@article{VermaDenkerBalthasaretal.2016,
  author    = {Verma, Meetu and Denker, Carsten and Balthasar, H. and Kuckein, Christoph and Gonz{\´a}lez Manrique, Sergio Javier and Sobotka, M. and Gonzalez, N. Bello and Hoch, S. and Diercke, Andrea and Kummerow, Philipp and Berkefeld, T. and Collados Vera, M. and Feller, A. and Hofmann, A. and Kneer, F. and Lagg, A. and L{\"o}hner-B{\"o}ttcher, J. and Nicklas, H. and Pastor Yabar, A. and Schlichenmaier, R. and Schmidt, D. and Schmidt, W. and Schubert, M. and Sigwarth, M. and Solanki, S. K. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Volkmer, R. and von der L{\"u}he, O. and Waldmann, T.},
  title     = {Horizontal flow fields in and around a small active region The transition period between flux emergence and decay},
  series = {Polymers},
  volume    = {596},
  journal   = {Polymers},
  publisher = {EDP Sciences},
  address   = {Les Ulis},
  issn      = {1432-0746},
  doi       = {10.1051/0004-6361/201628380},
  pages     = {12},
  year      = {2016},
  abstract  = {Context. The solar magnetic field is responsible for all aspects of solar activity. Thus, emergence of magnetic flux at the surface is the first manifestation of the ensuing solar activity. Aims. Combining high-resolution and synoptic observations aims to provide a comprehensive description of flux emergence at photospheric level and of the growth process that eventually leads to a mature active region. Methods. The small active region NOAA 12118 emerged on 2014 July 17 and was observed one day later with the 1.5-m GREGOR solar telescope on 2014 July 18. High-resolution time-series of blue continuum and G-band images acquired in the blue imaging channel (BIC) of the GREGOR Fabry-Perot Interferometer (GFPI) were complemented by synoptic line-of-sight magnetograms and continuum images obtained with the Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamics Observatory (SDO). Horizontal proper motions and horizontal plasma velocities were computed with local correlation tracking (LCT) and the differential affine velocity estimator (DAVE), respectively. Morphological image processing was employed to measure the photometric and magnetic area, magnetic flux, and the separation profile of the emerging flux region during its evolution. Results. The computed growth rates for photometric area, magnetic area, and magnetic flux are about twice as high as the respective decay rates. The space-time diagram using HMI magnetograms of five days provides a comprehensive view of growth and decay. It traces a leaf-like structure, which is determined by the initial separation of the two polarities, a rapid expansion phase, a time when the spread stalls, and a period when the region slowly shrinks again. The separation rate of 0.26 km s(-1) is highest in the initial stage, and it decreases when the separation comes to a halt. Horizontal plasma velocities computed at four evolutionary stages indicate a changing pattern of inflows. In LCT maps we find persistent flow patterns such as outward motions in the outer part of the two major pores, a diverging feature near the trailing pore marking the site of upwelling plasma and flux emergence, and low velocities in the interior of dark pores. We detected many elongated rapidly expanding granules between the two major polarities, with dimensions twice as large as the normal granules.},
  language  = {en}
}
@article{LiuTkachovKomberetal.2014,
  author    = {Liu, W. and Tkachov, R. and Komber, H. and Senkovskyy, V. and Schubert, M. and Wei, Z. and Facchetti, A. and Neher, Dieter and Kiriy, A.},
  title     = {Chain-growth polycondensation of perylene diimide-based copolymers: a new route to regio-regular perylene diimide-based acceptors for all-polymer solar cells and n-type transistors},
  series = {Polymer Chemistry},
  volume    = {5},
  journal   = {Polymer Chemistry},
  number    = {10},
  publisher = {Royal Society of Chemistry},
  address   = {Cambridge},
  issn      = {1759-9954},
  doi       = {10.1039/c3py01707a},
  pages     = {3404 -- 3411},
  year      = {2014},
  abstract  = {Herein, we report the chain-growth tin-free room temperature polymerization method to synthesize n-type perylene diimide-dithiophene-based conjugated polymers (PPDIT2s) suitable for solar cell and transistor applications. The palladium/electron-rich tri-tert-butylphosphine catalyst is effective to enable the chain-growth polymerization of anion-radical monomer Br-TPDIT-Br/Zn to PPDIT2 with a molecular weight up to M-w approximate to 50 kg mol(-1) and moderate polydispersity. This is the second example of the polymerization of unusual anion-radical aromatic complexes formed in a reaction of active Zn and electron-deficient diimide-based aryl halides. As such, the discovered polymerization method is not a specific reactivity feature of the naphthalene-diimide derivatives but is rather a general polymerization tool. This is an important finding, given the significantly higher maximum external quantum efficiency that can be reached with PDI-based copolymers (32-45\%) in all-polymer solar cells compared to NDI-based materials (15-30\%). Our studies revealed that PPDIT2 synthesized by the new method and the previously published polymer prepared by step-growth Stille polycondensation show similar electron mobility and all-polymer solar cell performance. At the same time, the polymerization reported herein has several technological advantages as it proceeds relatively fast at room temperature and does not involve toxic tin-based compounds. Because several chain-growth polymerization reactions are well-suited for the preparation of well-defined multi-functional polymer architectures, the next target is to explore the utility of the discovered polymerization in the synthesis of end-functionalized polymers and block copolymers. Such materials would be helpful to improve the nanoscale morphology of polymer blends in all-polymer solar cells.},
  language  = {en}
}