@phdthesis{Herenz2016, author = {Herenz, Edmund Christian}, title = {Detecting and understanding extragalactic Lyman α emission using 3D spectroscopy}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-102341}, school = {Universit{\"a}t Potsdam}, pages = {175}, year = {2016}, abstract = {In this thesis we use integral-field spectroscopy to detect and understand of Lyman α (Lyα) emission from high-redshift galaxies. Intrinsically the Lyα emission at λ = 1216 {\AA} is the strongest recombination line from galaxies. It arises from the 2p → 1s transition in hydrogen. In star-forming galaxies the line is powered by ionisation of the interstellar gas by hot O- and B- stars. Galaxies with star-formation rates of 1 - 10 Msol/year are expected to have Lyα luminosities of 42 dex - 43 dex (erg/s), corresponding to fluxes ~ -17 dex - -18 dex (erg/s/cm²) at redshifts z~3, where Lyα is easily accessible with ground-based telescopes. However, star-forming galaxies do not show these expected Lyα fluxes. Primarily this is a consequence of the high-absorption cross-section of neutral hydrogen for Lyα photons σ ~ -14 dex (cm²). Therefore, in typical interstellar environments Lyα photons have to undergo a complex radiative transfer. The exact conditions under which Lyα photons can escape a galaxy are poorly understood. Here we present results from three observational projects. In Chapter 2, we show integral field spectroscopic observations of 14 nearby star-forming galaxies in Balmer α radiation (Hα, λ = 6562.8 {\AA}). These observations were obtained with the Potsdam Multi Aperture Spectrophotometer at the Calar-Alto 3.5m Telescope}. Hα directly traces the intrinsic Lyα radiation field. We present Hα velocity fields and velocity dispersion maps spatially registered onto Hubble Space Telescope Lyα and Hα images. From our observations, we conjecture a causal connection between spatially resolved Hα kinematics and Lyα photometry for individual galaxies. Statistically, we find that dispersion-dominated galaxies are more likely to emit Lyα photons than galaxies where ordered gas-motions dominate. This result indicates that turbulence in actively star-forming systems favours an escape of Lyα radiation. Not only massive stars can power Lyα radiation, but also non-thermal emission from an accreting super-massive black hole in the galaxy centre. If a galaxy harbours such an active galactic nucleus, the rate of hydrogen-ionising photons can be more than 1000 times higher than that of a typical star-forming galaxy. This radiation can potentially ionise large regions well outside the main stellar body of galaxies. Therefore, it is expected that the neutral hydrogen from these circum-galactic regions shines fluorescently in Lyα. Circum-galactic gas plays a crucial role in galaxy formation. It may act as a reservoir for fuelling star formation, and it is also subject to feedback processes that expel galactic material. If Lyα emission from this circum-galactic medium (CGM) was detected, these important processes could be studied in-situ around high-z galaxies. In Chapter 3, we show observations of five radio-quiet quasars with PMAS to search for possible extended CGM emission in the Lyα line. However, in four of the five objects, we find no significant traces of this emission. In the fifth object, there is evidence for a weak and spatially quite compact Lyα excess at several kpc outside the nucleus. The faintness of these structures is consistent with the idea that radio-quiet quasars typically reside in dark matter haloes of modest masses. While we were not able to detect Lyα CGM emission, our upper limits provide constraints for the new generation of IFS instruments at 8--10m class telescopes. The Multi Unit Spectroscopic Explorer (MUSE) at ESOs Very Large Telescopeis such an unique instrument. One of the main motivating drivers in its construction was the use as a survey instrument for Lyα emitting galaxies at high-z. Currently, we are conducting such a survey that will cover a total area of ~100 square arcminutes with 1 hour exposures for each 1 square arcminute MUSE pointing. As a first result from this survey we present in Chapter 5 a catalogue of 831 emission-line selected galaxies from a 22.2 square arcminute region in the Chandra Deep Field South. In order to construct the catalogue, we developed and implemented a novel source detection algorithm -- LSDCat -- based on matched filtering for line emission in 3D spectroscopic datasets (Chapter 4). Our catalogue contains 237 Lyα emitting galaxies in the redshift range 3 ≲ z ≲ 6. Only four of those previously had spectroscopic redshifts in the literature. We conclude this thesis with an outlook on the construction of a Lyα luminosity function based on this unique sample (Chapter 6).}, language = {en} } @article{RauchQuinetHoyeretal.2016, author = {Rauch, Thomas and Quinet, P. and Hoyer, D. and Werner, K. and Richter, Philipp and Kruk, J. W. and Demleitner, M.}, title = {VII. New Kr IV - VII oscillator strengths and an improved spectral analysis of the hot, hydrogen-deficient DO-type white dwarf RE 0503-289}, series = {Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants}, volume = {590}, journal = {Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants}, publisher = {EDP Sciences}, address = {Les Ulis}, organization = {VERITAS Collaboration}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628131}, pages = {26}, year = {2016}, abstract = {Context. For the spectral analysis of high-resolution and high signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. New Kr IV-VII oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTE model-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods. We calculated Kr IV-VII oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high S/N ultraviolet (UV) observations of the hot white dwarf RE 0503-289. Results. We reanalyzed the effective temperature and surface gravity and determined T-eff = 70 000 +/- 2000 K and log (g/cm s(-2)) = 7.5 +/- 0.1. We newly identified ten Kr V lines and one Kr vi line in the spectrum of RE 0503-289. We measured a Kr abundance of 3.3 +/- 0.3 (logarithmic mass fraction). We discovered that the interstellar absorption toward RE 0503-289 has a multi-velocity structure within a radial-velocity interval of -40 km s(-1) < upsilon(rad) < +18 km s(-1). Conclusions. Reliable measurements and calculations of atomic data are a prerequisite for state-of-the-art NLTE stellar-atmosphere modeling. Observed Kr V-VII line profiles in the UV spectrum of the white dwarf RE 0503-289 were simultaneously well reproduced with our newly calculated oscillator strengths.}, language = {en} } @phdthesis{Schroeder2016, author = {Schr{\"o}der, Henning}, title = {Ultrafast electron dynamics in Fe(CO)5 and Cr(CO)6}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-94589}, school = {Universit{\"a}t Potsdam}, pages = {v, 87}, year = {2016}, abstract = {In this thesis, the two prototype catalysts Fe(CO)₅ and Cr(CO)₆ are investigated with time-resolved photoelectron spectroscopy at a high harmonic setup. In both of these metal carbonyls, a UV photon can induce the dissociation of one or more ligands of the complex. The mechanism of the dissociation has been debated over the last decades. The electronic dynamics of the first dissociation occur on the femtosecond timescale. For the experiment, an existing high harmonic setup was moved to a new location, was extended, and characterized. The modified setup can induce dynamics in gas phase samples with photon energies of 1.55eV, 3.10eV, and 4.65eV. The valence electronic structure of the samples can be probed with photon energies between 20eV and 40eV. The temporal resolution is 111fs to 262fs, depending on the combination of the two photon energies. The electronically excited intermediates of the two complexes, as well as of the reaction product Fe(CO)₄, could be observed with photoelectron spectroscopy in the gas phase for the first time. However, photoelectron spectroscopy gives access only to the final ionic states. Corresponding calculations to simulate these spectra are still in development. The peak energies and their evolution in time with respect to the initiation pump pulse have been determined, these peaks have been assigned based on literature data. The spectra of the two complexes show clear differences. The dynamics have been interpreted with the assumption that the motion of peaks in the spectra relates to the movement of the wave packet in the multidimensional energy landscape. The results largely confirm existing models for the reaction pathways. In both metal carbonyls, this pathway involves a direct excitation of the wave packet to a metal-to-ligand charge transfer state and the subsequent crossing to a dissociative ligand field state. The coupling of the electronic dynamics to the nuclear dynamics could explain the slower dissociation in Fe(CO)₅ as compared to Cr(CO)₆.}, language = {en} } @phdthesis{Rezanezhad2016, author = {Rezanezhad, Vahid}, title = {Inversion of the 2004 M6.0 Parkfield Earthquake Coseismic Offsets by Partition Model}, school = {Universit{\"a}t Potsdam}, pages = {83}, year = {2016}, language = {en} } @misc{Guehr2016, author = {G{\"u}hr, Markus}, title = {Ultrafast Soft X-ray Probing of Gas Phase Molecular Dynamics}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-97215}, year = {2016}, abstract = {The molecular ability to selectively and efficiently convert sunlight into other forms of energy like heat, bond change, or charge separation is truly remarkable. The decisive steps in these transformations often happen on a femtosecond timescale and require transitions among different electronic states that violate the Born-Oppenheimer approximation (BOA). Non-BOA transitions pose challenges to both theory and experiment. From a theoretical point of view, excited state dynamics and nonadiabatic transitions both are difficult problems (see Figure 1(a)). However, the theory on non-BOA dynamics has advanced significantly over the last two decades. Full dynamical simulations for molecules of the size of nucleobases have been possible for a couple of years and allow predictions of experimental observables like photoelectron energy or ion yield. The availability of these calculations for isolated molecules has spurred new experimental efforts to develop methods that are sufficiently different from all optical techniques. For determination of transient molecular structure, femtosecond X-ray diffraction and electron diffraction have been implemented on optically excited molecules.}, language = {en} } @phdthesis{Dionysopoulou2016, author = {Dionysopoulou, Kyriaki}, title = {General-relativistic magnetohydrodynamics in compact objects}, school = {Universit{\"a}t Potsdam}, pages = {144}, year = {2016}, language = {en} } @phdthesis{AmaroSeoane2016, author = {Amaro-Seoane, Pau}, title = {Dense stellar systems and massive black holes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-95439}, school = {Universit{\"a}t Potsdam}, pages = {239}, year = {2016}, abstract = {Gravity dictates the structure of the whole Universe and, although it is triumphantly described by the theory of General Relativity, it is the force that we least understand in nature. One of the cardinal predictions of this theory are black holes. Massive, dark objects are found in the majority of galaxies. Our own galactic center very contains such an object with a mass of about four million solar masses. Are these objects supermassive black holes (SMBHs), or do we need alternatives? The answer lies in the event horizon, the characteristic that defines a black hole. The key to probe the horizon is to model the movement of stars around a SMBH, and the interactions between them, and look for deviations from real observations. Nuclear star clusters harboring a massive, dark object with a mass of up to ~ ten million solar masses are good testbeds to probe the event horizon of the potential SMBH with stars. The channel for interactions between stars and the central MBH are the fact that (a) compact stars and stellar-mass black holes can gradually inspiral into the SMBH due to the emission of gravitational radiation, which is known as an "Extreme Mass Ratio Inspiral" (EMRI), and (b) stars can produce gases which will be accreted by the SMBH through normal stellar evolution, or by collisions and disruptions brought about by the strong central tidal field. Such processes can contribute significantly to the mass of the SMBH. These two processes involve different disciplines, which combined will provide us with detailed information about the fabric of space and time. In this habilitation I present nine articles of my recent work directly related with these topics.}, language = {en} } @phdthesis{Gomez2016, author = {Gomez, David}, title = {Mechanisms of biochemical reactions within crowded environments}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-94593}, school = {Universit{\"a}t Potsdam}, pages = {vii, 112}, year = {2016}, abstract = {The cell interior is a highly packed environment in which biological macromolecules evolve and function. This crowded media has effects in many biological processes such as protein-protein binding, gene regulation, and protein folding. Thus, biochemical reactions that take place in such crowded conditions differ from diluted test tube conditions, and a considerable effort has been invested in order to understand such differences. In this work, we combine different computationally tools to disentangle the effects of molecular crowding on biochemical processes. First, we propose a lattice model to study the implications of molecular crowding on enzymatic reactions. We provide a detailed picture of how crowding affects binding and unbinding events and how the separate effects of crowding on binding equilibrium act together. Then, we implement a lattice model to study the effects of molecular crowding on facilitated diffusion. We find that obstacles on the DNA impair facilitated diffusion. However, the extent of this effect depends on how dynamic obstacles are on the DNA. For the scenario in which crowders are only present in the bulk solution, we find that at some conditions presence of crowding agents can enhance specific-DNA binding. Finally, we make use of structure-based techniques to look at the impact of the presence of crowders on the folding a protein. We find that polymeric crowders have stronger effects on protein stability than spherical crowders. The strength of this effect increases as the polymeric crowders become longer. The methods we propose here are general and can also be applied to more complicated systems.}, language = {en} } @phdthesis{Lehmann2016, author = {Lehmann, Jascha In-su}, title = {Changes in extratropical storm track activity and their implications for extreme weather events}, pages = {221}, year = {2016}, language = {en} } @article{GhoshCherstvyPetrovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Petrov, Eugene P. and Metzler, Ralf}, title = {Interactions of rod-like particles on responsive elastic sheets}, series = {Soft matter}, journal = {Soft matter}, publisher = {RSC}, address = {London}, issn = {1744-6848}, doi = {10.1039/C6SM01522K}, year = {2016}, abstract = {What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed.}, language = {en} } @misc{GhoshCherstvyPetrovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Petrov, Eugene P. and Metzler, Ralf}, title = {Interactions of rod-like particles on responsive elastic sheets}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-95882}, year = {2016}, abstract = {What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed.}, language = {en} } @article{CherstvyMetzler2016, author = {Cherstvy, Andrey G. and Metzler, Ralf}, title = {Anomalous diffusion in time-fluctuating non-stationary diffusivity landscapes}, series = {Physical chemistry, chemical physics : PCCP ; a journal of European chemical societies}, volume = {18}, journal = {Physical chemistry, chemical physics : PCCP ; a journal of European chemical societies}, publisher = {RSC Publ.}, address = {Cambridge}, issn = {1463-9084}, doi = {10.1039/C6CP03101C}, pages = {23840 -- 23852}, year = {2016}, abstract = {We investigate the ensemble and time averaged mean squared displacements for particle diffusion in a simple model for disordered media by assuming that the local diffusivity is both fluctuating in time and has a deterministic average growth or decay in time. In this study we compare computer simulations of the stochastic Langevin equation for this random diffusion process with analytical results. We explore the regimes of normal Brownian motion as well as anomalous diffusion in the sub- and superdiffusive regimes. We also consider effects of the inertial term on the particle motion. The investigation of the resulting diffusion is performed for unconfined and confined motion.}, language = {en} } @misc{CherstvyMetzler2016, author = {Cherstvy, Andrey G. and Metzler, Ralf}, title = {Anomalous diffusion in time-fluctuating non-stationary diffusivity landscapes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-95901}, pages = {23840 -- 23852}, year = {2016}, abstract = {We investigate the ensemble and time averaged mean squared displacements for particle diffusion in a simple model for disordered media by assuming that the local diffusivity is both fluctuating in time and has a deterministic average growth or decay in time. In this study we compare computer simulations of the stochastic Langevin equation for this random diffusion process with analytical results. We explore the regimes of normal Brownian motion as well as anomalous diffusion in the sub- and superdiffusive regimes. We also consider effects of the inertial term on the particle motion. The investigation of the resulting diffusion is performed for unconfined and confined motion.}, language = {en} } @misc{Goychuk2016, author = {Goychuk, Igor}, title = {Quantum ergodicity breaking in semi-classical electron transfer dynamics}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-102264}, pages = {11}, year = {2016}, abstract = {Can the statistical properties of single-electron transfer events be correctly predicted within a common equilibrium ensemble description? This fundamental in nanoworld question of ergodic behavior is scrutinized within a very basic semi-classical curve-crossing problem. It is shown that in the limit of non-adiabatic electron transfer (weak tunneling) well-described by the Marcus-Levich-Dogonadze(MLD) rate the answer is yes. However, in the limit of the so-called solvent-controlled adiabatic electron transfer, a profound breaking of ergodicity occurs. Namely, a common description based on the ensemble reduced density matrix with an initial equilibrium distribution of the reaction coordinate is not able to reproduce the statistics of single-trajectory events in this seemingly classical regime. For sufficiently large activation barriers, the ensemble survival probability in a state remains nearly exponential with the inverse rate given by the sum of the adiabatic curve crossing (Kramers) time and the inverse MLD rate. In contrast, near to the adiabatic regime, the single-electron survival probability is clearly non-exponential, even though it possesses an exponential tail which agrees well with the ensemble description. Initially, it is well described by a Mittag-Leffler distribution with a fractional rate. Paradoxically, the mean transfer time in this classical on the ensemble level regime is well described by the inverse of the nonadiabatic quantum tunneling rate on a single particle level. An analytical theory is developed which perfectly agrees with stochastic simulations and explains our findings.}, language = {en} } @phdthesis{Kruesemann2016, author = {Kr{\"u}semann, Henning}, title = {First passage phenomena and single-file motion in ageing continuous time random walks and quenched energy landscapes}, school = {Universit{\"a}t Potsdam}, pages = {122}, year = {2016}, abstract = {In der Physik gibt es viele Prozesse, die auf Grund ihrer Komplexit{\"a}t nicht durch physikalische Gleichungen beschrieben werden k{\"o}nnen, beispielsweise die Bewegung eines Staubkorns in der Luft. Durch die vielen St{\"o}ße mit Luftmolek{\"u}len f{\"u}hrt es eine Zufallsbewegung aus, die so genannte Diffusion. Auch Molek{\"u}le in biologischen Zellen diffundieren, jedoch befinden sich in einer solchen Zelle im selben Volumen viel mehr oder viel gr{\"o}ßere Molek{\"u}le. Das beobachtete Teilchen st{\"o}ßt dementsprechend {\"o}fter mit anderen zusammen und die Diffusion wird langsamer, sie wird subdiffusiv. Mit der Zeit kann sich die Charakteristik der Subdiffusion {\"a}ndern; dies wird als (mikroskopisches) Altern bezeichnet. Ich untersuche in der vorliegenden Arbeit zwei mathematische Modelle f{\"u}r eindimensionale Subdiffusion, einmal den continuous time random walk (CTRW) und einmal die Zufallsbewegung in einer eingefrorenen Energielandschaft (QEL=quenched energy landscape). Beide sind Sprungprozesse, das heißt, sie sind Abfolgen von r{\"a}umlichen Spr{\"u}ngen, die durch zufallsverteilte Wartezeiten getrennt sind. Die Wartezeiten in der QEL sind r{\"a}umlich korrelliert, w{\"a}hrend sie im CTRW unkorrelliert sind. Ich untersuche in der vorliegenden Arbeit verschiedene statistische Gr{\"o}ßen in beiden Modellen. Zun{\"a}chst untersuche ich den Einfluss des Alters und den Einfluss der Korrellationen einer QEL auf die Verteilung der Zeiten, die das diffundierendes Teilchen ben{\"o}tigt, um eine (r{\"a}umliche) Schwelle zu {\"u}berqueren. Ausserdem bestimme ich den Effekt des Alters auf Str{\"o}me von (sub)diffundierenden Partikeln, die sich auf eine absorbierende Barriere zubewegen. Zuletzt besch{\"a}ftige ich mich mit der Diffusion einer eindimensionalen Anordnung von Teilchen in einer QEL, in der diese als harte Kugeln miteinander wechselwirken. Dabei vergleiche ich die gemeinsame Bewegung in einer QEL und als individuelle CTRWs miteinander {\"u}ber die Standartabweichung von der Startposition, f{\"u}r die ich das Mittel {\"u}ber mehrere QELs untersuche. Meine Arbeit setzt sich zusammen aus theoretischen {\"U}berlegungen und Berechnungen sowie der Simulation der Zufallsprozesse. Die Ergebnisse der Simulation und, soweit vorhanden, experimentelle Daten werden mit der Theorie verglichen.}, language = {en} } @article{deCarvalhoMetzlerCherstvy2016, author = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.}, title = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces}, series = {New journal of physics : the open-access journal for physics}, volume = {18}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Publ.}, address = {London}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/8/083037}, year = {2016}, abstract = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition—demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces—are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-H{\"u}ckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-H{\"u}ckel result, such that the required critical surface charge density for polyelectrolyte adsorption σc increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.}, language = {en} } @misc{deCarvalhoMetzlerCherstvy2016, author = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.}, title = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-100295}, pages = {17}, year = {2016}, abstract = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition—demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces—are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-H{\"u}ckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-H{\"u}ckel result, such that the required critical surface charge density for polyelectrolyte adsorption σc increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.}, language = {en} } @article{AldorettaStLouisRichardsonetal.2016, author = {Aldoretta, E. J. and St-Louis, N. and Richardson, N. D. and Moffat, Anthony F. J. and Eversberg, T. and Hill, G. M. and Shenar, Tomer and Artigau, E. and Gauza, B. and Knapen, J. H. and Kubat, Jiř{\´i} and Kubatova, Brankica and Maltais-Tariant, R. and Munoz, M. and Pablo, H. and Ramiaramanantsoa, T. and Richard-Laferriere, A. and Sablowski, D. P. and Simon-Diaz, S. and St-Jean, L. and Bolduan, F. and Dias, F. M. and Dubreuil, P. and Fuchs, D. and Garrel, T. and Grutzeck, G. and Hunger, T. and Kuesters, D. and Langenbrink, M. and Leadbeater, R. and Li, D. and Lopez, A. and Mauclaire, B. and Moldenhawer, T. and Potter, M. and dos Santos, E. M. and Schanne, L. and Schmidt, J. and Sieske, H. and Strachan, J. and Stinner, E. and Stinner, P. and Stober, B. and Strandbaek, K. and Syder, T. and Verilhac, D. and Waldschlaeger, U. and Weiss, D. and Wendt, A.}, title = {An extensive spectroscopic time series of three Wolf-Rayet stars - I. The lifetime of large-scale structures in the wind of WR 134}, series = {Monthly notices of the Royal Astronomical Society}, volume = {460}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw1188}, pages = {3407 -- 3417}, year = {2016}, abstract = {During the summer of 2013, a 4-month spectroscopic campaign took place to observe the variabilities in three Wolf-Rayet stars. The spectroscopic data have been analysed for WR 134 (WN6b), to better understand its behaviour and long-term periodicity, which we interpret as arising from corotating interaction regions (CIRs) in the wind. By analysing the variability of the He ii lambda 5411 emission line, the previously identified period was refined to P = 2.255 +/- 0.008 (s.d.) d. The coherency time of the variability, which we associate with the lifetime of the CIRs in the wind, was deduced to be 40 +/- 6 d, or similar to 18 cycles, by cross-correlating the variability patterns as a function of time. When comparing the phased observational grey-scale difference images with theoretical grey-scales previously calculated from models including CIRs in an optically thin stellar wind, we find that two CIRs were likely present. A separation in longitude of Delta I center dot a parts per thousand integral 90A degrees was determined between the two CIRs and we suggest that the different maximum velocities that they reach indicate that they emerge from different latitudes. We have also been able to detect observational signatures of the CIRs in other spectral lines (C iv lambda lambda 5802,5812 and He i lambda 5876). Furthermore, a DAC was found to be present simultaneously with the CIR signatures detected in the He i lambda 5876 emission line which is consistent with the proposed geometry of the large-scale structures in the wind. Small-scale structures also show a presence in the wind, simultaneously with the larger scale structures, showing that they do in fact co-exist.}, language = {en} } @phdthesis{Soriano2016, author = {Soriano, Manuel Flores}, title = {Short-term evolution and coexistence of photospheric and chromospheric activity on LQ Hydrae}, school = {Universit{\"a}t Potsdam}, pages = {90}, year = {2016}, language = {en} } @article{WisotzkiBaconBlaizotetal.2016, author = {Wisotzki, Lutz and Bacon, Roland and Blaizot, J. and Brinchmann, Jarle and Herenz, Edmund Christian and Schaye, Joop and Bouche, Nicolas and Cantalupo, Sebastiano and Contini, Thierry and Carollo, C. M. and Caruana, Joseph and Courbot, J. -B. and Emsellem, E. and Kamann, S. and Kerutt, Josephine Victoria and Leclercq, F. and Lilly, S. J. and Patricio, V. and Sandin, C. and Steinmetz, Matthias and Straka, Lorrie A. and Urrutia, Tanya and Verhamme, A. and Weilbacher, Peter Michael and Wendt, Martin}, title = {Extended Lyman alpha haloes around individual high-redshift galaxies revealed by MUSE}, series = {Science}, volume = {587}, journal = {Science}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527384}, pages = {27}, year = {2016}, abstract = {We report the detection of extended Ly alpha emission around individual star-forming galaxies at redshifts z = 3-6 in an ultradeep exposure of the Hubble Deep Field South obtained with MUSE on the ESO-VLT. The data reach a limiting surface brightness (1 sigma) of similar to 1 x 10(-19) erg s(-1) cm(-2) arcsec(-2) in azimuthally averaged radial profiles, an order of magnitude improvement over previous narrowband imaging. Our sample consists of 26 spectroscopically confirmed Ly alpha-emitting, but mostly continuum-faint (m(AB) greater than or similar to 27) galaxies. In most objects the Ly alpha emission is considerably more extended than the UV continuum light. While five of the faintest galaxies in the sample show no significantly detected Ly alpha haloes, the derived upper limits suggest that this is due to insufficient S/N. Ly alpha haloes therefore appear to be ubiquitous even for low-mass (similar to 10(8)-10(9) M-circle dot) star-forming galaxies at z > 3. We decompose the Ly alpha emission of each object into a compact component tracing the UV continuum and an extended halo component, and infer sizes and luminosities of the haloes. The extended Ly alpha emission approximately follows an exponential surface brightness distribution with a scale length of a few kpc. While these haloes are thus quite modest in terms of their absolute sizes, they are larger by a factor of 5-15 than the corresponding rest-frame UV continuum sources as seen by HST. They are also much more extended, by a factor similar to 5, than Ly alpha haloes around low-redshift star-forming galaxies. Between similar to 40\% and greater than or similar to 90\% of the observed Ly alpha flux comes from the extended halo component, with no obvious correlation of this fraction with either the absolute or the relative size of the Ly alpha halo. Our observations provide direct insights into the spatial distribution of at least partly neutral gas residing in the circumgalactic medium of low to intermediate mass galaxies at z > 3.}, language = {en} } @article{Steinmetz2016, author = {Steinmetz, Matthias}, title = {Die Vermessung des Universums}, series = {Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert}, journal = {Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert}, publisher = {Berlin-Brandenburgische Akademie der Wissenschaften}, address = {Berlin}, isbn = {978-3-939818-67-0}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:b4-opus4-25899}, pages = {197 -- 210}, year = {2016}, language = {de} } @phdthesis{Brauer2016, author = {Brauer, Doroth{\´e}e}, title = {Chemo-kinematic constraints on Milky Way models from the spectroscopic surveys SEGUE \& RAVE}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-403968}, school = {Universit{\"a}t Potsdam}, pages = {vii, 197}, year = {2016}, abstract = {The Milky Way is only one out of billions of galaxies in the universe. However, it is a special galaxy because it allows to explore the main mechanisms involved in its evolution and formation history by unpicking the system star-by-star. Especially, the chemical fingerprints of its stars provide clues and evidence of past events in the Galaxy's lifetime. These information help not only to decipher the current structure and building blocks of the Milky Way, but to learn more about the general formation process of galaxies. In the past decade a multitude of stellar spectroscopic Galactic surveys have scanned millions of stars far beyond the rim of the solar neighbourhood. The obtained spectroscopic information provide unprecedented insights to the chemo-dynamics of the Milky Way. In addition analytic models and numerical simulations of the Milky Way provide necessary descriptions and predictions suited for comparison with observations in order to decode the physical properties that underlie the complex system of the Galaxy. In the thesis various approaches are taken to connect modern theoretical modelling of galaxy formation and evolution with observations from Galactic stellar surveys. With its focus on the chemo-kinematics of the Galactic disk this work aims to determine new observational constraints on the formation of the Milky Way providing also proper comparisons with two different models. These are the population synthesis model TRILEGAL based on analytical distribution functions, which aims to simulate the number and distribution of stars in the Milky Way and its different components, and a hybrid model (MCM) that combines an N-body simulation of a Milky Way like galaxy in the cosmological framework with a semi-analytic chemical evolution model for the Milky Way. The major observational data sets in use come from two surveys, namely the "Radial Velocity Experiment" (RAVE) and the "Sloan Extension for Galactic Understanding and Exploration" (SEGUE). In the first approach the chemo-kinematic properties of the thin and thick disk of the Galaxy as traced by a selection of about 20000 SEGUE G-dwarf stars are directly compared to the predictions by the MCM model. As a necessary condition for this, SEGUE's selection function and its survey volume are evaluated in detail to correct the spectroscopic observations for their survey specific selection biases. Also, based on a Bayesian method spectro-photometric distances with uncertainties below 15\% are computed for the selection of SEGUE G-dwarfs that are studied up to a distance of 3 kpc from the Sun. For the second approach two synthetic versions of the SEGUE survey are generated based on the above models. The obtained synthetic stellar catalogues are then used to create mock samples best resembling the compiled sample of observed SEGUE G-dwarfs. Generally, mock samples are not only ideal to compare predictions from various models. They also allow validation of the models' quality and improvement as with this work could be especially achieved for TRILEGAL. While TRILEGAL reproduces the statistical properties of the thin and thick disk as seen in the observations, the MCM model has shown to be more suitable in reproducing many chemo-kinematic correlations as revealed by the SEGUE stars. However, evidence has been found that the MCM model may be missing a stellar component with the properties of the thick disk that the observations clearly show. While the SEGUE stars do indicate a thin-thick dichotomy of the stellar Galactic disk in agreement with other spectroscopic stellar studies, no sign for a distinct metal-poor disk is seen in the MCM model. Usually stellar spectroscopic surveys are limited to a certain volume around the Sun covering different regions of the Galaxy's disk. This often prevents to obtain a global view on the chemo-dynamics of the Galactic disk. Hence, a suitable combination of stellar samples from independent surveys is not only useful for the verification of results but it also helps to complete the picture of the Milky Way. Therefore, the thesis closes with a comparison of the SEGUE G-dwarfs and a sample of RAVE giants. The comparison reveals that the chemo-kinematic relations agree in disk regions where the samples of both surveys show a similar number of stars. For those parts of the survey volumes where one of the surveys lacks statistics they beautifully complement each other. This demonstrates that the comparison of theoretical models on the one side, and the combined observational data gathered by multiple surveys on the other side, are key ingredients to understand and disentangle the structure and formation history of the Milky Way.}, language = {en} } @article{YangGuehrVecchioneetal.2016, author = {Yang, Jie and G{\"u}hr, Markus and Vecchione, Theodore and Robinson, Matthew Scott and Li, Renkai and Hartmann, Nick and Shen, Xiaozhe and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Gaffney, Kelly and Gorkhover, Tais and Hast, Carsten and Jobe, Keith and Makasyuk, Igor and Reid, Alexander and Robinson, Joseph and Vetter, Sharon and Wang, Fenglin and Weathersby, Stephen and Yoneda, Charles and Centurion, Martin and Wang, Xijie}, title = {Diffractive imaging of a rotational wavepacket in nitrogen molecules with femtosecond megaelectronvolt electron pulses}, series = {Nature Communications}, volume = {7}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/ncomms11232}, pages = {9}, year = {2016}, abstract = {Imaging changes in molecular geometries on their natural femtosecond timescale with sub-Angstrom spatial precision is one of the critical challenges in the chemical sciences, as the nuclear geometry changes determine the molecular reactivity. For photoexcited molecules, the nuclear dynamics determine the photoenergy conversion path and efficiency. Here we report a gas-phase electron diffraction experiment using megaelectronvolt (MeV) electrons, where we captured the rotational wavepacket dynamics of nonadiabatically laser-aligned nitrogen molecules. We achieved a combination of 100 fs root-mean-squared temporal resolution and sub-Angstrom (0.76 angstrom) spatial resolution that makes it possible to resolve the position of the nuclei within the molecule. In addition, the diffraction patterns reveal the angular distribution of the molecules, which changes from prolate (aligned) to oblate (anti-aligned) in 300 fs. Our results demonstrate a significant and promising step towards making atomically resolved movies of molecular reactions.}, language = {en} } @misc{YangGuehrVecchioneetal.2016, author = {Yang, Jie and Guehr, Markus and Vecchione, Theodore and Robinson, Matthew Scott and Li, Renkai and Hartmann, Nick and Shen, Xiaozhe and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Gaffney, Kelly and Gorkhover, Tais and Hast, Carsten and Jobe, Keith and Makasyuk, Igor and Reid, Alexander and Robinson, Joseph and Vetter, Sharon and Wang, Fenglin and Weathersby, Stephen and Yoneda, Charles and Wang, Xijie and Centurion, Martin}, title = {Femtosecond gas phase electron diffraction with MeV electrons}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-394989}, pages = {19}, year = {2016}, abstract = {We present results on ultrafast gas electron diffraction (UGED) experiments with femtosecond resolution using the MeV electron gun at SLAC National Accelerator Laboratory. UGED is a promising method to investigate molecular dynamics in the gas phase because electron pulses can probe the structure with a high spatial resolution. Until recently, however, it was not possible for UGED to reach the relevant timescale for the motion of the nuclei during a molecular reaction. Using MeV electron pulses has allowed us to overcome the main challenges in reaching femtosecond resolution, namely delivering short electron pulses on a gas target, overcoming the effect of velocity mismatch between pump laser pulses and the probe electron pulses, and maintaining a low timing jitter. At electron kinetic energies above 3 MeV, the velocity mismatch between laser and electron pulses becomes negligible. The relativistic electrons are also less susceptible to temporal broadening due to the Coulomb force. One of the challenges of diffraction with relativistic electrons is that the small de Broglie wavelength results in very small diffraction angles. In this paper we describe the new setup and its characterization, including capturing static diffraction patterns of molecules in the gas phase, finding time-zero with sub-picosecond accuracy and first time-resolved diffraction experiments. The new device can achieve a temporal resolution of 100 fs root-mean-square, and sub-angstrom spatial resolution. The collimation of the beam is sufficient to measure the diffraction pattern, and the transverse coherence is on the order of 2 nm. Currently, the temporal resolution is limited both by the pulse duration of the electron pulse on target and by the timing jitter, while the spatial resolution is limited by the average electron beam current and the signal-to-noise ratio of the detection system. We also discuss plans for improving both the temporal resolution and the spatial resolution.}, language = {en} } @article{YangGuehrVecchioneetal.2016, author = {Yang, Jie and G{\"u}hr, Markus and Vecchione, Theodore and Robinson, Matthew Scott and Li, Renkai and Hartmann, Nick and Shen, Xiaozhe and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Gaffney, Kelly and Gorkhover, Tais and Hast, Carsten and Jobe, Keith and Makasyuk, Igor and Reid, Alexander and Robinson, Joseph and Vetter, Sharon and Wang, Fenglin and Weathersby, Stephen and Yoneda, Charles and Wang, Xijie and Centurion, Martin}, title = {Femtosecond gas phase electron diffraction with MeV electrons}, series = {Faraday discussions}, volume = {194}, journal = {Faraday discussions}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1359-6640}, doi = {10.1039/c6fd00071a}, pages = {563 -- 581}, year = {2016}, abstract = {We present results on ultrafast gas electron diffraction (UGED) experiments with femtosecond resolution using the MeV electron gun at SLAC National Accelerator Laboratory. UGED is a promising method to investigate molecular dynamics in the gas phase because electron pulses can probe the structure with a high spatial resolution. Until recently, however, it was not possible for UGED to reach the relevant timescale for the motion of the nuclei during a molecular reaction. Using MeV electron pulses has allowed us to overcome the main challenges in reaching femtosecond resolution, namely delivering short electron pulses on a gas target, overcoming the effect of velocity mismatch between pump laser pulses and the probe electron pulses, and maintaining a low timing jitter. At electron kinetic energies above 3 MeV, the velocity mismatch between laser and electron pulses becomes negligible. The relativistic electrons are also less susceptible to temporal broadening due to the Coulomb force. One of the challenges of diffraction with relativistic electrons is that the small de Broglie wavelength results in very small diffraction angles. In this paper we describe the new setup and its characterization, including capturing static diffraction patterns of molecules in the gas phase, finding time-zero with sub-picosecond accuracy and first time-resolved diffraction experiments. The new device can achieve a temporal resolution of 100 fs root-mean-square, and sub-angstrom spatial resolution. The collimation of the beam is sufficient to measure the diffraction pattern, and the transverse coherence is on the order of 2 nm. Currently, the temporal resolution is limited both by the pulse duration of the electron pulse on target and by the timing jitter, while the spatial resolution is limited by the average electron beam current and the signal-to-noise ratio of the detection system. We also discuss plans for improving both the temporal resolution and the spatial resolution.}, language = {en} } @article{YangGuehrShenetal.2016, author = {Yang, Jie and Guehr, Markus and Shen, Xiaozhe and Li, Renkai and Vecchione, Theodore and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Hartmann, Nick and Hast, Carsten and Hegazy, Kareem and Jobe, Keith and Makasyuk, Igor and Robinson, Joseph and Robinson, Matthew Scott and Vetter, Sharon and Weathersby, Stephen and Yoneda, Charles and Wang, Xijie and Centurion, Martin}, title = {Diffractive Imaging of Coherent Nuclear Motion in Isolated Molecules}, series = {Physical review letters}, volume = {117}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.117.153002}, pages = {6}, year = {2016}, abstract = {Observing the motion of the nuclear wave packets during a molecular reaction, in both space and time, is crucial for understanding and controlling the outcome of photoinduced chemical reactions. We have imaged the motion of a vibrational wave packet in isolated iodine molecules using ultrafast electron diffraction with relativistic electrons. The time-varying interatomic distance was measured with a precision 0.07 angstrom and temporal resolution of 230 fs full width at half maximum. The method is not only sensitive to the position but also the shape of the nuclear wave packet.}, language = {en} } @article{HassaninKliemSeehafer2016, author = {Hassanin, Alshaimaa and Kliem, Bernhard and Seehafer, Norbert}, title = {Helical kink instability in the confined solar eruption on 2002 May 27}, series = {Astronomische Nachrichten = Astronomical notes}, volume = {337}, journal = {Astronomische Nachrichten = Astronomical notes}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0004-6337}, doi = {10.1002/asna.201612446}, pages = {1082 -- 1089}, year = {2016}, language = {en} } @article{BeyeOebergXinetal.2016, author = {Beye, Martin and {\"O}berg, Henrik and Xin, Hongliang and Dakovski, Georgi L. and F{\"o}hlisch, Alexander and Gladh, Jorgen and Hantschmann, Markus and Hieke, Florian and Kaya, Sarp and K{\"u}hn, Danilo and LaRue, Jerry and Mercurio, Giuseppe and Minitti, Michael P. and Mitra, Ankush and Moeller, Stefan P. and Ng, May Ling and Nilsson, Anders and Nordlund, Dennis and Norskov, Jens and {\"O}str{\"o}m, Henrik and Ogasawara, Hirohito and Persson, Mats and Schlotter, William F. and Sellberg, Jonas A. and Wolf, Martin and Abild-Pedersen, Frank and Pettersson, Lars G. M. and Wurth, Wilfried}, title = {Chemical Bond Activation Observed with an X-ray Laser}, series = {The journal of physical chemistry letters}, volume = {7}, journal = {The journal of physical chemistry letters}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.6b01543}, pages = {3647 -- 3651}, year = {2016}, abstract = {The concept of bonding and antibonding orbitals is fundamental in chemistry. The population of those orbitals and the energetic difference between the two reflect the strength of the bonding interaction. Weakening the bond is expected to reduce this energetic splitting, but the transient character of bond-activation has so far prohibited direct experimental access. Here we apply time-resolved soft X-ray spectroscopy at a free electron laser to directly observe the decreased bonding antibonding splitting following bond-activation using an ultrashort optical laser pulse.}, language = {en} } @article{OttoJaumannKrohnetal.2016, author = {Otto, Katharina Alexandra and Jaumann, R. and Krohn, K. and Spahn, Frank and Raymond, C. A. and Russell, C. T.}, title = {The Coriolis effect on mass wasting during the Rheasilvia impact on asteroid Vesta}, series = {Geophysical research letters}, volume = {43}, journal = {Geophysical research letters}, publisher = {American Geophysical Union}, address = {Washington}, issn = {0094-8276}, doi = {10.1002/2016GL071539}, pages = {12340 -- 12347}, year = {2016}, abstract = {We investigate the influence of the Coriolis force on mass motion related to the Rheasilvia impact on asteroid Vesta. Observations by the NASA Dawn mission revealed a pattern of curved radial ridges, which are related to Coriolis-deflected mass-wasting during the initial modification stage of the crater. Utilizing the projected curvature of the mass-wasting trajectories, we developed a method that enabled investigation of the initial mass wasting of the Rheasilvia impact by observational means. We demonstrate that the Coriolis force can strongly affect the crater formation processes on rapidly rotating objects, and we derive the material's velocities (28.9 ± 22.5 m/s), viscosities (1.5-9.0 × 106 Pa s) and coefficients of friction (0.02-0.81) during the impact modification stage. The duration of the impact modification stage could be estimated to (1.1 ± 0.5) h. By analyzing the velocity distribution with respect to the topography, we deduce that the Rheasilvia impactor hit a heterogeneous target and that the initial crater walls were significantly steeper during the modification stage.}, language = {en} } @article{ShashevKupschLangeetal.2016, author = {Shashev, Yury and Kupsch, Andreas and Lange, Axel and M{\"u}ller, Bernd R. and Bruno, Giovanni}, title = {Improving the visibility of phase gratings for Talbot-Lau X-ray imaging}, series = {Materials testing : Materialpr{\~A}¼fung ; materials and components, technology and application}, volume = {58}, journal = {Materials testing : Materialpr{\~A}¼fung ; materials and components, technology and application}, publisher = {Hanser}, address = {M{\"u}nchen}, issn = {0025-5300}, doi = {10.3139/120.110948}, pages = {970 -- 974}, year = {2016}, abstract = {Talbot-Lau interferometry provides X-ray imaging techniques with significant enhancement of the radiographic contrast of weakly absorbing objects. The grating based technique allows separation of absorption, refraction and small angle scattering effects. The different efficiency of rectangular and triangular shaped phase gratings at varying detector distances is investigated. The interference patterns (Talbot carpets) are modeled for parallel monochromatic radiation and measured by synchrotron radiation. In comparison to rectangular shapes of phase gratings much higher visibility is obtained for triangular shapes which yield enhanced contrast of a glass capillary test specimen.}, language = {en} } @misc{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90553}, year = {2016}, abstract = {The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources.}, language = {en} } @article{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light}, series = {New journal of physics : the open-access journal for physics}, volume = {18}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Science}, address = {London}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023009}, pages = {1 -- 16}, year = {2016}, abstract = {The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources.}, language = {en} } @article{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light-the gravitational field of a laser pulse}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023009}, pages = {16}, year = {2016}, abstract = {The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources.}, language = {en} } @article{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {The effect of entanglement in gravitational photon-photon scattering}, series = {epl : a letters journal exploring the frontiers of physics}, volume = {115}, journal = {epl : a letters journal exploring the frontiers of physics}, publisher = {EDP Sciences}, address = {Mulhouse}, issn = {0295-5075}, doi = {10.1209/0295-5075/115/51002}, pages = {S12 -- S13}, year = {2016}, abstract = {The differential cross-section for gravitational photon-photon scattering calculated in perturbative quantum gravity is shown to depend on the degree of polarization entanglement of the two photons. The interaction between photons in the symmetric Bell state is stronger than between not entangled photons. In contrast, the interaction between photons in the anti-symmetric Bell state is weaker than between not entangled photons. The results are interpreted in terms of quantum interference, and it is shown how they fit into the idea of distance-dependent forces. Copyright (C) EPLA, 2016}, language = {en} } @article{PuhlmannHenkelHeueretal.2016, author = {Puhlmann, Dirk and Henkel, Carsten and Heuer, Axel and Pieplow, Gregor and Menzel, Ralf}, title = {Characterization of a remote optical element with bi-photons}, series = {Physica scripta : an international journal for experimental and theoretical physics}, volume = {91}, journal = {Physica scripta : an international journal for experimental and theoretical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0031-8949}, doi = {10.1088/0031-8949/91/2/023006}, pages = {113 -- 114}, year = {2016}, abstract = {We present a simple setup that exploits the interference of entangled photon pairs. 'Signal' photons are sent through a Mach-Zehnder-like interferometer, while 'idlers' are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger-Yelin-Englert inequality between contrast and predictability.}, language = {en} } @article{IntravaiaBehuninHenkeletal.2016, author = {Intravaia, F. and Behunin, R. O. and Henkel, Carsten and Busch, K. and Dalvit, D. A. R.}, title = {Failure of Local Thermal Equilibrium in Quantum Friction}, series = {Physical review letters}, volume = {117}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.117.100402}, pages = {989 -- 1010}, year = {2016}, abstract = {Recent progress in manipulating atomic and condensed matter systems has instigated a surge of interest in nonequilibrium physics, including many-body dynamics of trapped ultracold atoms and ions, near-field radiative heat transfer, and quantum friction. Under most circumstances the complexity of such nonequilibrium systems requires a number of approximations to make theoretical descriptions tractable. In particular, it is often assumed that spatially separated components of a system thermalize with their immediate surroundings, although the global state of the system is out of equilibrium. This powerful assumption reduces the complexity of nonequilibrium systems to the local application of well-founded equilibrium concepts. While this technique appears to be consistent for the description of some phenomena, we show that it fails for quantum friction by underestimating by approximately 80\% the magnitude of the drag force. Our results show that the correlations among the components of driven, but steady-state, quantum systems invalidate the assumption of local thermal equilibrium, calling for a critical reexamination of this approach for describing the physics of nonequilibrium systems.}, language = {en} } @article{IntravaiaBehuninHenkeletal.2016, author = {Intravaia, F. and Behunin, R. O. and Henkel, Carsten and Busch, K. and Dalvit, D. A. R.}, title = {Non-Markovianity in atom-surface dispersion forces}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {94}, journal = {Physical review : A, Atomic, molecular, and optical physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9926}, doi = {10.1103/PhysRevA.94.042114}, pages = {16}, year = {2016}, abstract = {We discuss the failure of the Markov approximation in the description of atom-surface fluctuation-induced interactions, both in equilibrium (Casimir-Polder forces) and out of equilibrium (quantum friction). Using general theoretical arguments, we show that the Markov approximation can lead to erroneous predictions of such phenomena with regard to both strength and functional dependencies on system parameters. In particular, we show that the long-time power-law tails of two-time dipole correlations and their corresponding low-frequency behavior, neglected in the Markovian limit, affect the prediction of the force. Our findings highlight the importance of non-Markovian effects in dispersion interactions.}, language = {en} } @article{JaphaZhouKeiletal.2016, author = {Japha, Yonathan and Zhou, Shuyu and Keil, Mark and Folman, Ron and Henkel, Carsten and Vardi, Amichay}, title = {Suppression and enhancement of decoherence in an atomic Josephson junction}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/5/055008}, pages = {22}, year = {2016}, abstract = {We investigate the role of interatomic interactions when a Bose gas, in a double-well potential with a finite tunneling probability (a 'Bose-Josephson junction'), is exposed to external noise. We examine the rate of decoherence of a system initially in its ground state with equal probability amplitudes in both sites. The noise may induce two kinds of effects: firstly, random shifts in the relative phase or number difference between the two wells and secondly, loss of atoms from the trap. The effects of induced phase fluctuations are mitigated by atom-atom interactions and tunneling, such that the dephasing rate may be suppressed by half its single-atom value. Random fluctuations may also be induced in the population difference between the wells, in which case atom-atom interactions considerably enhance the decoherence rate. A similar scenario is predicted for the case of atom loss, even if the loss rates from the two sites are equal. We find that if the initial state is number-squeezed due to interactions, then the loss process induces population fluctuations that reduce the coherence across the junction. We examine the parameters relevant for these effects in a typical atom chip device, using a simple model of the trapping potential, experimental data, and the theory of magnetic field fluctuations near metallic conductors. These results provide a framework for mapping the dynamical range of barriers engineered for specific applications and set the stage for more complex atom circuits ('atomtronics').}, language = {en} } @article{KumphHenkelRabletal.2016, author = {Kumph, Muir and Henkel, Carsten and Rabl, Peter and Brownnutt, Michael and Blatt, Rainer}, title = {Electric-field noise above a thin dielectric layer on metal electrodes}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023020}, pages = {1125 -- 1136}, year = {2016}, abstract = {The electric-field noise above a layered structure composed of a planar metal electrode covered by a thin dielectric is evaluated and it is found that the dielectric film considerably increases the noise level, in proportion to its thickness. Importantly, even a thin (mono) layer of a low-loss dielectric can enhance the noise level by several orders of magnitude compared to the noise above a bare metal. Close to this layered surface, the power spectral density of the electric field varies with the inverse fourth power of the distance to the surface, rather than with the inverse square, as it would above a bare metal surface. Furthermore, compared to a clean metal, where the noise spectrum does not vary with frequency (in the radio-wave and microwave bands), the dielectric layer can generate electricfield noise which scales in inverse proportion to the frequency. For various realistic scenarios, the noise levels predicted from this model are comparable to those observed in trapped-ion experiments. Thus, these findings are of particular importance for the understanding and mitigation of unwanted heating and decoherence in miniaturized ion traps.}, language = {en} } @phdthesis{Bendre2016, author = {Bendre, Abhijit B.}, title = {Growth and saturation of dynamo in spiral galaxies via direct simulations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407517}, school = {Universit{\"a}t Potsdam}, pages = {xviii, 133}, year = {2016}, abstract = {We do magnetohydrodynamic (MHD) simulations of local box models of turbulent Interstellar Medium (ISM) and analyse the process of amplification and saturation of mean magnetic fields with methods of mean field dynamo theory. It is shown that the process of saturation of mean fields can be partially described by the prolonged diffusion time scales in presence of the dynamically significant magnetic fields. However, the outward wind also plays an essential role in the saturation in higher SN rate case. Algebraic expressions for the back reaction of the magnetic field onto the turbulent transport coefficients are derived, which allow a complete description of the nonlinear dynamo. We also present the effects of dynamically significant mean fields on the ISM configuration and pressure distribution. We further add the cosmic ray component in the simulations and investigate the kinematic growth of mean fields with a dynamo perspective.}, language = {en} } @misc{TomovPenaRoqueetal.2016, author = {Tomov, Petar and Pena, Rodrigo F. O. and Roque, Antonio C. and Zaks, Michael A.}, title = {Mechanisms of self-sustained oscillatory states in hierarchical modular networks with mixtures of electrophysiological cell types}, series = {Frontiers in computational neuroscience}, journal = {Frontiers in computational neuroscience}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407724}, pages = {17}, year = {2016}, abstract = {In a network with a mixture of different electrophysiological types of neurons linked by excitatory and inhibitory connections, temporal evolution leads through repeated epochs of intensive global activity separated by intervals with low activity level. This behavior mimics "up" and "down" states, experimentally observed in cortical tissues in absence of external stimuli. We interpret global dynamical features in terms of individual dynamics of the neurons. In particular, we observe that the crucial role both in interruption and in resumption of global activity is played by distributions of the membrane recovery variable within the network. We also demonstrate that the behavior of neurons is more influenced by their presynaptic environment in the network than by their formal types, assigned in accordance with their response to constant current.}, language = {en} } @article{JeonJavanainenMartinezSearaetal.2016, author = {Jeon, Jae-Hyung and Javanainen, Matti and Martinez-Seara, Hector and Metzler, Ralf and Vattulainen, Ilpo}, title = {Protein Crowding in Lipid Bilayers Gives Rise to Non-Gaussian Anomalous Lateral Diffusion of Phospholipids and Proteins}, series = {Physical review : X, Expanding access}, volume = {6}, journal = {Physical review : X, Expanding access}, publisher = {American Physical Society}, address = {College Park}, issn = {2160-3308}, doi = {10.1103/PhysRevX.6.021006}, pages = {17}, year = {2016}, abstract = {Biomembranes are exceptionally crowded with proteins with typical protein-to-lipid ratios being around 1:50 - 1:100. Protein crowding has a decisive role in lateral membrane dynamics as shown by recent experimental and computational studies that have reported anomalous lateral diffusion of phospholipids and membrane proteins in crowded lipid membranes. Based on extensive simulations and stochastic modeling of the simulated trajectories, we here investigate in detail how increasing crowding by membrane proteins reshapes the stochastic characteristics of the anomalous lateral diffusion in lipid membranes. We observe that correlated Gaussian processes of the fractional Langevin equation type, identified as the stochastic mechanism behind lipid motion in noncrowded bilayer, no longer adequately describe the lipid and protein motion in crowded but otherwise identical membranes. It turns out that protein crowding gives rise to a multifractal, non-Gaussian, and spatiotemporally heterogeneous anomalous lateral diffusion on time scales from nanoseconds to, at least, tens of microseconds. Our investigation strongly suggests that the macromolecular complexity and spatiotemporal membrane heterogeneity in cellular membranes play critical roles in determining the stochastic nature of the lateral diffusion and, consequently, the associated dynamic phenomena within membranes. Clarifying the exact stochastic mechanism for various kinds of biological membranes is an important step towards a quantitative understanding of numerous intramembrane dynamic phenomena.}, language = {en} } @article{Beta2016, author = {Beta, Carsten}, title = {To turn or not to turn?}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/5/051003}, pages = {1 -- 17}, year = {2016}, abstract = {Bacteria typically swim in straight runs, interruped by sudden turning events. In particular, some species are limited to a reversal in the swimming direction as the only turning maneuver at their disposal. In a recent article, Grossmann et al (2016 New J. Phys. 18 043009) introduce a theoretical framework to analyze the diffusive properties of active particles following this type of run-and-reverse pattern. Based on a stochastic clock model to mimic the regulatory pathway that triggers reversal events, they show that a run-and-reverse swimmer can optimize its diffusive spreading by tuning the reversal rate according to the level of rotational noise. With their approach, they open up promising new perspectives of how to incorporate the dynamics of intracellular signaling into coarse-grained active particle descriptions.}, language = {en} } @article{ThiemBagheriGrosseSiestrupetal.2016, author = {Thiem, A. and Bagheri, M. and Grosse-Siestrup, C. and Zehbe, Rolf}, title = {Gelatin-poly(lactic-co-glycolic acid) scaffolds with oriented pore channel architecture - From in vitro to in vivo testing}, series = {Vision research : an international journal for functional aspects of vision.}, volume = {62}, journal = {Vision research : an international journal for functional aspects of vision.}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0928-4931}, doi = {10.1016/j.msec.2016.02.019}, pages = {585 -- 595}, year = {2016}, abstract = {A gelatin-poly(lactic-co-glycolic acid), PLGA, composite scaffold, featuring a highly oriented pore channel structure, was developed as a template for articular cartilage regeneration. As a design principle the composite scaffold was optimized to contain only medical grade educts and accordingly no chemical cross linking agents or other toxicological relevant substances or methods were used. Scaffolds were synthesized using a freeze structuring method combined with an electrochemical process followed by freeze-drying. Finally, cross linking was performed using dehydrothermal treatment, which was simultaneously used for sterilization purposes. These composite scaffolds were analyzed in regard to structural and biomechanical properties, and to their degradation behavior. Furthermore, cell culture performance was tested using chondrocytes originated from joint articular cartilage tissue from 6 to 10 months old domestic pigs. Finally, the scaffolds were tested for tissue biocompatibility and their ability for tissue integration in a rat model. The scaffolds showed both excellent functional performance and high biocompatibility in vitro and in vivo. We expect that these gelatin-PLGA scaffolds can effectively support chondrogenesis in vivo demonstrating great potential for the use in cartilage defect treatment. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{XueYanChengetal.2016, author = {Xue, Zhike and Yan, Xiaoli and Cheng, Xin and Yang, Liheng and Su, Yingna and Kliem, Bernhard and Zhang, Jun and Liu, Zhong and Bi, Yi and Xiang, Yongyuan and Yang, Kai and Zhao, Li}, title = {Observing the release of twist by magnetic reconnection in a solar filament eruption}, series = {Nature Communications}, volume = {7}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/ncomms11837}, pages = {11}, year = {2016}, abstract = {Magnetic reconnection is a fundamental process of topology change and energy release, taking place in plasmas on the Sun, in space, in astrophysical objects and in the laboratory. However, observational evidence has been relatively rare and typically only partial. Here we present evidence of fast reconnection in a solar filament eruption using high-resolution H-alpha images from the New Vacuum Solar Telescope, supplemented by extreme ultraviolet observations. The reconnection is seen to occur between a set of ambient chromospheric fibrils and the filament itself. This allows for the relaxation of magnetic tension in the filament by an untwisting motion, demonstrating a flux rope structure. The topology change and untwisting are also found through nonlinear force-free field modelling of the active region in combination with magnetohydrodynamic simulation. These results demonstrate a new role for reconnection in solar eruptions: the release of magnetic twist.}, language = {en} } @article{Kuznetsov2016, author = {Kuznetsov, Sergey P.}, title = {Parametric chaos generator operating on a varactor diode with the instability limitation decay mechanism}, series = {Technical Physics}, volume = {61}, journal = {Technical Physics}, publisher = {Pleiades Publ.}, address = {New York}, issn = {1063-7842}, doi = {10.1134/S1063784216030129}, pages = {436 -- 445}, year = {2016}, abstract = {Equations are derived for a parametric chaos generator containing three oscillatory circuits and a variable-capacitance diode (varactor) and are reduced to equations for slow amplitudes of parametrically interacting modes. With allowance for quadratic nonlinearity, the problem is reduced to a system of three first-order differential equations for Pikovsky-Rabinovich-Trakhtengerts real amplitudes with a Lorenz-type attractor. In a more accurate description of nonlinearity of the varactor, the equations for slow amplitudes are complex-valued, which leads to the loss of robustness of chaotic dynamics, which is typical of the Lorenz attractor. The results of numerical calculations (portraits of attractors and Lyapunov exponents) in models with different approximation levels are compared.}, language = {en} } @article{LenskeWagnerWirthetal.2016, author = {Lenske, Gerlinde and Wagner, Wolfgang and Wirth, Joachim and Thillmann, Hubertina and Cauet, Eva and Liepertz, Sven and Leutner, Detlev}, title = {The importance of pedagogical knowledge for classroom management and for and for students' achievement}, series = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, volume = {19}, journal = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, publisher = {Springer}, address = {Wiesbaden}, issn = {1434-663X}, doi = {10.1007/s11618-015-0659-x}, pages = {211 -- 233}, year = {2016}, abstract = {Im Rahmen der vorliegenden Studie wurde untersucht, ob das p{\"a}dagogisch-psychologische Wissen von Lehrkr{\"a}ften die prozessuale Qualit{\"a}t des Physikunterrichts mit Blick auf die Klassenf{\"u}hrung und den Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler beeinflusst. Das p{\"a}dagogisch-psychologische Professionswissen, konzeptualisiert als ein f{\"a}cher{\"u}bergreifendes, handlungsleitendes Wissen {\"u}ber Strategien und Mittel zur Unterrichtsgestaltung, wurde {\"u}ber einen Paper-Pencil-Test, bestehend aus einer Skala zum deklarativen und einer Skala zum konditional-prozeduralen Wissen erhoben (Lenske et al. 2015). Als ein grundlegendes Merkmal prozessualer Unterrichtsqualit{\"a}t wurde die Klassenf{\"u}hrung anhand von Videoratings zu zwei Messzeitpunkten (zwei Unterrichtsstunden) erfasst. Der Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler wurde {\"u}ber standardisierte Fachwissenstests im Pr{\"a}-Post-Testdesign gemessen. Die Stichprobe umfasst 34 Gymnasiallehrkr{\"a}fte und deren Sch{\"u}lerinnen und Sch{\"u}ler (N = 993). Auf Basis eines Complex-Bootstrap-Mediations-Modells zeigte sich, dass das p{\"a}dagogisch-psychologische Professionswissen {\"u}ber die Klassenf{\"u}hrung vermittelt den Lernzuwachs der Sch{\"u}ler und Sch{\"u}lerinnen positiv beeinflusst. In the present study it was investigated whether the pedagogical knowledge of teachers has an influence on the process quality of physics instruction and on the learning achievement of students as well. Pedagogical knowledge, conceptualized as knowledge about strategies in classroom instruction that is domain-general and relevant for teaching behaviors, was measured using a paper-and-pencil test with two scales: one scale on declarative knowledge, the other on conditional-procedural knowledge (Lenske et al. 2015). As a basic aspect of the process quality of classroom instruction, classroom management was assessed using video ratings of two lessons from each participating teacher. Students' learning achievement was assessed using standardized domain-specific knowledge tests in a pretest-posttest design. The sample included 34 teachers from higher-track secondary schools and their students (N = 993). A complex bootstrapping mediation model shows that teachers' pedagogical knowledge, mediated by their classroom management, has a positive effect on their students' learning achievement.}, language = {de} } @article{ShiEijtSandeepetal.2016, author = {Shi, Wenqin and Eijt, Stephan W. H. and Sandeep, Chandramathi Sukumaran Suchand and Siebbeles, Laurens D. A. and Houtepen, Arjan J. and Kinge, Sachin and Bruck, Ekkes and Barbiellini, Bernardo and Bansil, Arun}, title = {Ligand-surface interactions and surface oxidation of colloidal PbSe quantum dots revealed by thin-film positron annihilation methods}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4942609}, pages = {213 -- 230}, year = {2016}, abstract = {Positron Two Dimensional Angular Correlation of Annihilation Radiation (2D-ACAR) measurements reveal modifications of the electronic structure and composition at the surfaces of PbSe quantum dots (QDs), deposited as thin films, produced by various ligands containing either oxygen or nitrogen atoms. In particular, the 2D--ACAR measurements on thin films of colloidal PbSe QDs capped with oleic acid ligands yield an increased intensity in the electron momentum density (EMD) at high momenta compared to PbSe quantum dots capped with oleylamine. Moreover, the EMD of PbSe QDs is strongly affected by the small ethylenediamine ligands, since these molecules lead to small distances between QDs and favor neck formation between near neighbor QDs, inducing electronic coupling between neighboring QDs. The high sensitivity to the presence of oxygen atoms at the surface can be also exploited to monitor the surface oxidation of PbSe QDs upon exposure to air. Our study clearly demonstrates that positron annihilation spectroscopy applied to thin films can probe surface transformations of colloidal semiconductor QDs embedded in functional layers. (C) 2016 AIP Publishing LLC.}, language = {en} } @article{LiuKliemTitovetal.2016, author = {Liu, Rui and Kliem, Bernhard and Titov, Viacheslav S. and Chen, Jun and Wang, Yuming and Wang, Haimin and Liu, Chang and Xu, Yan and Wiegelmann, Thomas}, title = {STRUCTURE, STABILITY, AND EVOLUTION OF MAGNETIC FLUX ROPES FROM THE PERSPECTIVE OF MAGNETIC TWIST}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {818}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/818/2/148}, pages = {22}, year = {2016}, abstract = {We investigate the evolution of NOAA Active Region (AR) 11817 during 2013 August 10-12, when it developed a complex field configuration and produced four confined, followed by two eruptive, flares. These C-and-above flares are all associated with a magnetic flux rope (MFR) located along the major polarity inversion line, where shearing and converging photospheric flows are present. Aided by the nonlinear force-free field modeling, we identify the MFR through mapping magnetic connectivities and computing the twist number \${{ \mathcal T }}_{w}\$ for each individual field line. The MFR is moderately twisted (\$| {{ \mathcal T }}_{w}| \lt 2\$) and has a well-defined boundary of high squashing factor Q. We found that the field line with the extremum \$| {{ \mathcal T }}_{w}| \$ is a reliable proxy of the rope axis, and that the MFR's peak \$| {{ \mathcal T }}_{w}| \$ temporarily increases within half an hour before each flare while it decreases after the flare peak for both confined and eruptive flares. This pre-flare increase in \$| {{ \mathcal T }}_{w}| \$ has little effect on the AR's free magnetic energy or any other parameters derived for the whole region, due to its moderate amount and the MFR's relatively small volume, while its decrease after flares is clearly associated with the stepwise decrease in the whole region's free magnetic energy due to the flare. We suggest that \${{ \mathcal T }}_{w}\$ may serve as a useful parameter in forewarning the onset of eruption, and therefore, the consequent space weather effects. The helical kink instability is identified as the prime candidate onset mechanism for the considered flares.}, language = {en} } @article{ZaksTomov2016, author = {Zaks, Michael A. and Tomov, Petar}, title = {Onset of time dependence in ensembles of excitable elements with global repulsive coupling}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.020201}, pages = {5}, year = {2016}, abstract = {We consider the effect of global repulsive coupling on an ensemble of identical excitable elements. An increase of the coupling strength destabilizes the synchronous equilibrium and replaces it with many attracting oscillatory states, created in the transcritical heteroclinic bifurcation. The period of oscillations is inversely proportional to the distance from the critical parameter value. If the elements interact with the global field via the first Fourier harmonics of their phases, the stable equilibrium is in one step replaced by the attracting continuum of periodic motions.}, language = {en} } @article{GodecMetzler2016, author = {Godec, Aljaz and Metzler, Ralf}, title = {First passage time distribution in heterogeneity controlled kinetics: going beyond the mean first passage time}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep20349}, pages = {11}, year = {2016}, abstract = {The first passage is a generic concept for quantifying when a random quantity such as the position of a diffusing molecule or the value of a stock crosses a preset threshold (target) for the first time. The last decade saw an enlightening series of new results focusing mostly on the so-called mean and global first passage time (MFPT and GFPT, respectively) of such processes. Here we push the understanding of first passage processes one step further. For a simple heterogeneous system we derive rigorously the complete distribution of first passage times (FPTs). Our results demonstrate that the typical FPT significantly differs from the MFPT, which corresponds to the long time behaviour of the FPT distribution. Conversely, the short time behaviour is shown to correspond to trajectories connecting directly from the initial value to the target. Remarkably, we reveal a previously overlooked third characteristic time scale of the first passage dynamics mirroring brief excursion away from the target.}, language = {en} } @article{SandmannGarzMenzel2016, author = {Sandmann, Michael and Garz, Andreas and Menzel, Ralf}, title = {Physiological response of two different Chlamydomonas reinhardtii strains to light-dark rhythms}, series = {Botany}, volume = {94}, journal = {Botany}, publisher = {NRC Research Press}, address = {Ottawa}, issn = {1916-2790}, doi = {10.1139/cjb-2015-0144}, pages = {53 -- 64}, year = {2016}, abstract = {Cells of a cell-wall deficient line (cw15-type) of Chlamydomonas reinhardtii and of the corresponding wild type were grown during repetitive light-dark cycles. In a direct comparison, both lines showed approximately the same relative biomass increase during light phase but the cw-line produced significantly more, and smaller, daughter cells. Throughout the light period the average cellular starch content, the cellular chlorophyll content, the cellular rate of dark respiration, and the cellular rate of photosynthesis of the cw-line was lower. Despite this, several non-cell volume related parameters like the development of starch content per cell volume were clearly different over time between the strains. Additionally, the chlorophyll-based photosynthesis rates were 2-fold higher in the mutant than in the wild-type cells, and the ratio of chlorophyll a to chlorophyll b as well as the light-saturation index were also consistently higher in the mutant cells. Differences in the starch content were also confirmed by single cell analyses using a sensitive SHG-based microscopy approach. In summary, the cw15-type mutant deviates from its genetic background in the entire cell physiology. Both lines should be used in further studies in comparative systems biology with focus on the detailed relation between cell volume increase, photosynthesis, starch metabolism, and daughter cell productivity.}, language = {en} } @article{GhoshCherstvyPetrovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Petrov, Eugene P. and Metzler, Ralf}, title = {Interactions of rod-like particles on responsive elastic sheets}, series = {Soft matter}, volume = {12}, journal = {Soft matter}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c6sm01522k}, pages = {7908 -- 7919}, year = {2016}, abstract = {What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed.}, language = {en} } @article{MuenchKipfstuhlFreitagetal.2016, author = {M{\"u}nch, Thomas and Kipfstuhl, Sepp and Freitag, Johannes and Meyer, Hanno and Laepple, Thomas}, title = {Regional climate signal vs. local noise: a two-dimensional view of water isotopes in Antarctic firn at Kohnen Station, Dronning Maud Land}, series = {Climate of the past : an interactive open access journal of the European Geosciences Union}, volume = {12}, journal = {Climate of the past : an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1814-9324}, doi = {10.5194/cp-12-1565-2016}, pages = {1565 -- 1581}, year = {2016}, abstract = {In low-accumulation regions, the reliability of delta O-18-derived temperature signals from ice cores within the Holocene is unclear, primarily due to the small climate changes relative to the intrinsic noise of the isotopic signal. In order to learn about the representativity of single ice cores and to optimise future ice-core-based climate reconstructions, we studied the stable-water isotope composition of firn at Kohnen Station, Dronning Maud Land, Antarctica. Analysing delta O-18 in two 50m long snow trenches allowed us to create an unprecedented, two-dimensional image characterising the isotopic variations from the centimetre to the 100-metre scale. Our results show seasonal layering of the isotopic composition but also high horizontal isotopic variability caused by local stratigraphic noise. Based on the horizontal and vertical structure of the isotopic variations, we derive a statistical noise model which successfully explains the trench data. The model further allows one to determine an upper bound for the reliability of climate reconstructions conducted in our study region at seasonal to annual resolution, depending on the number and the spacing of the cores taken.}, language = {en} } @article{ZehbeZaslanskyMochalesetal.2016, author = {Zehbe, Rolf and Zaslansky, Paul and Mochales, Carolina and Mueller, Wolf-Dieter and Fleck, Claudia}, title = {Synchrotron micro tomographic evaluation of multilayered zirconia ceramics-Volumetric effects after indentation}, series = {Journal of the European Ceramic Society}, volume = {36}, journal = {Journal of the European Ceramic Society}, publisher = {Elsevier}, address = {Oxford}, issn = {0955-2219}, doi = {10.1016/j.jeurceramsoc.2015.09.015}, pages = {171 -- 177}, year = {2016}, abstract = {Electrophoretic deposition was used to produce zirconia specimen consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia. In this configuration, the tetragonal stabilized zirconia layers can undergo transformation toughening upon mechanical induced stresses, while the cubic stabilized layers can act as confining element. To understand the volumetric changes due to transformation toughening in these layered materials after indentation, we used an advanced synchrotron-based X-ray mu CT setup and compared the results with surface sensitive methods like Raman spectroscopy, AFM and white light interferometry. The high spatial resolution and the adapted beam energy between the absorption edges of zirconia and yttria allowed discriminating between individual layers due to differences in their yttria content. Furthermore we were able to identify single indents and link volume changes to different physical effects in the different stabilized zirconia parts and visualize the three dimensional volume around only few micrometre sized indents. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @misc{GessnerGuehr2016, author = {Gessner, Oliver and G{\"u}hr, Markus}, title = {Monitoring Ultrafast Chemical Dynamics by Time-Domain X-ray Photo- and Auger-Electron Spectroscopy}, series = {Accounts of chemical research}, volume = {49}, journal = {Accounts of chemical research}, publisher = {American Chemical Society}, address = {Washington}, issn = {0001-4842}, doi = {10.1021/acs.accounts.5b00361}, pages = {138 -- 145}, year = {2016}, abstract = {The directed flow of charge and energy is at the heart of all chemical processes. Extraordinary efforts are underway to monitor and understand the concerted motion of electrons and nuclei with ever increasing spatial and temporal sensitivity. The element specificity, chemical sensitivity, and temporal resolution of ultrafast X-ray spectroscopy techniques hold great promise to provide new insight into the fundamental interactions underlying chemical dynamics in systems ranging from isolated molecules to application-like devices. Here, we focus on the potential of ultrafast X-ray spectroscopy techniques based on the detection of photo- and Auger electrons to provide new fundamental insight into photochemical processes of systems with various degrees of complexity. Isolated nucleobases provide an excellent testing ground for our most fundamental understanding of intramolecular coupling between electrons and nuclei beyond the traditionally applied Born-Oppenheimer approximation. Ultrafast electronic relaxation dynamics enabled by the breakdown of this approximation is the major component of the nucleobase photoprotection mechanisms. Transient X-ray induced Auger electron spectroscopy on photoexcited thymine molecules provides atomic-site specific details of the extremely efficient coupling that converts potentially bond changing ultraviolet photon energy into benign heat. In particular, the time-dependent spectral shift of a specific Auger band is sensitive to the length of a single bond within the molecule. The X-ray induced Auger transients show evidence for an electronic transition out of the initially excited state within only similar to 200 fs in contrast to theoretically predicted picosecond population trapping behind a reaction barrier. Photoinduced charge transfer dynamics between transition metal complexes and semiconductor nanostructures are of central importance for many emerging energy and climate relevant technologies. Numerous demonstrations of photovoltaic and photocatalytic activity have been performed based on the combination of strong light absorption in dye molecules with charge separation and transport in adjacent semiconductor nanostructures. However, a fundamental understanding of the enabling and limiting dynamics on critical atomic length- and time scales is often still lacking. Femtosecond time-resolved X-ray photoelectron spectroscopy is employed to gain a better understanding of a short-lived intermediate that may be linked to the unexpectedly limited performance of ZnO based dye-sensitized solar cells by delaying the generation of free charge carriers. The transient spectra strongly suggest that photoexcited dye molecules attached to ZnO nanocrystals inject their charges into the substrate within less than 1 ps but the electrons are then temporarily trapped at the surface of the semiconductor in direct vicinity of the injecting molecules. The experiments are extended to monitor the electronic response of the semiconductor substrate to the collective injection from a monolayer of dye molecules and the subsequent electron-ion recombination dynamics. The results indicate some qualitative similarities but quantitative differences between the recombination dynamics at molecule-semiconductor interfaces and previously studied bulk-surface electron-hole recombination dynamics in photoexcited semiconductors.}, language = {en} } @article{MartinezGonzalezPastorYabarLaggetal.2016, author = {Martinez Gonzalez, M. J. and Pastor Yabar, A. and Lagg, A. and Asensio Ramos, A. and Collados Vera, M. and Solanki, S. K. and Balthasar, H. and Berkefeld, T. and Denker, Carsten and Doerr, H. P. and Feller, A. and Franz, M. and Gonz{\´a}lez Manrique, Sergio Javier and Hofmann, A. and Kneer, F. and Kuckein, Christoph and Louis, R. and von der L{\"u}he, O. and Nicklas, H. and Orozco, D. and Rezaei, R. and Schlichenmaier, R. and Schmidt, D. and Schmidt, W. and Sigwarth, M. and Sobotka, M. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Verma, Meetu and Waldman, T. and Volkmer, R.}, title = {Inference of magnetic fields in the very quiet Sun}, series = {Journal of geophysical research : Earth surface}, volume = {596}, journal = {Journal of geophysical research : Earth surface}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628449}, pages = {11}, year = {2016}, abstract = {Context. Over the past 20 yr, the quietest areas of the solar surface have revealed a weak but extremely dynamic magnetism occurring at small scales (<500 km), which may provide an important contribution to the dynamics and energetics of the outer layers of the atmosphere. Understanding this magnetism requires the inference of physical quantities from high-sensitivity spectro-polarimetric data with high spatio-temporal resolution. Aims. We present high-precision spectro-polarimetric data with high spatial resolution (0.4") of the very quiet Sun at 1.56 mu m obtained with the GREGOR telescope to shed some light on this complex magnetism. Methods. We used inversion techniques in two main approaches. First, we assumed that the observed profiles can be reproduced with a constant magnetic field atmosphere embedded in a field-free medium. Second, we assumed that the resolution element has a substructure with either two constant magnetic atmospheres or a single magnetic atmosphere with gradients of the physical quantities along the optical depth, both coexisting with a global stray-light component. Results. Half of our observed quiet-Sun region is better explained by magnetic substructure within the resolution element. However, we cannot distinguish whether this substructure comes from gradients of the physical parameters along the line of sight or from horizontal gradients (across the surface). In these pixels, a model with two magnetic components is preferred, and we find two distinct magnetic field populations. The population with the larger filling factor has very weak (similar to 150 G) horizontal fields similar to those obtained in previous works. We demonstrate that the field vector of this population is not constrained by the observations, given the spatial resolution and polarimetric accuracy of our data. The topology of the other component with the smaller filling factor is constrained by the observations for field strengths above 250 G: we infer hG fields with inclinations and azimuth values compatible with an isotropic distribution. The filling factors are typically below 30\%. We also find that the flux of the two polarities is not balanced. From the other half of the observed quiet-Sun area similar to 50\% are two-lobed Stokes V profiles, meaning that 23\% of the field of view can be adequately explained with a single constant magnetic field embedded in a non-magnetic atmosphere. The magnetic field vector and filling factor are reliable inferred in only 50\% based on the regular profiles. Therefore, 12\% of the field of view harbour hG fields with filling factors typically below 30\%. At our present spatial resolution, 70\% of the pixels apparently are non-magnetised.}, language = {en} } @article{VermaDenkerBalthasaretal.2016, author = {Verma, Meetu and Denker, Carsten and Balthasar, H. and Kuckein, Christoph and Gonz{\´a}lez Manrique, Sergio Javier and Sobotka, M. and Gonzalez, N. Bello and Hoch, S. and Diercke, Andrea and Kummerow, Philipp and Berkefeld, T. and Collados Vera, M. and Feller, A. and Hofmann, A. and Kneer, F. and Lagg, A. and L{\"o}hner-B{\"o}ttcher, J. and Nicklas, H. and Pastor Yabar, A. and Schlichenmaier, R. and Schmidt, D. and Schmidt, W. and Schubert, M. and Sigwarth, M. and Solanki, S. K. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Volkmer, R. and von der L{\"u}he, O. and Waldmann, T.}, title = {Horizontal flow fields in and around a small active region The transition period between flux emergence and decay}, series = {Polymers}, volume = {596}, journal = {Polymers}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628380}, pages = {12}, year = {2016}, abstract = {Context. The solar magnetic field is responsible for all aspects of solar activity. Thus, emergence of magnetic flux at the surface is the first manifestation of the ensuing solar activity. Aims. Combining high-resolution and synoptic observations aims to provide a comprehensive description of flux emergence at photospheric level and of the growth process that eventually leads to a mature active region. Methods. The small active region NOAA 12118 emerged on 2014 July 17 and was observed one day later with the 1.5-m GREGOR solar telescope on 2014 July 18. High-resolution time-series of blue continuum and G-band images acquired in the blue imaging channel (BIC) of the GREGOR Fabry-Perot Interferometer (GFPI) were complemented by synoptic line-of-sight magnetograms and continuum images obtained with the Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamics Observatory (SDO). Horizontal proper motions and horizontal plasma velocities were computed with local correlation tracking (LCT) and the differential affine velocity estimator (DAVE), respectively. Morphological image processing was employed to measure the photometric and magnetic area, magnetic flux, and the separation profile of the emerging flux region during its evolution. Results. The computed growth rates for photometric area, magnetic area, and magnetic flux are about twice as high as the respective decay rates. The space-time diagram using HMI magnetograms of five days provides a comprehensive view of growth and decay. It traces a leaf-like structure, which is determined by the initial separation of the two polarities, a rapid expansion phase, a time when the spread stalls, and a period when the region slowly shrinks again. The separation rate of 0.26 km s(-1) is highest in the initial stage, and it decreases when the separation comes to a halt. Horizontal plasma velocities computed at four evolutionary stages indicate a changing pattern of inflows. In LCT maps we find persistent flow patterns such as outward motions in the outer part of the two major pores, a diverging feature near the trailing pore marking the site of upwelling plasma and flux emergence, and low velocities in the interior of dark pores. We detected many elongated rapidly expanding granules between the two major polarities, with dimensions twice as large as the normal granules.}, language = {en} } @article{RyabchunKolloscheWegeneretal.2016, author = {Ryabchun, Alexander and Kollosche, Matthias and Wegener, Michael and Sakhno, Oksana}, title = {Holographic Structuring of Elastomer Actuator: First True Monolithic Tunable Elastomer Optics}, series = {Advanced materials}, volume = {28}, journal = {Advanced materials}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0935-9648}, doi = {10.1002/adma.201602881}, pages = {10217 -- 10223}, year = {2016}, abstract = {Volume diffraction gratings (VDGs) are inscribed selectively by diffusive introduction of benzophenone and subsequent UV-holographic structuring into an electroactive dielectric elastomer actuator (DEA), to afford a continuous voltage-controlled grating shift of 17\%. The internal stress coupling of DEA and optical domain allows for a new generation of true monolithic tunable elastomer optics with voltage controlled properties.}, language = {en} } @article{KuikLauerChurkinaetal.2016, author = {Kuik, Friderike and Lauer, Axel and Churkina, Galina and Van der Gon, Hugo A. C. Denier and Fenner, Daniel and Mar, Kathleen A. and Butler, Tim M.}, title = {Air quality modelling in the Berlin-Brandenburg region using WRF-Chem v3.7.1: sensitivity to resolution of model grid and input data}, series = {Geoscientific model development : an interactive open access journal of the European Geosciences Union}, volume = {9}, journal = {Geoscientific model development : an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1991-959X}, doi = {10.5194/gmd-9-4339-2016}, pages = {4339 -- 4363}, year = {2016}, abstract = {Air pollution is the number one environmental cause of premature deaths in Europe. Despite extensive regulations, air pollution remains a challenge, especially in urban areas. For studying summertime air quality in the Berlin-Brandenburg region of Germany, the Weather Research and Forecasting Model with Chemistry (WRF-Chem) is set up and evaluated against meteorological and air quality observations from monitoring stations as well as from a field campaign conducted in 2014. The objective is to assess which resolution and level of detail in the input data is needed for simulating urban background air pollutant concentrations and their spatial distribution in the Berlin-Brandenburg area. The model setup includes three nested domains with horizontal resolutions of 15, 3 and 1 km and anthropogenic emissions from the TNO-MACC III inventory. We use RADM2 chemistry and the MADE/SORGAM aerosol scheme. Three sensitivity simulations are conducted updating input parameters to the single-layer urban canopy model based on structural data for Berlin, specifying land use classes on a sub-grid scale (mosaic option) and downscaling the original emissions to a resolution of ca. 1 km × 1 km for Berlin based on proxy data including traffic density and population density. The results show that the model simulates meteorology well, though urban 2 m temperature and urban wind speeds are biased high and nighttime mixing layer height is biased low in the base run with the settings described above. We show that the simulation of urban meteorology can be improved when specifying the input parameters to the urban model, and to a lesser extent when using the mosaic option. On average, ozone is simulated reasonably well, but maximum daily 8 h mean concentrations are underestimated, which is consistent with the results from previous modelling studies using the RADM2 chemical mechanism. Particulate matter is underestimated, which is partly due to an underestimation of secondary organic aerosols. NOx (NO + NO2) concentrations are simulated reasonably well on average, but nighttime concentrations are overestimated due to the model's underestimation of the mixing layer height, and urban daytime concentrations are underestimated. The daytime underestimation is improved when using downscaled, and thus locally higher emissions, suggesting that part of this bias is due to deficiencies in the emission input data and their resolution. The results further demonstrate that a horizontal resolution of 3 km improves the results and spatial representativeness of the model compared to a horizontal resolution of 15 km. With the input data (land use classes, emissions) at the level of detail of the base run of this study, we find that a horizontal resolution of 1 km does not improve the results compared to a resolution of 3 km. However, our results suggest that a 1 km horizontal model resolution could enable a detailed simulation of local pollution patterns in the Berlin-Brandenburg region if the urban land use classes, together with the respective input parameters to the urban canopy model, are specified with a higher level of detail and if urban emissions of higher spatial resolution are used.}, language = {en} } @misc{BerensteinBetaDeDecker2016, author = {Berenstein, Igal and Beta, Carsten and De Decker, Yannick}, title = {Comment on "Flow-induced arrest of spatiotemporal chaos and transition to a stationary pattern in the Gray-Scott model"}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {94}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.94.046201}, pages = {3}, year = {2016}, abstract = {In this Comment, we review the results of pattern formation in a reaction-diffusion-advection system following the kinetics of the Gray-Scott model. A recent paper by Das [Phys. Rev. E 92, 052914 (2015)] shows that spatiotemporal chaos of the intermittency type can disappear as the advective flow is increased. This study, however, refers to a single point in the space of kinetic parameters of the original Gray-Scott model. Here we show that the wealth of patterns increases substantially as some of these parameters are changed. In addition to spatiotemporal intermittency, defect-mediated turbulence can also be found. In all cases, however, the chaotic behavior is seen to disappear as the advective flow is increased, following a scenario similar to what was reported in our earlier work [I. Berenstein and C. Beta, Phys. Rev. E 86, 056205 (2012)] as well as by Das. We also point out that a similar phenomenon can be found in other reaction-diffusion-advection models, such as the Oregonator model for the Belousov-Zhabotinsky reaction under flow conditions.}, language = {en} } @article{LaeppleHoerholdMuenchetal.2016, author = {Laepple, Thomas and H{\"o}rhold, Maria and M{\"u}nch, Thomas and Freitag, Johannes and Wegner, Anna and Kipfstuhl, Sepp}, title = {Layering of surface snow and firn at Kohnen Station, Antarctica: Noise or seasonal signal?}, series = {Journal of geophysical research : Earth surface}, volume = {121}, journal = {Journal of geophysical research : Earth surface}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9003}, doi = {10.1002/2016JF003919}, pages = {1849 -- 1860}, year = {2016}, abstract = {The density of firn is an important property for monitoring and modeling the ice sheets as well as to model the pore close-off and thus to interpret ice core-based greenhouse gas records. One feature, which is still in debate, is the potential existence of an annual cycle of firn density in low-accumulation regions. Several studies describe or assume seasonally successive density layers, horizontally evenly distributed, as seen in radar data. On the other hand, high-resolution density measurements on firn cores in Antarctica and Greenland show no clear seasonal cycle in the top few meters. A major caveat of most existing snow-pit and firn-core-based studies is that they represent one vertical profile from a laterally heterogeneous density field. To overcome this, we created an extensive data set of horizontal and vertical density data at Kohnen Station, Dronning Maud Land, on the East Antarctic Plateau. We drilled and analyzed three 90m long firn cores as well as 143 one-meter-long vertical profiles from two elongated snow trenches to obtain a two-dimensional view of the density variations. The analysis of the 45m wide and 1m deep density fields reveals a seasonal cycle in density. However, the seasonality is overprinted by strong stratigraphic noise, making it invisible when analyzing single firn cores. Our density data set extends the view from the local ice core perspective to a hundred meter scale and thus supports linking spatially integrating methods such as radar and seismic studies to ice and firn cores.}, language = {en} } @article{VelkUhligVikulinaetal.2016, author = {Velk, Natalia and Uhlig, Katja and Vikulina, Anna and Duschl, Claus and Volodkin, Dmitry}, title = {Mobility of lysozyme in poly(L-lysine)/hyaluronic acid multilayer films}, series = {Colloids and surfaces : an international journal devoted to fundamental and applied research on colloid and interfacial phenomena in relation to systems of biological origin ; B, Biointerfaces}, volume = {147}, journal = {Colloids and surfaces : an international journal devoted to fundamental and applied research on colloid and interfacial phenomena in relation to systems of biological origin ; B, Biointerfaces}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-7765}, doi = {10.1016/j.colsurfb.2016.07.055}, pages = {343 -- 350}, year = {2016}, abstract = {The spatial and temporal control over presentation of protein-based biomolecules such as growth factors and hormones is crucial for in vitro applications to mimic the complex in vivo environment. We investigated the interaction of a model protein lysozyme (Lys) with poly(L-lysine)/hyaluronic acid (PLL/HA) multilayer films. We focused on Lys diffusion as well as adsorption and retention within the film as a function of the film deposition conditions and post-treatment. Additionally, an effect of Lys concentration on its mobility was probed. A combination of confocal fluorescence microscopy, fluorescence recovery after photobleaching, and microfluidics was employed for this investigation. Our main finding is that adsorption of PLL and HA after protein loading induces acceleration and reduction of Lys mobility, respectively. These results suggest that a charge balance in the film to a high extent governs the protein-film interaction. We believe that control over protein mobility is a key to reach the full potential of the PLL/HA films as reservoirs for biomolecules depending on the application demand. (C) 2016 The Authors. Published by Elsevier B.V.}, language = {en} } @article{TurnerSchayeCrainetal.2016, author = {Turner, Monica L. and Schaye, Joop and Crain, Robert A. and Theuns, Tom and Wendt, Martin}, title = {Observations of metals in the z approximate to 3.5 intergalactic medium and comparison to the EAGLE simulations}, series = {Monthly notices of the Royal Astronomical Society}, volume = {462}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw1816}, pages = {2440 -- 2464}, year = {2016}, abstract = {We study the z approximate to 3.5 intergalactic medium (IGM) by comparing new, high-quality absorption spectra of eight QSOs with < z(QSO)> = 3.75, to virtual observations of the Evolution and Assembly of Galaxies and their Environments (EAGLE) cosmological hydrodynamical simulations. We employ the pixel optical depth method and uncover strong correlations between various combinations of H I, C III, C IV, Si III, Si IV, and O VI. We find good agreement between many of the simulated and observed correlations, including tau(O) (VI) (tau(H) (I)). However, the observed median optical depths for the tau(C) (IV) (tau(H) (I)) and tau(Si) (IV) (tau(H) (I)) relations are higher than those measured from the mock spectra. The discrepancy increases from up to approximate to 0.1 dex at tau(H) (I) = 1 to approximate to 1 dex at tau(H) (I) = 10(2), where we are likely probing dense regions at small galactocentric distances. As possible solutions, we invoke (a) models of ionizing radiation softened above 4 Ryd to account for delayed completion of He II reionization; (b) simulations run at higher resolution; (c) the inclusion of additional line broadening due to unresolved turbulence; and (d) increased elemental abundances; however, none of these factors can fully explain the observed differences. Enhanced photoionization of H I by local sources, which was not modelled, could offer a solution. However, the much better agreement with the observed O VI(H I) relation, which we find probes a hot and likely collisionally ionized gas phase, indicates that the simulations are not in tension with the hot phase of the IGM, and suggests that the simulated outflows may entrain insufficient cool gas.}, language = {en} } @article{ValliappanArltDierckeetal.2016, author = {Valliappan, Senthamizh Pavai and Arlt, Rainer and Diercke, Andrea and Denker, Carsten and Vaquero, J. M.}, title = {Sunspot group tilt angle measurements from historical observations}, series = {Advances in space research}, volume = {58}, journal = {Advances in space research}, publisher = {Elsevier}, address = {Oxford}, issn = {0273-1177}, doi = {10.1016/j.asr.2016.03.002}, pages = {1468 -- 1474}, year = {2016}, abstract = {Sunspot positions from various historical sets of solar drawings are analyzed with respect to the tilt angles of bipolar sunspot groups. Data by Scheiner, Hevelius, Staudacher, Zucconi, Schwabe, and Sporer deliver a series of average tilt angles spanning a period of 270 years, additional to previously found values for 20th-century data obtained by other authors. We find that the average tilt angles before the Maunder minimum were not significantly different from the modem values. However, the average tilt angles of a period 50 years after the Maunder minimum, namely for cycles 0 and 1, were much lower and near zero. The normal tilt angles before the Maunder minimum suggest that it was not abnormally low tilt angles which drove the solar cycle into a grand minimum. (C) 2016 COSPAR. Published by Elsevier Ltd. All rights reserved.}, language = {en} } @article{FischerBaderAbel2016, author = {Fischer, Jost Leonhardt and Bader, Rolf and Abel, Markus}, title = {Aeroacoustical coupling and synchronization of organ pipes}, series = {The journal of the Acoustical Society of America}, volume = {140}, journal = {The journal of the Acoustical Society of America}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0001-4966}, doi = {10.1121/1.4964135}, pages = {2344 -- 2351}, year = {2016}, abstract = {A synchronization experiment on two mutual interacting organ pipes is compared with a theoretical model which takes into account the coupling mechanisms by the underlying first principles of fluid mechanics and aeroacoustics. The focus is on the Arnold-tongue, a mathematical object in the parameter space of detuning and coupling strength which quantitatively captures the interaction of the synchronized sound sources. From the experiment, a nonlinearly shaped Arnold-tongue is obtained, describing the coupling of the synchronized pipe-pipe system. This is in contrast to the linear shaped Arnold-tongue found in a preliminary experiment of the coupled system pipe-loudspeaker. To understand the experimental result, a coarse-grained model of two nonlinear coupled self-sustained oscillators is developed. The model, integrated numerically, is in very good agreement with the synchronization experiment for separation distances of the pipes in the far field and in the intermediate field. The methods introduced open the door for a deeper understanding of the fundamental processes of sound generation and the coupling mechanisms on mutual interacting acoustic oscillators. (C) 2016 Acoustical Society of America.}, language = {en} } @article{deCarvalhoMetzlerCherstvy2016, author = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.}, title = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces: the nonlinear Poisson-Boltzmann approach}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/8/083037}, pages = {17}, year = {2016}, abstract = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces-are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-Huckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-Huckel result, such that the required critical surface charge density for polyelectrolyte adsorption sigma(c) increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.}, language = {en} } @article{SantosdeLimaYandeGouveiaDalPinoetal.2016, author = {Santos de Lima, Reinaldo and Yan, Huirong and de Gouveia Dal Pino, E. M. and Lazarian, A.}, title = {Limits on the ion temperature anisotropy in the turbulent intracluster medium}, series = {Monthly notices of the Royal Astronomical Society}, volume = {460}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw1079}, pages = {2492 -- 2504}, year = {2016}, abstract = {Turbulence in the weakly collisional intracluster medium (ICM) of galaxies is able to generate strong thermal velocity anisotropies in the ions (with respect to the local magnetic field direction), if the magnetic moment of the particles is conserved in the absence of Coulomb collisions. In this scenario, the anisotropic pressure magnetohydrodynamic (AMHD) turbulence shows a very different statistical behaviour from the standard MHD one and is unable to amplify seed magnetic fields. This is in contrast to previous cosmological MHD simulations that are successful in explaining the observed magnetic fields in the ICM. On the other hand, temperature anisotropies can also drive plasma instabilities that can relax the anisotropy. This work aims to compare the relaxation rate with the growth rate of the anisotropies driven by the turbulence. We employ quasi-linear theory to estimate the ion scattering rate resulting from the parallel firehose, mirror and ion-cyclotron instabilities, for a set of plasma parameters resulting from AMHD simulations of the turbulent ICM. We show that the ICM turbulence can sustain only anisotropy levels very close to the instability thresholds. We argue that the AMHD model that bounds the anisotropies at the marginal stability levels can describe the Alfv,nic turbulence cascade in the ICM.}, language = {en} } @article{WaldripNivenAbeletal.2016, author = {Waldrip, S. H. and Niven, R. K. and Abel, Markus and Schlegel, M.}, title = {Maximum Entropy Analysis of Hydraulic Pipe Flow Networks}, series = {Journal of hydraulic engineering}, volume = {142}, journal = {Journal of hydraulic engineering}, publisher = {American Society of Civil Engineers}, address = {Reston}, issn = {0733-9429}, doi = {10.1061/(ASCE)HY.1943-7900.0001126}, pages = {332 -- 347}, year = {2016}, language = {en} } @article{RettigDornesThielemannKuehnetal.2016, author = {Rettig, L. and Dornes, C. and Thielemann-Kuehn, Nele and Pontius, N. and Zabel, Hartmut and Schlagel, D. L. and Lograsso, T. A. and Chollet, M. and Robert, A. and Sikorski, M. and Song, S. and Glownia, J. M. and Schuessler-Langeheine, Christian and Johnson, S. L. and Staub, U.}, title = {Itinerant and Localized Magnetization Dynamics in Antiferromagnetic Ho}, series = {Physical review letters}, volume = {116}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.116.257202}, pages = {6382 -- 6389}, year = {2016}, abstract = {Using femtosecond time-resolved resonant magnetic x-ray diffraction at the Ho L-3 absorption edge, we investigate the demagnetization dynamics in antiferromagnetically ordered metallic Ho after femtosecond optical excitation. Tuning the x-ray energy to the electric dipole (E1, 2p -> 5d) or quadrupole (E2, 2p -> 4f) transition allows us to selectively and independently study the spin dynamics of the itinerant 5d and localized 4f electronic subsystems via the suppression of the magnetic (2 1 3-tau) satellite peak. We find demagnetization time scales very similar to ferromagnetic 4f systems, suggesting that the loss of magnetic order occurs via a similar spin-flip process in both cases. The simultaneous demagnetization of both subsystems demonstrates strong intra-atomic 4f-5d exchange coupling. In addition, an ultrafast lattice contraction due to the release of magneto-striction leads to a transient shift of the magnetic satellite peak.}, language = {en} } @article{DzhanoevSchmidtLiuetal.2016, author = {Dzhanoev, Arsen R. and Schmidt, J. and Liu, X. and Spahn, Frank}, title = {Charging of small grains in a space plasma: Application to Jovian stream particles}, series = {International psychogeriatrics}, volume = {591}, journal = {International psychogeriatrics}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527891}, pages = {647 -- 684}, year = {2016}, abstract = {Context. Most theoretical investigations of dust charging processes in space have treated the current balance condition as independent of grain size. However, for small grains, since they are often observed in space environments, a dependence on grain size is expected owing to secondary electron emission (SEE). Here, by the term "small" we mean a particle size comparable to the typical penetration depth for given primary electron energy. The results are relevant for the dynamics of small, charged dust particles emitted by the volcanic moon Io, which forms the Jovian dust streams. Aims. We revise the theory of charging of small (submicron sized) micrometeoroids to take into account a high production of secondary electrons for small grains immersed in an isotropic flux of electrons. We apply our model to obtain an improved estimate for the charge of the dust streams leaving the Jovian system, detected by several spacecraft. Methods. We apply a continuum model to describe the penetration of primary electrons in a grain and the emission of secondary electrons along the path. Averaging over an isotropic flux of primaries, we derive a new expression for the secondary electron yield, which can be used to express the secondary electron current on a grain. Results. For the Jupiter plasma environment we derive the surface potential of grains composed of NaCl (believed to be the major constituent of Jovian dust stream particles) or silicates. For small particles, the potential depends on grain size and the secondary electron current induces a sensitivity to material properties. As a result of the small particle effect, the estimates for the charging times and for the fractional charge fluctuations of NaCl grains obtained using our general approach to SEE give results qualitatively different from the analogous estimates derived from the traditional approach to SEE. We find that for the charging environment considered in this paper field emission does not limit the charging of NaCl grains.}, language = {en} } @article{GuberRichter2016, author = {Guber, Christoph R. and Richter, Philipp}, title = {Dust depletion of Ca and Ti in QSO absorption-line systems}, series = {Wiley Interdisciplinary Reviews : Water}, volume = {591}, journal = {Wiley Interdisciplinary Reviews : Water}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628466}, pages = {16}, year = {2016}, abstract = {Aims. To explore the role of titanium-and calcium-dust depletion in gas in and around galaxies, we systematically study Ti/Ca abundance ratios in intervening absorption-line systems at low and high redshift. Methods. We investigate high-resolution optical spectra obtained by the UVES instrument at the Very Large Telescope (VLT) and spectroscopically analyze 34 absorption-line systems at z <= 0.5 to measure column densities (or limits) for Ca II and Ti II. We complement our UVES data set with previously published absorption-line data on Ti/Ca for redshifts up to z similar to 3.8. Our absorber sample contains 110 absorbers including damped Lyman alpha systems (DLAs), sub-DLAs, and Lyman-Limit systems (LLS). We compare our Ti/Ca findings with results from the MilkyWay and the Magellanic Clouds and discuss the properties of Ti/Ca absorbers in the general context of quasar absorption-line systems. Results. Our analysis indicates that there are two distinct populations of absorbers with either high or low Ti/Ca ratios with a separation at [Ti/Ca] approximate to 1. While the calcium-dust depletion in most of the absorbers appears to be severe, the titanium depletions are mild in systems with high Ti/Ca ratios. The derived trend indicates that absorbers with high Ti/Ca ratios have dust-to-gas ratios that are substantially lower than in the Milky Way. We characterize the overall nature of the absorbers by correlating Ti/Ca with other observables (e.g., metallicity, velocity-component structure) and by modeling the ionization properties of singly-ionized Ca and Ti in different environments. Conclusions. We conclude that Ca II and Ti II bearing absorption-line systems trace predominantly neutral gas in the disks and inner halo regions of galaxies, where the abundance of Ca and Ti reflects the local metal and dust content of the gas. Our study suggests that the Ti/Ca ratio represents a useful measure for the gas-to-dust ratio and overall metallicity in intervening absorption-line systems.}, language = {en} } @article{SchwarzlGodecOshaninetal.2016, author = {Schwarzl, Maria and Godec, Aljaz and Oshanin, Gleb and Metzler, Ralf}, title = {A single predator charging a herd of prey: effects of self volume and predator-prey decision-making}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {49}, journal = {Journal of physics : A, Mathematical and theoretical}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8113/49/22/225601}, pages = {19}, year = {2016}, abstract = {We study the degree of success of a single predator hunting a herd of prey on a two-dimensional square lattice landscape. We explicitly consider the self volume of the prey restraining their dynamics on the lattice. The movement of both predator and prey is chosen to include an intelligent, decision making step based on their respective sighting ranges, the radius in which they can detect the other species (prey cannot recognise each other besides the self volume interaction): after spotting each other the motion of prey and predator turns from a nearest neighbour random walk into directed escape or chase, respectively. We consider a large range of prey densities and sighting ranges and compute the mean first passage time for a predator to catch a prey as well as characterise the effective dynamics of the hunted prey. We find that the prey's sighting range dominates their life expectancy and the predator profits more from a bad eyesight of the prey than from his own good eye sight. We characterise the dynamics in terms of the mean distance between the predator and the nearest prey. It turns out that effectively the dynamics of this distance coordinate can be captured in terms of a simple Ornstein-Uhlenbeck picture. Reducing the many-body problem to a simple two-body problem by imagining predator and nearest prey to be connected by an effective Hookean bond, all features of the model such as prey density and sighting ranges merge into the effective binding constant.}, language = {en} } @article{LoveChouHuangetal.2016, author = {Love, John A. and Chou, Shu-Hua and Huang, Ye and Bazan, Guillermo C. and Thuc-Quyen Nguyen,}, title = {Effects of solvent additive on "s-shaped" curves in solution-processed small molecule solar cells}, series = {Beilstein journal of organic chemistry}, volume = {12}, journal = {Beilstein journal of organic chemistry}, publisher = {Beilstein-Institut zur F{\~A}\Prderung der Chemischen Wissenschaften}, address = {Frankfurt, Main}, issn = {1860-5397}, doi = {10.3762/bjoc.12.249}, pages = {2543 -- 2555}, year = {2016}, abstract = {A novel molecular chromophore, p-SIDT(FBTThCA8)(2), is introduced as an electron-donor material for bulk heterojunction (BHJ) solar cells with broad absorption and near ideal energy levels for the use in combination with common acceptor materials. It is found that films cast from chlorobenzene yield devices with strongly s-shaped current-voltage curves, drastically limiting performance. We find that addition of the common solvent additive diiodooctane, in addition to facilitating crystallization, leads to improved vertical phase separation. This yields much better performing devices, with improved curve shape, demonstrating the importance of morphology control in BHJ devices and improving the understanding of the role of solvent additives.}, language = {en} } @article{Qiu2016, author = {Qiu, Xunlin}, title = {Significant enhancement of the charging efficiency in the cavities of ferroelectrets through gas exchange during charging}, series = {Applied physics letters}, volume = {109}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4971259}, pages = {2543 -- 2555}, year = {2016}, abstract = {Ferroelectrets are non-polar polymer foams or polymer systems with internally charged cavities. They are charged through a series of dielectric barrier discharges (DBDs) that are caused by the electrical breakdown of the gas inside the cavities. Thus, the breakdown strength of the gas strongly influences the charging process of ferroelectrets. A gas with a lower breakdown strength has a lower threshold voltage, thus decreasing the onset voltage for DBD charging. However, a lower threshold voltage also leads to a lower value for the remanent polarization, as back discharges that are caused by the electric field of the internally deposited charges can take place already at lower charge levels. On this basis, a charging strategy is proposed where the DBDs start in a gas with a lower breakdown strength (in the present example, helium) and are completed at a higher breakdown strength (e.g., nitrogen or atmospheric air). Thus, the exchange of the gas in the cavities during charging can significantly enhance the charging efficiency, i.e., yield much higher piezoelectric coefficients in ferroelectrets at significantly lower charging voltages. Published by AIP Publishing.}, language = {en} } @article{GodecMetzler2016, author = {Godec, Aljaz and Metzler, Ralf}, title = {Universal Proximity Effect in Target Search Kinetics in the Few-Encounter Limit}, series = {Physical review : X, Expanding access}, volume = {6}, journal = {Physical review : X, Expanding access}, publisher = {American Physical Society}, address = {College Park}, issn = {2160-3308}, doi = {10.1103/PhysRevX.6.041037}, pages = {11}, year = {2016}, abstract = {When does a diffusing particle reach its target for the first time? This first-passage time (FPT) problem is central to the kinetics of molecular reactions in chemistry and molecular biology. Here, we explain the behavior of smooth FPT densities, for which all moments are finite, and demonstrate universal yet generally non-Poissonian long-time asymptotics for a broad variety of transport processes. While Poisson-like asymptotics arise generically in the presence of an effective repulsion in the immediate vicinity of the target, a time-scale separation between direct and reflected indirect trajectories gives rise to a universal proximity effect: Direct paths, heading more or less straight from the point of release to the target, become typical and focused, with a narrow spread of the corresponding first-passage times. Conversely, statistically dominant indirect paths exploring the entire system tend to be massively dissimilar. The initial distance to the target particularly impacts gene regulatory or competitive stochastic processes, for which few binding events often determine the regulatory outcome. The proximity effect is independent of details of the transport, highlighting the robust character of the FPT features uncovered here.}, language = {en} } @article{AliuArchambaultArcheretal.2016, author = {Aliu, E. and Archambault, S. and Archer, A. and Benbow, W. and Bird, R. and Biteau, Jonathan and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Ciupik, L. and Connolly, M. P. and Cui, W. and Dickinson, H. J. and Eisch, J. D. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Flinders, A. and Fortin, P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Huetten, M. and Hakansson, Nils and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Lang, M. J. and Loo, A. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Moriarty, P. and Mukherjee, R. and Nguyen, T. and Nieto, D. and Ong, R. A. and Otte, A. N. and Pandel, D. and Park, N. and Pelassa, V. and Petrashyk, A. and Pohl, M. and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Varlotta, A. and Vincent, S. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wilhelm, Alina and Williams, D. A. and Zitzer, B. and Chernyakova, M. and Roberts, M. S. E.}, title = {A SEARCH FOR VERY HIGH ENERGY GAMMA RAYS FROM THE MISSING LINK BINARY PULSAR J1023+0038 WITH VERITAS}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {831}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/831/2/193}, pages = {7}, year = {2016}, abstract = {The binary millisecond radio pulsar PSR J1023+0038 exhibits many characteristics similar to the gamma-ray binary system PSR B1259-63/LS 2883, making it an ideal candidate for the study of high-energy nonthermal emission. It has been the subject of multiwavelength campaigns following the disappearance of the pulsed radio emission in 2013 June, which revealed the appearance of an accretion disk around the neutron star. We present the results of very high energy (VHE) gamma-ray observations carried out by the Very Energetic Radiation Imaging Telescope Array System before and after this change of state. Searches for steady and pulsed emission of both data sets yield no significant gamma-ray signal above 100 GeV, and upper limits are given for both a steady and pulsed gamma-ray flux. These upper limits are used to constrain the magnetic field strength in the shock region of the PSR J1023+0038 system. Assuming that VHE gamma rays are produced via an inverse Compton mechanism in the shock region, we constrain the shock magnetic field to be greater than similar to 2 G before the disappearance of the radio pulsar and greater than similar to 10 G afterward.}, language = {en} } @article{KomarovBazhenov2016, author = {Komarov, Maxim and Bazhenov, Maxim}, title = {Linking dynamics of the inhibitory network to the input structure}, series = {Journal of computational neuroscience}, volume = {41}, journal = {Journal of computational neuroscience}, publisher = {Springer}, address = {Dordrecht}, issn = {0929-5313}, doi = {10.1007/s10827-016-0622-8}, pages = {367 -- 391}, year = {2016}, language = {en} } @article{ArltValliappanSchmieletal.2016, author = {Arlt, Rainer and Valliappan, Senthamizh Pavai and Schmiel, C. and Spada, F.}, title = {Sunspot positions, areas, and group tilt angles for 1611-1631 from observations by Christoph Scheiner}, series = {Mountain research and development}, volume = {595}, journal = {Mountain research and development}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201629000}, pages = {10}, year = {2016}, abstract = {Methods. In most cases, the given orientation of the ecliptic is used to set up the heliographic coordinate system for the drawings. Positions and sizes are measured manually on screen. Very early drawings have no indication of their orientation. A rotational matching using common spots of adjacent days is used in some cases, while in other cases, the assumption that images were aligned with a zenith-horizon coordinate system appeared to be the most probable.}, language = {en} } @article{KruesemannSchwarzlMetzler2016, author = {Kruesemann, Henning and Schwarzl, Richard and Metzler, Ralf}, title = {Ageing Scher-Montroll Transport}, series = {Transport in Porous Media}, volume = {115}, journal = {Transport in Porous Media}, publisher = {Springer}, address = {New York}, issn = {0169-3913}, doi = {10.1007/s11242-016-0686-y}, pages = {327 -- 344}, year = {2016}, abstract = {We study the properties of ageing Scher-Montroll transport in terms of a biased subdiffusive continuous time random walk in which the waiting times between consecutive jumps of the charge carriers are distributed according to the power law probability with . As we show, the dynamical properties of the Scher-Montroll transport depend on the ageing time span between the initial preparation of the system and the start of the observation. The Scher-Montroll transport theory was originally shown to describe the photocurrent in amorphous solids in the presence of an external electric field, but it has since been used in many other fields of physical sciences, in particular also in the geophysical context for the description of the transport of tracer particles in subsurface aquifers. In the absence of ageing () the photocurrent of the classical Scher-Montroll model or the breakthrough curves in the groundwater context exhibit a crossover between two power law regimes in time with the scaling exponents and . In the presence of ageing a new power law regime and an initial plateau regime of the current emerge. We derive the different power law regimes and crossover times of the ageing Scher-Montroll transport and show excellent agreement with simulations of the process. Experimental data of ageing Scher-Montroll transport in polymeric semiconductors are shown to agree well with the predictions of our theory.}, language = {en} } @article{BalthasarGoemoeryGonzalezManriqueetal.2016, author = {Balthasar, H. and G{\"o}m{\"o}ry, P. and Gonz{\´a}lez Manrique, Sergio Javier and Kuckein, Christoph and Kavka, J. and Kucera, A. and Schwartz, P. and Vaskova, R. and Berkefeld, T. and Collados Vera, M. and Denker, Carsten and Feller, A. and Hofmann, A. and Lagg, A. and Nicklas, H. and Suarez, D. and Pastor Yabar, A. and Rezaei, R. and Schlichenmaier, R. and Schmidt, D. and Schmidt, W. and Sigwarth, M. and Sobotka, M. and Solanki, S. K. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Volkmer, R. and von der L{\"u}he, O. and Waldmann, T.}, title = {Spectropolarimetric observations of an arch filament system with the GREGOR solar telescope}, series = {Astronomische Nachrichten = Astronomical notes}, volume = {337}, journal = {Astronomische Nachrichten = Astronomical notes}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0004-6337}, doi = {10.1002/asna.201612432}, pages = {1050 -- 1056}, year = {2016}, abstract = {Arch filament systems occur in active sunspot groups, where a fibril structure connects areas of opposite magnetic polarity, in contrast to active region filaments that follow the polarity inversion line. We used the GREGOR Infrared Spectrograph (GRIS) to obtain the full Stokes vector in the spectral lines SiI lambda 1082.7 nm, He I lambda 1083.0 nm, and Ca I lambda 1083.9 nm. We focus on the near-infrared calcium line to investigate the photospheric magnetic field and velocities, and use the line core intensities and velocities of the helium line to study the chromospheric plasma. The individual fibrils of the arch filament system connect the sunspot with patches of magnetic polarity opposite to that of the spot. These patches do not necessarily coincide with pores, where the magnetic field is strongest. Instead, areas are preferred not far from the polarity inversion line. These areas exhibit photospheric downflows of moderate velocity, but significantly higher downflows of up to 30 km s(-1) in the chromospheric helium line. Our findings can be explained with new emerging flux where the matter flows downward along the field lines of rising flux tubes, in agreement with earlier results. (C) 2016 WILEY-VCH Verlag GmbH\& Co. KGaA, Weinheim}, language = {en} } @article{GonzalezManriqueKuckeinPastorYabaretal.2016, author = {Gonzalez Manrique, Sergio Javier and Kuckein, Christoph and Pastor Yabar, A. and Collados Vera, M. and Denker, Carsten and Fischer, C. E. and G{\"o}m{\"o}ry, P. and Diercke, Andrea and Gonzalez, N. Bello and Schlichenmaier, R. and Balthasar, H. and Berkefeld, T. and Feller, A. and Hoch, S. and Hofmann, A. and Kneer, F. and Lagg, A. and Nicklas, H. and Orozco Suarez, D. and Schmidt, D. and Schmidt, W. and Sigwarth, M. and Sobotka, M. and Solanki, S. K. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Verma, Meetu and Volkmer, R. and von der L{\"u}he, O. and Waldmann, T.}, title = {Fitting peculiar spectral profiles in He I 10830 angstrom absorption features}, series = {Astronomische Nachrichten = Astronomical notes}, volume = {337}, journal = {Astronomische Nachrichten = Astronomical notes}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0004-6337}, doi = {10.1002/asna.201512433}, pages = {1057 -- 1063}, year = {2016}, abstract = {The new generation of solar instruments provides better spectral, spatial, and temporal resolution for a better understanding of the physical processes that take place on the Sun. Multiple-component profiles are more commonly observed with these instruments. Particularly, the He i 10830 triplet presents such peculiar spectral profiles, which give information on the velocity and magnetic fine structure of the upper chromosphere. The purpose of this investigation is to describe a technique to efficiently fit the two blended components of the He i 10830 triplet, which are commonly observed when two atmospheric components are located within the same resolution element. The observations used in this study were taken on 2015 April 17 with the very fast spectroscopic mode of the GREGOR Infrared Spectrograph (GRIS) attached to the 1.5-m GREGOR solar telescope, located at the Observatorio del Teide, Tenerife, Spain. We apply a double-Lorentzian fitting technique using Levenberg-Marquardt least-squares minimization. This technique is very simple and much faster than inversion codes. Line-of-sight Doppler velocities can be inferred for a whole map of pixels within just a few minutes. Our results show sub-and supersonic downflow velocities of up to 32 km s(-1) for the fast component in the vicinity of footpoints of filamentary structures. The slow component presents velocities close to rest. (C) 2016 WILEY-VCH Verlag GmbH\& Co. KGaA, Weinheim}, language = {en} } @article{VermaDenkerBoehmetal.2016, author = {Verma, Meetu and Denker, Carsten and B{\"o}hm, F. and Balthasar, H. and Fischer, C. E. and Kuckein, Christoph and Gonzalez, N. Bello and Berkefeld, T. and Collados Vera, M. and Diercke, Andrea and Feller, A. and Gonzalez Manrique, Sergio Javier and Hofmann, A. and Lagg, A. and Nicklas, H. and Orozco Suarez, D. and Pator Yabar, A. and Rezaei, R. and Schlichenmaier, R. and Schmidt, D. and Schmidt, W. and Sigwarth, M. and Sobotka, M. and Solanki, S. K. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Volkmer, R. and von der L{\"u}he, O. and Waldmann, T.}, title = {Flow and magnetic field properties in the trailing sunspots of active region NOAA 12396}, series = {Astronomische Nachrichten = Astronomical notes}, volume = {337}, journal = {Astronomische Nachrichten = Astronomical notes}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0004-6337}, doi = {10.1002/asna.201612447}, pages = {1090 -- 1098}, year = {2016}, abstract = {Improved measurements of the photospheric and chromospheric three-dimensional magnetic and flow fields are crucial for a precise determination of the origin and evolution of active regions. We present an illustrative sample of multi-instrument data acquired during a two-week coordinated observing campaign in August 2015 involving, among others, the GREGOR solar telescope (imaging and near-infrared spectroscopy) and the space missions Solar Dynamics Observatory (SDO) and Interface Region Imaging Spectrograph (IRIS). The observations focused on the trailing part of active region NOAA 12396 with complex polarity inversion lines and strong intrusions of opposite polarity flux. The GREGOR Infrared Spectrograph (GRIS) provided Stokes IQUV spectral profiles in the photospheric Si i.1082.7 nm line, the chromospheric He I lambda 1083.0 nm triplet, and the photospheric Ca I lambda 1083.9 nm line. Carefully calibrated GRIS scans of the active region provided maps of Doppler velocity and magnetic field at different atmospheric heights. We compare quick-look maps with those obtained with the " Stokes Inversions based on Response functions" (SIR) code, which furnishes deeper insight into the magnetic properties of the region. We find supporting evidence that newly emerging flux and intruding opposite polarity flux are hampering the formation of penumbrae, i.e., a penumbra fully surrounding a sunspot is only expected after cessation of flux emergence in proximity to the sunspots. (C) 2016 WILEY-VCH Verlag GmbH\& Co.KGaA, Weinheim}, language = {en} } @article{DenkerHeibelRendteletal.2016, author = {Denker, Carsten and Heibel, C. and Rendtel, J. and Arlt, K. and Balthasar, H. and Diercke, Andrea and Gonzalez Manrique, Sergio Javier and Hofmann, A. and Kuckein, Christoph and {\"O}nel, H. and Valliappan, Senthamizh Pavai and Staude, J. and Verma, Meetu}, title = {Solar physics at the Einstein Tower}, series = {Astronomische Nachrichten = Astronomical notes}, volume = {337}, journal = {Astronomische Nachrichten = Astronomical notes}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0004-6337}, doi = {10.1002/asna.201612442}, pages = {1105 -- 1113}, year = {2016}, language = {en} } @article{SchreckWernet2016, author = {Schreck, Simon and Wernet, Philippe}, title = {Isotope effects in liquid water probed by transmission mode x-ray absorption spectroscopy at the oxygen K-edge}, series = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, volume = {145}, journal = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-9606}, doi = {10.1063/1.4962237}, pages = {24 -- 32}, year = {2016}, abstract = {The effects of isotope substitution in liquid water are probed by x-ray absorption spectroscopy at the O K-edge as measured in transmission mode. Confirming earlier x-ray Raman scattering experiments, the D2O spectrum is found to be blue shifted with respect to H2O, and the D2O spectrum to be less broadened. Following the earlier interpretations of UV and x-ray Raman spectra, the shift is related to the difference in ground-state zero-point energies between D2O and H2O, while the difference in broadening is related to the difference in ground-state vibrational zero-point distributions. We demonstrate that the transmission-mode measurements allow for determining the spectral shapes with unprecedented accuracy. Owing in addition to the increased spectral resolution and signal to noise ratio compared to the earlier measurements, the new data enable the stringent determination of blue shift and broadening in the O K-edge x-ray absorption spectrum of liquid water upon isotope substitution. The results are compared to UV absorption data, and it is discussed to which extent they reflect the differences in zero-point energies and vibrational zero-point distributions in the ground-states of the liquids. The influence of the shape of the final-state potential, inclusion of the Franck-Condon structure, and differences between liquid H2O and D2O resulting from different hydrogen-bond environments in the liquids are addressed. The differences between the O K-edge absorption spectra of water from our transmission-mode measurements and from the state-of-the-art x-ray Raman scattering experiments are discussed in addition. The experimentally extracted values of blue shift and broadening are proposed to serve as a test for calculations of ground-state zero-point energies and vibrational zero-point distributions in liquid H2O and D2O. This clearly motivates the need for new calculations of the O K-edge x-ray absorption spectrum of liquid water. Published by AIP Publishing.}, language = {en} } @article{CherstvyMetzler2016, author = {Cherstvy, Andrey G. and Metzler, Ralf}, title = {Anomalous diffusion in time-fluctuating non-stationary diffusivity landscapes}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {18}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c6cp03101c}, pages = {23840 -- 23852}, year = {2016}, abstract = {We investigate the ensemble and time averaged mean squared displacements for particle diffusion in a simple model for disordered media by assuming that the local diffusivity is both fluctuating in time and has a deterministic average growth or decay in time. In this study we compare computer simulations of the stochastic Langevin equation for this random diffusion process with analytical results. We explore the regimes of normal Brownian motion as well as anomalous diffusion in the sub- and superdiffusive regimes. We also consider effects of the inertial term on the particle motion. The investigation of the resulting diffusion is performed for unconfined and confined motion.}, language = {en} } @article{GodecMetzler2016, author = {Godec, Aljaz and Metzler, Ralf}, title = {Active transport improves the precision of linear long distance molecular signalling}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {49}, journal = {Journal of physics : A, Mathematical and theoretical}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8113/49/36/364001}, pages = {11}, year = {2016}, abstract = {Molecular signalling in living cells occurs at low copy numbers and is thereby inherently limited by the noise imposed by thermal diffusion. The precision at which biochemical receptors can count signalling molecules is intimately related to the noise correlation time. In addition to passive thermal diffusion, messenger RNA and vesicle-engulfed signalling molecules can transiently bind to molecular motors and are actively transported across biological cells. Active transport is most beneficial when trafficking occurs over large distances, for instance up to the order of 1 metre in neurons. Here we explain how intermittent active transport allows for faster equilibration upon a change in concentration triggered by biochemical stimuli. Moreover, we show how intermittent active excursions induce qualitative changes in the noise in effectively one-dimensional systems such as dendrites. Thereby they allow for significantly improved signalling precision in the sense of a smaller relative deviation in the concentration read-out by the receptor. On the basis of linear response theory we derive the exact mean field precision limit for counting actively transported molecules. We explain how intermittent active excursions disrupt the recurrence in the molecular motion, thereby facilitating improved signalling accuracy. Our results provide a deeper understanding of how recurrence affects molecular signalling precision in biological cells and novel medical-diagnostic devices.}, language = {en} } @article{KunnusJosefssonRajkovicetal.2016, author = {Kunnus, Kristjan and Josefsson, Ida and Rajkovic, Ivan and Schreck, Simon and Quevedo, Wilson and Beye, Martin and Gr{\"u}bel, Sebastian and Scholz, Mirko and Nordlund, Dennis and Zhang, Wenkai and Hartsock, Robert W. and Gaffney, Kelly J. and Schlotter, William F. and Turner, Joshua J. and Kennedy, Brian and Hennies, Franz and Techert, Simone and Wernet, Philippe and Odelius, Michael and F{\"o}hlisch, Alexander}, title = {Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/10/103011}, pages = {9}, year = {2016}, abstract = {Ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbital and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)(5) in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given-which will be covered experimentally by upcoming transform-limited x-ray sources.}, language = {en} } @misc{MetzlerJeonCherstvy2016, author = {Metzler, Ralf and Jeon, J. -H. and Cherstvy, Andrey G.}, title = {Non-Brownian diffusion in lipid membranes: Experiments and simulations}, series = {Biochimica et biophysica acta : Biomembranes}, volume = {1858}, journal = {Biochimica et biophysica acta : Biomembranes}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0005-2736}, doi = {10.1016/j.bbamem.2016.01.022}, pages = {2451 -- 2467}, year = {2016}, abstract = {The dynamics of constituents and the surface response of cellular membranes also in connection to the binding of various particles and macromolecules to the membrane are still a matter of controversy in the membrane biophysics community, particularly with respect to crowded membranes of living biological cells. We here put into perspective recent single particle tracking experiments in the plasma membranes of living cells and supercomputing studies of lipid bilayer model membranes with and without protein crowding. Special emphasis is put on the observation of anomalous, non-Brownian diffusion of both lipid molecules and proteins embedded in the lipid bilayer. While single component, pure lipid bilayers in simulations exhibit only transient anomalous diffusion of lipid molecules on nanosecond time scales, the persistence of anomalous diffusion becomes significantly longer ranged on the addition of disorder through the addition of cholesterol or proteins and on passing of the membrane lipids to the gel phase. Concurrently, experiments demonstrate the anomalous diffusion of membrane embedded proteins up to macroscopic time scales in the minute time range. Particular emphasis will be put on the physical character of the anomalous diffusion, in particular, the occurrence of ageing observed in the experiments the effective diffusivity of the measured particles is a decreasing function of time. Moreover, we present results for the time dependent local scaling exponent of the mean squared displacement of the monitored particles. Recent results finding deviations from the commonly assumed Gaussian diffusion patterns in protein crowded membranes are reported. The properties of the displacement autocorrelation function of the lipid molecules are discussed in the light of their appropriate physical anomalous diffusion models, both for non-crowded and crowded membranes. In the last part of this review we address the upcoming field of membrane distortion by elongated membrane-binding particles. We discuss how membrane compartmentalisation and the particle-membrane binding energy may impact the dynamics and response of lipid membranes. This article is part of a Special Issue entitled: Biosimulations edited by Ilpo Vattulainen and Tomasz Rog. (C) 2016 The Authors. Published by Elsevier B.V.}, language = {en} } @article{ZehbeZehbe2016, author = {Zehbe, Rolf and Zehbe, Kerstin}, title = {Strontium doped poly-epsilon-caprolactone composite scaffolds made by reactive foaming}, series = {The European journal of the history of economic thought}, volume = {67}, journal = {The European journal of the history of economic thought}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0928-4931}, doi = {10.1016/j.msec.2016.05.045}, pages = {259 -- 266}, year = {2016}, abstract = {In the reconstruction and regeneration of bone tissue, a primary goal is to initiate bone growth and to stabilize the surrounding bone. In this regard, a potentially useful component in biomaterials for bone tissue engineering is strontium, which acts as cationic active agent, triggering certain intracellular pathways and acting as so called dual action bone agent which inhibits bone resorption while stimulating bone regeneration. In this study we established a novel processing for the foaming of a polymer (poly-epsilon-caprolactone) and simultaneous chemical reaction of a mixture of calcium and strontium hydroxides to the respective carbonates using supercritical carbon dioxide. The resultant porous composite scaffold was optimized in composition and strontium content and was characterized via different spectroscopic (infrared and Raman spectroscopy, energy dispersive X-ray spectroscopy), imaging (SEM, mu CT), mechanical testing and in vitro methods (fluorescence vital staining, MTT-assay). As a result, the composite scaffold showed good in vitro biocompatibility with partly open pore structure and the expected chemistry. First mechanical testing results indicate sufficient mechanical stability to support future in vivo applications. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{PalyulinChechkinKlagesetal.2016, author = {Palyulin, Vladimir V. and Chechkin, Aleksei V. and Klages, Rainer and Metzler, Ralf}, title = {Search reliability and search efficiency of combined Levy-Brownian motion: long relocations mingled with thorough local exploration}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {49}, journal = {Journal of physics : A, Mathematical and theoretical}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8113/49/39/394002}, pages = {2189 -- 2193}, year = {2016}, abstract = {A combined dynamics consisting of Brownian motion and Levy flights is exhibited by a variety of biological systems performing search processes. Assessing the search reliability of ever locating the target and the search efficiency of doing so economically of such dynamics thus poses an important problem. Here we model this dynamics by a one-dimensional fractional Fokker-Planck equation combining unbiased Brownian motion and Levy flights. By solving this equation both analytically and numerically we show that the superposition of recurrent Brownian motion and Levy flights with stable exponent alpha < 1, by itself implying zero probability of hitting a point on a line, leads to transient motion with finite probability of hitting any point on the line. We present results for the exact dependence of the values of both the search reliability and the search efficiency on the distance between the starting and target positions as well as the choice of the scaling exponent a of the Levy flight component.}, language = {en} } @article{VafinSchlickeiserYoon2016, author = {Vafin, Sergei and Schlickeiser, R. and Yoon, P. H.}, title = {AMPLIFICATION OF COLLECTIVE MAGNETIC FLUCTUATIONS IN MAGNETIZED BI-MAXWELLIAN PLASMAS FOR PARALLEL WAVE VECTORS. I. ELECTRON-PROTON PLASMA}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {829}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/829/1/41}, pages = {8}, year = {2016}, abstract = {The general electromagnetic fluctuation theory is a powerful tool to analyze the magnetic fluctuation spectrum of a plasma. Recent works utilizing this theory for a magnetized non-relativistic isotropic Maxwellian electron-proton plasma have demonstrated that the equilibrium ratio of vertical bar delta B vertical bar/B-0 can be as high as 10(-12). This value results from the balance between spontaneous emission of fluctuations and their damping, and it is considerably smaller than the observed value vertical bar delta B vertical bar/B-0 in the solar wind at 1 au, where 10(-3) less than or similar to vertical bar delta B vertical bar/B-0 less than or similar to 10(-1). In the present manuscript, we consider an anisotropic bi-Maxwellian distribution function to investigate the effect of plasma instabilities on the magnetic field fluctuations. We demonstrate that these instabilities strongly amplify the magnetic field fluctuations and provide a sufficient mechanism to explain the observed value of vertical bar delta B vertical bar/B-0 in the solar wind at 1 au.}, language = {en} } @article{ClusellaPolitiRosenblum2016, author = {Clusella, Pau and Politi, Antonio and Rosenblum, Michael}, title = {A minimal model of self-consistent partial synchrony}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/9/093037}, pages = {15}, year = {2016}, abstract = {We show that self-consistent partial synchrony in globally coupled oscillatory ensembles is a general phenomenon. We analyze in detail appearance and stability properties of this state in possibly the simplest setup of a biharmonic Kuramoto-Daido phase model as well as demonstrate the effect in limit-cycle relaxational Rayleigh oscillators. Such a regime extends the notion of splay state from a uniform distribution of phases to an oscillating one. Suitable collective observables such as the Kuramoto order parameter allow detecting the presence of an inhomogeneous distribution. The characteristic and most peculiar property of self-consistent partial synchrony is the difference between the frequency of single units and that of the macroscopic field.}, language = {en} } @misc{BuergerMagdansGies2016, author = {B{\"u}rger, Andreas and Magdans, Uta and Gies, Hermann}, title = {Adsorption of amino acids on the magnetite-(111)-surface: a force field study (vol 19, 851, 2013)}, series = {Journal of molecular modeling}, volume = {22}, journal = {Journal of molecular modeling}, publisher = {Springer}, address = {New York}, issn = {1610-2940}, doi = {10.1007/s00894-016-3124-8}, pages = {3}, year = {2016}, language = {en} } @article{NegretePumirHsuetal.2016, author = {Negrete, Jose and Pumir, Alain and Hsu, Hsin-Fang and Westendorf, Christian and Tarantola, Marco and Beta, Carsten and Bodenschatz, Eberhard}, title = {Noisy Oscillations in the Actin Cytoskeleton of Chemotactic Amoeba}, series = {Physical review letters}, volume = {117}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.117.148102}, pages = {5}, year = {2016}, abstract = {Biological systems with their complex biochemical networks are known to be intrinsically noisy. Here we investigate the dynamics of actin polymerization of amoeboid cells, which are close to the onset of oscillations. We show that the large phenotypic variability in the polymerization dynamics can be accurately captured by a generic nonlinear oscillator model in the presence of noise. We determine the relative role of the noise with a single dimensionless, experimentally accessible parameter, thus providing a quantitative description of the variability in a population of cells. Our approach, which rests on a generic description of a system close to a Hopf bifurcation and includes the effect of noise, can characterize the dynamics of a large class of noisy systems close to an oscillatory instability.}, language = {en} } @article{RichardsonShenarRoyLoubieretal.2016, author = {Richardson, Noel D. and Shenar, Tomer and Roy-Loubier, Olivier and Schaefer, Gail and Moffat, Anthony F. J. and St-Louis, Nicole and Gies, Douglas R. and Farrington, Chris and Hill, Grant M. and Williams, Peredur M. and Gordon, Kathryn and Pablo, Herbert and Ramiaramanantsoa, Tahina}, title = {The CHARA Array resolves the long-period Wolf-Rayet binaries WR 137 and WR 138}, series = {Monthly notices of the Royal Astronomical Society}, volume = {461}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw1585}, pages = {4115 -- 4124}, year = {2016}, abstract = {We report on interferometric observations with the CHARAArray of two classical Wolf-Rayet (WR) stars in suspected binary systems, namely WR 137 and WR 138. In both cases, we resolve the component stars to be separated by a few milliarcseconds. The data were collected in the H band, and provide a measure of the fractional flux for both stars in each system. We find that the WR star is the dominant H-band light source in both systems (fWR, 137 = 0.59 +/- 0.04; fWR, 138 = 0.67 +/- 0.01), which is confirmed through both comparisons with estimated fundamental parameters for WR stars and O dwarfs, as well as through spectral modelling of each system. Our spectral modelling also provides fundamental parameters for the stars and winds in these systems. The results on WR 138 provide evidence that it is a binary system which may have gone through a previous mass-transfer episode to create the WR star. The separation and position of the stars in the WR 137 system together with previous results from the IOTA interferometer provides evidence that the binary is seen nearly edgeon. The possible edge-on orbit of WR 137 aligns well with the dust production site imaged by the Hubble Space Telescope during a previous periastron passage, showing that the dust production may be concentrated in the orbital plane.}, language = {en} } @article{PedatellaFangJinetal.2016, author = {Pedatella, Nick M. and Fang, T. -W. and Jin, Hao and Sassi, F. and Schmidt, H. and Chau, Jorge Luis and Siddiqui, Tarique Adnan and Goncharenko, L.}, title = {Multimodel comparison of the ionosphere variability during the 2009 sudden stratosphere warming}, series = {Journal of geophysical research : Space physics}, volume = {121}, journal = {Journal of geophysical research : Space physics}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2016JA022859}, pages = {7204 -- 7225}, year = {2016}, abstract = {A comparison of different model simulations of the ionosphere variability during the 2009 sudden stratosphere warming (SSW) is presented. The focus is on the equatorial and low-latitude ionosphere simulated by the Ground-to-topside model of the Atmosphere and Ionosphere for Aeronomy (GAIA), Whole Atmosphere Model plus Global Ionosphere Plasmasphere (WAM+GIP), and Whole Atmosphere Community Climate Model eXtended version plus Thermosphere-Ionosphere-Mesosphere-Electrodynamics General Circulation Model (WACCMX+TIMEGCM). The simulations are compared with observations of the equatorial vertical plasma drift in the American and Indian longitude sectors, zonal mean Fregion peak density (NmF2) from the Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) satellites, and ground-based Global Positioning System (GPS) total electron content (TEC) at 75 degrees W. The model simulations all reproduce the observed morning enhancement and afternoon decrease in the vertical plasma drift, as well as the progression of the anomalies toward later local times over the course of several days. However, notable discrepancies among the simulations are seen in terms of the magnitude of the drift perturbations, and rate of the local time shift. Comparison of the electron densities further reveals that although many of the broad features of the ionosphere variability are captured by the simulations, there are significant differences among the different model simulations, as well as between the simulations and observations. Additional simulations are performed where the neutral atmospheres from four different whole atmosphere models (GAIA, HAMMONIA (Hamburg Model of the Neutral and Ionized Atmosphere), WAM, and WACCMX) provide the lower atmospheric forcing in the TIME-GCM. These simulations demonstrate that different neutral atmospheres, in particular, differences in the solar migrating semidiurnal tide, are partly responsible for the differences in the simulated ionosphere variability in GAIA, WAM+GIP, and WACCMX+TIMEGCM.}, language = {en} } @article{KunnusZhangDelceyetal.2016, author = {Kunnus, Kristjan and Zhang, Wenkai and Delcey, Mickael G. and Pinjari, Rahul V. and Miedema, Piter S. and Schreck, Simon and Quevedo, Wilson and Schr{\"o}der, Henning and F{\"o}hlisch, Alexander and Gaffney, Kelly J. and Lundberg, Marcus and Odelius, Michael and Wernet, Philippe}, title = {Viewing the Valence Electronic Structure of Ferric and Ferrous Hexacyanide in Solution from the Fe and Cyanide Perspectives}, series = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, volume = {120}, journal = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, publisher = {American Chemical Society}, address = {Washington}, issn = {1520-6106}, doi = {10.1021/acs.jpcb.6b04751}, pages = {7182 -- 7194}, year = {2016}, abstract = {The valence-excited states of ferric and ferrous hexacyanide ions in aqueous solution were mapped by resonant inelastic X-ray scattering (RIXS) at the Fe L-2,L-3 and N K edges. Probing of both the central Fe and the ligand N atoms enabled identification of the metal-and ligand-centered excited states, as well as ligand-to-metal and metal-to-ligand charge-transfer excited states. Ab initio calculations utilizing the RASPT2 method were used to simulate the Fe L-2,L-3-edge RIXS spectra and enabled quantification of the covalencies of both occupied and empty orbitals of pi and sigma symmetry. We found that pi back-donation in the ferric complex is smaller than that in the ferrous complex. This is evidenced by the relative amounts of Fe 3d character in the nominally 2 pi CN- molecular orbital of 7\% and 9\% in ferric and ferrous hexacyanide, respectively. Utilizing the direct sensitivity of Fe L-3-edge RIXS to the Fe 3d character in the occupied molecular orbitals, we also found that the donation interactions are dominated by sigma bonding. The latter was found to be stronger in the ferric complex, with an Fe 3d contribution to the nominally 5 sigma CN- molecular orbitals of 29\% compared to 20\% in the ferrous complex. These results are consistent with the notion that a higher charge at the central metal atom increases donation and decreases back-donation.}, language = {en} } @misc{WuesthoffSohl2016, author = {Wuesthoff, Martin and Sohl, F.}, title = {Obliquity tides have an impact in diurnal tidal stresses on the Moon.}, series = {Macromolecules : a publication of the American Chemical Society}, volume = {51}, journal = {Macromolecules : a publication of the American Chemical Society}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {1086-9379}, pages = {A672 -- A672}, year = {2016}, language = {en} } @article{XiongStolleLuehr2016, author = {Xiong, Chao and Stolle, Claudia and L{\"u}hr, Hermann}, title = {The Swarm satellite loss of GPS signal and its relation to ionospheric plasma irregularities}, series = {Space Weather: The International Journal of Research and Applications}, volume = {14}, journal = {Space Weather: The International Journal of Research and Applications}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1542-7390}, doi = {10.1002/2016SW001439}, pages = {563 -- 577}, year = {2016}, abstract = {In this study we investigated conditions for loss of GPS signals observed by the Swarm satellites during a 2 year period, from December 2013 to November 2015. Our result shows that the Swarm satellites encountered most of the total loss of GPS signal at the ionization anomaly crests, between +/- 5 degrees and +/- 20 degrees magnetic latitude, forming two bands along the magnetic equator, and these low-latitude events mainly appear around postsunset hours from 19: 00 to 22: 00 local time. By further checking the in situ electron density measurements of Swarm, we found that practically, all the total loss of GPS signal events at low latitudes are related to equatorial plasma irregularities (EPIs) that show absolute density depletions larger than 10 x 10(11) m(-3); then, the Swarm satellites encountered for up to 95\% loss of GPS signal for at least one channel and up to 45\% tracked less than four GPS satellites (making precise orbit determination impossible). For those EPIs with density depletions less than 10 x 10(11) m(-3), the chance of tracked GPS signals less than four reduces to only 1.0\%. Swarm also observed total loss of all GPS signal at high latitudes, mainly around local noon, and these events are related to large spatial density gradients due to polar patches or increased geomagnetic/auroral activities. We further found that the loss of GPS signals were less frequent after appropriate settings of the Swarm GPS receivers had been updated. However, the more recent period of the mission, e.g., after the GPS receiver settings have been updated, also coincides with less severe electron density depletions due to the declining solar cycle, making GPS loss events less likely. We conclude that both lower electron density gradients and appropriate GPS receiver settings reduce the probability for Swarm satellites loss of GPS signals.}, language = {en} }