@phdthesis{Fechler2012, author = {Fechler, Nina}, title = {Salts as highly diverse porogens : functional ionic liquid-derived carbons and carbon-based composites for energy-related applications}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-64775}, school = {Universit{\"a}t Potsdam}, year = {2012}, abstract = {The present thesis is to be brought into line with the current need for alternative and sustainable approaches toward energy management and materials design. In this context, carbon in particular has become the material of choice in many fields such as energy conversion and storage. Herein, three main topics are covered: 1)An alternative synthesis strategy toward highly porous functional carbons with tunable porosity using ordinary salts as porogen (denoted as "salt templating") 2)The one-pot synthesis of porous metal nitride containing functional carbon composites 3)The combination of both approaches, enabling the generation of highly porous composites with finely tunable properties All approaches have in common that they are based on the utilization of ionic liquids, salts which are liquid below 100 °C, as precursors. Just recently, ionic liquids were shown to be versatile precursors for the generation of heteroatom-doped carbons since the liquid state and a negligible vapor pressure are highly advantageous properties. However, in most cases the products do not possess any porosity which is essential for many applications. In the first part, "salt templating", the utilization of salts as diverse and sustainable porogens, is introduced. Exemplarily shown for ionic liquid derived nitrogen- and nitrogen-boron-co-doped carbons, the control of the porosity and morphology on the nanometer scale by salt templating is presented. The studies within this thesis were conducted with the ionic liquids 1-Butyl-3-methyl-pyridinium dicyanamide (Bmp-dca), 1-Ethyl-3-methyl-imidazolium dicyanamide (Emim-dca) and 1 Ethyl 3-methyl-imidazolium tetracyanoborate (Emim-tcb). The materials are generated through thermal treatment of precursor mixtures containing one of the ionic liquids and a porogen salt. By simple removal of the non-carbonizable template salt with water, functional graphitic carbons with pore sizes ranging from micro- to mesoporous and surface areas up to 2000 m2g-1 are obtained. The carbon morphologies, which presumably originate from different onsets of demixing, mainly depend on the nature of the porogen salt whereas the nature of the ionic liquid plays a minor role. Thus, a structural effect of the porogen salt rather than activation can be assumed. This offers an alternative to conventional activation and templating methods, enabling to avoid multiple-step and energy-consuming synthesis pathways as well as employment of hazardous chemicals for the template removal. The composition of the carbons can be altered via the heat-treatment procedure, thus at lower synthesis temperatures rather polymeric carbonaceous materials with a high degree of functional groups and high surface areas are accessible. First results suggest the suitability of the materials for CO2 utilization. In order to further illustrate the potential of ionic liquids as carbon precursors and to expand the class of carbons which can be obtained, the ionic liquid 1-Ethyl-3-methyl-imidazolium thiocyanate (Emim-scn) is introduced for the generation of nitrogen-sulfur-co-doped carbons in combination with the already studied ionic liquids Bmp-dca and Emim-dca. Here, the salt templating approach should also be applicable eventually further illustrating the potential of salt templating, too. In the second part, a one-pot and template-free synthesis approach toward inherently porous metal nitride nanoparticle containing nitrogen-doped carbon composites is presented. Since ionic liquids also offer outstanding solubility properties, the materials can be generated through the carbonization of homogeneous solutions of an ionic liquid acting as nitrogen as well as carbon source and the respective metal precursor. The metal content and surface area are easily tunable via the initial metal precursor amount. Furthermore, it is also possible to synthesize composites with ternary nitride nanoparticles whose composition is adjustable by the metal ratio in the precursor solution. Finally, both approaches are combined into salt templating of the one-pot composites. This opens the way to the one-step synthesis of composites with tunable composition, particle size as well as precisely controllable porosity and morphology. Thereby, common synthesis strategies where the product composition is often negatively affected by the template removal procedure can be avoided. The composites are further shown to be suitable as electrodes for supercapacitors. Here, different properties such as porosity, metal content and particle size are investigated and discussed with respect to their influence on the energy storage performance. Because a variety of ionic liquids, metal precursors and salts can be combined and a simple closed-loop process including salt recycling is imaginable, the approaches present a promising platform toward sustainable materials design.}, language = {en} } @phdthesis{Fassbender2003, author = {Faßbender, Marcel}, title = {Angriffe auf Datenangebote im Internet und deren strafrechtliche Relevanz : Distributed denial of service angriffe}, series = {Recht der Neuen Medien}, volume = {6}, journal = {Recht der Neuen Medien}, publisher = {Kova?}, address = {Hamburg}, isbn = {3-8300-0870-8}, issn = {1616-9603}, pages = {151 S.}, year = {2003}, language = {de} } @phdthesis{Fayyaz2015, author = {Fayyaz, Susann}, title = {Bedeutung bioaktiver Lipidderivate bei der Entstehung hepatischer Insulinresistenz}, pages = {173}, year = {2015}, language = {de} } @phdthesis{Fawaz2019, author = {Fawaz, Emadeldin}, title = {The interactive effect of visionary leadership and leader prototypicality on team outcomes}, school = {Universit{\"a}t Potsdam}, pages = {134}, year = {2019}, abstract = {A new model that links visionary leadership with team performance is postulated. It is proposed that leader prototypicality will negatively moderate the effect of visionary leadership on team goal monitoring and performance. This model underlines that teams will compensate for the less prototypicality of a visionary leader by engaging in more goal monitoring, which is a process that is conducive to team performance. A field study included 60 teams, 180 individuals, and 60 team leaders was conducted in Egypt. Parameters were collected on the individual level. Aggregation measures (rwg, ICC1 \& ICC2) were acceptable and the averages were calculated for each team. The proposed three-factor model exhibited a reasonable fit to the data, χ2(130) = 259.93, p-value0.01; CFI = 0.90; and RMSEA = 0.13). The hypothesized negative moderation effect of leader prototypicality on the relationship between visionary leadership and team goal monitoring was statistically significant (-0.16; s.e.= 0.06; t = -3.13; p <0.01; 95\% CI: -0.31, -0.07). Results showed a significant index of moderated mediation (-0.07; s.e.= 0.05; 95\% CI: -0.20, -0.01). As predicted, the indirect effect of visionary leadership on team performance mediated by team goal monitoring was more strongly positive when leader prototypicality was low (b = 0.27; s.e.= 0.16; 95\% CI: 0.04, 0.68), rather than high (b = 0.13; s.e.= 0.10; 95\% CI: 0.01, 0.45). A proposal for extending the dimensions of identity-based leadership is discussed. This dissertation makes four significant contributions to theory and research on leadership. First, the main contribution of this research lies in showing that visionary leadership is more strongly positively related to team performance when leader prototypicality is low, rather than high. Second, this dissertation provides a contribution toward overcoming the fragmentation in the leadership literature by desegregating the literature on visionary leadership and leader-team prototypicality. Third, team goal monitoring as a mechanism that explains the interactive effects of visionary leadership and leader prototypicality on team performance was identified. Fourth, this study tests the postulated research model in Egypt, a culture that has in the past received scant attention.}, language = {en} } @phdthesis{Faust1993, author = {Faust, Heike}, title = {Untersuchungen zum Entwicklungsstand und den Perspektiven didaktischer und institutioneller Differenzierung im Hochschulsport}, pages = {164, 72 Bl. : graph. Darst.}, year = {1993}, language = {de} } @phdthesis{Faulstich2002, author = {Faulstich, Andrea}, title = {Konzeptualisierungen in wirtschaftsbezogenen Pressetexten : eine Untersuchung anhand von Texten der italienischen, portugiesischen und brasilianischen Tagespresse zur europ{\"a}ischen W{\"a}hrungsunion 1992 - 1998}, series = {Studium Sprachwissenschaft}, volume = {36}, journal = {Studium Sprachwissenschaft}, publisher = {Nodus-Publ}, address = {M{\"u}nster}, isbn = {3-89323-136-6}, issn = {0721-7129}, pages = {438 S.}, year = {2002}, language = {de} } @phdthesis{Fasten2011, author = {Fasten, Ines}, title = {Die grenzen der Notwehr im Wandel der Zeit}, series = {Strafrecht in Forschung und Praxis}, volume = {205}, journal = {Strafrecht in Forschung und Praxis}, publisher = {Kovac}, address = {Hamburg}, isbn = {978-3-3-8300-5812-0}, issn = {1615-8148}, pages = {287 S.}, year = {2011}, language = {de} } @phdthesis{Farre2001, author = {Farre, Eva M.}, title = {Compartementation in potato tubers}, pages = {147 S.}, year = {2001}, language = {en} } @phdthesis{Farkas2022, author = {Farkas, Marton Pal}, title = {Hydraulic fracturing in hard rock - numerical studies from laboratory to reservoir scale}, doi = {10.25932/publishup-54934}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-549343}, school = {Universit{\"a}t Potsdam}, pages = {155}, year = {2022}, abstract = {Hydraulic-driven fractures play a key role in subsurface energy technologies across several scales. By injecting fluid at high hydraulic pressure into rock with intrinsic low permeability, in-situ stress field and fracture development pattern can be characterised as well as rock permeability can be enhanced. Hydraulic fracturing is a commercial standard procedure for enhanced oil and gas production of rock reservoirs with low permeability in petroleum industry. However, in EGS utilization, a major geological concern is the unsolicited generation of earthquakes due to fault reactivation, referred to as induced seismicity, with a magnitude large enough to be felt on the surface or to damage facilities and buildings. Furthermore, reliable interpretation of hydraulic fracturing tests for stress measurement is a great challenge for the energy technologies. Therefore, in this cumulative doctoral thesis the following research questions are investigated. (1): How do hydraulic fractures grow in hard rock at various scales?; (2): Which parameters control hydraulic fracturing and hydro-mechanical coupling?; and (3): How can hydraulic fracturing in hard rock be modelled? In the laboratory scale study, several laboratory hydraulic fracturing experiments are investigated numerically using Irazu2D that were performed on intact cubic Pocheon granite samples from South Korea applying different injection protocols. The goal of the laboratory experiments is to test the concept of cyclic soft stimulation which may enable sustainable permeability enhancement (Publication 1). In the borehole scale study, hydraulic fracturing tests are reported that were performed in boreholes located in central Hungary to determine the in-situ stress for a geological site investigation. At depth of about 540 m, the recorded pressure versus time curves in mica schist with low dip angle foliation show atypical evolution. In order to provide explanation for this observation, a series of discrete element computations using Particle Flow Code 2D are performed (Publication 2). In the reservoir scale study, the hydro-mechanical behaviour of fractured crystalline rock due to one of the five hydraulic stimulations at the Pohang Enhanced Geothermal site in South Korea is studied. Fluid pressure perturbation at faults of several hundred-meter lengths during hydraulic stimulation is simulated using FracMan (Publication 3). The doctoral research shows that the resulting hydraulic fracturing geometry will depend "locally", i.e. at the length scale of representative elementary volume (REV) and below that (sub-REV), on the geometry and strength of natural fractures, and "globally", i.e. at super-REV domain volume, on far-field stresses. Regarding hydro-mechanical coupling, it is suggested to define separate coupling relationship for intact rock mass and natural fractures. Furthermore, the relative importance of parameters affecting the magnitude of formation breakdown pressure, a parameter characterising hydro-mechanical coupling, is defined. It can be also concluded that there is a clear gap between the capacity of the simulation software and the complexity of the studied problems. Therefore, the computational time of the simulation of complex hydraulic fracture geometries must be reduced while maintaining high fidelity simulation results. This can be achieved either by extending the computational resources via parallelization techniques or using time scaling techniques. The ongoing development of used numerical models focuses on tackling these methodological challenges.}, language = {en} } @phdthesis{Farhy2019, author = {Farhy, Yael}, title = {Universals and particulars in morphology}, doi = {10.25932/publishup-47003}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-470033}, school = {Universit{\"a}t Potsdam}, pages = {VI, 167}, year = {2019}, abstract = {For many years, psycholinguistic evidence has been predominantly based on findings from native speakers of Indo-European languages, primarily English, thus providing a rather limited perspective into the human language system. In recent years a growing body of experimental research has been devoted to broadening this picture, testing a wide range of speakers and languages, aiming to understanding the factors that lead to variability in linguistic performance. The present dissertation investigates sources of variability within the morphological domain, examining how and to what extent morphological processes and representations are shaped by specific properties of languages and speakers. Firstly, the present work focuses on a less explored language, Hebrew, to investigate how the unique non-concatenative morphological structure of Hebrew, namely a non-linear combination of consonantal roots and vowel patterns to form lexical entries (L-M-D + CiCeC = limed 'teach'), affects morphological processes and representations in the Hebrew lexicon. Secondly, a less investigated population was tested: late learners of a second language. We directly compare native (L1) and non-native (L2) speakers, specifically highly proficient and immersed late learners of Hebrew. Throughout all publications, we have focused on a morphological phenomenon of inflectional classes (called binyanim; singular: binyan), comparing productive (class Piel, e.g., limed 'teach') and unproductive (class Paal, e.g., lamad 'learn') verbal inflectional classes. By using this test case, two psycholinguistic aspects of morphology were examined: (i) how morphological structure affects online recognition of complex words, using masked priming (Publications I and II) and cross-modal priming (Publication III) techniques, and (ii) what type of cues are used when extending morpho-phonological patterns to novel complex forms, a process referred to as morphological generalization, using an elicited production task (Publication IV). The findings obtained in the four manuscripts, either published or under review, provide significant insights into the role of productivity in Hebrew morphological processing and generalization in L1 and L2 speakers. Firstly, the present L1 data revealed a close relationship between productivity of Hebrew verbal classes and recognition process, as revealed in both priming techniques. The consonantal root was accessed only in the productive class (Piel) but not the unproductive class (Paal). Another dissociation between the two classes was revealed in the cross-modal priming, yielding a semantic relatedness effect only for Paal but not Piel primes. These findings are taken to reflect that the Hebrew mental representations display a balance between stored undecomposable unstructured stems (Paal) and decomposed structured stems (Piel), in a similar manner to a typical dual-route architecture, showing that the Hebrew mental lexicon is less unique than previously claimed in psycholinguistic research. The results of the generalization study, however, indicate that there are still substantial differences between inflectional classes of Hebrew and other Indo-European classes, particularly in the type of information they rely on in generalization to novel forms. Hebrew binyan generalization relies more on cues of argument structure and less on phonological cues. Secondly, clear L1/L2 differences were observed in the sensitivity to abstract morphological and morpho-syntactic information during complex word recognition and generalization. While L1 Hebrew speakers were sensitive to the binyan information during recognition, expressed by the contrast in root priming, L2 speakers showed similar root priming effects for both classes, but only when the primes were presented in an infinitive form. A root priming effect was not obtained for primes in a finite form. These patterns are interpreted as evidence for a reduced sensitivity of L2 speakers to morphological information, such as information about inflectional classes, and evidence for processing costs in recognition of forms carrying complex morpho-syntactic information. Reduced reliance on structural information cues was found in production of novel verbal forms, when the L2 group displayed a weaker effect of argument structure for Piel responses, in comparison to the L1 group. Given the L2 results, we suggest that morphological and morphosyntactic information remains challenging for late bilinguals, even at high proficiency levels.}, language = {en} }