@phdthesis{Buschmann2018,
  author    = {Buschmann, Stefan},
  title     = {A software framework for GPU-based geo-temporal visualization techniques},
  doi       = {10.25932/publishup-44340},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-443406},
  school      = {Universit{\"a}t Potsdam},
  pages     = {viii, 99},
  year      = {2018},
  abstract  = {R{\"a}umlich-zeitliche Daten sind Daten, welche sowohl einen Raum- als auch einen Zeitbezug aufweisen. So k{\"o}nnen beispielsweise Zeitreihen von Geodaten, thematische Karten die sich {\"u}ber die Zeit ver{\"a}ndern, oder Bewegungsaufzeichnungen von sich bewegenden Objekten als r{\"a}umlich-zeitliche Daten aufgefasst werden. In der heutigen automatisierten Welt gibt es eine wachsende Anzahl von Datenquellen, die best{\"a}ndig r{\"a}umlich-zeitliche Daten generieren. Hierzu geh{\"o}ren beispielsweise Verkehrs{\"u}berwachungssysteme, die Bewegungsdaten von Menschen oder Fahrzeugen aufzeichnen, Fernerkundungssysteme, welche regelm{\"a}ßig unsere Umgebung scannen und digitale Abbilder wie z.B. Stadt- und Landschaftsmodelle erzeugen, sowie Sensornetzwerke in unterschiedlichsten Anwendungsgebieten, wie z.B. der Logistik, der Verhaltensforschung von Tieren, oder der Klimaforschung. Zur Analyse r{\"a}umlich-zeitlicher Daten werden neben der automatischen Analyse mittels statistischer Methoden und Data-Mining auch explorative Methoden angewendet, welche auf der interaktiven Visualisierung der Daten beruhen. Diese Methode der Analyse basiert darauf, dass Anwender in Form interaktiver Visualisierung die Daten explorieren k{\"o}nnen, wodurch die menschliche Wahrnehmung sowie das Wissen der User genutzt werden, um Muster zu erkennen und dadurch einen Einblick in die Daten zu erlangen. Diese Arbeit beschreibt ein Software-Framework f{\"u}r die Visualisierung r{\"a}umlich-zeitlicher Daten, welches GPU-basierte Techniken beinhaltet, um eine interaktive Visualisierung und Exploration großer r{\"a}umlich-zeitlicher Datens{\"a}tze zu erm{\"o}glichen. Die entwickelten Techniken umfassen Datenhaltung, Prozessierung und Rendering und erm{\"o}glichen es, große Datenmengen in Echtzeit zu prozessieren und zu visualisieren. Die Hauptbeitr{\"a}ge der Arbeit umfassen: - Konzept und Implementierung einer GPU-zentrierten Visualisierungspipeline. Die beschriebenen Techniken basieren auf dem Konzept einer GPU-zentrierten Visualisierungspipeline, in welcher alle Stufen -- Prozessierung,Mapping, Rendering -- auf der GPU ausgef{\"u}hrt werden. Bei diesem Konzept werden die r{\"a}umlich-zeitlichen Daten direkt im GPU-Speicher abgelegt. W{\"a}hrend des Rendering-Prozesses werden dann mittels Shader-Programmen die Daten prozessiert, gefiltert, ein Mapping auf visuelle Attribute vorgenommen, und schließlich die Geometrien f{\"u}r die Visualisierung erzeugt. Datenprozessierung, Filtering und Mapping k{\"o}nnen daher in Echtzeit ausgef{\"u}hrt werden. Dies erm{\"o}glicht es Usern, die Mapping-Parameter sowie den gesamten Visualisierungsprozess interaktiv zu steuern und zu kontrollieren. - Interaktive Visualisierung attributierter 3D-Trajektorien. Es wurde eine Visualisierungsmethode f{\"u}r die interaktive Exploration einer großen Anzahl von 3D Bewegungstrajektorien entwickelt. Die Trajektorien werden dabei innerhalb einer virtuellen geographischen Umgebung in Form von einfachen Geometrien, wie Linien, B{\"a}ndern, Kugeln oder R{\"o}hren dargestellt. Durch interaktives Mapping k{\"o}nnen Attributwerte der Trajektorien oder einzelner Messpunkte auf visuelle Eigenschaften abgebildet werden. Hierzu stehen Form, H{\"o}he, Gr{\"o}ße, Farbe, Textur, sowie Animation zur Verf{\"u}gung. Mithilfe dieses dynamischen Mappings wurden außerdem verschiedene Visualisierungsmethoden implementiert, wie z.B. eine Focus+Context-Visualisierung von Trajektorien mithilfe von interaktiven Dichtekarten, sowie einer Space-Time-Cube-Visualisierung zur Darstellung des zeitlichen Ablaufs einzelner Bewegungen. - Interaktive Visualisierung geographischer Netzwerke. Es wurde eine Visualisierungsmethode zur interaktiven Exploration geo-referenzierter Netzwerke entwickelt, welche die Visualisierung von Netzwerken mit einer großen Anzahl von Knoten und Kanten erm{\"o}glicht. Um die Analyse von Netzwerken verschiedener Gr{\"o}ßen und in unterschiedlichen Kontexten zu erm{\"o}glichen, stehen mehrere virtuelle geographische Umgebungen zur Verf{\"u}gung, wie bspw. ein virtueller 3D-Globus, als auch 2D-Karten mit unterschiedlichen geographischen Projektionen. Zur interaktiven Analyse dieser Netzwerke stehen interaktive Tools wie Filterung, Mapping und Selektion zur Verf{\"u}gung. Des weiteren wurden Visualisierungsmethoden f{\"u}r verschiedene Arten von Netzwerken, wie z.B. 3D-Netzwerke und zeitlich ver{\"a}nderliche Netzwerke, implementiert. Zur Demonstration des Konzeptes wurden interaktive Tools f{\"u}r zwei unterschiedliche Anwendungsf{\"a}lle entwickelt. Das erste beinhaltet die Visualisierung attributierter 3D-Trajektorien, welche die Bewegungen von Flugzeugen um einen Flughafen beschreiben. Es erm{\"o}glicht Nutzern, die Trajektorien von ankommenden und startenden Flugzeugen {\"u}ber den Zeitraum eines Monats interaktiv zu explorieren und zu analysieren. Durch Verwendung der interaktiven Visualisierungsmethoden f{\"u}r 3D-Trajektorien und interaktiven Dichtekarten k{\"o}nnen Einblicke in die Daten gewonnen werden, wie beispielsweise h{\"a}ufig genutzte Flugkorridore, typische sowie untypische Bewegungsmuster, oder ungew{\"o}hnliche Vorkommnisse wie Fehlanfl{\"u}ge. Der zweite Anwendungsfall beinhaltet die Visualisierung von Klimanetzwerken, welche geographischen Netzwerken in der Klimaforschung darstellen. Klimanetzwerke repr{\"a}sentieren die Dynamiken im Klimasystem durch eine Netzwerkstruktur, die die statistische Beziehungen zwischen Orten beschreiben. Das entwickelte Tool erm{\"o}glicht es Analysten, diese großen Netzwerke interaktiv zu explorieren und dadurch die Struktur des Netzwerks zu analysieren und mit den geographischen Daten in Beziehung zu setzen. Interaktive Filterung und Selektion erm{\"o}glichen es, Muster in den Daten zu identifizieren, und so bspw. Cluster in der Netzwerkstruktur oder Str{\"o}mungsmuster zu erkennen.},
  language  = {en}
}
@phdthesis{VillatoroLeal2018,
  author    = {Villatoro Leal, Jos{\´e} Andr{\´e}s},
  title     = {A combined approach for the analysis of biomolecules using IR-MALDI ion mobility spectrometry and molecular dynamics simulations of peptide ions in the gas phase},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-419723},
  school      = {Universit{\"a}t Potsdam},
  pages     = {133},
  year      = {2018},
  abstract  = {The aim of this doctoral thesis was to establish a technique for the analysis of biomolecules with infrared matrix-assisted laser dispersion (IR-MALDI) ion mobility (IM) spectrometry. The main components of the work were the characterization of the IR-MALDI process, the development and characterization of different ion mobility spectrometers, the use of IR-MALDI-IM spectrometry as a robust, standalone spectrometer and the development of a collision cross-section estimation approach for peptides based on molecular dynamics and thermodynamic reweighting. First, the IR-MALDI source was studied with atmospheric pressure ion mobility spectrometry and shadowgraphy. It consisted of a metal capillary, at the tip of which a self-renewing droplet of analyte solution was met by an IR laser beam. A relationship between peak shape, ion desolvation, diffusion and extraction pulse delay time (pulse delay) was established. First order desolvation kinetics were observed and related to peak broadening by diffusion, both influenced by the pulse delay. The transport mechanisms in IR-MALDI were then studied by relating different laser impact positions on the droplet surface to the corresponding ion mobility spectra. Two different transport mechanisms were determined: phase explosion due to the laser pulse and electrical transport due to delayed ion extraction. The velocity of the ions stemming from the phase explosion was then measured by ion mobility and shadowgraphy at different time scales and distances from the source capillary, showing an initially very high but rapidly decaying velocity. Finally, the anatomy of the dispersion plume was observed in detail with shadowgraphy and general conclusions over the process were drawn. Understanding the IR-MALDI process enabled the optimization of the different IM spectrometers at atmospheric and reduced pressure (AP and RP, respectively). At reduced pressure, both an AP and an RP IR-MALDI source were used. The influence of the pulsed ion extraction parameters (pulse delay, width and amplitude) on peak shape, resolution and area was systematically studied in both AP and RP IM spectrometers and discussed in the context of the IR-MALDI process. Under RP conditions, the influence of the closing field and of the pressure was also examined for both AP and RP sources. For the AP ionization RP IM spectrometer, the influence of the inlet field (IF) in the source region was also examined. All of these studies led to the determination of the optimal analytical parameters as well as to a better understanding of the initial ion cloud anatomy. The analytical performance of the spectrometer was then studied. Limits of detection (LOD) and linear ranges were determined under static and pulsed ion injection conditions and interpreted in the context of the IR-MALDI mechanism. Applications in the separation of simple mixtures were also illustrated, demonstrating good isomer separation capabilities and the advantages of singly charged peaks. The possibility to couple high performance liquid chromatography (HPLC) to IR-MALDI-IM spectrometry was also demonstrated. Finally, the reduced pressure spectrometer was used to study the effect of high reduced field strength on the mobility of polyatomic ions in polyatomic gases. The last focus point was on the study of peptide ions. A dataset obtained with electrospray IM spectrometry was characterized and used for the calibration of a collision cross-section (CCS) determination method based on molecular dynamics (MD) simulations at high temperature. Instead of producing candidate structures which are evaluated one by one, this semi-automated method uses the simulation as a whole to determine a single average collision cross-section value by reweighting the CCS of a few representative structures. The method was compared to the intrinsic size parameter (ISP) method and to experimental results. Additional MD data obtained from the simulations was also used to further analyze the peptides and understand the experimental results, an advantage with regard to the ISP method. Finally, the CCS of peptide ions analyzed by IR-MALDI were also evaluated with both ISP and MD methods and the results compared to experiment, resulting in a first validation of the MD method. Thus, this thesis brings together the soft ionization technique that is IR-MALDI, which produces mostly singly charged peaks, with ion mobility spectrometry, which can distinguish between isomers, and a collision cross-section determination method which also provides structural information on the analyte at hand.},
  language  = {en}
}
@phdthesis{Engelhardt2018,
  author    = {Engelhardt, Jonathan},
  title     = {40Ar/39Ar geochronology of ICDP PALEOVAN drilling cores},
  doi       = {10.25932/publishup-42953},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-429539},
  school      = {Universit{\"a}t Potsdam},
  pages     = {xxi, 338},
  year      = {2018},
  abstract  = {The scientific drilling campaign PALEOVAN was conducted in the summer of 2010 and was part of the international continental drilling programme (ICDP). The main goal of the campaign was the recovery of a sensitive climate archive in the East of Anatolia. Lacustrine deposits underneath the lake floor of 'Lake Van' constitute this archive. The drilled core material was recovered from two locations: the Ahlat Ridge and the Northern Basin. A composite core was constructed from cored material of seven parallel boreholes at the Ahlat Ridge and covers an almost complete lacustrine history of Lake Van. The composite record offered sensitive climate proxies such as variations of total organic carbon, K/Ca ratios, or a relative abundance of arboreal pollen. These proxies revealed patterns that are similar to climate proxy variations from Greenland ice cores. Climate variations in Greenland ice cores have been dated by modelling the timing of orbital forces to affect the climate. Volatiles from melted ice aliquots are often taken as high-resolution proxies and provide a base for fitting the according temporal models. The ICDP PALEOVAN scientific team fitted proxy data from the lacustrine drilling record to ice core data and constructed an age model. Embedded volcaniclastic layers had to be dated radiometrically in order to provide independent age constraints to the climate-stratigraphic age model. Solving this task by an application of the 40Ar/39Ar method was the main objective of this thesis. Earlier efforts to apply the 40Ar/39Ar dating resulted in inaccuracies that could not be explained satisfactorily. The absence of K-rich feldspars in suitable tephra layers implied that feldspar crystals needed to be 500 μm in size minimum, in order to apply single-crystal 40Ar/39Ar dating. Some of the samples did not contain any of these grain sizes or only very few crystals of that size. In order to overcome this problem this study applied a combined single-crystal and multi-crystal approach with different crystal fractions from the same sample. The preferred method of a stepwise heating analysis of an aliquot of feldspar crystals has been applied to three samples. The Na-rich crystals and their young geological age required 20 mg of inclusion-free, non-corroded feldspars. Small sample volumes (usually 25 \% aliquots of 5 cm3 of sample material - a spoon full of tephra) and the widespread presence of melt-inclusion led to the application of combined single- and multigrain total fusion analyses. 40Ar/39Ar analyses on single crystals have the advantage of being able to monitor the presence of excess 40Ar and detrital or xenocrystic contamination in the samples. Multigrain analyses may hide the effects from these obstacles. The results from the multigrain analyses are therefore discussed with respect to the findings from the respective cogenetic single crystal ages. Some of the samples in this study were dated by 40Ar/39Ar on feldspars on multigrain separates and (if available) in combination with only a few single crystals. 40Ar/39Ar ages from two of the samples deviated statistically from the age model. All other samples resulted in identical ages. The deviations displayed older ages than those obtained from the age model. t-Tests compared radiometric ages with available age control points from various proxies and from the relative paleointensity of the earth magnetic field within a stratigraphic range of ± 10 m. Concordant age control points from different relative chronometers indicated that deviations are a result of erroneous 40Ar/39Ar ages. The thesis argues two potential reasons for these ages: (1) the irregular appearance of 40Ar from rare melt- and fluid- inclusions and (2) the contamination of the samples with older crystals due to a rapid combination of assimilation and ejection. Another aliquot of feldspar crystals that underwent separation for the application of 40Ar/39Ar dating was investigated for geochemical inhomogeneities. Magmatic zoning is ubiquitous in the volcaniclastic feldspar crystals. Four different types of magmatic zoning were detected. The zoning types are compositional zoning (C-type zoning), pseudo-oscillatory zoning of trace ele- ment concentrations (PO-type zoning), chaotic and patchy zoning of major and trace element concentrations (R-type zoning) and concentric zoning of trace elements (CC-type zoning). Sam- ples that deviated in 40Ar/39Ar ages showed C-type zoning, R-type zoning or a mix of different types of zoning (C-type and PO-type). Feldspars showing PO-type zoning typically represent the smallest grain size fractions in the samples. The constant major element compositions of these crystals are interpreted to represent the latest stages in the compositional evolution of feldspars in a peralkaline melt. PO-type crystals contain less melt- inclusions than other zoning types and are rarely corroded. This thesis concludes that feldspars that show PO-type zoning are most promising chronometers for the 40Ar/39Ar method, if samples provide mixed zoning types of Quaternary anorthoclase feldspars. Five samples were dated by applying the 40Ar/39Ar method to volcanic glass. High fractions of atmospheric Ar (typically > 98\%) significantly hampered the precision of the 40Ar/39Ar ages and resulted in rough age estimates that widely overlap the age model. Ar isotopes indicated that the glasses bore a chorine-rich Ar-end member. The chlorine-derived 38Ar indicated chlorine-rich fluid-inclusions or the hydration of the volcanic glass shards. This indication strengthened the evidence that irregularly distributed melt-inclusions and thus irregular distributed excess 40Ar influenced the problematic feldspar 40Ar/39Ar ages. Whether a connection between a corrected initial 40Ar/36Ar ratio from glasses to the 40Ar/36Ar ratios from pore waters exists remains unclear. This thesis offers another age model, which is similarly based on the interpolation of the temporal tie points from geophysical and climate-stratigraphic data. The model used a PCHIP- interpolation (piecewise cubic hermite interpolating polynomial) whereas the older age model used a spline-interpolation. Samples that match in ages from 40Ar/39Ar dating of feldspars with the earlier published age model were additionally assigned with an age from the PCHIP- interpolation. These modelled ages allowed a recalculation of the Alder Creek sanidine mineral standard. The climate-stratigraphic calibration of an 40Ar/39Ar mineral standard proved that the age versus depth interpolations from PAELOVAN drilling cores were accurate, and that the applied chronometers recorded the temporal evolution of Lake Van synchronously. Petrochemical discrimination of the sampled volcaniclastic material is also given in this thesis. 41 from 57 sampled volcaniclastic layers indicate Nemrut as their provenance. Criteria that served for the provenance assignment are provided and reviewed critically. Detailed correlations of selected PALEOVAN volcaniclastics to onshore samples that were described in detail by earlier studies are also discussed. The sampled volcaniclastics dominantly have a thickness of < 40 cm and have been ejected by small to medium sized eruptions. Onshore deposits from these types of eruptions are potentially eroded due to predominant strong winds on Nemrut and S{\"u}phan slopes. An exact correlation with the data presented here is therefore equivocal or not possible at all. Deviating feldspar 40Ar/39Ar ages can possibly be explained by inherited 40Ar from feldspar xenocrysts contaminating the samples. In order to test this hypothesis diffusion couples of Ba were investigated in compositionally zoned feldspar crystals. The diffusive behaviour of Ba in feldspar is known, and gradients in the changing concentrations allowed for the calculation of the duration of the crystal's magmatic development since the formation of the zoning interface. Durations were compared with degassing scenarios that model the Ar-loss during assimilation and subsequent ejection of the xenocrystals. Diffusive equilibration of the contrasting Ba concentrations is assumed to generate maximum durations as the gradient could have been developed in several growth and heating stages. The modelling does not show any indication of an involvement of inherited 40Ar in any of the deviating samples. However, the analytical set-up represents the lower limit of the required spatial resolution. Therefore, it cannot be excluded that the degassing modelling relies on a significant overestimation of the maximum duration of the magmatic history. Nevertheless, the modelling of xenocrystal degassing evidences that the irregular incorporation of excess 40Ar by melt- and fluid inclusions represents the most critical problem that needs to be overcome in dating volcaniclastic feldspars from the PALEOVAN drill cores. This thesis provides the complete background in generating and presenting 40Ar/39Ar ages that are compared to age data from a climate-stratigraphic model. Deviations are identified statistically and then discussed in order to find explanations from the age model and/or from 40Ar/39Ar geochronology. Most of the PALEOVAN stratigraphy provides several chronometers that have been proven for their synchronicity. Lacustrine deposits from Lake Van represent a key archive for reconstructing climate evolution in the eastern Mediterranean and in the Near East. The PALEOVAN record offers a climate-stratigraphic age model with a remarkable accuracy and resolution.},
  language  = {en}
}
@phdthesis{Belling2018,
  author    = {Belling, Johannes},
  title     = {"Vor{\"u}bergehende" Leiharbeit},
  series = {Schriften zum B{\"u}rgerlichen Recht ; 485},
  journal   = {Schriften zum B{\"u}rgerlichen Recht ; 485},
  publisher = {Duncker \& Humblot},
  address   = {Berlin},
  isbn      = {978-3-428-15451-7},
  school      = {Universit{\"a}t Potsdam},
  pages     = {263},
  year      = {2018},
  abstract  = {Leiharbeit ist aus dem modernen Arbeitsleben nicht mehr wegzudenken. Von besonderer Bedeutung f{\"u}r Entleiher und Leiharbeitnehmer waren und sind seit jeher die zeitliche Limitierung von Leiharbeit. Die Unbestimmtheit des durch die Leiharbeitsrichtlinie eingef{\"u}hrten Merkmals der »vor{\"u}bergehenden« Dauer von Leiharbeit hat in Literatur und Rechtsprechung viele Meinungen hervorgerufen. Rechtssicherheit haben all diese nicht gebracht. Der Autor widmet sich der Herkunft und Bedeutung des Begriffs der vor{\"u}bergehenden Dauer und bietet ein grundrechts- und unionsrechtskonformes L{\"o}sungsmodell zum Verst{\"a}ndnis und Umgang mit diesem Merkmal. Die gefundenen Ergebnisse {\"u}bertr{\"a}gt er auf die A{\"U}G-Novelle von 2017. Anhand des religi{\"o}sen Selbstverst{\"a}ndnisses der Kirchen und des darauf beruhenden Begriffs der »Dienstgemeinschaft« untersucht der Autor Zul{\"a}ssigkeit und Grenzen der Leiharbeit in kirchlichen Einrichtungen. Er empfiehlt die Schaffung von Regelwerken zur Einhaltung kirchlicher Loyalit{\"a}tspflichten.},
  language  = {de}
}