Gustavo Esteban and Bosch-Ramon, Valentin and Marcote, Benito and del Valle, Maria Victoria}, title = {A model for the repeating FRB 121102 in the AGN scenario}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {602}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201730556}, pages = {7}, year = {2017}, abstract = {Fast radio bursts (FRBs) are transient sources of unknown origin. Recent radio and optical observations have provided strong evidence for an extragalactic origin of the phenomenon and the precise localization of the repeating FRB 121102. Observations using the Karl G. Jansky Very Large Array (VLA) and very-long-baseline interferometry (VLBI) have revealed the existence of a continuum non-thermal radio source consistent with the location of the bursts in a dwarf galaxy. All these new data rule out several models that were previously proposed, and impose stringent constraints to new models. Aims. We aim to model FRB 121102 in light of the new observational results in the active galactic nucleus (AGN) scenario. Methods. We propose a model for repeating FRBs in which a non-steady relativistic e(+)-beam, accelerated by an impulsive magneto-hydrodynamic driven mechanism, interacts with a cloud at the centre of a star-forming dwarf galaxy. The interaction generates regions of high electrostatic field called cavitons in the plasma cloud. Turbulence is also produced in the beam. These processes, plus particle isotropization, the interaction scale, and light retardation effects, provide the necessary ingredients for short-lived, bright coherent radiation bursts. Results. The mechanism studied in this work explains the general properties of FRB 121102, and may also be applied to other repetitive FRBs. Conclusions. Coherent emission from electrons and positrons accelerated in cavitons provides a plausible explanation of FRBs.}, language = {en} } @article{HintscheWaljorGrossmannetal.2017, author = {Hintsche, Marius and Waljor, Veronika and Grossmann, Robert and K{\"u}hn, Marco J. and Thormann, Kai M. and Peruani, Fernando and Beta, Carsten}, title = {A polar bundle of flagella can drive bacterial swimming by pushing, pulling, or coiling around the cell body}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Macmillan Publishers Limited, part of Springer Nature}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-16428-9}, pages = {10}, year = {2017}, abstract = {Bacteria swim in sequences of straight runs that are interrupted by turning events. They drive their swimming locomotion with the help of rotating helical flagella. Depending on the number of flagella and their arrangement across the cell body, different run-and-turn patterns can be observed. Here, we present fluorescence microscopy recordings showing that cells of the soil bacterium Pseudomonas putida that are decorated with a polar tuft of helical flagella, can alternate between two distinct swimming patterns. On the one hand, they can undergo a classical push-pull-push cycle that is well known from monopolarly flagellated bacteria but has not been reported for species with a polar bundle of multiple flagella. Alternatively, upon leaving the pulling mode, they can enter a third slow swimming phase, where they propel themselves with their helical bundle wrapped around the cell body. A theoretical estimate based on a random-walk model shows that the spreading of a population of swimmers is strongly enhanced when cycling through a sequence of pushing, pulling, and wrapped flagellar configurations as compared to the simple push-pull-push pattern.}, language = {en} } @article{PostnovOskinovaTorrejon2017, author = {Postnov, K. and Oskinova, Lida and Torrejon, J. M.}, title = {A propelling neutron star in the enigmatic Be-star gamma Cassiopeia}, series = {Monthly notices of the Royal Astronomical Society}, volume = {465}, journal = {Monthly notices of the Royal Astronomical Society}, number = {1}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnrasl/slw223}, pages = {L119 -- L123}, year = {2017}, abstract = {gamma Cassiopeia (gamma Cas), is known to be a binary system consisting of a Be-type star and a low-mass (M similar to 1M(circle dot)) companion of unknown nature orbiting in the Be-disc plane. Here, we apply the quasi-spherical accretion theory on to a compact magnetized star and show that if the low-mass companion of gamma Cas is a fast spinning neutron star, the key observational signatures of. Cas are remarkably well reproduced. Direct accretion on to this fast rotating neutron star is impeded by the propeller mechanism. In this case, around the neutron star magnetosphere a hot shell is formed which emits thermal X-rays in qualitative and quantitative agreement with observed properties of the X-ray emission from gamma Cas. We suggest that gamma Cas and its analogues constitute a new subclass of Be-type X-ray binaries hosting rapidly rotating neutron stars formed in supernova explosions with small kicks. The subsequent evolutionary stage of gamma Cas and its analogues should be the X Per-type binaries comprising low-luminosity slowly rotating X-ray pulsars. The model explains the enigmatic X-ray emission from gamma Cas, and also establishes evolutionary connections between various types of rotating magnetized neutron stars in Be-binaries.}, language = {en} } @article{JaervinenHubrigIlyinetal.2017, author = {Jaervinen, S. P. and Hubrig, Swetlana and Ilyin, Ilya and Shenar, Tomer and Schoeller, M.}, title = {A search for spectral variability in the highly magnetized O9.7 V star HD 54879}, series = {Astronomische Nachrichten = Astronomical notes}, volume = {338}, journal = {Astronomische Nachrichten = Astronomical notes}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0004-6337}, doi = {10.1002/asna.201713402}, pages = {952 -- 958}, year = {2017}, abstract = {The O9.7 V star HD 54879 possesses the second strongest magnetic field among the single, magnetic, O-type stars. In contrast to other magnetic O-type stars, the chemical abundance analysis of HD 54879 indicated a rather normal optical spectrum without obvious element enhancements or depletions. Furthermore, spectral variability was detected only in lines partly formed in the magnetosphere. As this star shows such a deviate, almost nonvariable, spectral behavior, we performed a deeper analysis of its spectral variability on different timescales using all currently available HARPSpol and FORS 2 spectropolarimetric observations. The longitudinal magnetic field strengths measured at different epochs indicate the presence of variability possibly related to stellar rotation, but the current data do not allow us yet to identify the periodicity of the field variation. As spectropolarimetric observations obtained at different epochs consist of subexposures with different integration times, we investigated spectral variability on timescales of minutes. The detected level of variability in line profiles of different elements is rather low, between 0.2 and 1.7\%, depending on the integration time of the exposures and the considered element.}, language = {en} } @article{HerrmannMetzlerEngbert2017, author = {Herrmann, Carl J. J. and Metzler, Ralf and Engbert, Ralf}, title = {A self-avoiding walk with neural delays as a model of fixational eye movements}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-13489-8}, pages = {17}, year = {2017}, abstract = {Fixational eye movements show scaling behaviour of the positional mean-squared displacement with a characteristic transition from persistence to antipersistence for increasing time-lag. These statistical patterns were found to be mainly shaped by microsaccades (fast, small-amplitude movements). However, our re-analysis of fixational eye-movement data provides evidence that the slow component (physiological drift) of the eyes exhibits scaling behaviour of the mean-squared displacement that varies across human participants. These results suggest that drift is a correlated movement that interacts with microsaccades. Moreover, on the long time scale, the mean-squared displacement of the drift shows oscillations, which is also present in the displacement auto-correlation function. This finding lends support to the presence of time-delayed feedback in the control of drift movements. Based on an earlier non-linear delayed feedback model of fixational eye movements, we propose and discuss different versions of a new model that combines a self-avoiding walk with time delay. As a result, we identify a model that reproduces oscillatory correlation functions, the transition from persistence to antipersistence, and microsaccades.}, language = {en} } @article{HerrmannMetzler2017, author = {Herrmann, Carl J. J. and Metzler, Ralf}, title = {A self-avoiding walk with neural delays as a model of fixational eye movements}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Springer Nature}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-13489-8}, pages = {1 -- 17}, year = {2017}, abstract = {Fixational eye movements show scaling behaviour of the positional mean-squared displacement with a characteristic transition from persistence to antipersistence for increasing time-lag. These statistical patterns were found to be mainly shaped by microsaccades (fast, small-amplitude movements). However, our re-analysis of fixational eye-movement data provides evidence that the slow component (physiological drift) of the eyes exhibits scaling behaviour of the mean-squared displacement that varies across human participants. These results suggest that drift is a correlated movement that interacts with microsaccades. Moreover, on the long time scale, the mean-squared displacement of the drift shows oscillations, which is also present in the displacement auto-correlation function. This finding lends support to the presence of time-delayed feedback in the control of drift movements. Based on an earlier non-linear delayed feedback model of fixational eye movements, we propose and discuss different versions of a new model that combines a self-avoiding walk with time delay. As a result, we identify a model that reproduces oscillatory correlation functions, the transition from persistence to antipersistence, and microsaccades.}, language = {en} } @article{KamannHusserDreizleretal.2017, author = {Kamann, Sebastian and Husser, T. -O. and Dreizler, S. and Emsellem, E. and Weilbacher, Peter Michael and Martens, S. and Bacon, R. and den Brok, M. and Giesers, B. and Krajnovic, Davor and Roth, Martin M. and Wendt, Martin and Wisotzki, Lutz}, title = {A stellar census in globular clusters with MUSE}, series = {Monthly notices of the Royal Astronomical Society}, volume = {473}, journal = {Monthly notices of the Royal Astronomical Society}, number = {4}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stx2719}, pages = {5591 -- 5616}, year = {2017}, abstract = {This is the first of a series of papers presenting the results from our survey of 25 Galactic globular clusters with the MUSE integral-field spectrograph. In combination with our dedicated algorithm for source deblending, MUSE provides unique multiplex capabilities in crowded stellar fields and allows us to acquire samples of up to 20 000 stars within the half-light radius of each cluster. The present paper focuses on the analysis of the internal dynamics of 22 out of the 25 clusters, using about 500 000 spectra of 200 000 individual stars. Thanks to the large stellar samples per cluster, we are able to perform a detailed analysis of the central rotation and dispersion fields using both radial profiles and two-dimensional maps. The velocity dispersion profiles we derive show a good general agreement with existing radial velocity studies but typically reach closer to the cluster centres. By comparison with proper motion data, we derive or update the dynamical distance estimates to 14 clusters. Compared to previous dynamical distance estimates for 47 Tuc, our value is in much better agreement with other methods. We further find significant (>3 sigma) rotation in the majority (13/22) of our clusters. Our analysis seems to confirm earlier findings of a link between rotation and the ellipticities of globular clusters. In addition, we find a correlation between the strengths of internal rotation and the relaxation times of the clusters, suggesting that the central rotation fields are relics of the cluster formation that are gradually dissipated via two-body relaxation.}, language = {en} } @article{VazdaCruzErtanCoutoetal.2017, author = {Vaz da Cruz, Vinicius and Ertan, Emelie and Couto, Rafael C. and Eckert, Sebastian and Fondell, Mattis and Dantz, Marcus and Kennedy, Brian and Schmitt, Thorsten and Pietzsch, Annette and Guimaraes, Freddy F. and {\AA}gren, Hans and Odelius, Michael and F{\"o}hlisch, Alexander and Kimberg, Victor}, title = {A study of the water molecule using frequency control over nuclear dynamics in resonant X-ray scattering}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {19}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c7cp01215b}, pages = {19573 -- 19589}, year = {2017}, abstract = {In this combined theoretical and experimental study we report a full analysis of the resonant inelastic X-ray scattering (RIXS) spectra of H2O, D2O and HDO. We demonstrate that electronically-elastic RIXS has an inherent capability to map the potential energy surface and to perform vibrational analysis of the electronic ground state in multimode systems. We show that the control and selection of vibrational excitation can be performed by tuning the X-ray frequency across core-excited molecular bands and that this is clearly reflected in the RIXS spectra. Using high level ab initio electronic structure and quantum nuclear wave packet calculations together with high resolution RIXS measurements, we discuss in detail the mode coupling, mode localization and anharmonicity in the studied systems.}, language = {en} } @article{VandewalBenduhnSchellhammeretal.2017, author = {Vandewal, Koen and Benduhn, Johannes and Schellhammer, Karl Sebastian and Vangerven, Tim and R{\"u}ckert, Janna E. and Piersimoni, Fortunato and Scholz, Reinhard and Zeika, Olaf and Fan, Yeli and Barlow, Stephen and Neher, Dieter and Marder, Seth R. and Manca, Jean and Spoltore, Donato and Cuniberti, Gianaurelio and Ortmann, Frank}, title = {Absorption Tails of Donor}, series = {Journal of the American Chemical Society}, volume = {139}, journal = {Journal of the American Chemical Society}, number = {4}, publisher = {American Chemical Society}, address = {Washington}, issn = {0002-7863}, doi = {10.1021/jacs.6b12857}, pages = {1699 -- 1704}, year = {2017}, abstract = {In disordered organic semiconductors, the transfer of a rather localized charge carrier from one site to another triggers a deformation of the molecular structure quantified by the intramolecular relaxation energy. A similar structural relaxation occurs upon population of intermolecular charge-transfer (CT) states formed at organic electron donor (D)-acceptor (A) interfaces. Weak CT absorption bands for D A complexes occur at photon energies below the optical gaps of both the donors and the C-60 acceptor as a result of optical transitions from the neutral ground state to the ionic CT state. In this work, we show that temperature-activated intramolecular vibrations of the ground state play a major role in determining the line shape of such CT absorption bands. This allows us to extract values for the relaxation energy related to the geometry change from neutral to ionic CT complexes. Experimental values for the relaxation energies of 20 D:C-60 CT complexes correlate with values calculated within density functional theory. These results provide an experimental method for determining the polaron relaxation energy in solid-state organic D-A blends and show the importance of a reduced relaxation energy, which we introduce to characterize thermally activated CT processes.}, language = {en} } @article{KarCherstvyMetzler2017, author = {Kar, Prathitha and Cherstvy, Andrey G. and Metzler, Ralf}, title = {Acceleration of bursty multiprotein target search kinetics on DNA by colocalisation}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {20}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, number = {12}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c7cp06922g}, pages = {7931 -- 7946}, year = {2017}, abstract = {Proteins are capable of locating specific targets on DNA by employing a facilitated diffusion process with intermittent 1D and 3D search steps. Gene colocalisation and coregulation-i.e. the spatial proximity of two communicating genes-is one factor capable of accelerating the target search process along the DNA. We perform Monte Carlo computer simulations and demonstrate the benefits of gene colocalisation for minimising the search time in a model DNA-protein system. We use a simple diffusion model to mimic the search for targets by proteins, produced initially in bursts of multiple proteins and performing the first-passage search on the DNA chain. The behaviour of the mean first-passage times to the target is studied as a function of distance between the initial position of proteins and the DNA target position, as well as versus the concentration of proteins. We also examine the properties of bursty target search kinetics for varying physical-chemical protein-DNA binding affinity. Our findings underline the relevance of colocalisation of production and binding sites for protein search inside biological cells.}, language = {en} } @article{AnielskiBarbosaPfannesBeta2017, author = {Anielski, Alexander and Barbosa Pfannes, Eva Katharina and Beta, Carsten}, title = {Adaptive microfluidic gradient generator for quantitative chemotaxis experiments}, series = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, volume = {88}, journal = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0034-6748}, doi = {10.1063/1.4978535}, pages = {10}, year = {2017}, abstract = {Chemotactic motion in a chemical gradient is an essential cellular function that controls many processes in the living world. For a better understanding and more detailed modelling of the underlying mechanisms of chemotaxis, quantitative investigations in controlled environments are needed. We developed a setup that allows us to separately address the dependencies of the chemotactic motion on the average background concentration and on the gradient steepness of the chemoattractant. In particular, both the background concentration and the gradient steepness can be kept constant at the position of the cell while it moves along in the gradient direction. This is achieved by generating a well-defined chemoattractant gradient using flow photolysis. In this approach, the chemoattractant is released by a light-induced reaction from a caged precursor in a microfluidic flow chamber upstream of the cell. The flow photolysis approach is combined with an automated real-time cell tracker that determines changes in the cell position and triggers movement of the microscope stage such that the cell motion is compensated and the cell remains at the same position in the gradient profile. The gradient profile can be either determined experimentally using a caged fluorescent dye or may be alternatively determined by numerical solutions of the corresponding physical model. To demonstrate the function of this adaptive microfluidic gradient generator, we compare the chemotactic motion of Dictyostelium discoideum cells in a static gradient and in a gradient that adapts to the position of the moving cell. Published by AIP Publishing.}, language = {en} } @article{ChechkinKantzMetzler2017, author = {Chechkin, Aleksei V. and Kantz, Holger and Metzler, Ralf}, title = {Ageing effects in ultraslow continuous time random walks}, series = {The European physical journal : B, Condensed matter and complex systems}, volume = {90}, journal = {The European physical journal : B, Condensed matter and complex systems}, publisher = {Springer}, address = {New York}, issn = {1434-6028}, doi = {10.1140/epjb/e2017-80270-9}, pages = {12}, year = {2017}, abstract = {In ageing systems physical observables explicitly depend on the time span elapsing between the original initiation of the system and the actual start of the recording of the particle motion. We here study the signatures of ageing in the framework of ultraslow continuous time random walk processes with super-heavy tailed waiting time densities. We derive the density for the forward or recurrent waiting time of the motion as function of the ageing time, generalise the Montroll-Weiss equation for this process, and analyse the ageing behaviour of the ensemble and time averaged mean squared displacements.}, language = {en} } @article{SafdariCherstvyChechkinetal.2017, author = {Safdari, Hadiseh and Cherstvy, Andrey G. and Chechkin, Aleksei V. and Bodrova, Anna and Metzler, Ralf}, title = {Aging underdamped scaled Brownian motion}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {95}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.95.012120}, pages = {15}, year = {2017}, abstract = {We investigate both analytically and by computer simulations the ensemble- and time-averaged, nonergodic, and aging properties of massive particles diffusing in a medium with a time dependent diffusivity. We call this stochastic diffusion process the (aging) underdamped scaled Brownian motion (UDSBM). We demonstrate how the mean squared displacement (MSD) and the time-averaged MSD of UDSBM are affected by the inertial term in the Langevin equation, both at short, intermediate, and even long diffusion times. In particular, we quantify the ballistic regime for the MSD and the time-averaged MSD as well as the spread of individual time-averaged MSD trajectories. One of the main effects we observe is that, both for the MSD and the time-averaged MSD, for superdiffusive UDSBM the ballistic regime is much shorter than for ordinary Brownian motion. In contrast, for subdiffusive UDSBM, the ballistic region extends to much longer diffusion times. Therefore, particular care needs to be taken under what conditions the overdamped limit indeed provides a correct description, even in the long time limit. We also analyze to what extent ergodicity in the Boltzmann-Khinchin sense in this nonstationary system is broken, both for subdiffusive and superdiffusive UDSBM. Finally, the limiting case of ultraslow UDSBM is considered, with a mixed logarithmic and power-law dependence of the ensemble-and time-averaged MSDs of the particles. In the limit of strong aging, remarkably, the ordinary UDSBM and the ultraslow UDSBM behave similarly in the short time ballistic limit. The approaches developed here open ways for considering other stochastic processes under physically important conditions when a finite particle mass and aging in the system cannot be neglected.}, language = {en} } @article{MishurovaCabezaArtztetal.2017, author = {Mishurova, Tatiana and Cabeza, Sandra and Artzt, Katia and Haubrich, Jan and Klaus, Manuela and Genzel, Christoph and Requena, Guillermo and Bruno, Giovanni}, title = {An Assessment of Subsurface Residual Stress Analysis in SLM Ti-6Al-4V}, series = {Materials}, volume = {10}, journal = {Materials}, publisher = {MDPI}, address = {Basel}, issn = {1996-1944}, doi = {10.3390/ma10040348}, pages = {14}, year = {2017}, abstract = {Ti-6Al-4V bridges were additively fabricated by selective laser melting (SLM) under different scanning speed conditions, to compare the effect of process energy density on the residual stress state. Subsurface lattice strain characterization was conducted by means of synchrotron diffraction in energy dispersive mode. High tensile strain gradients were found at the frontal surface for samples in an as-built condition. The geometry of the samples promotes increasing strains towards the pillar of the bridges. We observed that the higher the laser energy density during fabrication, the lower the lattice strains. A relief of lattice strains takes place after heat treatment.}, language = {en} } @article{RichterNuzaFoxetal.2017, author = {Richter, Philipp and Nuza, S. E. and Fox, Andrew J. and Wakker, Bart P. and Lehner, N. and Ben Bekhti, Nadya and Fechner, Cora and Wendt, Martin and Howk, J. Christopher and Muzahid, S. and Ganguly, R. and Charlton, Jane C.}, title = {An HST/COS legacy survey of high-velocity ultraviolet absorption in the}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {607}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201630081}, pages = {90}, year = {2017}, abstract = {Context. The Milky Way is surrounded by large amounts of diffuse gaseous matter that connects the stellar body of our Galaxy with its large-scale Local Group (LG) environment. Aims. To characterize the absorption properties of this circumgalactic medium (CGM) and its relation to the LG we present the so-far largest survey of metal absorption in Galactic high-velocity clouds (HVCs) using archival ultraviolet (UV) spectra of extragalactic background sources. The UV data are obtained with the Cosmic Origins Spectrograph (COS) onboard the Hubble Space Telescope (HST) and are supplemented by 21 cm radio observations of neutral hydrogen. Methods. Along 270 sightlines we measure metal absorption in the lines of Si II, Si III, C II, and C IV and associated H I 21 cm emission in HVCs in the velocity range vertical bar v(LSR)vertical bar = 100-500 km s(-1). With this unprecedented large HVC sample we were able to improve the statistics on HVC covering fractions, ionization conditions, small-scale structure, CGM mass, and inflow rate. For the first time, we determine robustly the angular two point correlation function of the high-velocity absorbers, systematically analyze antipodal sightlines on the celestial sphere, and compare the HVC absorption characteristics with that of damped Lyman alpha absorbers (DLAs) and constrained cosmological simulations of the LG (CLUES project).}, language = {en} } @article{IgnaceHoleOskinovaetal.2017, author = {Ignace, R. and Hole, K. T. and Oskinova, Lida and Rotter, J. P.}, title = {An X-Ray Study of Two B plus B Binaries: AH Cep and CW Cep}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {850}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aa93ea}, pages = {7}, year = {2017}, abstract = {AH Cep and CW Cep are both early B-type binaries with short orbital periods of 1.8. days and 2.7. days, respectively. All four components are B0.5V types. The binaries are also double-lined spectroscopic and eclipsing. Consequently, solutions for orbital and stellar parameters make the pair of binaries ideal targets for a study of the colliding winds between two B. stars. Chandra ACIS-I observations were obtained to determine X-ray luminosities. AH. Cep was detected with an unabsorbed X-ray luminosity at a 90\% confidence interval of (9-33) x 10(30) erg s(-1), or (0.5-1.7) x 10(-7) L-Bol , relative to the combined Bolometric luminosities of the two components. While formally consistent with expectations for embedded wind shocks, or binary wind collision, the near-twin system of CW Cep was a surprising nondetection. For CW Cep, an upper limit was determined with L-X/L-Bol < 10(-8), again for the combined components. One difference between these two systems is that AH Cep is part of a multiple system. The X-rays from AH. Cep may not arise from standard wind shocks nor wind collision, but perhaps instead from magnetism in any one of the four components of the system. The possibility could be tested by searching for cyclic X-ray variability in AH. Cep on the short orbital period of the inner B. stars.}, language = {en} } @article{StangeHintscheSachseetal.2017, author = {Stange, Maike and Hintsche, Marius and Sachse, Kirsten and Gerhardt, Matthias and Valleriani, Angelo and Beta, Carsten}, title = {Analyzing the spatial positioning of nuclei in polynuclear giant cells}, series = {Journal of Physics D: Applied Physics}, volume = {50}, journal = {Journal of Physics D: Applied Physics}, number = {46}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0022-3727}, doi = {10.1088/1361-6463/aa8da0}, pages = {8}, year = {2017}, abstract = {How cells establish and maintain a well-defined size is a fundamental question of cell biology. Here we investigated to what extent the microtubule cytoskeleton can set a predefined cell size, independent of an enclosing cell membrane. We used electropulse-induced cell fusion to form giant multinuclear cells of the social amoeba Dictyostelium discoideum. Based on dual-color confocal imaging of cells that expressed fluorescent markers for the cell nucleus and the microtubules, we determined the subcellular distributions of nuclei and centrosomes in the giant cells. Our two- and three-dimensional imaging results showed that the positions of nuclei in giant cells do not fall onto a regular lattice. However, a comparison with model predictions for random positioning showed that the subcellular arrangement of nuclei maintains a low but still detectable degree of ordering. This can be explained by the steric requirements of the microtubule cytoskeleton, as confirmed by the effect of a microtubule degrading drug.}, language = {en} } @article{StolterfohtWolffAmiretal.2017, author = {Stolterfoht, Martin and Wolff, Christian Michael and Amir, Yohai and Paulke, Andreas and Perdig{\´o}n-Toro, Lorena and Caprioglio, Pietro and Neher, Dieter}, title = {Approaching the fill factor Shockley-Queisser limit in stable, dopant-free triple cation perovskite solar cells}, series = {Energy \& Environmental Science}, volume = {10}, journal = {Energy \& Environmental Science}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1754-5692}, doi = {10.1039/c7ee00899f}, pages = {1530 -- 1539}, year = {2017}, abstract = {Perovskite solar cells now compete with their inorganic counterparts in terms of power conversion efficiency, not least because of their small open-circuit voltage (V-OC) losses. A key to surpass traditional thin-film solar cells is the fill factor (FF). Therefore, more insights into the physical mechanisms that define the bias dependence of the photocurrent are urgently required. In this work, we studied charge extraction and recombination in efficient triple cation perovskite solar cells with undoped organic electron/hole transport layers (ETL/HTL). Using integral time of flight we identify the transit time through the HTL as the key figure of merit for maximizing the fill factor (FF) and efficiency. Complementarily, intensity dependent photocurrent and V-OC measurements elucidate the role of the HTL on the bias dependence of non-radiative and transport-related loss channels. We show that charge transport losses can be completely avoided under certain conditions, yielding devices with FFs of up to 84\%. Optimized cells exhibit power conversion efficiencies of above 20\% for 6 mm(2) sized pixels and 18.9\% for a device area of 1 cm(2). These are record efficiencies for hybrid perovskite devices with dopant-free transport layers, highlighting the potential of this device technology to avoid charge-transport limitations and to approach the Shockley-Queisser limit.}, language = {en} } @article{ZachariasChenWagner2017, author = {Zacharias, Michael and Chen, Xuhui and Wagner, Stefan}, title = {Attenuation of TeV gamma-rays by the starlight photon field of the host galaxy}, series = {Monthly notices of the Royal Astronomical Society}, volume = {465}, journal = {Monthly notices of the Royal Astronomical Society}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw3032}, pages = {3767 -- 3774}, year = {2017}, abstract = {The absorption of TeV gamma-ray photons produced in relativistic jets by surrounding soft photon fields is a long-standing problem of jet physics. In some cases, the most likely emission site close to the central black hole is ruled out because of the high opacity caused by strong optical and infrared photon sources, such as the broad-line region. Mostly neglected for jet modelling is the absorption of gamma-rays in the starlight photon field of the host galaxy. Analysing the absorption for arbitrary locations and observation angles of the gamma-ray emission site within the host galaxy, we find that the distance to the galaxy centre, the observation angle, and the distribution of starlight in the galaxy are crucial for the amount of absorption. We derive the absorption value for a sample of 20 TeV-detected blazars with a redshift z(r) < 0.2. The absorption value of the gamma-ray emission located in the galaxy centre may be as high as 20 per cent, with an average value of 6 per cent. This is important in order to determine the intrinsic blazar parameters. We see no significant trends in our sample between the degree of absorption and host properties, such as starlight emissivity, galactic size, half-light radius, and redshift. While the uncertainty of the spectral properties of the extragalactic background light exceeds the effect of absorption by stellar light from the host galaxy in distant objects, the latter is a dominant effect in nearby sources. It may also be revealed in a differential comparison of sources with similar redshifts.}, language = {en} } @article{SchoellerHubrigFossatietal.2017, author = {Sch{\"o}ller, Markus and Hubrig, Swetlana and Fossati, L. and Carroll, Thorsten Anthony and Briquet, Maryline and Oskinova, Lida and J{\"a}rvinen, S. and Ilyin, Ilya and Castro, N. and Morel, T. and Langer, N. and Przybilla, N. and Nieva, M. -F. and Kholtygin, A. F. and Sana, H. and Herrero, A. and Barba, R. H. and de Koter, A.}, title = {B fields in OB stars (BOB)}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {599}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, organization = {BOB Collaboration}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628905}, pages = {11}, year = {2017}, abstract = {Aims. The B fields in OB stars (BOB) Collaboration is based on an ESO Large Programme to study the occurrence rate, properties, and ultimately the origin of magnetic fields in massive stars. Methods. In the framework of this program, we carried out low-resolution spectropolarimetric observations of a large sample of massive stars using FORS2 installed at the ESO VLT 8m telescope. Results. We determined the magnetic field values with two completely independent reduction and analysis pipelines. Our in-depth study of the magnetic field measurements shows that differences between our two pipelines are usually well within 3 sigma errors. From the 32 observations of 28 OB stars, we were able to monitor the magnetic fields in CPD -57 degrees 3509 and HD164492C, confirm the magnetic field in HD54879, and detect a magnetic field in CPD -62 degrees 2124. We obtain a magnetic field detection rate of 6 +/- 3\% for the full sample of 69 OB stars observed with FORS 2 within the BOB program. For the preselected objects with a nu sin i below 60 km s(-1), we obtain a magnetic field detection rate of 5 +/- 5\%. We also discuss X-ray properties and multiplicity of the objects in our FORS2 sample with respect to the magnetic field detections.}, language = {en} } @article{DelleSideNassisiPennettaetal.2017, author = {Delle Side, Domenico and Nassisi, Vincenzo and Pennetta, Cecilia and Alifano, Pietro and Di Salvo, Marco and Tala, Adelfia and Chechkin, Aleksei V. and Seno, Flavio and Trovato, Antonio}, title = {Bacterial bioluminescence onset and quenching: a dynamical model for a quorum sensing-mediated property}, series = {Royal Society Open Science}, volume = {4}, journal = {Royal Society Open Science}, publisher = {Royal Society}, address = {London}, issn = {2054-5703}, doi = {10.1098/rsos.171586}, pages = {12}, year = {2017}, abstract = {We present an effective dynamical model for the onset of bacterial bioluminescence, one of the most studied quorum sensing-mediated traits. Our model is built upon simple equations that describe the growth of the bacterial colony, the production and accumulation of autoinducer signal molecules, their sensing within bacterial cells, and the ensuing quorum activation mechanism that triggers bioluminescent emission. The model is directly tested to quantitatively reproduce the experimental distributions of photon emission times, previously measured for bacterial colonies of Vibrio jasicida, a luminescent bacterium belonging to the Harveyi clade, growing in a highly drying environment. A distinctive and novel feature of the proposed model is bioluminescence 'quenching' after a given time elapsed from activation. Using an advanced fitting procedure based on the simulated annealing algorithm, we are able to infer from the experimental observations the biochemical parameters used in the model. Such parameters are in good agreement with the literature data. As a further result, we find that, at least in our experimental conditions, light emission in bioluminescent bacteria appears to originate from a subtle balance between colony growth and quorum activation due to autoinducers diffusion, with the two phenomena occurring on the same time scale. This finding is consistent with a negative feedback mechanism previously reported for Vibrio harveyi.}, language = {en} } @article{SandevSokolovMetzleretal.2017, author = {Sandev, Trifce and Sokolov, Igor M. and Metzler, Ralf and Chechkin, Aleksei V.}, title = {Beyond monofractional kinetics}, series = {Chaos, solitons \& fractals : applications in science and engineering ; an interdisciplinary journal of nonlinear science}, volume = {102}, journal = {Chaos, solitons \& fractals : applications in science and engineering ; an interdisciplinary journal of nonlinear science}, publisher = {Elsevier}, address = {Oxford}, issn = {0960-0779}, doi = {10.1016/j.chaos.2017.05.001}, pages = {210 -- 217}, year = {2017}, abstract = {We discuss generalized integro-differential diffusion equations whose integral kernels are not of a simple power law form, and thus these equations themselves do not belong to the family of fractional diffusion equations exhibiting a monoscaling behavior. They instead generate a broad class of anomalous nonscaling patterns, which correspond either to crossovers between different power laws, or to a non-power-law behavior as exemplified by the logarithmic growth of the width of the distribution. We consider normal and modified forms of these generalized diffusion equations and provide a brief discussion of three generic types of integral kernels for each form, namely, distributed order, truncated power law and truncated distributed order kernels. For each of the cases considered we prove the non-negativity of the solution of the corresponding generalized diffusion equation and calculate the mean squared displacement. (C) 2017 Elsevier Ltd. All rights reserved.}, language = {en} } @article{BolotovSmirnovOsipovetal.2017, author = {Bolotov, Maxim I. and Smirnov, Lev A. and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Breathing chimera in a system of phase oscillators}, series = {JETP Letters}, volume = {106}, journal = {JETP Letters}, publisher = {Pleiades Publ.}, address = {New York}, issn = {0021-3640}, doi = {10.1134/S0021364017180059}, pages = {393 -- 399}, year = {2017}, abstract = {Chimera states consisting of synchronous and asynchronous domains in a medium of nonlinearly coupled phase oscillators have been considered. Stationary inhomogeneous solutions of the Ott-Antonsen equation for a complex order parameter that correspond to fundamental chimeras have been constructed. The direct numerical simulation has shown that these structures under certain conditions are transformed to oscillatory (breathing) chimera regimes because of the development of instability.}, language = {en} } @article{ChechkinSenoMetzleretal.2017, author = {Chechkin, Aleksei V. and Seno, Flavio and Metzler, Ralf and Sokolov, Igor M.}, title = {Brownian yet Non-Gaussian Diffusion: From Superstatistics to Subordination of Diffusing Diffusivities}, series = {Physical review : X, Expanding access}, volume = {7}, journal = {Physical review : X, Expanding access}, publisher = {American Physical Society}, address = {College Park}, issn = {2160-3308}, doi = {10.1103/PhysRevX.7.021002}, pages = {20}, year = {2017}, abstract = {A growing number of biological, soft, and active matter systems are observed to exhibit normal diffusive dynamics with a linear growth of the mean-squared displacement, yet with a non-Gaussian distribution of increments. Based on the Chubinsky-Slater idea of a diffusing diffusivity, we here establish and analyze a minimal model framework of diffusion processes with fluctuating diffusivity. In particular, we demonstrate the equivalence of the diffusing diffusivity process with a superstatistical approach with a distribution of diffusivities, at times shorter than the diffusivity correlation time. At longer times, a crossover to a Gaussian distribution with an effective diffusivity emerges. Specifically, we establish a subordination picture of Brownian but non-Gaussian diffusion processes, which can be used for a wide class of diffusivity fluctuation statistics. Our results are shown to be in excellent agreement with simulations and numerical evaluations.}, language = {en} } @article{KuckeinDierckeGonzalezManriqueetal.2017, author = {Kuckein, Christoph and Diercke, Andrea and Gonz{\´a}lez Manrique, Sergio Javier and Verma, Meetu and Loehner-Boettcher, Johannes and Socas-Navarro, H. and Balthasar, Horst and Sobotka, M. and Denker, Carsten}, title = {Ca II 8542 angstrom brightenings induced by a solar microflare}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {608}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201731319}, pages = {13}, year = {2017}, abstract = {Aims. We study small-scale brightenings in Ca II 8542 angstrom line-core images to determine their nature and effect on localized heating and mass transfer in active regions. Methods. High-resolution two-dimensional spectroscopic observations of a solar active region in the near-infrared Ca II 8542 angstrom line were acquired with the GREGOR Fabry-Perot Interferometer attached to the 1.5-m GREGOR telescope. Inversions of the spectra were carried out using the NICOLE code to infer temperatures and line-of-sight (LOS) velocities. Response functions of the Ca II line were computed for temperature and LOS velocity variations. Filtergrams of the Atmospheric Imaging Assembly (AIA) and magnetograms of the Helioseismic and Magnetic Imager (HMI) were coaligned to match the ground-based observations and to follow the Ca II brightenings along all available layers of the atmosphere. Results. We identified three brightenings of sizes up to 2 ' x 2 ' that appeared in the Ca II 8542 angstrom line-core images. Their lifetimes were at least 1.5 min. We found evidence that the brightenings belonged to the footpoints of a microflare (MF). The properties of the observed brightenings disqualified the scenarios of Ellerman bombs or Interface Region Imaging Spectrograph (IRIS) bombs. However, this MF shared some common properties with flaring active-region fibrils or flaring arch filaments (FAFs): (1) FAFs and MFs are both apparent in chromospheric and coronal layers according to the AIA channels; and (2) both show flaring arches with lifetimes of about 3.0-3.5 min and lengths of similar to 20 ' next to the brightenings. The inversions revealed heating by 600 K at the footpoint location in the ambient chromosphere during the impulsive phase. Connecting the footpoints, a dark filamentary structure appeared in the Ca II line-core images. Before the start of the MF, the spectra of this structure already indicated average blueshifts, meaning upward motions of the plasma along the LOS. During the impulsive phase, these velocities increased up to -2.2 km s(-1). The structure did not disappear during the observations. Downflows dominated at the footpoints. However, in the upper photosphere, slight upflows occurred during the impulsive phase. Hence, bidirectional flows are present in the footpoints of the MF.}, language = {en} } @article{YinInhesterVeeduetal.2017, author = {Yin, Zhong and Inhester, Ludger and Veedu, Sreevidya Thekku and Quevedo, Wilson and Pietzsch, Annette and Wernet, Philippe and Groenhof, Gerrit and F{\"o}hlisch, Alexander and Grubmueller, Helmut and Techert, Simone}, title = {Cationic and Anionic Impact on the Electronic Structure of Liquid Water}, series = {The journal of physical chemistry letters}, volume = {8}, journal = {The journal of physical chemistry letters}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.7b01392}, pages = {3759 -- 3764}, year = {2017}, abstract = {Hydration shells around ions are crucial for many fundamental biological and chemical processes. Their local physicochemical properties are quite different from those of bulk water and hard to probe experimentally. We address this problem by combining soft X-ray spectroscopy using a liquid jet and molecular dynamics (MD) simulations together with ab initio electronic structure calculations to elucidate the water ion interaction in a MgCl2 solution at the molecular level. Our results reveal that salt ions mainly affect the electronic properties of water molecules in close vicinity and that the oxygen K-edge X-ray emission spectrum of water molecules in the first solvation shell differs significantly from that of bulk water. Ion-specific effects are identified by fingerprint features in the water X-ray emission spectra. While Mg2+ ions cause a bathochromic shift of the water lone pair orbital, the 3p orbital of the Cl- ions causes an additional peak in the water emission spectrum at around 528 eV.}, language = {en} } @article{PetereitPikovskij2017, author = {Petereit, Johannes and Pikovskij, Arkadij}, title = {Chaos synchronization by nonlinear coupling}, series = {Communications in nonlinear science \& numerical simulation}, volume = {44}, journal = {Communications in nonlinear science \& numerical simulation}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1007-5704}, doi = {10.1016/j.cnsns.2016.09.002}, pages = {344 -- 351}, year = {2017}, abstract = {We study synchronization properties of three nonlinearly coupled chaotic maps. Coupling is introduced in such a way, that it cannot be reduced to pairwise terms, but includes combined action of all interacting units. For two models of nonlinear coupling we characterize the transition to complete synchrony, as well as partially synchronized states. Relation to hypernetworks of chaotic units is also discussed.}, language = {en} } @article{PolitiPikovskijUllner2017, author = {Politi, Antonio and Pikovskij, Arkadij and Ullner, Ekkehard}, title = {Chaotic macroscopic phases in one-dimensional oscillators}, series = {European physical journal special topics}, volume = {226}, journal = {European physical journal special topics}, publisher = {Springer}, address = {Heidelberg}, issn = {1951-6355}, doi = {10.1140/epjst/e2017-70056-4}, pages = {1791 -- 1810}, year = {2017}, abstract = {The connection between the macroscopic description of collective chaos and the underlying microscopic dynamics is thoroughly analysed in mean-field models of one-dimensional oscillators. We investigate to what extent infinitesimal perturbations of the microscopic configurations can provide information also on the stability of the corresponding macroscopic phase. In ensembles of identical one-dimensional dynamical units, it is possible to represent the microscopic configurations so as to make transparent their connection with the macroscopic world. As a result, we find evidence of an intermediate, mesoscopic, range of distances, over which the instability is neither controlled by the microscopic equations nor by the macroscopic ones. We examine a whole series of indicators, ranging from the usual microscopic Lyapunov exponents, to the collective ones, including finite-amplitude exponents. A system of pulse-coupled oscillators is also briefly reviewed as an example of non-identical phase oscillators where collective chaos spontaneously emerges.}, language = {en} } @article{AbdallaAbramowskiAharonianetal.2017, author = {Abdalla, H. and Abramowski, A. and Aharonian, Felix A. and Benkhali, F. Ait and Akhperjanian, A. G. and Andersson, T. and Anguener, E. O. and Arrieta, M. and Aubert, P. and Backes, M. and Balzer, A. and Barnard, M. and Becherini, Y. and Tjus, J. Becker and Berge, D. and Bernhard, S. and Bernlorhr, K. and Blackwell, R. and Bottcher, M. and Boisson, C. and Bolmont, J. and Bordas, Pol and Bregeon, J. and Brun, F. and Brun, P. and Bryan, M. and Bulik, T. and Capasso, M. and Carr, J. and Casanova, Sabrina and Cerruti, M. and Chakraborty, N. and Chalme-Calvet, R. and Chaves, R. C. G. and Chen, A. and Chevalier, J. and Chretien, M. and Colafrancesco, S. and Cologna, G. and Condon, B. and Conrad, J. and Cui, Y. and Davids, I. D. and Decock, J. and Degrange, B. and Deil, C. and Devin, J. and deWilt, P. and Dirson, L. and Djannati-Atai, A. and Domainko, W. and Donath, A. and Dubus, G. and Dutson, K. and Dyks, J. and Edwards, T. and Egberts, Kathrin and Eger, P. and Ernenwein, J. -P. and Eschbach, S. and Farnier, C. and Fegan, S. and Fernandes, M. V. and Fiasson, A. and Fontaine, G. and Foerster, A. and Funk, S. and Fuessling, M. and Gabici, S. and Gajdus, M. and Gallant, Y. A. and Garrigoux, T. and Giavitto, G. and Giebels, B. and Glicenstein, J. F. and Gottschall, D. and Goyal, A. and Grondin, M. -H. and Hadasch, D. and Hahn, J. and Haupt, M. and Hawkes, J. and Heinzelmann, G. and Henri, G. and Hermann, G. and Hervet, O. and Hinton, J. A. and Hofmann, W. and Hoischen, Clemens and Holler, M. and Horns, D. and Ivascenko, A. and Jacholkowska, A. and Jamrozy, M. and Janiak, M. and Jankowsky, D. and Jankowsky, F. and Jingo, M. and Jogler, T. and Jouvin, L. and Jung-Richardt, I. and Kastendieck, M. A. and Katarzynski, K. and Katz, U. and Kerszberg, D. and Khelifi, B. and Er, M. Kie Ff and King, J. and Klepser, S. and Klochkov, D. and Kluzniak, W. and Kolitzus, D. and Komin, Nu. and Kosack, K. and Krakau, S. and Kraus, M. and Krayzel, F. and Kruger, P. P. and Laffon, H. and Lamanna, G. and Lau, J. and Lees, J. -P. and Lefaucheur, J. and Lefranc, V. and Lemiere, A. and Lemoine-Goumard, M. and Lenain, J. -P. and Leser, E. and Lohse, T. and Lorentz, M. and Liu, R. and Lopez-Coto, R. and Lypova, I. and Marandon, V. and Marcowith, Alexandre and Mariaud, C. and Marx, R. and Maurin, G. and Maxted, N. and Mayer, M. and Meintjes, P. J. and Meyer, M. and Mitchell, A. M. W. and Moderski, R. and Mohamed, M. and Mohrmann, L. and Mora, K. and Moulin, Emmanuel and Murach, T. and de Naurois, M. and Niederwanger, F. and Niemiec, J. and Oakes, L. and Odaka, H. and Oettl, S. and Ohm, S. and Ostrowski, M. and Oya, I. and Padovani, M. and Panter, M. and Parsons, R. D. and Pekeur, N. W. and Pelletier, G. and Perennes, C. and Petrucci, P. -O. and Peyaud, B. and Piel, Q. and Pita, S. and Poon, H. and Prokhorov, D. and Prokoph, H. and Puehlhofer, G. and Punch, M. and Quirrenbach, A. and Raab, S. and Reimer, A. and Reimer, O. and Renaud, M. and de los Reyes, R. and Rieger, F. and Romoli, C. and Rosier-Lees, S. and Rowell, G. and Rudak, B. and Rulten, C. B. and Sahakian, V. and Salek, D. and Sanchez, D. A. and Santangelo, A. and Sasaki, M. and Schlickeiser, R. and Schussler, F. and Schulz, A. and Schwanke, U. and Schwemmer, S. and Settimo, M. and Seyffert, A. S. and Shafi, N. and Shilon, I. and Simoni, R. and Sol, H. and Spanier, F. and Spengler, G. and Spies, F. and Ert, Ff and Stawarz, L. and Steenkamp, R. and Stegmann, Christian Michael and Stinzing, F. and Stycz, K. and Sushch, I. and Tavernet, J. -P. and Tavernier, T. and Taylor, A. M. and Terrier, R. and Tibaldo, L. and Tiziani, D. and Tluczykont, M. and Trichard, C. and Tuffs, R. and Uchiyama, Y. and van der Walt, D. J. and van Eldik, C. and van Rensburg, C. and van Soelen, B. and Vasileiadis, G. and Veh, J. and Venter, C. and Viana, A. and Vincent, P. and Vink, J. and Voisin, F. and Voelk, H. J. and Vuillaume, T. and Wadiasingh, Z. and Wagner, S. J. and Wagner, P. and Wagner, R. M. and White, R. and Wierzcholska, A. and Willmann, P. and Woernlein, A. and Wouters, D. and Yang, R. and Zabalza, V. and Zaborov, D. and Zacharias, M. and Zdziarski, A. A. and Zech, Alraune and Zefi, F. and Ziegler, A. and Zywucka, N.}, title = {Characterizing the gamma-ray long-term variability of PKS2155 304 with HESS and Fermi-LAT}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {598}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, organization = {HESS Collaboration}, issn = {1432-0746}, doi = {10.1051/0004-6361/201629419}, pages = {11}, year = {2017}, abstract = {Studying the temporal variability of BL Lac objects at the highest energies provides unique insights into the extreme physical processes occurring in relativistic jets and in the vicinity of super-massive black holes. To this end, the long-term variability of the BL Lac object PKS 2155 304 is analyzed in the high (HE, 100MeV < E < 300 GeV) and very high energy (VHE, E > 200 GeV) gamma-ray domain. Over the course of similar to 9 yr of H. E. S. S. observations the VHE light curve in the quiescent state is consistent with a log-normal behavior. The VHE variability in this state is well described by flicker noise (power-spectral-density index beta(VHE) = 1 .10(+ 0 : 10) (0 : 13)) on timescales larger than one day. An analysis of similar to 5.5 yr of HE Fermi-LAT data gives consistent results (beta(HE) = 1 : 20(+ 0 : 21) (0 : 23), on timescales larger than 10 days) compatible with the VHE findings. The HE and VHE power spectral densities show a scale invariance across the probed time ranges. A direct linear correlation between the VHE and HE fluxes could neither be excluded nor firmly established. These long-term-variability properties are discussed and compared to the red noise behavior (beta similar to 2) seen on shorter timescales during VHE-flaring states. The difference in power spectral noise behavior at VHE energies during quiescent and flaring states provides evidence that these states are influenced by different physical processes, while the compatibility of the HE and VHE long-term results is suggestive of a common physical link as it might be introduced by an underlying jet-disk connection.}, language = {en} } @article{RolandYanZhangetal.2017, author = {Roland, Steffen and Yan, Liang and Zhang, Qianqian and Jiao, Xuechen and Hunt, Adrian and Ghasemi, Masoud and Ade, Harald and You, Wei and Neher, Dieter}, title = {Charge Generation and Mobility-Limited Performance of Bulk Heterojunction Solar Cells with a Higher Adduct Fullerene}, series = {The journal of physical chemistry : C, Nanomaterials and interfaces}, volume = {121}, journal = {The journal of physical chemistry : C, Nanomaterials and interfaces}, publisher = {American Chemical Society}, address = {Washington}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.7b02288}, pages = {10305 -- 10316}, year = {2017}, abstract = {Alternative electron acceptors are being actively explored in order to advance the development of bulk-heterojunction (BHJ) organic solar cells (OSCs). The indene-C-60 bisadduct (ICBA) has been regarded as a promising candidate, as it provides high open-circuit voltage in BHJ solar cells; however, the photovoltaic performance of such ICBA-based devices is often inferior when compared to cells with the omnipresent PCBM electron acceptor. Here, by pairing the high performance polymer (FTAZ) as the donor with either PCBM or ICBA as the acceptor, we explore the physical mechanism behind the reduced performance of the ICBA-based device. Time delayed collection field (TDCF) experiments reveal reduced, yet field-independent free charge generation in the FTAZ:ICBA system, explaining the overall lower photocurrent in its cells. Through the analysis of the photoluminescence, photogeneration, and electroluminescence, we find that the lower generation efficiency is neither caused by inefficient exciton splitting, nor do we find evidence for significant energy back-transfer from the CT state to singlet excitons. In fact, the increase in open circuit voltage when replacing PCBM by ICBA is entirely caused by the increase in the CT energy, related to the shift in the LUMO energy, while changes in the radiative and nonradiative recombination losses are nearly absent. On the other hand, space charge limited current (SCLC) and bias-assisted charge extraction (BACE) measurements consistently reveal a severely lower electron mobilitiy in the FTAZ:ICBA blend. Studies of the blends with resonant soft X-ray scattering (R-SoXS), grazing incident wide-angle X-ray scattering (GIWAXS), and scanning transmission X-ray microscopy (STXM) reveal very little differences in the mesoscopic morphology but significantly less nanoscale molecular ordering of the fullerene domains in the ICBA based blends, which we propose as the main cause for the lower generation efficiency and smaller electron mobility. Calculations of the JV curves with an analytical model, using measured values, show good agreement with the experimentally determined JV characteristics, proving that these devices suffer from slow carrier extraction, resulting in significant bimolecular recombination losses. Therefore, this study highlights the importance of high charge carrier mobility for newly synthesized acceptor materials, in addition to having suitable energy levels.}, language = {en} } @article{KoopmanNataliDonatietal.2017, author = {Koopman, Wouter-Willem Adriaan and Natali, Marco and Donati, Giovanni P. and Muccini, Michele and Toffanin, Stefano}, title = {Charge-exciton interaction rate in organic field-effect transistors by means of transient photoluminescence electromodulated spectroscopy}, series = {ACS photonics}, volume = {4}, journal = {ACS photonics}, number = {2}, publisher = {American Chemical Society}, address = {Washington, DC}, issn = {2330-4022}, doi = {10.1021/acsphotonics.6b00573}, pages = {282 -- 291}, year = {2017}, abstract = {Organic light-emitting transistors (OLETs) offer a huge potential for the design of highly integrated multifunctional optoelectronic systems and of intense nano scale light sources, such as the long-searched-for electrically pumped organic laser. In order to fulfill these promises, the efficiency and brightness of the current state-of-the-art devices have to be increased significantly. The dominating quenching process limiting the external quantum efficiency in OLETs is charge-exciton interaction. A comprehensive understanding of this quenching process is therefore of paramount importance. The present article reports a systematic investigation of charge-exciton interaction in organic transistors employing time resolved photoluminescence electro-modulation (PLEM) spectroscopy on the picosecond time scale. The results show that the injected charges reduce the exciton radiative recombination in two ways: (i) charges may prevent the generation of excitons and (ii) charges activate a further nonradiative channel for the exciton decay. Moreover, the transient PLEM measurements clearly reveal that not only trapped charges, as already reported in literature, but rather the entire injected charge density contributes to the quenching of the exciton population.}, language = {en} } @article{WangRychkovGerhard2017, author = {Wang, Jingwen and Rychkov, Dmitry and Gerhard, Reimund}, title = {Chemical modification with orthophosphoric acid enhances surface-charge stability on polypropylene electrets}, series = {Applied physics letters}, volume = {110}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4983348}, pages = {5}, year = {2017}, abstract = {The low surface-charge stability of polypropylene (PP) frequently limits its application as an electret material. In this paper, we demonstrate how the treatment of PP-film surfaces with orthophosphoric acid (H3PO4) enhances their charge stability. To discriminate between the effects of chemical modification and thermal treatment, as-received and annealed PP films are used as reference samples. The electret properties of treated and non-treated PP films are characterized with thermally stimulated discharge (TSD) and isothermal surface-potential decay (ISPD) experiments, from which considerable improvement in thermal and temporal charge stability is observed for samples modified with H3PO4. The half-value temperature (T-1/2) observed on TSD curves of chemically treated PP increases to 131 and 145 degrees C for positive and negative charges, respectively. The enhancement might be attributed to the phosphoric compounds detected on the H3PO4-modified surfaces via attenuated-total-reflection infrared spectroscopy. Deeper surface traps formed at the "foreign" phosphorus-containing structures are able to capture the charges over longer time periods and at higher temperatures, thus leading to significant improvements in the temporal and thermal surface-charge stabilities of PP electrets. Published by AIP Publishing.}, language = {en} } @article{SmirnovOsipovPikovskij2017, author = {Smirnov, Lev A. and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Chimera patterns in the Kuramoto-Battogtokh model}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {50}, journal = {Journal of physics : A, Mathematical and theoretical}, number = {8}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8121/aa55f1}, pages = {10}, year = {2017}, abstract = {Kuramoto and Battogtokh (2002 Nonlinear Phenom. Complex Syst. 5 380) discovered chimera states represented by stable coexisting synchrony and asynchrony domains in a lattice of coupled oscillators. After a reformulation in terms of a local order parameter, the problem can be reduced to partial differential equations. We find uniformly rotating, spatially periodic chimera patterns as solutions of a reversible ordinary differential equation, and demonstrate a plethora of such states. In the limit of neutral coupling they reduce to analytical solutions in the form of one-and two-point chimera patterns as well as localized chimera solitons. Patterns at weakly attracting coupling are characterized by virtue of a perturbative approach. Stability analysis reveals that only the simplest chimeras with one synchronous region are stable.}, language = {en} } @article{ZaksPikovskij2017, author = {Zaks, Michael and Pikovskij, Arkadij}, title = {Chimeras and complex cluster states in arrays of spin-torque oscillators}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-04918-9}, pages = {10}, year = {2017}, abstract = {We consider synchronization properties of arrays of spin-torque nano-oscillators coupled via an RC load. We show that while the fully synchronized state of identical oscillators may be locally stable in some parameter range, this synchrony is not globally attracting. Instead, regimes of different levels of compositional complexity are observed. These include chimera states (a part of the array forms a cluster while other units are desynchronized), clustered chimeras (several clusters plus desynchronized oscillators), cluster state (all oscillators form several clusters), and partial synchronization (no clusters but a nonvanishing mean field). Dynamically, these states are also complex, demonstrating irregular and close to quasiperiodic modulation. Remarkably, when heterogeneity of spin-torque oscillators is taken into account, dynamical complexity even increases: close to the onset of a macroscopic mean field, the dynamics of this field is rather irregular.}, language = {en} } @article{ZaksPikovskij2017, author = {Zaks, Michael A. and Pikovskij, Arkadij}, title = {Chimeras and complex cluster states in arrays of spin-torque oscillators}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Macmillan Publishers Limited}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-04918-9}, year = {2017}, abstract = {We consider synchronization properties of arrays of spin-torque nano-oscillators coupled via an RC load. We show that while the fully synchronized state of identical oscillators may be locally stable in some parameter range, this synchrony is not globally attracting. Instead, regimes of different levels of compositional complexity are observed. These include chimera states (a part of the array forms a cluster while other units are desynchronized), clustered chimeras (several clusters plus desynchronized oscillators), cluster state (all oscillators form several clusters), and partial synchronization (no clusters but a nonvanishing mean field). Dynamically, these states are also complex, demonstrating irregular and close to quasiperiodic modulation. Remarkably, when heterogeneity of spin-torque oscillators is taken into account, dynamical complexity even increases: close to the onset of a macroscopic mean field, the dynamics of this field is rather irregular.}, language = {en} } @article{WernetLeitnerJosefssonetal.2017, author = {Wernet, Philippe and Leitner, T. and Josefsson, Ida and Mazza, T. and Miedema, P. S. and Schroder, H. and Beye, Martin and Kunnus, K. and Schreck, S. and Radcliffe, P. and Dusterer, S. and Meyer, M. and Odelius, Michael and Fohlisch, Alexander}, title = {Communication: Direct evidence for sequential dissociation of gas-phase Fe(CO)(5) via a singlet pathway upon excitation at 266 nm}, series = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, volume = {146}, journal = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-9606}, doi = {10.1063/1.4984774}, pages = {5}, year = {2017}, abstract = {We prove the hitherto hypothesized sequential dissociation of Fe(CO)(5) in the gas phase upon photoexcitation at 266 nm via a singlet pathway with time-resolved valence and core-level photoelectron spectroscopy with an x-ray free-electron laser. Valence photoelectron spectra are used to identify free CO molecules and to determine the time constants of stepwise dissociation to Fe(CO)(4) within the temporal resolution of the experiment and further to Fe(CO)(3) within 3 ps. Fe 3p core-level photoelectron spectra directly reflect the singlet spin state of the Fe center in Fe(CO)(5), Fe(CO)(4), and Fe(CO)(3) showing that the dissociation exclusively occurs along a singlet pathway without triplet-state contribution. Our results are important for assessing intra- and intermolecular relaxation processes in the photodissociation dynamics of the prototypical Fe(CO)(5) complex in the gas phase and in solution, and they establish time-resolved core-level photoelectron spectroscopy as a powerful tool for determining the multiplicity of transition metals in photochemical reactions of coordination complexes. Published by AIP Publishing.}, language = {en} } @article{SchimkaGordievskayaLomadzeetal.2017, author = {Schimka, Selina and Gordievskaya, Yulia D. and Lomadze, Nino and Lehmann, Maren and von Klitzing, Regine and Rumyantsev, Artem M. and Kramarenko, Elena Yu. and Santer, Svetlana}, title = {Communication: Light driven remote control of microgels' size in the presence of photosensitive surfactant: Complete phase diagram}, series = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, volume = {147}, journal = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-9606}, doi = {10.1063/1.4986143}, pages = {5}, year = {2017}, abstract = {Here we report on a light triggered remote control of microgel size in the presence of photosensitive surfactant. The hydrophobic tail of the cationic surfactant contains azobenzene group that undergoes a reversible photo-isomerization reaction from a trans-to a cis-state accompanied by a change in the hydrophobicity of the surfactant. We have investigated light assisted behaviour and the complex formation of the microgels with azobenzene containing surfactant over the broad concentrational range starting far below and exceeding several times of the critical micelle concentration (CMC). At small surfactant concentration in solution (far below CMC), the surfactant in the trans-state accommodates within the microgel causing its compaction, while the cis-isomer desorbs out of microgel resulting in its swelling. The process of the microgel size change can be described as swelling on UV irradiation (trans-cis isomerization) and shrinking on irradiation with blue light (cis-trans isomerization). However, at the surfactant concentrations larger than CMC, the opposite behaviour is observed: the microgel swells on blue irradiation and shrinks during exposure to UV light. We explain this behaviour theoretically taking into account isomer dependent micellization of surfactant within the microgels. Published by AIP Publishing.}, language = {en} } @article{PalyulinMantsevichKlagesetal.2017, author = {Palyulin, Vladimir V. and Mantsevich, Vladimir N. and Klages, Rainer and Metzler, Ralf and Chechkin, Aleksei V.}, title = {Comparison of pure and combined search strategies for single and multiple targets}, series = {The European physical journal : B, Condensed matter and complex systems}, volume = {90}, journal = {The European physical journal : B, Condensed matter and complex systems}, publisher = {Springer}, address = {New York}, issn = {1434-6028}, doi = {10.1140/epjb/e2017-80372-4}, pages = {20 -- 37}, year = {2017}, abstract = {We address the generic problem of random search for a point-like target on a line. Using the measures of search reliability and efficiency to quantify the random search quality, we compare Brownian search with Levy search based on long-tailed jump length distributions. We then compare these results with a search process combined of two different long-tailed jump length distributions. Moreover, we study the case of multiple targets located by a Levy searcher.}, language = {en} } @article{GoldobinPimenovaRosenblumetal.2017, author = {Goldobin, Denis S. and Pimenova, Anastasiya V. and Rosenblum, Michael and Pikovskij, Arkadij}, title = {Competing influence of common noise and desynchronizing coupling on synchronization in the Kuramoto-Sakaguchi ensemble}, series = {European physical journal special topics}, volume = {226}, journal = {European physical journal special topics}, publisher = {Springer}, address = {Heidelberg}, issn = {1951-6355}, doi = {10.1140/epjst/e2017-70039-y}, pages = {1921 -- 1937}, year = {2017}, abstract = {We describe analytically synchronization and desynchronization effects in an ensemble of phase oscillators driven by common noise and by global coupling. Adopting the Ott-Antonsen ansatz, we reduce the dynamics to closed stochastic equations for the order parameters, and study these equations for the cases of populations of identical and nonidentical oscillators. For nonidentical oscillators we demonstrate a counterintuitive effect of divergence of individual frequencies for moderate repulsive coupling, while the order parameter remains large.}, language = {en} } @article{MenzelPuhlmannHeuer2017, author = {Menzel, Ralf and Puhlmann, Dirk and Heuer, Axel}, title = {Complementarity in single photon interference - the role of the mode function and vacuum fields}, series = {Journal of the European Optical Society-Rapid}, volume = {13}, journal = {Journal of the European Optical Society-Rapid}, publisher = {Springer}, issn = {1990-2573}, doi = {10.1186/s41476-017-0036-x}, pages = {7}, year = {2017}, abstract = {Background In earlier experiments the role of the vacuum fields could be demonstrated as the source of complementarity with respect to the temporal properties (Heuer et al., Phys. Rev. Lett. 114:053601, 2015). Methods Single photon first order interferences of spatially separated regions from the cone structure of spontaneous parametric down conversion allow for analyzing the role of the mode function in quantum optics regarding the complementarity principle. Results Here the spatial coherence properties of these vacuum fields are demonstrated as the physical reason for complementarity in these single photon quantum optical experiments. These results are directly connected to the mode picture in classical optics. Conclusion The properties of the involved vacuum fields selected via the measurement process are the physical background of the complementarity principle in quantum optics.}, language = {en} } @article{ShenarOskinovaJaervinenetal.2017, author = {Shenar, Tomer and Oskinova, Lida and Jaervinen, S. P. and Luckas, P. and Hainich, Rainer and Todt, Helge Tobias and Hubrig, Swetlana and Sander, Andreas Alexander Christoph and Ilyin, Ilya and Hamann, Wolf-Rainer}, title = {Constraining the weak-wind problem}, series = {Contributions Of The Astronomical Observatory Skalnate Pleso}, volume = {48}, journal = {Contributions Of The Astronomical Observatory Skalnate Pleso}, number = {1}, publisher = {Astronomick{\´y} {\´U}stav SAV}, address = {Tatransk{\´a} Lomnica}, issn = {1335-1842}, doi = {10.1051/0004-6361/201731291}, pages = {139 -- 143}, year = {2017}, abstract = {Mass-loss rates of massive, late type main sequence stars are much weaker than currently predicted, but their true values are very difficult to measure. We suggest that confined stellar winds of magnetic stars can be exploited to constrain the true mass-loss rates M of massive main sequence stars. We acquired UV, X-ray, and optical amateur data of HD 54879 (09.7 V), one of a few O-type stars with a detected atmospheric magnetic field (B-d greater than or similar to 2 kG). We analyze these data with the Potsdam Wolf-Rayet (PoWR) and XSPEC codes. We can roughly estimate the mass-loss rate the star would have in the absence of a magnetic field as log M-B=0 approximate to -9.0 M-circle dot yr(-1). Since the wind is partially trapped within the Alfven radius rA greater than or similar to 12 R-*,, the true mass-loss rate of HD 54879 is log M less than or similar to -10.2 M-circle dot yr(-1). Moreover, we find that the microturbulent, macroturbulent, and projected rotational velocities are lower than previously suggested (< 4 km s(-1)). An initial mass of 16 M-circle dot and an age of 5 Myr are inferred. We derive a mean X-ray emitting temperature of log T-x = 6.7 K and an X-ray luminosity of log L-x = 32 erg s(-1). The latter implies a significant X-ray excess (log L-x/L-Bol approximate to - 6.0), most likely stemming from collisions at the magnetic equator. A tentative period of P approximate to 5 yr is derived from variability of the Ha line. Our study confirms that strongly magnetized stars lose little or no mass, and supplies important constraints on the weak-wind problem of massive main sequence stars.}, language = {en} } @article{MuenchKipfstuhlFreitagetal.2017, author = {Muench, Thomas and Kipfstuhl, Sepp and Freitag, Johannes and Meyer, Hanno and Laepple, Thomas}, title = {Constraints on post-depositional isotope modifications in East Antarctic firn from analysing temporal changes of isotope profiles}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {11}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-11-2175-2017}, pages = {2175 -- 2188}, year = {2017}, abstract = {The isotopic composition of water in ice sheets is extensively used to infer past climate changes. In low-accumulation regions their interpretation is, however, challenged by poorly constrained effects that may influence the initial isotope signal during and after deposition of the snow. This is reflected in snow-pit isotope data from Kohnen Station, Antarctica, which exhibit a seasonal cycle but also strong interannual variations that contradict local temperature observations. These inconsistencies persist even after averaging many profiles and are thus not explained by local stratigraphic noise. Previous studies have suggested that post-depositional processes may significantly influence the isotopic composition of East Antarctic firn. Here, we investigate the importance of post-depositional processes within the open-porous firn (greater than or similar to 10 cm depth) at Kohnen Station by separating spatial from temporal variability. To this end, we analyse 22 isotope profiles obtained from two snow trenches and examine the temporal isotope modifications by comparing the new data with published trench data extracted 2 years earlier. The initial isotope profiles undergo changes over time due to downward advection, firn diffusion and densification in magnitudes consistent with independent estimates. Beyond that, we find further modifications of the original isotope record to be unlikely or small in magnitude (<< 1 parts per thousand RMSD). These results show that the discrepancy between local temperatures and isotopes most likely originates from spatially coherent processes prior to or during deposition, such as precipitation intermittency or systematic isotope modifications acting on drifting or loose surface snow.}, language = {en} } @article{KegelesOriti2017, author = {Kegeles, Alexander and Oriti, Daniele}, title = {Continuous point symmetries in group field theories}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {50}, journal = {Journal of physics : A, Mathematical and theoretical}, number = {12}, publisher = {IOP Publishing Ltd}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8121/aa5c14}, pages = {36}, year = {2017}, abstract = {We discuss the notion of symmetries in non-local field theories characterized by integro-differential equations of motion, from a geometric perspective. We then focus on group field theory (GFT) models of quantum gravity and provide a general analysis of their continuous point symmetry transformations, including the generalized conservation laws following from them.}, language = {en} } @article{DahlkeMaturilli2017, author = {Dahlke, Sandro and Maturilli, Marion}, title = {Contribution of atmospheric advection to the amplified winter warming in the arctic north atlantic region}, series = {Advances in meteorology}, journal = {Advances in meteorology}, publisher = {Hindawi Publ. Corp.}, address = {New York}, issn = {1687-9309}, doi = {10.1155/2017/4928620}, pages = {8}, year = {2017}, abstract = {Arctic Amplification of climate warming is caused by various feedback processes in the atmosphere-ocean-ice system and yields the strongest temperature increase during winter in the Arctic North Atlantic region. In our study, we attempt to quantify the advective contribution to the observed atmospheric warming in the Svalbard area. Based on radiosonde measurements from Ny-{\AA}lesund, a strong dependence of the tropospheric temperature on the synoptic flow direction is revealed. Using FLEXTRA backward trajectories, an increase of advection from the lower latitude Atlantic region towards Ny-{\AA}lesund is found that is attributed to a change in atmospheric circulation patterns. We find that about one-quarter (0.45 K per decade) of the observed atmospheric winter near surface warming trend in the North Atlantic region of the Arctic (2 K per decade) is due to increased advection of warm and moist air from the lower latitude Atlantic region, affecting the entire troposphere.}, language = {en} } @article{GarakaniRichterBoeker2017, author = {Garakani, Tayebeh Mirzaei and Richter, Marina Juliane and B{\"o}ker, Alexander}, title = {Controlling the bio-inspired synthesis of silica}, series = {Journal of colloid and interface science}, volume = {488}, journal = {Journal of colloid and interface science}, publisher = {Elsevier}, address = {San Diego}, issn = {0021-9797}, doi = {10.1016/j.jcis.2016.10.069}, pages = {322 -- 334}, year = {2017}, abstract = {The influence of different parameters on the silicification procedure using lysozyme is reported. When polyethoxysiloxane (PEOS), an internally crosslinked silica reservoir, is used, regular structures with a narrow size distribution could be obtained only via introducing the silica precursor in two steps including initial dropping and subsequent addition of residual oil phase in one portion. We found that mixing sequence of mineralizing agents in the presence of a positively charged surfactant plays a key role in terms of silica precipitation when tetraethoxyorthosilicate (TEOS) is the oil phase. In contrast, well mineralized crumpled features with high specific surface area could be synthesized in the presence of PEOS as a silica precursor polymer, regardless of mixing sequence. Moreover, introducing sodium dodecyl sulfate (SDS) as a negatively charged surfactant resulted in regular silica sphere formation only in combination with hexylene glycol (MPD) as a specific co-solvent. Finally, it is demonstrated that by inclusion of different nanoparticles even more sophisticated hybrid materials can be generated.}, language = {en} } @article{SanderHamannTodtetal.2017, author = {Sander, Andreas Alexander Christoph and Hamann, Wolf-Rainer and Todt, Helge Tobias and Hainich, Rainer and Shenar, Tomer}, title = {Coupling hydrodynamics with comoving frame radiative transfer I. A unified approach for OB and WR stars}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {603}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201730642}, pages = {14}, year = {2017}, abstract = {Context. For more than two decades, stellar atmosphere codes have been used to derive the stellar and wind parameters of massive stars. Although they have become a powerful tool and sufficiently reproduce the observed spectral appearance, they can hardly be used for more than measuring parameters. One major obstacle is their inconsistency between the calculated radiation field and the wind stratification due to the usage of prescribed mass-loss rates and wind-velocity fields. Aims. We present the concepts for a new generation of hydrodynamically consistent non-local thermodynamical equilibrium (nonLTE) stellar atmosphere models that allow for detailed studies of radiation-driven stellar winds. As a first demonstration, this new kind of model is applied to a massive O star. Methods. Based on earlier works, the PoWR code has been extended with the option to consistently solve the hydrodynamic equation together with the statistical equations and the radiative transfer in order to obtain a hydrodynamically consistent atmosphere stratification. In these models, the whole velocity field is iteratively updated together with an adjustment of the mass-loss rate. Results. The concepts for obtaining hydrodynamically consistent models using a comoving-frame radiative transfer are outlined. To provide a useful benchmark, we present a demonstration model, which was motivated to describe the well-studied O4 supergiant zeta Pup. The obtained stellar and wind parameters are within the current range of literature values. Conclusions. For the first time, the PoWR code has been used to obtain a hydrodynamically consistent model for a massive O star. This has been achieved by a profound revision of earlier concepts used for Wolf-Rayet stars. The velocity field is shaped by various elements contributing to the radiative acceleration, especially in the outer wind. The results further indicate that for more dense winds deviations from a standard beta-law occur.}, language = {en} } @article{CaetanodeCarvalhoMetzleretal.2017, author = {Caetano, Daniel L. Z. and de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.}, title = {Critical adsorption of periodic and random polyampholytes onto charged surfaces}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {19}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c7cp04040g}, pages = {23397 -- 23413}, year = {2017}, abstract = {How different are the properties of critical adsorption of polyampholytes and polyelectrolytes onto charged surfaces? How important are the details of polyampholyte charge distribution on the onset of critical adsorption transition? What are the scaling relations governing the dependence of critical surface charge density on salt concentration in the surrounding solution? Here, we employ Metropolis Monte Carlo simulations and uncover the scaling relations for critical adsorption for quenched periodic and random charge distributions along the polyampholyte chains. We also evaluate and discuss the dependence of the adsorbed layer width on solution salinity and details of the charge distribution. We contrast our findings to the known results for polyelectrolyte adsorption onto oppositely charged surfaces, in particular, their dependence on electrolyte concentration.}, language = {en} } @article{HenkelSauerProukakis2017, author = {Henkel, Carsten and Sauer, Tim-O and Proukakis, N. P.}, title = {Cross-over to quasi-condensation: mean-field theories and beyond}, series = {Journal of physics : B, Atomic, molecular and optical physics}, volume = {50}, journal = {Journal of physics : B, Atomic, molecular and optical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0953-4075}, doi = {10.1088/1361-6455/aa6888}, pages = {19}, year = {2017}, abstract = {We analyze the cross-over of a homogeneous, weakly interacting Bose gas in one dimension from the ideal gas into the dense quasi-condensate phase. We review a number of mean-field theories, perturbative or self-consistent, and provide accurate evaluations of equation of state, density fluctuations, and correlation functions. A smooth crossover is reproduced by classical-field simulations based on the stochastic Gross-Pitaevskii equation and the Yang-Yang solution to the one-dimensional Bose gas.}, language = {en} } @article{ArchambaultArcherBenbowetal.2017, author = {Archambault, S. and Archer, A. and Benbow, W. and Bird, R. and Bourbeau, E. and Brantseg, T. and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cerruti, M. and Christiansen, J. L. and Connolly, M. P. and Cui, W. and Daniel, M. K. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Geringer-Sameth, A. and Griffin, S. and Grube, J. and H{\"u}tten, M. and Hakansson, N. and Hanna, D. and Hervet, O. and Holder, J. and Hughes, G. and Hummensky, B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Koushiappas, S. and Krause, M. and Krennrich, F. and Lang, M. J. and Lin, T. T. Y. and McArthur, S. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Pohl, M. and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Trepanier, S. and Tucci, J. V. and Tyler, J. and Wakely, S. P. and Weinstein, A. and Wilcox, P. and Williams, D. A. and Zitzer, B.}, title = {Dark matter constraints from a joint analysis of dwarf Spheroidal galaxy observations with VERITAS}, series = {Physical review : D, Particles, fields, gravitation, and cosmology}, volume = {95}, journal = {Physical review : D, Particles, fields, gravitation, and cosmology}, number = {8}, publisher = {American Physical Society}, address = {College Park}, organization = {VERITAS Collaboration}, issn = {2470-0010}, doi = {10.1103/PhysRevD.95.082001}, pages = {14}, year = {2017}, abstract = {We present constraints on the annihilation cross section of weakly interacting massive particles dark matter based on the joint statistical analysis of four dwarf galaxies with VERITAS. These results are derived from an optimized photon weighting statistical technique that improves on standard imaging atmospheric Cherenkov telescope (IACT) analyses by utilizing the spectral and spatial properties of individual photon events. We report on the results of similar to 230 hours of observations of five dwarf galaxies and the joint statistical analysis of four of the dwarf galaxies. We find no evidence of gamma-ray emission from any individual dwarf nor in the joint analysis. The derived upper limit on the dark matter annihilation cross section from the joint analysis is 1.35 x 10(-23) cm(3) s(-1) at 1 TeV for the bottom quark (b (b) over bar) final state, 2.85 x 10(-24) cm(3) s(-1) at 1 TeV for the tau lepton (tau+tau(-)) final state and 1.32 x 10-25 cm(3) s(-1) at 1 TeV for the gauge boson (gamma gamma) final state.}, language = {en} } @article{KimShprits2017, author = {Kim, Kyung-Chan and Shprits, Yuri Y.}, title = {Dependence of the amplitude of magnetosonic waves on the solar wind and AE index using Van Allen Probes}, series = {Journal of geophysical research : Space physics}, volume = {122}, journal = {Journal of geophysical research : Space physics}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2017JA024094}, pages = {6022 -- 6034}, year = {2017}, abstract = {We present the dependence of the magnetosonic wave amplitudes both outside and inside the plasmapause on the solar wind and AE index using Van Allen Probe-A spacecraft during the time period of 1 October 2012 to 31 December 2015, based on a correlation and regression analysis. Solar wind parameters considered are the southward interplanetary magnetic field (IMF B-S), solar wind number density (N-SW), and bulk speed (V-SW). We find that the wave amplitudes outside (inside) the plasmapause are well correlated with the preceding AE, IMF B-S, and N-SW with time delays, each corresponding to 2-3 h (3-4 h), 4-5 h (3-4 h), and 2-3 h (8-9 h), while the correlation with V-SW is ambiguous both inside and outside the plasmapause. As measured by the correlation coefficient, the IMF B-S is the most influential solar wind parameter that affects the dayside wave amplitudes both outside and inside the plasmapause, while N-SW contributes to enhancing the duskside waves outside the plasmapause. The AE effect on wave amplitudes is comparable to that of IMF B-S. More interestingly, regression with time histories of the solar wind parameters and the AE index preceding the wave measurements outside the plasmapause shows significant dependence on the IMF B-S, N-SW, and AE: the region of peak coefficients is changed with time delay for IMF B-S and AE, while isolated peaks around duskside remain gradually decrease with time for N-SW. In addition, the regression with magnetosonic waves inside the plasmapause shows high coefficients around prenoon sector with preceding IMF B-S and V-SW.}, language = {en} } @article{PillitteriFossatiRodriguezetal.2017, author = {Pillitteri, Ignazio and Fossati, Luca and Rodriguez, N. Castro and Oskinova, Lida and Wolk, Scott J.}, title = {Detection of magnetic field in the B2 star rho Ophiuchi A with ESO FORS2}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {610}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201732078}, pages = {4}, year = {2017}, abstract = {Circumstantial evidence suggests that magnetism and enhanced X-ray emission are likely correlated in early B-type stars: similar fractions of them (similar to 10\%) are strong and hard X-ray sources and possess strong magnetic fields. It is also known that some B-type stars have spots on their surface. Yet up to now no X-ray activity associated with spots on early-type stars was detected. In this Letter we report the detection of a magnetic field on the B2V star rho Oph A. Previously, we assessed that the X-ray activity of this star is associated with a surface spot, herewith we establish its magnetic origin. We analyze spectra of rho Oph A obtained with the FORS2 spectrograph at ESO Very Large Telescope (VLT) at two epochs, and detect a longitudinal component of the magnetic field of the order of similar to 500 G in one of the datasets. The detection of the magnetic field only at one epoch can be explained by stellar rotation which is also invoked to explain observed periodic X-ray activity. From archival HARPS ESO VLT high resolution spectra we derived the fundamental stellar parameters of rho Oph A and further constrained its age. We conclude that rho Oph A provides strong evidence for the presence of active X-ray emitting regions on young magnetized early type stars.}, language = {en} } @article{JavanainenMartinezSearaMetzleretal.2017, author = {Javanainen, Matti and Martinez-Seara, Hector and Metzler, Ralf and Vattulainen, Ilpo}, title = {Diffusion of Integral Membrane Proteins in Protein-Rich Membranes}, series = {The journal of physical chemistry letters}, volume = {8}, journal = {The journal of physical chemistry letters}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.7b01758}, pages = {4308 -- 4313}, year = {2017}, abstract = {The lateral diffusion of embedded proteins along lipid membranes in protein-poor conditions has been successfully described in terms of the Saffman-Delbruck (SD) model, which predicts that the protein diffusion coefficient D is weakly dependent on its radius R as D proportional to ln(1/R). However, instead of being protein-poor, native cell membranes are extremely crowded with proteins. On the basis of extensive molecular simulations, we here demonstrate that protein crowding of the membrane at physiological levels leads to deviations from the SD relation and to the emergence of a stronger Stokes-like dependence D proportional to 1/R. We propose that this 1/R law mainly arises due to geometrical factors: smaller proteins are able to avoid confinement effects much better than their larger counterparts. The results highlight that the lateral dynamics in the crowded setting found in native membranes is radically different from protein-poor conditions and plays a significant role in formation of functional multiprotein complexes.}, language = {en} } @article{AbeysekaraArchambaultArcheretal.2017, author = {Abeysekara, A. U. and Archambault, S. and Archer, A. and Benbow, W. and Bird, R. and Brose, Robert and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Cerruti, M. and Connolly, M. P. and Cui, W. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Huetten, M. and Hanna, D. and Hervet, O. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Petrashyk, A. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Staszak, D. and Telezhinsky, Igor O. and Tyler, J. and Vassiliev, V. V. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Zitzer, B.}, title = {Discovery of Very-high-energy Emission from RGB J2243+203 and Derivation of Its Redshift Upper Limit}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, volume = {233}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0067-0049}, doi = {10.3847/1538-4365/aa8d76}, pages = {1188 -- 1204}, year = {2017}, abstract = {Very-high-energy (VHE; > 100 GeV) gamma-ray emission from the blazar RGB J2243+203 was discovered with the VERITAS Cherenkov telescope array, during the period between 2014 December 21 and 24. The VERITAS energy spectrum from this source can be fitted by a power law with a photon index of 4.6 +/- 0.5, and a flux normalization at 0.15 TeV of (6.3 +/- 1.1) x 10(-10) cm(-2) s(-1) TeV-1. The integrated Fermi-LAT flux from 1 to 100 GeV during the VERITAS detection is (4.1 +/- 0.8) x 10(-8) cm(-2) s(-1), which is an order of magnitude larger than the four-year-averaged flux in the same energy range reported in the 3FGL catalog, (4.0 +/- 0.1 x 10(-9) cm(-2) s(-1)). The detection with VERITAS triggered observations in the X-ray band with the Swift-XRT. However, due to scheduling constraints Swift-XRT observations were performed 67 hr after the VERITAS detection, rather than simultaneously with the VERITAS observations. The observed X-ray energy spectrum between 2 and 10 keV can be fitted with a power law with a spectral index of 2.7 +/- 0.2, and the integrated photon flux in the same energy band is (3.6 +/- 0.6) x 10(-13) cm(-2) s(-1). EBL-model-dependent upper limits of the blazar redshift have been derived. Depending on the EBL model used, the upper limit varies in the range from z < 0.9 to z < 1.1.}, language = {en} } @article{NiskanenSahleGilmoreetal.2017, author = {Niskanen, Johannes and Sahle, Christoph J. and Gilmore, Keith and Uhlig, Frank and Smiatek, Jens and F{\"o}hlisch, Alexander}, title = {Disentangling structural information from core-level excitation spectra}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {96}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.96.013319}, pages = {8}, year = {2017}, abstract = {Core-level spectra of liquids can be difficult to interpret due to the presence of a range of local environments. We present computational methods for investigating core-level spectra based on the idea that both local structural parameters and the x-ray spectra behave as functions of the local atomic configuration around the absorbing site. We identify correlations between structural parameters and spectral intensities in defined regions of interest, using the oxygen K-edge excitation spectrum of liquid water as a test case. Our results show that this kind of analysis can find the main structure-spectral relationships of ice, liquid water, and supercritical water.}, language = {en} } @article{HofackerNeher2017, author = {Hofacker, Andreas and Neher, Dieter}, title = {Dispersive and steady-state recombination in organic disordered semiconductors}, series = {Physical review : B, Condensed matter and materials physics}, volume = {96}, journal = {Physical review : B, Condensed matter and materials physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9950}, doi = {10.1103/PhysRevB.96.245204}, pages = {11}, year = {2017}, abstract = {Charge carrier recombination in organic disordered semiconductors is strongly influenced by the thermalization of charge carriers in the density of states (DOS). Measurements of recombination dynamics, conducted under transient or steady-state conditions, can easily be misinterpreted when a detailed understanding of the interplay of thermalization and recombination is missing. To enable adequate measurement analysis, we solve the multiple-trapping problem for recombining charge carriers and analyze it in the transient and steady excitation paradigm for different DOS distributions. We show that recombination rates measured after pulsed excitation are inherently time dependent since recombination gradually slows down as carriers relax in the DOS. When measuring the recombination order after pulsed excitation, this leads to an apparent high-order recombination at short times. As times goes on, the recombination order approaches an asymptotic value. For the Gaussian and the exponential DOS distributions, this asymptotic value equals the recombination order of the equilibrated system under steady excitation. For a more general DOS distribution, the recombination order can also depend on the carrier density, under both transient and steady-state conditions. We conclude that transient experiments can provide rich information about recombination in and out of equilibrium and the underlying DOS occupation provided that consistent modeling of the system is performed.}, language = {en} } @article{HofackerNeher2017, author = {Hofacker, Andreas and Neher, Dieter}, title = {Dispersive and steady-state recombination in organic disordered semiconductors}, series = {Physical review : B, Condensed matter and materials physics}, volume = {96}, journal = {Physical review : B, Condensed matter and materials physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9950}, doi = {10.1103/PhysRevB.96.245204}, pages = {5640 -- 5649}, year = {2017}, abstract = {Charge carrier recombination in organic disordered semiconductors is strongly influenced by the thermalization of charge carriers in the density of states (DOS). Measurements of recombination dynamics, conducted under transient or steady-state conditions, can easily be misinterpreted when a detailed understanding of the interplay of thermalization and recombination is missing. To enable adequate measurement analysis, we solve the multiple-trapping problem for recombining charge carriers and analyze it in the transient and steady excitation paradigm for different DOS distributions. We show that recombination rates measured after pulsed excitation are inherently time dependent since recombination gradually slows down as carriers relax in the DOS. When measuring the recombination order after pulsed excitation, this leads to an apparent high-order recombination at short times. As times goes on, the recombination order approaches an asymptotic value. For the Gaussian and the exponential DOS distributions, this asymptotic value equals the recombination order of the equilibrated system under steady excitation. For a more general DOS distribution, the recombination order can also depend on the carrier density, under both transient and steady-state conditions. We conclude that transient experiments can provide rich information about recombination in and out of equilibrium and the underlying DOS occupation provided that consistent modeling of the system is performed.}, language = {en} } @article{ZhangPikovskijLiu2017, author = {Zhang, Xiyun and Pikovskij, Arkadij and Liu, Zonghua}, title = {Dynamics of oscillators globally coupled via two mean fields}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-02283-1}, pages = {16}, year = {2017}, abstract = {Many studies of synchronization properties of coupled oscillators, based on the classical Kuramoto approach, focus on ensembles coupled via a mean field. Here we introduce a setup of Kuramoto-type phase oscillators coupled via two mean fields. We derive stability properties of the incoherent state and find traveling wave solutions with different locking patterns; stability properties of these waves are found numerically. Mostly nontrivial states appear when the two fields compete, i.e. one tends to synchronize oscillators while the other one desynchronizes them. Here we identify normal branches which bifurcate from the incoherent state in a usual way, and anomalous branches, appearance of which cannot be described as a bifurcation. Furthermore, hybrid branches combining properties of both are described. In the situations where no stable traveling wave exists, modulated quasiperiodic in time dynamics is observed. Our results indicate that a competition between two coupling channels can lead to a complex system behavior, providing a potential generalized framework for understanding of complex phenomena in natural oscillatory systems.}, language = {en} } @article{KretschmerRungeCoumou2017, author = {Kretschmer, Marlene and Runge, Jakob and Coumou, Dim}, title = {Early prediction of extreme stratospheric polar vortex states based on causal precursors}, series = {Geophysical research letters}, volume = {44}, journal = {Geophysical research letters}, publisher = {American Geophysical Union}, address = {Washington}, issn = {0094-8276}, doi = {10.1002/2017GL074696}, pages = {8592 -- 8600}, year = {2017}, abstract = {Variability in the stratospheric polar vortex (SPV) can influence the tropospheric circulation and thereby winter weather. Early predictions of extreme SPV states are thus important to improve forecasts of winter weather including cold spells. However, dynamical models are usually restricted in lead time because they poorly capture low-frequency processes. Empirical models often suffer from overfitting problems as the relevant physical processes and time lags are often not well understood. Here we introduce a novel empirical prediction method by uniting a response-guided community detection scheme with a causal discovery algorithm. This way, we objectively identify causal precursors of the SPV at subseasonal lead times and find them to be in good agreement with known physical drivers. A linear regression prediction model based on the causal precursors can explain most SPV variability (r(2)=0.58), and our scheme correctly predicts 58\% (46\%) of extremely weak SPV states for lead times of 1-15 (16-30)days with false-alarm rates of only approximately 5\%. Our method can be applied to any variable relevant for (sub)seasonal weather forecasts and could thus help improving long-lead predictions.}, language = {en} } @article{NadammalCabezaMishurovaetal.2017, author = {Nadammal, Naresh and Cabeza, Sandra and Mishurova, Tatiana and Thiede, Tobias and Kromm, Arne and Seyfert, Christoph and Farahbod, Lena and Haberland, Christoph and Schneider, Judith Ann and Portella, Pedro Dolabella and Bruno, Giovanni}, title = {Effect of hatch length on the development of microstructure, texture and residual stresses in selective laser melted superalloy Inconel 718}, series = {Materials \& Design}, volume = {134}, journal = {Materials \& Design}, publisher = {Elsevier}, address = {Oxford}, issn = {0264-1275}, doi = {10.1016/j.matdes.2017.08.049}, pages = {139 -- 150}, year = {2017}, abstract = {In the present study, samples fabricated by varying the deposition hatch length during selective laser melting of nickel based superalloy Inconel 718 were investigated. Microstructure and texture of these samples was characterized using scanning electron microscopy, combined with electron back-scattered diffraction, and residual stress assessment, using neutron diffraction method. Textured columnar grains oriented along the sample building direction were observed in the shorter hatch length processed sample. A ten-fold increase in the hatch length reduced the texture intensity by a factor of two attributed to the formation of finer grains in the longer hatch length sample. Larger gradients of transverse residual stress in the longer hatch length sample were also observed. Along the build direction, compressive stresses in the shorter hatch length and negligible stresses for the longer hatch length specimen were observed. Changes to the temperature gradient (G) in response to the hatch length variation, influenced the G to growth rate (R) ratio and the product GxR, in agreement with the microstructures and textures formed. For the residual stress development, geometry of the part also played an important role. In summary, tailored isotropy could be induced in Inconel 718 by a careful selection of parameters during selective laser melting.}, language = {en} } @article{CooperBrunoWheeleretal.2017, author = {Cooper, Ryan C. and Bruno, Giovanni and Wheeler, M. R. and Pandey, A. and Watkins, T. R. and Shyarn, A.}, title = {Effect of microcracking on the uniaxial tensile response of beta-eucryptite ceramics}, series = {Acta Materialia}, volume = {135}, journal = {Acta Materialia}, publisher = {Elsevier}, address = {Oxford}, issn = {1359-6454}, doi = {10.1016/j.actamat.2017.06.033}, pages = {361 -- 371}, year = {2017}, abstract = {A constitutive model for the nonlinear or "pseudoplastic" mechanical behavior in a linear-elastic solid with thermally induced microcracks is developed and applied to experimental results. The model is termed strain dependent microcrack density approximation (SDMDA) and is an extension of the modified differential scheme that describes the slope of the stress-strain curves of microcracked solids. SDMDA allows a continuous variation in the microcrack density with tensile loading. Experimental uniaxial tensile response of beta-eucryptite glass and ceramics with controlled levels of microcracking is reported. It is demonstrated that SDMDA can well describe the extent of non-linearity in the experimental uniaxial tensile response of beta-eucryptite with varying levels of microcracking. The advantages of the SDMDA are discussed in regard to tensile loading.}, language = {en} } @article{RaetzelWilkensMenzel2017, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Effect of polarization entanglement in photon-photon scattering}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {95}, journal = {Physical review : A, Atomic, molecular, and optical physics}, number = {1}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9926}, doi = {10.1103/PhysRevA.95.012101}, pages = {6}, year = {2017}, abstract = {It is found that the differential cross section of photon-photon scattering is a function of the degree of polarization entanglement of the two-photon state. A reduced general expression for the differential cross section of photon-photon scattering is derived by applying simple symmetry arguments. An explicit expression is obtained for the example of photon-photon scattering due to virtual electron-positron pairs in quantum electrodynamics. It is shown how the effect in this explicit example can be explained as an effect of quantum interference and that it fits with the idea of distance-dependent forces.}, language = {en} } @article{MardoukhiMardoukhiHokkaetal.2017, author = {Mardoukhi, Ahmad and Mardoukhi, Yousof and Hokka, Mikko and Kuokkala, Veli-Tapani}, title = {Effects of heat shock on the dynamic tensile behavior of granitic rocks}, series = {Rock mechanics and rock engineering}, volume = {50}, journal = {Rock mechanics and rock engineering}, publisher = {Springer}, address = {Wien}, issn = {0723-2632}, doi = {10.1007/s00603-017-1168-4}, pages = {1171 -- 1182}, year = {2017}, abstract = {This paper presents a new experimental method for the characterization of the surface damage caused by a heat shock on a Brazilian disk test sample. Prior to mechanical testing with a Hopkinson Split Pressure bar device, the samples were subjected to heat shock by placing a flame torch at a fixed distance from the sample's surface for periods of 10, 30, and 60 s. The sample surfaces were studied before and after the heat shock using optical microscopy and profilometry, and the images were analyzed to quantify the damage caused by the heat shock. The complexity of the surface crack patterns was quantified using fractal dimension of the crack patterns, which were used to explain the results of the mechanical testing. Even though the heat shock also causes damage below the surface which cannot be quantified from the optical images, the presented surface crack pattern analysis can give a reasonable estimate on the drop rate of the tension strength of the rock.}, language = {en} } @article{MardoukhiMardoukhiHokkaetal.2017, author = {Mardoukhi, Ahmad and Mardoukhi, Yousof and Hokka, Mikko and Kuokkala, Veli-Tapani}, title = {Effects of strain rate and surface cracks on the mechanical behaviour of Balmoral Red granite}, series = {Philosophical Transactions of the Royal Society of London, Series A : Mathematical, Physical and Engineering Sciences}, volume = {375}, journal = {Philosophical Transactions of the Royal Society of London, Series A : Mathematical, Physical and Engineering Sciences}, number = {2085}, publisher = {Royal Society}, address = {London}, issn = {1364-503X}, doi = {10.1098/rsta.2016.0179}, pages = {11}, year = {2017}, abstract = {This work presents a systematic study on the effects of strain rate and surface cracks on the mechanical properties and behaviour of Balmoral Red granite. The tensile behaviour of the rock was studied at low and high strain rates using Brazilian disc samples. Heat shocks were used to produce samples with different amounts of surface cracks. The surface crack patterns were analysed using optical microscopy, and the complexity of the patterns was quantified by calculating the fractal dimensions of the patterns. The strength of the rock clearly drops as a function of increasing fractal dimensions in the studied strain rate range. However, the dynamic strength of the rock drops significantly faster than the quasi-static strength, and, because of this, also the strain rate sensitivity of the rock decreases with increasing fractal dimensions. This can be explained by the fracture behaviour and fragmentation during the dynamic loading, which is more strongly affected by the heat shock than the fragmentation at low strain rates.}, language = {en} } @article{GrebenkovMetzlerOshanin2017, author = {Grebenkov, Denis S. and Metzler, Ralf and Oshanin, Gleb}, title = {Effects of the target aspect ratio and intrinsic reactivity onto diffusive search in bounded domains}, series = {New journal of physics : the open-access journal for physics}, volume = {19}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/aa8ed9}, pages = {11}, year = {2017}, abstract = {We study the mean first passage time (MFPT) to a reaction event on a specific site in a cylindrical geometry-characteristic, for instance, for bacterial cells, with a concentric inner cylinder representing the nuclear region of the bacterial cell. A similar problem emerges in the description of a diffusive search by a transcription factor protein for a specific binding region on a single strand of DNA. We develop a unified theoretical approach to study the underlying boundary value problem which is based on a self-consistent approximation of the mixed boundary condition. Our approach permits us to derive explicit, novel, closed-form expressions for the MFPT valid for a generic setting with an arbitrary relation between the system parameters. We analyse this general result in the asymptotic limits appropriate for the above-mentioned biophysical problems. Our investigation reveals the crucial role of the target aspect ratio and of the intrinsic reactivity of the binding region, which were disregarded in previous studies. Theoretical predictions are confirmed by numerical simulations.}, language = {en} } @article{GrebenkovMetzlerOshanin2017, author = {Grebenkov, Denis S. and Metzler, Ralf and Oshanin, Gleb}, title = {Effects of the target aspect ratio and intrinsic reactivity onto diffusive search in bounded domains}, series = {New journal of physics}, volume = {19}, journal = {New journal of physics}, publisher = {IOP}, address = {London}, issn = {1367-2630}, doi = {10.1088/1367-2630/aa8ed9}, pages = {1 -- 11}, year = {2017}, abstract = {Westudy the mean first passage time (MFPT) to a reaction event on a specific site in a cylindrical geometry—characteristic, for instance, for bacterial cells, with a concentric inner cylinder representing the nuclear region of the bacterial cell. Asimilar problem emerges in the description of a diffusive search by a transcription factor protein for a specific binding region on a single strand of DNA.We develop a unified theoretical approach to study the underlying boundary value problem which is based on a self-consistent approximation of the mixed boundary condition. Our approach permits us to derive explicit, novel, closed-form expressions for the MFPT valid for a generic setting with an arbitrary relation between the system parameters.Weanalyse this general result in the asymptotic limits appropriate for the above-mentioned biophysical problems. Our investigation reveals the crucial role of the target aspect ratio and of the intrinsic reactivity of the binding region, which were disregarded in previous studies. Theoretical predictions are confirmed by numerical simulations.}, language = {en} } @article{ElNagarSarhanAbouserieetal.2017, author = {El-Nagar, Gumaa A. and Sarhan, Radwan Mohamed and Abouserie, Ahed and Maticiuc, Natalia and Bargheer, Matias and Lauermann, Iver and Roth, Christina}, title = {Efficient 3D-Silver Flower-like Microstructures for Non-Enzymatic Hydrogen Peroxide (H2O2) Amperometric Detection}, series = {Scientific reports}, volume = {7}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-017-11965-9}, pages = {8}, year = {2017}, language = {en} } @article{ZhangChenArminetal.2017, author = {Zhang, Kai and Chen, Zhiming and Armin, Ardalan and Dong, Sheng and Xia, Ruoxi and Yip, Hin-Lap and Shoaee, Safa and Huang, Fei and Cao, Yong}, title = {Efficient large area organic solar cells processed by blade-coating with single-component green solvent}, series = {Solar Rrl}, volume = {2}, journal = {Solar Rrl}, number = {1}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {2367-198X}, doi = {10.1002/solr.201700169}, pages = {9}, year = {2017}, abstract = {While the performance of laboratory-scale organic solar cells (OSCs) continues to grow, development of high efficiency large area OSCs remains a big challenge. Although a few attempts to produce large area organic solar cells (OSCs) have been reported, there are still challenges on the way to realizing efficient module devices, such as the low compatibility of the thickness-sensitive active layer with large area coating techniques, the frequent need for toxic solvents and tedious optimization processes used during device fabrication. In this work, highly efficient thickness-insensitive OSCs based on PTB7-Th:PC71BM that processed with single-component green solvent 2-methylanisole are presented, in which both junction thickness limitation and solvent toxicity issues are simultaneously addressed. Careful investigation reveals that this green solvent prevents the evolution of PC71BM into large area clusters resulting in reduced charge carrier recombination, and largely eliminates trapping centers, and thus improves the thickness tolerance of the films. These findings enable us to address the scalability and solvent toxicity issues and to fabricate a 16 cm(2) OSC with doctor-blade coating with a state-of-the-art power conversion efficiency of 7.5\% using green solvent.}, language = {en} } @article{JoštAlbrechtKegelmannetal.2017, author = {Jošt, Marko and Albrecht, Steve and Kegelmann, Lukas and Wolff, Christian Michael and Lang, Felix and Lipovšek, Benjamin and Krč, Janez and Korte, Lars and Neher, Dieter and Rech, Bernd and Topič, Marko}, title = {Efficient light management by textured nanoimprinted layers for perovskite solar cells}, series = {ACS photonics}, volume = {4}, journal = {ACS photonics}, publisher = {American Chemical Society}, address = {Washington}, issn = {2330-4022}, doi = {10.1021/acsphotonics.7b00138}, pages = {1232 -- 1239}, year = {2017}, abstract = {Inorganic-organic perovskites like methylammonium-lead-iodide have proven to be an effective class of 17 materials for fabricating efficient solar cells. To improve their performance, light management techniques using textured surfaces, similar to those used in established solar cell technologies, should be considered. Here, we apply a light management foil created by UV nanoimprint lithography on the glass side of an inverted (p-i-n) perovskite solar cell with 16.3\% efficiency. The obtained 1 mA cm(-2) increase in the short-circuit current density translates to a relative improvement in cell performance of 5\%, which results in a power conversion efficiency of 17.1\%. Optical 3D simulations based on experimentally obtained parameters were used to support the experimental findings. A good match between the simulated and experimental data was obtained, validating the model. Optical simulations reveal that the main improvement in device performance is due to a reduction in total reflection and that relative improvement in the short-circuit current density of up to 10\% is possible for large-area devices. Therefore, our results present the potential of light management foils for improving the device performance of perovskite solar cells and pave the way for further use of optical simulations in the field of perovskite solar cells.}, language = {en} } @article{MorgnerBennemannCywińskietal.2017, author = {Morgner, Frank and Bennemann, Mark and Cywiński, Piotr J. and Kollosche, Matthias and G{\´o}rski, Krzysztof and Pietraszkiewicz, Marek and Geßner, Andr{\´e} and L{\"o}hmannsr{\"o}ben, Hans-Gerd}, title = {Elastic FRET sensors for contactless pressure measurement}, series = {RSC Advances : an international journal to further the chemical sciences}, volume = {7}, journal = {RSC Advances : an international journal to further the chemical sciences}, publisher = {RSC Publishing}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/c7ra06379b}, pages = {50578 -- 50583}, year = {2017}, abstract = {Contactless pressure monitoring based on Forster resonance energy transfer between donor/acceptor pairs immobilized within elastomers is demonstrated. The donor/acceptor energy transfer is employed by dispersing terbium(III) tris[(2-hydroxybenzoyl)-2-aminoethyl] amine complex (LLC, donor) and CdSe/ZnS quantum dots (QD655, acceptor) in styrene-ethylene/buthylene-styrene (SEBS) and poly(dimethylsiloxane) (PDMS). The continuous monitoring of QD luminescence showed a reversible intensity change as the pressure signal is alternated between two stable states indicating a pressure sensitivity of 6350 cps kPa(-1). Time-resolved measurements show the pressure impact on the FRET signal due to an increase of decay time (270 ms up to 420 ms) for the donor signal and parallel drop of decay time (170 mu s to 155 mu s) for the acceptor signal as the net pressure applied. The LLC/QD655 sensors enable a contactless readout as well as space resolved monitoring to enable miniaturization towards smaller integrated stretchable opto-electronics. Elastic FRET sensors can potentially lead to developing profitable analysis systems capable to outdo conventional wired electronic systems (inductive, capacitive, ultrasonic and photoelectric sensors) especially for point-of-care diagnostics, biological monitoring required for wearable electronics.}, language = {en} } @article{ShinCherstvyKimetal.2017, author = {Shin, Jaeoh and Cherstvy, Andrey G. and Kim, Won Kyu and Zaburdaev, Vasily}, title = {Elasticity-based polymer sorting in active fluids: a Brownian dynamics study}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {19}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c7cp02947k}, pages = {18338 -- 18347}, year = {2017}, abstract = {While the dynamics of polymer chains in equilibrium media is well understood by now, the polymer dynamics in active non-equilibrium environments can be very different. Here we study the dynamics of polymers in a viscous medium containing self-propelled particles in two dimensions by using Brownian dynamics simulations. We find that the polymer center of mass exhibits a superdiffusive motion at short to intermediate times and the motion turns normal at long times, but with a greatly enhanced diffusivity. Interestingly, the long time diffusivity shows a non-monotonic behavior as a function of chain length and stiffness. We analyze how the polymer conformation and the accumulation of self-propelled particles, and therefore the directed motion of the polymer, are correlated. At the point of maximal polymer diffusivity, the polymer has preferentially bent conformations maintained by the balance between the chain elasticity and the propelling force generated by the active particles. We also consider the barrier crossing dynamics of actively-driven polymers in a double-well potential. The barrier crossing times are demonstrated to have a peculiar non-monotonic dependence, related to that of the diffusivity. This effect can be potentially utilized for sorting polymers from solutions in in vitro experiments.}, language = {en} } @article{BohdanNiemiecKobzaretal.2017, author = {Bohdan, Artem and Niemiec, Jacek and Kobzar, Oleh and Pohl, Martin}, title = {Electron Pre-acceleration at Nonrelativistic High-Mach-number Perpendicular Shocks}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {847}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aa872a}, pages = {17}, year = {2017}, abstract = {We perform particle-in-cell simulations of perpendicular nonrelativistic collisionless shocks to study electron heating and pre-acceleration for parameters that permit the extrapolation to the conditions at young supernova remnants. Our high-resolution large-scale numerical experiments sample a representative portion of the shock surface and demonstrate that the efficiency of electron injection is strongly modulated with the phase of the shock reformation. For plasmas with low and moderate temperature (plasma beta beta p =5.10(-4) and 0.5 beta p =), we explore the nonlinear shock structure and electron pre-acceleration for various orientations of the large-scale magnetic field with respect to the simulation plane, while keeping it at 90 degrees to the shock normal. Ion reflection off of the shock leads to the formation of magnetic filaments in the shock ramp, resulting from Weibel-type instabilities, and electrostatic Buneman modes in the shock foot. In all of the cases under study, the latter provides first-stage electron energization through the shock-surfing acceleration mechanism. The subsequent energization strongly depends on the field orientation and proceeds through adiabatic or second-order Fermi acceleration processes for configurations with the out-of-plane and in-plane field components, respectively. For strictly out-of-plane field, the fraction of suprathermal electrons is much higher than for other configurations, because only in this case are the Buneman modes fully captured by the 2D simulation grid. Shocks in plasma with moderate bp provide more efficient pre-acceleration. The relevance of our results to the physics of fully 3D systems is discussed.}, language = {en} } @article{MaassUtechtStremlauetal.2017, author = {Maass, Friedrich and Utecht, Manuel Martin and Stremlau, Stephan and Gille, Marie and Schwarz, Jutta and Hecht, Stefan and Klamroth, Tillmann and Tegeder, Petra}, title = {Electronic structure changes during the on-surface synthesis of nitrogen-doped chevron-shaped graphene nanoribbons}, series = {Physical review : B, Condensed matter and materials physics}, volume = {96}, journal = {Physical review : B, Condensed matter and materials physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9950}, doi = {10.1103/PhysRevB.96.045434}, pages = {7}, year = {2017}, abstract = {Utilizing suitable precursor molecules, a thermally activated and surface-assisted synthesis results in the formation of defect-free graphene nanoribbons (GNRs), which exhibit electronic properties that are not present in extended graphene. Most importantly, they have a band gap in the order of a few electron volts, depending on the nanoribbon width. In this study, we investigate the electronic structure changes during the formation of GNRs, nitrogen-doped (singly and doubly N-doped) as well as non-N-doped chevron-shaped CGNRs on Au(111). Thus we determine the optical gaps of the precursor molecules, the intermediate nonaromatic polymers, and finally the aromatic GNRs, using high-resolution electron energy loss spectroscopy and density functional theory calculations. As expected, we find no influence of N-doping on the size of the optical gaps. The gap of the precursor molecules is around 4.5 eV. Polymerization leads to a reduction of the gap to a value of 3.2 eV due to elongation and thus enhanced delocalization. The CGNRs exhibit a band gap of 2.8 eV, thus the gap is further reduced in the nanoribbons, since they exhibit an extended delocalized pi-electron system.}, language = {en} } @article{DrozdovShpritsUsanovaetal.2017, author = {Drozdov, Alexander and Shprits, Yuri Y. and Usanova, Maria E. and Aseev, Nikita and Kellerman, Adam C. and Zhu, H.}, title = {EMIC wave parameterization in the long-term VERB code simulation}, series = {Journal of geophysical research : Space physics}, volume = {122}, journal = {Journal of geophysical research : Space physics}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2017JA024389}, pages = {8488 -- 8501}, year = {2017}, abstract = {Electromagnetic ion cyclotron (EMIC) waves play an important role in the dynamics of ultrarelativistic electron population in the radiation belts. However, as EMIC waves are very sporadic, developing a parameterization of such wave properties is a challenging task. Currently, there are no dynamic, activity-dependent models of EMIC waves that can be used in the long-term (several months) simulations, which makes the quantitative modeling of the radiation belt dynamics incomplete. In this study, we investigate Kp, Dst, and AE indices, solar wind speed, and dynamic pressure as possible parameters of EMIC wave presence. The EMIC waves are included in the long-term simulations (1year, including different geomagnetic activity) performed with the Versatile Electron Radiation Belt code, and we compare results of the simulation with the Van Allen Probes observations. The comparison shows that modeling with EMIC waves, parameterized by solar wind dynamic pressure, provides a better agreement with the observations among considered parameterizations. The simulation with EMIC waves improves the dynamics of ultrarelativistic fluxes and reproduces the formation of the local minimum in the phase space density profiles.}, language = {en} } @article{ZhelavskayaShpritsSpasojevic2017, author = {Zhelavskaya, Irina and Shprits, Yuri Y. and Spasojevic, Maria}, title = {Empirical Modeling of the Plasmasphere Dynamics Using Neural Networks}, series = {Journal of geophysical research : Space physics}, volume = {122}, journal = {Journal of geophysical research : Space physics}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2017JA024406}, pages = {11227 -- 11244}, year = {2017}, abstract = {We present the PINE (Plasma density in the Inner magnetosphere Neural network\&\#8208;based Empirical) model \&\#8208; a new empirical model for reconstructing the global dynamics of the cold plasma density distribution based only on solar wind data and geomagnetic indices. Utilizing the density database obtained using the NURD (Neural\&\#8208;network\&\#8208;based Upper hybrid Resonance Determination) algorithm for the period of 1 October 2012 to 1 July 2016, in conjunction with solar wind data and geomagnetic indices, we develop a neural network model that is capable of globally reconstructing the dynamics of the cold plasma density distribution for 2\&\#8804;L\&\#8804;6 and all local times. We validate and test the model by measuring its performance on independent data sets withheld from the training set and by comparing the model\&\#8208;predicted global evolution with global images of He+ distribution in the Earth's plasmasphere from the IMAGE Extreme UltraViolet (EUV) instrument. We identify the parameters that best quantify the plasmasphere dynamics by training and comparing multiple neural networks with different combinations of input parameters (geomagnetic indices, solar wind data, and different durations of their time history). The optimal model is based on the 96\&\#8201;h time history of Kp, AE, SYM\&\#8208;H, and F10.7 indices. The model successfully reproduces erosion of the plasmasphere on the nightside and plume formation and evolution. We demonstrate results of both local and global plasma density reconstruction. This study illustrates how global dynamics can be reconstructed from local in situ observations by using machine learning techniques.}, language = {en} } @article{PrattBusseMuelleretal.2017, author = {Pratt, Jane and Busse, Angela and Mueller, W-C and Watkins, Nikolas W. and Chapman, Sandra C.}, title = {Extreme-value statistics from Lagrangian convex hull analysis for homogeneous turbulent Boussinesq convection and MHD convection}, series = {New journal of physics : the open-access journal for physics}, volume = {19}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/aa6fe8}, pages = {18}, year = {2017}, abstract = {We investigate the utility of the convex hull of many Lagrangian tracers to analyze transport properties of turbulent flows with different anisotropy. In direct numerical simulations of statistically homogeneous and stationary Navier-Stokes turbulence, neutral fluid Boussinesq convection, and MHD Boussinesq convection a comparison with Lagrangian pair dispersion shows that convex hull statistics capture the asymptotic dispersive behavior of a large group of passive tracer particles. Moreover, convex hull analysis provides additional information on the sub-ensemble of tracers that on average disperse most efficiently in the form of extreme value statistics and flow anisotropy via the geometric properties of the convex hulls. We use the convex hull surface geometry to examine the anisotropy that occurs in turbulent convection. Applying extreme value theory, we show that the maximal square extensions of convex hull vertices are well described by a classic extreme value distribution, the Gumbel distribution. During turbulent convection, intermittent convective plumes grow and accelerate the dispersion of Lagrangian tracers. Convex hull analysis yields information that supplements standard Lagrangian analysis of coherent turbulent structures and their influence on the global statistics of the flow.}, language = {en} } @article{FangMaLietal.2017, author = {Fang, Peng and Ma, Xingchen and Li, Xiangxin and Qiu, Xunlin and Gerhard, Reimund and Zhang, Xiaoqing and Li, Guanglin}, title = {Fabrication, Structure Characterization, and Performance Testing of Piezoelectret-Film Sensors for Recording Body Motion}, series = {IEEE Sensors Journal}, volume = {18}, journal = {IEEE Sensors Journal}, number = {1}, publisher = {Inst. of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1530-437X}, doi = {10.1109/JSEN.2017.2766663}, pages = {401 -- 412}, year = {2017}, abstract = {During muscle contractions, radial-force distributions are generated on muscle surfaces due to muscle-volume changes, from which the corresponding body motions can be recorded by means of so-called force myography (FMG). Piezo- or ferroelectrets are flexible piezoelectric materials with attractive materials and sensing properties. In addition to several other applications, they are suitable for detecting force variations by means of wearable devices. In this paper, we prepared piezoelectrets from cellular polypropylene films by optimizing the fabrication procedures, and developed an FMG-recording system based on piezoelectret sensors. Different hand and wrist movements were successfully detected on able-bodied subjects with the FMG system. The FMG patterns were evaluated and identified by means of linear discriminant analysis and artificial neural network algorithms, and average motion-classification accuracies of 96.1\% and 94.8\%, respectively, were obtained. This paper demonstrates the feasibility of using piezoelectret-film sensors for FMG and may thus lead to alternative methods for detecting body motion and to related applications, e.g., in biomedical engineering or structural-health monitoring.}, language = {en} } @article{LiuCherstvyMetzler2017, author = {Liu, Lin and Cherstvy, Andrey G. and Metzler, Ralf}, title = {Facilitated Diffusion of Transcription Factor Proteins with Anomalous Bulk Diffusion}, series = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, volume = {121}, journal = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, publisher = {American Chemical Society}, address = {Washington}, issn = {1520-6106}, doi = {10.1021/acs.jpcb.6b12413}, pages = {1284 -- 1289}, year = {2017}, abstract = {What are the physical laws of the diffusive search of proteins for their specific binding sites on DNA in the presence of the macromolecular crowding in cells? We performed extensive computer simulations to elucidate the protein target search on DNA. The novel feature is the viscoelastic non-Brownian protein bulk diffusion recently observed experimentally. We examine the influence of the protein-DNA binding affinity and the anomalous diffusion exponent on the target search time. In all cases an optimal search time is found. The relative contribution of intermittent three-dimensional bulk diffusion and one-dimensional sliding of proteins along the DNA is quantified. Our results are discussed in the light of recent single molecule tracking experiments, aiming at a better understanding of the influence of anomalous kinetics of proteins on the facilitated diffusion mechanism.}, language = {en} } @article{JuaristiAlducinSaalfrank2017, author = {Juaristi, J. I. and Alducin, Maite and Saalfrank, Peter}, title = {Femtosecond laser induced desorption of H-2, D-2, and HD from Ru(0001)}, series = {Physical review : B, Condensed matter and materials physics}, volume = {95}, journal = {Physical review : B, Condensed matter and materials physics}, number = {12}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9950}, doi = {10.1103/PhysRevB.95.125439}, pages = {7}, year = {2017}, abstract = {We perform ab initio molecular dynamics simulations to study the femtosecond laser induced desorption of H-2, D-2, and HD from a H: D-saturated Ru(0001) surface. To this aim we have extended the ab initio molecular dynamics with electronic friction (AIMDEF) scheme to include a random force that is a function of a timedependent electronic temperature. The latter characterizes the action of the ultrashort laser pulse according to a two temperature model. This allows us to perform multidimensional, hot-electron driven reaction dynamics and investigate the dependence of the desorption yields on the relative H: D isotope concentration on the surface. Our AIMDEF simulations show that the desorption process takes place in the presence of a heated adsorbate system that clearly influences the desorption dynamics. The heating of the adsorbate system is more (less) pronounced the larger is the concentration of the lighter (heavier) isotope. As a result, we conclude that the presence of H on the surface favors the desorption of molecules, whereas the presence of D hampers it, in agreement with previous experimental observations in which the phenomenon of "dynamical promotion" of a surface reaction had been postulated.}, language = {en} } @article{GodecMetzler2017, author = {Godec, Aljaž and Metzler, Ralf}, title = {First passage time statistics for two-channel diffusion}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {50}, journal = {Journal of physics : A, Mathematical and theoretical}, number = {8}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8121/aa5204}, pages = {17}, year = {2017}, abstract = {We present rigorous results for the mean first passage time and first passage time statistics for two-channel Markov additive diffusion in a 3-dimensional spherical domain. Inspired by biophysical examples we assume that the particle can only recognise the target in one of the modes, which is shown to effect a non-trivial first passage behaviour. We also address the scenario of intermittent immobilisation. In both cases we prove that despite the perfectly non-recurrent motion of two-channel Markov additive diffusion in 3 dimensions the first passage statistics at long times do not display Poisson-like behaviour if none of the phases has a vanishing diffusion coefficient. This stands in stark contrast to the standard (one-channel) Markov diffusion counterpart. We also discuss the relevance of our results in the context of cellular signalling.}, language = {en} } @article{GoemoeryBalthasarKuckeinetal.2017, author = {G{\"o}m{\"o}ry, Peter and Balthasar, Horst and Kuckein, Christoph and Koza, Julis and Veronig, Astrid M. and Gonz{\´a}lez Manrique, Sergio Javier and Kucera, Ales and Schwartz, Pavol and Hanslmeier, Arnold}, title = {Flare-induced changes of the photospheric magnetic field in a delta-spot deduced from ground-based observations}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {602}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201730644}, pages = {14 -- 27}, year = {2017}, abstract = {Aims. Changes of the magnetic field and the line-of-sight velocities in the photosphere are being reported for an M-class flare that originated at a delta-spot belonging to active region NOAA 11865. Methods. High-resolution ground-based near-infrared spectropolarimetric observations were acquired simultaneously in two photospheric spectral lines, Fe I 10783 angstrom and Si I 10786 angstrom, with the Tenerife Infrared Polarimeter at the Vacuum Tower Telescope (VTT) in Tenerife on 2013 October 15. The observations covered several stages of the M-class flare. Inversions of the full-Stokes vector of both lines were carried out and the results were put into context using (extreme)-ultraviolet filtergrams from the Solar Dynamics Observatory (SDO). Results. The active region showed high flaring activity during the whole observing period. After the M-class flare, the longitudinal magnetic field did not show significant changes along the polarity inversion line (PIL). However, an enhancement of the transverse magnetic field of approximately 550G was found that bridges the PIL and connects umbrae of opposite polarities in the delta-spot. At the same time, a newly formed system of loops appeared co-spatially in the corona as seen in 171 angstrom filtergrams of the Atmospheric Imaging Assembly (AIA) on board SDO. However, we cannot exclude that the magnetic connection between the umbrae already existed in the upper atmosphere before the M-class flare and became visible only later when it was filled with hot plasma. The photospheric Doppler velocities show a persistent upflow pattern along the PIL without significant changes due to the flare. Conclusions. The increase of the transverse component of the magnetic field after the flare together with the newly formed loop system in the corona support recent predictions of flare models and flare observations.}, language = {en} } @article{Goychuk2017, author = {Goychuk, Igor}, title = {Fractional Bhatnagar-Gross-Krook kinetic equation}, series = {The European physical journal : B, Condensed matter and complex systems}, volume = {90}, journal = {The European physical journal : B, Condensed matter and complex systems}, publisher = {Springer}, address = {New York}, issn = {1434-6028}, doi = {10.1140/epjb/e2017-80297-x}, pages = {13}, year = {2017}, abstract = {The linear Boltzmann equation approach is generalized to describe fractional superdiffusive transport of the Levy walk type in external force fields. The time distribution between scattering events is assumed to have a finite mean value and infinite variance. It is completely characterized by the two scattering rates, one fractional and a normal one, which defines also the mean scattering rate. We formulate a general fractional linear Boltzmann equation approach and exemplify it with a particularly simple case of the Bohm and Gross scattering integral leading to a fractional generalization of the Bhatnagar, Gross and Krook kinetic equation. Here, at each scattering event the particle velocity is completely randomized and takes a value from equilibrium Maxwell distribution at a given fixed temperature. We show that the retardation effects are indispensable even in the limit of infinite mean scattering rate and argue that this novel fractional kinetic equation provides a viable alternative to the fractional Kramers-Fokker-Planck (KFP) equation by Barkai and Silbey and its generalization by Friedrich et al. based on the picture of divergent mean time between scattering events. The case of divergent mean time is also discussed at length and compared with the earlier results obtained within the fractional KFP. Also a phenomenological fractional BGK equation without retardation effects is proposed in the limit of infinite scattering rates. It cannot be, however, rigorously derived from a scattering model, being rather clever postulated. It this respect, this retardationless equation is similar to the fractional KFP by Barkai and Silbey. However, it corresponds to the opposite, much more physical limit and, therefore, also presents a viable alternative.}, language = {en} } @article{KurzkeKietheHeueretal.2017, author = {Kurzke, Henning and Kiethe, Jan and Heuer, Axel and Jechow, Andreas}, title = {Frequency doubling of incoherent light from a superluminescent diode in a periodically poled lithium niobate waveguide crystal}, series = {Laser physics letters}, volume = {14}, journal = {Laser physics letters}, publisher = {IOP Publ.}, address = {Bristol}, issn = {1612-2011}, doi = {10.1088/1612-202X/aa6889}, pages = {5}, year = {2017}, abstract = {The amplified spontaneous emission from a superluminescent diode was frequency doubled in a periodically poled lithium niobate waveguide crystal. The temporally incoherent radiation of such a superluminescent diode is characterized by a relatively broad spectral bandwidth and thermal-like photon statistics, as the measured degree of second order coherence, g((2))(0)= 1.9 +/- 0.1, indicates. Despite the non-optimized scenario in the spectral domain, we achieve six orders of magnitude higher conversion efficiency than previously reported with truly incoherent light. This is possible by using single spatial mode radiation and quasi phase matched material with a waveguide architecture. This work is a principle step towards efficient frequency conversion of temporally incoherent radiation in one spatial mode to access wavelengths where no radiation from superluminescent diodes is available, especially with tailored quasi phase matched crystals. The frequency doubled light might find application in imaging, metrology and quantum optics experiments.}, language = {en} } @article{FeldmannLevermann2017, author = {Feldmann, Johannes and Levermann, Anders}, title = {From cyclic ice streaming to Heinrich-like events: the grow-and-surge instability in the Parallel Ice Sheet Model}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {11}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-11-1913-2017}, pages = {1913 -- 1932}, year = {2017}, abstract = {Here we report on a cyclic, physical ice-discharge instability in the Parallel Ice Sheet Model, simulating the flow of a three-dimensional, inherently buttressed ice-sheet-shelf system which periodically surges on a millennial timescale. The thermomechanically coupled model on 1 km horizontal resolution includes an enthalpy-based formulation of the thermodynamics, a nonlinear stress-balance-based sliding law and a very simple subglacial hydrology. The simulated unforced surging is characterized by rapid ice streaming through a bed trough, resulting in abrupt discharge of ice across the grounding line which is eventually calved into the ocean. We visualize the central feedbacks that dominate the subsequent phases of ice buildup, surge and stabilization which emerge from the interaction between ice dynamics, thermodynamics and the subglacial till layer. Results from the variation of surface mass balance and basal roughness suggest that ice sheets of medium thickness may be more susceptible to surging than relatively thin or thick ones for which the surge feedback loop is damped. We also investigate the influence of different basal sliding laws (ranging from purely plastic to nonlinear to linear) on possible surging. The presented mechanisms underlying our simulations of self-maintained, periodic ice growth and destabilization may play a role in large-scale ice-sheet surging, such as the surging of the Laurentide Ice Sheet, which is associated with Heinrich events, and ice-stream shutdown and reactivation, such as observed in the Siple Coast region of West Antarctica.}, language = {en} } @article{FinleyBoucheContinietal.2017, author = {Finley, Hayley and Bouche, Nicolas and Contini, Thierry and Epinat, Benoit and Bacon, Roland and Brinchmann, Jarle and Cantalupo, Sebastiano and Erroz-Ferrer, Santiago and Marino, Aella Anna and Maseda, Michael and Richard, Johan and Schroetter, Ilane and Verhamme, Anne and Weilbacher, Peter Michael and Wendt, Martin and Wisotzki, Lutz}, title = {Galactic winds with MUSE: A direct detection of Fe II* emission from a z=1.29 galaxy}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {605}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201730428}, pages = {15}, year = {2017}, abstract = {Emission signatures from galactic winds provide an opportunity to directly map the outflowing gas, but this is traditionally challenging because of the low surface brightness. Using very deep observations (27 h) of the Hubble Deep Field South with the Multi Unit Spectroscopic Explorer (MUSE) instrument, we identify signatures of an outflow in both emission and absorption from a spatially resolved galaxy at z = 1.29 with a stellar mass M-star = 8 x 10(9) M-circle dot, star formation rate SFR = 77(-25)(+40) M-circle dot yr(-1), and star formation rate surface brightness Sigma(SFR) = 1.6 M-circle dot kpc(-2) within the [OII] lambda lambda 3727, 3729 half-light radius R-1/2, ([OII]) = 2.76 +/- 0.17 kpc. From a component of the strong resonant Mg II and Fe II absorptions at -350 km s(-1), we infer a mass outflow rate that is comparable to the star formation rate. We detect non-resonant Fe II* emission, at lambda 2365, lambda 2396, lambda 2612, and lambda 2626, at 1.2-2.4-1.5-2.7 x 10-(18) erg s(-1) cm(-2) respectively. The flux ratios are consistent with the expectations for optically thick gas. By combining the four non-resonant Fe II* emission lines, we spatially map the Fe II* emission from an individual galaxy for the first time. The Fe II* emission has an elliptical morphology that is roughly aligned with the galaxy minor kinematic axis, and its integrated half-light radius, R-1/2, (Fe II*) = 4.1 +/- 0.4 kpc, is 70\% larger than the stellar continuum (R-1/2,(star) similar or equal to 2.34 +/- 0.17) or the [O II] nebular line. Moreover, the Fe II* emission shows a blue wing extending up to -400 km s(-1), which is more pronounced along the galaxy minor kinematic axis and reveals a C-shaped pattern in a p - v diagram along that axis. These features are consistent with a bi-conical outflow.}, language = {en} } @article{HaniSparreEllisonetal.2017, author = {Hani, Maan H. and Sparre, Martin and Ellison, Sara L. and Torrey, Paul and Vogelsberger, Mark}, title = {Galaxy mergers moulding the circum-galactic medium}, series = {Monthly notices of the Royal Astronomical Society}, volume = {475}, journal = {Monthly notices of the Royal Astronomical Society}, number = {1}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stx3252}, pages = {1160 -- 1176}, year = {2017}, abstract = {Galaxies are surrounded by sizeable gas reservoirs which host a significant amount of metals: the circum-galactic medium (CGM). The CGM acts as a mediator between the galaxy and the extragalactic medium. However, our understanding of how galaxy mergers, a major evolutionary transformation, impact the CGM remains deficient. We present a theoretical study of the effect of galaxy mergers on the CGM. We use hydrodynamical cosmological zoom-in simulations of a major merger selected from the Illustris project such that the z = 0 descendant has a halo mass and stellar mass comparable to the Milky Way. To study the CGM we then re-simulated this system at a 40 times better mass resolution, and included detailed post-processing ionization modelling. Our work demonstrates the effect the merger has on the characteristic size of the CGM, its metallicity, and the predicted covering fraction of various commonly observed gas-phase species, such as H I, C IV, and O VI. We show that merger-induced outflows can increase the CGM metallicity by 0.2-0.3 dex within 0.5 Gyr post-merger. These effects last up to 6 Gyr post-merger. While the merger increases the total metal covering fractions by factors of 2-3, the covering fractions of commonly observed UV ions decrease due to the hard ionizing radiation from the active galactic nucleus, which we model explicitly. Our study of the single simulated major merger presented in this work demonstrates the significant impact that a galaxy interaction can have on the size, metallicity, and observed column densities of the CGM.}, language = {en} } @article{ArchambaultArcherBenbowetal.2017, author = {Archambault, S. and Archer, A. and Benbow, Wystan and Bird, Ralph and Bourbeau, E. and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Cerruti, M. and Connolly, M. P. and Cui, W. and Dwarkadas, Vikram V. and Errando, M. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Griffin, S. and Huetten, M. and Hanna, D. and Holder, J. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and McCann, A. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, Nahee and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Slane, P. and Staszak, D. and Telezhinsky, Igor O. and Trepanier, S. and Tyler, J. and Wakely, S. P. and Weinstein, A. and Weisgarber, T. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Zitzer, B.}, title = {Gamma-ray Observations of Tycho's Supernova Remnant with VERITAS and Fermi}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {836}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/836/1/23}, pages = {8}, year = {2017}, language = {en} } @article{ArchambaultArcherBenbowetal.2017, author = {Archambault, S. and Archer, A. and Benbow, W. and Bird, Ralph and Bourbeau, E. and Bouvier, A. and Buchovecky, M. and Bugaev, V. and Cardenzana, J. V. and Cerruti, M. and Ciupik, L. and Connolly, M. P. and Cui, W. and Daniel, M. K. and Errando, M. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Hanna, D. and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Hutten, M. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kertzman, M. and Kieda, D. and Krause, M. and Lang, M. J. and Lin, T. T. Y. and Maier, G. and McArthur, S. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, I. and Sembroski, G. H. and Shahinyan, K. and Staszak, D. and Telezhinsky, Igor O. and Trepanier, S. and Wakely, S. P. and Weinstein, A. and Wilcox, P. and Williams, D. A. and Zitzer, B.}, title = {Gamma-ray observations under bright moonlight with VERITAS}, series = {Astroparticle physics}, volume = {91}, journal = {Astroparticle physics}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-6505}, doi = {10.1016/j.astropartphys.2017.03.001}, pages = {34 -- 43}, year = {2017}, abstract = {Imaging atmospheric Cherenkov telescopes (IACTs) are equipped with sensitive photomultiplier tube (PMT) cameras. Exposure to high levels of background illumination degrades the efficiency of and potentially destroys these photo-detectors over time, so IACTs cannot be operated in the same configuration in the presence of bright moonlight as under dark skies. Since September 2012, observations have been carried out with the VERITAS IACTs under bright moonlight (defined as about three times the night-sky-background (NSB) of a dark extragalactic field, typically occurring when Moon illumination > 35\%) in two observing modes, firstly by reducing the voltage applied to the PMTs and, secondly, with the addition of ultra-violet (UV) bandpass filters to the cameras. This has allowed observations at up to about 30 times previous NSB levels (around 80\% Moon illumination), resulting in 30\% more observing time between the two modes over the course of a year. These additional observations have already allowed for the detection of a flare from the 1ES 1727 + 502 and for an observing program targeting a measurement of the cosmic-ray positron fraction. We provide details of these new observing modes and their performance relative to the standard VERITAS observations. (C) 2017 Elsevier B.V. All rights reserved.}, language = {en} } @article{Richter2017, author = {Richter, Philipp}, title = {Gas accretion onto the Milky Way}, series = {Astrophysics and space science library}, volume = {430}, journal = {Astrophysics and space science library}, editor = {Fox, Andrew J. and Dav{\´e}, Romeel}, publisher = {Springer}, address = {Cham}, isbn = {978-3-319-52512-9}, issn = {0067-0057}, doi = {10.1007/978-3-319-52512-9_2}, pages = {15 -- 47}, year = {2017}, abstract = {The Milky Way is surrounded by large amounts of gaseous matter that are slowly being accreted over cosmic timescales to support star formation in the disk. The corresponding gas-accretion rate represents a key parameter for the past, present, and future evolution of the Milky Way. In this chapter, we discuss our current understanding of gas accretion processes in the Galaxy by reviewing past and recent observational and theoretical studies. The first part of this review deals with the spatial distribution of the different gas phases in the Milky Way halo, the origin of the gas, and its total mass. The second part discusses the gas dynamics and the physical processes that regulate the gas flow from the outer Galactic halo to the disk. From the most recent studies follows that the present-day gas accretion rate of the Milky Way is a few solar masses per year, which is sufficient to maintain the Galaxy's star-formation rate at its current level.}, language = {en} } @article{RaetzelWilkensMenzel2017, author = {Raetzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light: The emission of counter-propagating laser pulses from an atom}, series = {Physical review : D, Particles, fields, gravitation, and cosmology}, volume = {95}, journal = {Physical review : D, Particles, fields, gravitation, and cosmology}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0010}, doi = {10.1103/PhysRevD.95.084008}, pages = {11}, year = {2017}, language = {en} } @article{KocReinhardtvonReppertetal.2017, author = {Koc, A. and Reinhardt, M. and von Reppert, Alexander and R{\"o}ssle, Matthias and Leitenberger, Wolfram and Gleich, M. and Weinelt, M. and Zamponi, Flavio and Bargheer, Matias}, title = {Grueneisen-approach for the experimental determination of transient spin and phonon energies from ultrafast x-ray diffraction data: gadolinium}, series = {Journal of physics : Condensed matter}, volume = {29}, journal = {Journal of physics : Condensed matter}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0953-8984}, doi = {10.1088/1361-648X/aa7187}, pages = {5884 -- 5891}, year = {2017}, abstract = {We study gadolinium thin films as a model system for ferromagnets with negative thermal expansion. Ultrashort laser pulses heat up the electronic subsystem and we follow the transient strain via ultrafast x-ray diffraction. In terms of a simple Grueneisen approach, the strain is decomposed into two contributions proportional to the thermal energy of spin and phonon subsystems. Our analysis reveals that upon femtosecond laser excitation, phonons and spins can be driven out of thermal equilibrium for several nanoseconds.}, language = {en} } @article{PuppeHoehnKaczoreketal.2017, author = {Puppe, Daniel and H{\"o}hn, Axel and Kaczorek, Danuta and Wanner, Manfred and Wehrhan, Marc and Sommer, Michael}, title = {How big is the influence of biogenic silicon pools on short-term changes in water-soluble silicon in soils? Implications from a study of a 10-year-old soil-plant system}, series = {Biogeosciences}, volume = {14}, journal = {Biogeosciences}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1726-4170}, doi = {10.5194/bg-14-5239-2017}, pages = {14}, year = {2017}, abstract = {The significance of biogenic silicon (BSi) pools as a key factor for the control of Si fluxes from terrestrial to aquatic ecosystems has been recognized for decades. However, while most research has been focused on phytogenic Si pools, knowledge of other BSi pools is still limited. We hypothesized that different BSi pools influence short-term changes in the water-soluble Si fraction in soils to different extents. To test our hypothesis we took plant (Calamagrostis epigejos, Phragmites australis) and soil samples in an artificial catchment in a post-mining landscape in the state of Brandenburg, Germany. We quantified phytogenic (phytoliths), protistic (diatom frustules and testate amoeba shells) and zoogenic (sponge spicules) Si pools as well as Tironextractable and water-soluble Si fractions in soils at the beginning (t(0)) and after 10 years (t(10)) of ecosystem development. As expected the results of Tiron extraction showed that there are no consistent changes in the amorphous Si pool at Chicken Creek (Huhnerwasser) as early as after 10 years. In contrast to t(0) we found increased water-soluble Si and BSi pools at t(10); thus we concluded that BSi pools are the main driver of short-term changes in water-soluble Si. However, because total BSi represents only small proportions of water-soluble Si at t(0) (< 2 \%) and t(10) (2.8-4.3 \%) we further concluded that smaller (< 5 mu m) and/or fragile phytogenic Si structures have the biggest impact on short-term changes in water-soluble Si. In this context, extracted phytoliths (> 5 mu m) only amounted to about 16\% of total Si con-tents of plant materials of C. epigejos and P. australis at t(10); thus about 84\% of small-scale and/or fragile phytogenic Si is not quantified by the used phytolith extraction method. Analyses of small-scale and fragile phytogenic Si structures are urgently needed in future work as they seem to represent the biggest and most reactive Si pool in soils. Thus they are the most important drivers of Si cycling in terrestrial biogeosystems.}, language = {en} } @article{FeudelTuckermanZaksetal.2017, author = {Feudel, Fred and Tuckerman, Laurette S. and Zaks, Michael and Hollerbach, Rainer}, title = {Hysteresis of dynamos in rotating spherical shell convection}, series = {Physical review fluids / American Physical Society}, volume = {2}, journal = {Physical review fluids / American Physical Society}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-990X}, doi = {10.1103/PhysRevFluids.2.053902}, pages = {11}, year = {2017}, abstract = {Bifurcations of dynamos in rotating and buoyancy-driven spherical Rayleigh-Benard convection in an electrically conducting fluid are investigated numerically. Both nonmagnetic and magnetic solution branches comprised of rotating waves are traced by path-following techniques, and their bifurcations and interconnections for different Ekman numbers are determined. In particular, the question of whether the dynamo branches bifurcate super- or sub-critically and whether a direct link to the primary pure convective states exists is answered.}, language = {en} } @article{RanRolandLoveetal.2017, author = {Ran, Niva A. and Roland, Steffen and Love, John A. and Savikhin, Victoria and Takacs, Christopher J. and Fu, Yao-Tsung and Li, Hong and Coropceanu, Veaceslav and Liu, Xiaofeng and Bredas, Jean-Luc and Bazan, Guillermo C. and Toney, Michael F. and Neher, Dieter and Thuc-Quyen Nguyen,}, title = {Impact of interfacial molecular orientation on radiative recombination and charge generation efficiency}, series = {Nature Communications}, volume = {8}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/s41467-017-00107-4}, pages = {9}, year = {2017}, abstract = {A long standing question in organic electronics concerns the effects of molecular orientation at donor/acceptor heterojunctions. Given a well-controlled donor/acceptor bilayer system, we uncover the genuine effects of molecular orientation on charge generation and recombination. These effects are studied through the point of view of photovoltaics-however, the results have important implications on the operation of all optoelectronic devices with donor/ acceptor interfaces, such as light emitting diodes and photodetectors. Our findings can be summarized by two points. First, devices with donor molecules face-on to the acceptor interface have a higher charge transfer state energy and less non-radiative recombination, resulting in larger open-circuit voltages and higher radiative efficiencies. Second, devices with donor molecules edge-on to the acceptor interface are more efficient at charge generation, attributed to smaller electronic coupling between the charge transfer states and the ground state, and lower activation energy for charge generation.}, language = {en} } @article{UsanovaShprits2017, author = {Usanova, Maria E. and Shprits, Yuri Y.}, title = {Inner magnetosphere coupling}, series = {Journal of geophysical research : Space physics}, volume = {122}, journal = {Journal of geophysical research : Space physics}, number = {1}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2016JA023614}, pages = {102 -- 104}, year = {2017}, abstract = {The dynamics of the inner magnetosphere is strongly governed by the interactions between different plasma populations that are coupled through large-scale electric and magnetic fields, currents, and wave-particle interactions. Inner magnetospheric plasma undergoes self-consistent interactions with global electric and magnetic fields. Waves excited in the inner magnetosphere from unstable particle distributions can provide energy exchange between different particle populations in the inner magnetosphere and affect the ring current and radiation belt dynamics. The ionosphere serves as an energy sink and feeds the magnetosphere back through the cold plasma outflow. The precipitating inner magnetospheric particles influence the ionosphere and upper atmospheric chemistry and affect climate. Satellite measurements and theoretical studies have advanced our understanding of the dynamics of various plasma populations in the inner magnetosphere. However, our knowledge of the coupling processes among the plasmasphere, ring current, radiation belts, global magnetic and electric fields, and plasma waves generated within these systems is still incomplete. This special issue incorporates extended papers presented at the Inner Magnetosphere Coupling III conference held 23-27 March 2015 in Los Angeles, California, USA, and includes modeling and observational contributions addressing interactions within different plasma populations in the inner magnetosphere (plasmasphere, ring current, and radiation belts), coupling between fields and plasma populations, as well as effects of the inner magnetosphere on the ionosphere and atmosphere.}, language = {en} } @article{ColladoFregosoHoodShoaeeetal.2017, author = {Collado-Fregoso, Elisa and Hood, Samantha N. and Shoaee, Safa and Schr{\"o}der, Bob C. and McCulloch, Iain and Kassal, Ivan and Neher, Dieter and Durrant, James R.}, title = {Intercalated vs Nonintercalated Morphologies in Donor-Acceptor Bulk Heterojunction Solar Cells: PBTTT:Fullerene Charge Generation and Recombination Revisited}, series = {The journal of physical chemistry letters}, volume = {8}, journal = {The journal of physical chemistry letters}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.7b01571}, pages = {4061 -- 4068}, year = {2017}, abstract = {In this Letter, we study the role of the donor:acceptor interface nanostructure upon charge separation and recombination in organic photovoltaic devices and blend films, using mixtures of PBTTT and two different fullerene derivatives (PC70BM and ICTA) as models for intercalated and nonintercalated morphologies, respectively. Thermodynamic simulations show that while the completely intercalated system exhibits a large free-energy barrier for charge separation, this barrier is significantly lower in the nonintercalated system and almost vanishes when energetic disorder is included in the model. Despite these differences, both femtosecond-resolved transient absorption spectroscopy (TAS) and time-delayed collection field (TDCF) exhibit extensive first-order losses in both systems, suggesting that geminate pairs are the primary product of photoexcitation. In contrast, the system that comprises a combination of fully intercalated polymer:fullerene areas and fullerene-aggregated domains (1:4 PBTTT:PC70BM) is the only one that shows slow, second-order recombination of free charges, resulting in devices with an overall higher short-circuit current and fill factor. This study therefore provides a novel consideration of the role of the interfacial nanostructure and the nature of bound charges and their impact upon charge generation and recombination.}, language = {en} } @article{BetaKruse2017, author = {Beta, Carsten and Kruse, Karsten}, title = {Intracellular oscillations and waves}, series = {Annual review of condensed matter physics}, volume = {8}, journal = {Annual review of condensed matter physics}, publisher = {Annual Reviews}, address = {Palo Alto}, isbn = {978-0-8243-5008-6}, issn = {1947-5454}, doi = {10.1146/annurev-conmatphys-031016-025210}, pages = {239 -- 264}, year = {2017}, abstract = {Dynamic processes in living cells are highly organized in space and time. Unraveling the underlying molecular mechanisms of spatiotemporal pattern formation remains one of the outstanding challenges at the interface between physics and biology. A fundamental recurrent pattern found in many different cell types is that of self-sustained oscillations. They are involved in a wide range of cellular functions, including second messenger signaling, gene expression, and cytoskeletal dynamics. Here, we review recent developments in the field of cellular oscillations and focus on cases where concepts from physics have been instrumental for understanding the underlying mechanisms. We consider biochemical and genetic oscillators as well as oscillations that arise from chemo-mechanical coupling. Finally, we highlight recent studies of intracellular waves that have increasingly moved into the focus of this research field.}, language = {en} } @article{BenduhnTvingstedtPiersimonietal.2017, author = {Benduhn, Johannes and Tvingstedt, Kristofer and Piersimoni, Fortunato and Ullbrich, Sascha and Fan, Yeli and Tropiano, Manuel and McGarry, Kathryn A. and Zeika, Olaf and Riede, Moritz K. and Douglas, Christopher J. and Barlow, Stephen and Marder, Seth R. and Neher, Dieter and Spoltore, Donato and Vandewal, Koen}, title = {Intrinsic non-radiative voltage losses in fullerene-based organic solar cells}, series = {Nature Energy}, volume = {2}, journal = {Nature Energy}, publisher = {Nature Publ. Group}, address = {London}, issn = {2058-7546}, doi = {10.1038/nenergy.2017.53}, pages = {6}, year = {2017}, abstract = {Organic solar cells demonstrate external quantum efficiencies and fill factors approaching those of conventional photovoltaic technologies. However, as compared with the optical gap of the absorber materials, their open-circuit voltage is much lower, largely due to the presence of significant non-radiative recombination. Here, we study a large data set of published and new material combinations and find that non-radiative voltage losses decrease with increasing charge-transfer-state energies. This observation is explained by considering non-radiative charge-transfer-state decay as electron transfer in the Marcus inverted regime, being facilitated by a common skeletal molecular vibrational mode. Our results suggest an intrinsic link between non-radiative voltage losses and electron-vibration coupling, indicating that these losses are unavoidable. Accordingly, the theoretical upper limit for the power conversion efficiency of single-junction organic solar cells would be reduced to about 25.5\% and the optimal optical gap increases to (1.45-1.65) eV, that is, (0.2-0.3) eV higher than for technologies with minimized non-radiative voltage losses.}, language = {en} }