@article{KossmannSanchezManjavacasBrandtetal.2022, author = {Kossmann, Janina and Sanchez-Manjavacas, Maria Luz Ortiz and Brandt, Jessica and Heil, Tobias and L{\´o}pez-Salas, Nieves and Albero, Josep}, title = {Mn(ii) sub-nanometric site stabilization in noble, N-doped carbonaceous materials for electrochemical CO2 reduction}, series = {Chemical communications : ChemComm / The Royal Society of Chemistry}, volume = {58}, journal = {Chemical communications : ChemComm / The Royal Society of Chemistry}, number = {31}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1359-7345}, doi = {10.1039/d2cc00585a}, pages = {4841 -- 4844}, year = {2022}, abstract = {The preparation of stable and efficient electrocatalysts comprising abundant and non-critical row-materials is of paramount importance for their industrial implementation. Herein, we present a simple synthetic route to prepare Mn(ii) sub-nanometric active sites over a highly N-doped noble carbonaceous support. This support not only promotes a strong stabilization of the Mn(ii) sites, improving its stability against oxidation, but also provides a convenient coordination environment in the Mn(ii) sites able to produce CO, HCOOH and CH3COOH from electrochemical CO2 reduction.}, language = {en} }