@misc{ToepferTremblay2016, author = {T{\"o}pfer, Kai and Tremblay, Jean Christophe}, title = {How surface reparation prevents catalytic oxidation of carbon monoxide on atomic gold at defective magnesium oxide surfaces}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-394978}, pages = {8}, year = {2016}, abstract = {In this contribution, we study using first principles the co-adsorption and catalytic behaviors of CO and O2 on a single gold atom deposited at defective magnesium oxide surfaces. Using cluster models and point charge embedding within a density functional theory framework, we simulate the CO oxidation reaction for Au1 on differently charged oxygen vacancies of MgO(001) to rationalize its experimentally observed lack of catalytic activity. Our results show that: (1) co-adsorption is weakly supported at F0 and F2+ defects but not at F1+ sites, (2) electron redistribution from the F0 vacancy via the Au1 cluster to the adsorbed molecular oxygen weakens the O2 bond, as required for a sustainable catalytic cycle, (3) a metastable carbonate intermediate can form on defects of the F0 type, (4) only a small activation barrier exists for the highly favorable dissociation of CO2 from F0, and (5) the moderate adsorption energy of the gold atom on the F0 defect cannot prevent insertion of molecular oxygen inside the defect. Due to the lack of protection of the color centers, the surface becomes invariably repaired by the surrounding oxygen and the catalytic cycle is irreversibly broken in the first oxidation step.}, language = {en} } @misc{GronostajWernerBochowetal.2016, author = {Gronostaj, Anna and Werner, Elise and Bochow, Eric and Vock, Miriam}, title = {How to learn things at school you don't already know}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, number = {415}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-405211}, pages = {16}, year = {2016}, abstract = {Skipping a grade, one specific form of acceleration, is an intervention used for gifted students. Quantitative research has shown acceleration to be a highly successful intervention regarding academic achievement, but less is known about the social-emotional outcomes of grade-skipping. In the present study, the authors used the grounded theory approach to examine the experiences of seven gifted students aged 8 to 16 years who skipped a grade. The interviewees perceived their feeling of being in the wrong place before the grade-skipping as strongly influenced by their teachers, who generally did not respond adequately to their needs. We observed a close interrelationship between the gifted students' intellectual fit and their social situation in class. Findings showed that the grade-skipping in most of the cases bettered the situation in school intellectually as well as socially, but soon further interventions, for instance, a specialized and demanding class- or subject-specific acceleration were added to provide sufficiently challenging learning opportunities.}, language = {en} } @inproceedings{OPUS4-40678, title = {HPI Future SOC Lab}, editor = {Meinel, Christoph and Polze, Andreas and Oswald, Gerhard and Strotmann, Rolf and Seibold, Ulrich and Schulzki, Bernhard}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-406787}, pages = {iii, 180}, year = {2016}, abstract = {The "HPI Future SOC Lab" is a cooperation of the Hasso Plattner Institute (HPI) and industrial partners. Its mission is to enable and promote exchange and interaction between the research community and the industrial partners. The HPI Future SOC Lab provides researchers with free of charge access to a complete infrastructure of state of the art hard and software. This infrastructure includes components, which might be too expensive for an ordinary research environment, such as servers with up to 64 cores and 2 TB main memory. The offerings address researchers particularly from but not limited to the areas of computer science and business information systems. Main areas of research include cloud computing, parallelization, and In-Memory technologies. This technical report presents results of research projects executed in 2016. Selected projects have presented their results on April 5th and November 3th 2016 at the Future SOC Lab Day events.}, language = {en} } @article{Schmuck2016, author = {Schmuck, Thomas}, title = {Humboldt in Goethes Bibliothek}, series = {HiN : Alexander von Humboldt im Netz ; International Review for Humboldtian Studies}, volume = {XVII}, journal = {HiN : Alexander von Humboldt im Netz ; International Review for Humboldtian Studies}, number = {32}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {1617-5239}, doi = {10.18443/236}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90793}, pages = {65 -- 83}, year = {2016}, abstract = {In Goethes privater Bibliothek im Goethehaus in Weimar ist Alexander von Humboldt mehrfach vertreten: durch pers{\"o}nlich {\"u}bersandte B{\"u}cher, durch Brosch{\"u}ren und Grafiken. Einige dieser Publikationen Humboldts tragen handschriftliche Widmungen. Die Anmerkungen Goethes, seine Bearbeitungsspuren, die Bemerkungen im Tagebuch und nicht zuletzt der Briefwechsel geben Aufschluss {\"u}ber eine komplizierte Beziehung, die von Wohlwollen und von wissenschaftlichem Interesse an der Arbeit des anderen gepr{\"a}gt war, im Alter aber, insbesondere bei Humboldt, sp{\"u}rbar distanzierter wurde. Erstmals werden in diesem Beitrag alle handschriftlichen Widmungen Humboldts an Goethe abgebildet und die Publikationen Humboldts in Goethes Bibliothek in einen wissenschaftshistorischen und lebensgeschichtlichen Kontext gestellt.}, language = {de} } @phdthesis{Pavlenko2016, author = {Pavlenko, Elena}, title = {Hybrid nanolayer architectures for ultrafast acousto-plasmonics in soft matter}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-99544}, school = {Universit{\"a}t Potsdam}, pages = {85}, year = {2016}, abstract = {The goal of the presented work is to explore the interaction between gold nanorods (GNRs) and hyper-sound waves. For the generation of the hyper-sound I have used Azobenzene-containing polymer transducers. Multilayer polymer structures with well-defined thicknesses and smooth interfaces were built via layer-by-layer deposition. Anionic polyelectrolytes with Azobenzene side groups (PAzo) were alternated with cationic polymer PAH, for the creation of transducer films. PSS/PAH multilayer were built for spacer layers, which do not absorb in the visible light range. The properties of the PAzo/PAH film as a transducer are carefully characterized by static and transient optical spectroscopy. The optical and mechanical properties of the transducer are studied on the picosecond time scale. In particular the relative change of the refractive index of the photo-excited and expanded PAH/PAzo is Δn/n = - 2.6*10-4. Calibration of the generated strain is performed by ultrafast X-ray diffraction calibrated the strain in a Mica substrate, into which the hyper-sound is transduced. By simulating the X-ray data with a linear-chain-model the strain in the transducer under the excitation is derived to be Δd/d ~ 5*10-4. Additional to the investigation of the properties of the transducer itself, I have performed a series of experiments to study the penetration of the generated strain into various adjacent materials. By depositing the PAzo/PAH film onto a PAH/PSS structure with gold nanorods incorporated in it, I have shown that nanoscale impurities can be detected via the scattering of hyper-sound. Prior to the investigation of complex structures containing GNRs and the transducer, I have performed several sets of experiments on GNRs deposited on a small buffer of PSS/PAH. The static and transient response of GNRs is investigated for different fluence of the pump beam and for different dielectric environments (GNRs covered by PSS/PAH). A systematic analysis of sample architectures is performed in order to construct a sample with the desired effect of GNRs responding to the hyper-sound strain wave. The observed shift of a feature related to the longitudinal plasmon resonance in the transient reflection spectra is interpreted as the event of GNRs sensing the strain wave. We argue that the shift of the longitudinal plasmon resonance is caused by the viscoelastic deformation of the polymer around the nanoparticle. The deformation is induced by the out of plane difference in strain in the area directly under a particle and next to it. Simulations based on the linear chain model support this assumption. Experimentally this assumption is proven by investigating the same structure, with GNRs embedded in a PSS/PAH polymer layer. The response of GNRs to the hyper-sound wave is also observed for the sample structure with GNRs embedded in PAzo/PAH films. The response of GNRs in this case is explained to be driven by the change of the refractive index of PAzo during the strain propagation.}, language = {en} } @phdthesis{Grewe2016, author = {Grewe, Sina}, title = {Hydro- and biogeochemical investigations of lake sediments in the Kenyan Rift Valley}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-98342}, school = {Universit{\"a}t Potsdam}, pages = {110}, year = {2016}, abstract = {Die Seen im kenianischen Riftsystem bieten die einmalige Gelegenheit eine große Bandbreite an hydrochemischen Umweltbedingungen zu studieren, die von S{\"u}ßwasserseen bis hin zu hochsalinen und alkalinen Seen reichen. Da wenig {\"u}ber die hydro- und biogeochemischen Bedingungen in den darunterliegenden Seesedimenten bekannt ist, war es das Ziel dieser Arbeit, bereits existierende Datens{\"a}tze mit Daten aus der Porenwasser- und Biomarker-Analyse zu erweitern. Zus{\"a}tzlich wurden reduzierte Schwefelkomponenten und Sulfatreduktionsraten in den Sedimenten bestimmt. Mit den neu gewonnenen Daten wurde der anthropogene und mikrobielle Einfluss auf die Seesedimente untersucht sowie der Einfluss der Wasserchemie auf den Abbau und den Erhalt von organischem Material im Sediment. Zu den untersuchten Seen geh{\"o}rten: Logipi, Eight (ein kleiner Kratersee in der Region Kangirinyang), Baringo, Bogoria, Naivasha, Oloiden und Sonachi. Die Biomarker-Zusammensetzungen in den untersuchten Seesedimenten waren {\"a}hnlich; allerdings gab es einige Unterschiede zwischen den salinen Seen und den S{\"u}ßwasserseen. Einer dieser Unterschiede war das Vorkommen eines mit β-Carotin verwandten Molek{\"u}ls, das nur in den salinen Seen gefunden wurde. Dieses Molek{\"u}l stammt wahrscheinlich von Cyanobakterien, Einzellern die in großer Anzahl in salinen Seen vorkommen. In den beiden S{\"u}ßwasserseen wurde Stigmasterol gefunden, ein f{\"u}r S{\"u}ßwasseralgen charakteristisches Sterol. In dieser Studie hat sich gezeigt, dass Bogoria und Sonachi f{\"u}r Umweltrekonstruktionen mit Biomarkern besonders gut geeignet sind, da die Abwesenheit von Sauerstoff an deren Seegr{\"u}nden den Abbau von organischem Material verlangsamt. Andere Seen, wie zum Beispiel Naivasha, sind aufgrund des großen anthropogenen Einflusses weniger gut f{\"u}r solche Rekonstruktionen geeignet. Die Biomarker-Analyse bot jedoch die M{\"o}glichkeit, den menschlichen Einfluss auf den See zu studieren. Desweiteren zeigte diese Studie, dass sich Horizonte mit einem hohen Anteil an elementarem Schwefel als temporale Marker nutzen lassen. Diese Horizonte wurden zu einer Zeit abgelagert, als die Wasserpegel sehr niedrig waren. Der Schwefel wurde von Mikroorganismen abgelagert, die zu anoxygener Photosynthese oder Sulfidoxidation f{\"a}hig sind.}, language = {en} } @misc{NeugebauerSchwabWaldmannetal.2016, author = {Neugebauer, Ina and Schwab, M. J. and Waldmann, Nicolas D. and Tjallingii, Rik and Frank, U. and Hadzhiivanova, E. and Naumann, R. and Taha, N. and Agnon, Amotz and Enzel, Y. and Brauer, Achim}, title = {Hydroclimatic variability in the Levant during the early last glacial (similar to 117-75 ka) derived from micro-facies analyses of deep Dead Sea sediments}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {549}, issn = {1866-8372}, doi = {10.25932/publishup-41187}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-411879}, pages = {16}, year = {2016}, abstract = {The new sediment record from the deep Dead Sea basin (ICDP core 5017-1) provides a unique archive for hydroclimatic variability in the Levant. Here, we present high-resolution sediment facies analysis and elemental composition by micro-X-ray fluorescence (mu XRF) scanning of core 5017-1 to trace lake levels and responses of the regional hydroclimatology during the time interval from ca. 117 to 75 ka, i. e. the transition between the last interglacial and the onset of the last glaciation. We distinguished six major micro-facies types and interpreted these and their alterations in the core in terms of relative lake level changes. The two end-member facies for highest and lowest lake levels are (a) up to several metres thick, greenish sediments of alternating aragonite and detrital marl laminae (aad) and (b) thick halite facies, respectively. Intermediate lake levels are characterised by detrital marls with varying amounts of aragonite, gypsum or halite, reflecting lower-amplitude, shorter-term variability. Two intervals of pronounced lake level drops occurred at similar to 110-108 +/- 5 and similar to 93-87 +/- 7 ka. They likely coincide with stadial conditions in the central Mediterranean (Melisey I and II pollen zones in Monticchio) and low global sea levels during Marine Isotope Stage (MIS) 5d and 5b. However, our data do not support the current hypothesis of an almost complete desiccation of the Dead Sea during the earlier of these lake level low stands based on a recovered gravel layer. Based on new petrographic analyses, we propose that, although it was a low stand, this well-sorted gravel layer may be a vestige of a thick turbidite that has been washed out during drilling rather than an in situ beach deposit. Two intervals of higher lake stands at similar to 108-93 +/- 6 and similar to 87-75 +/- 7 ka correspond to interstadial conditions in the central Mediterranean, i. e. pollen zones St. Germain I and II in Monticchio, and Greenland interstadials (GI) 24+23 and 21 in Greenland, as well as to sapropels S4 and S3 in the Mediterranean Sea. These apparent correlations suggest a close link of the climate in the Levant to North Atlantic and Mediterranean climates during the time of the build-up of Northern Hemisphere ice shields in the early last glacial period.}, language = {en} } @misc{AdhikariGlombitzaNickeletal.2016, author = {Adhikari, Rishi Ram and Glombitza, Clemens and Nickel, Julia C. and Anderson, Chloe H. and Dunlea, Ann G. and Spivack, Arthur J. and Murray, Richard W. and D'Hondt, Steven and Kallmeyer, Jens}, title = {Hydrogen utilization potential in subsurface sediments}, series = {Frontiers in microbiology}, journal = {Frontiers in microbiology}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407678}, pages = {16}, year = {2016}, abstract = {Subsurface microbial communities undertake many terminal electron-accepting processes, often simultaneously. Using a tritium-based assay, we measured the potential hydrogen oxidation catalyzed by hydrogenase enzymes in several subsurface sedimentary environments (Lake Van, Barents Sea, Equatorial Pacific, and Gulf of Mexico) with different predominant electron-acceptors. Hydrogenases constitute a diverse family of enzymes expressed by microorganisms that utilize molecular hydrogen as a metabolic substrate, product, or intermediate. The assay reveals the potential for utilizing molecular hydrogen and allows qualitative detection of microbial activity irrespective of the predominant electron-accepting process. Because the method only requires samples frozen immediately after recovery, the assay can be used for identifying microbial activity in subsurface ecosystems without the need to preserve live material. We measured potential hydrogen oxidation rates in all samples from multiple depths at several sites that collectively span a wide range of environmental conditions and biogeochemical zones. Potential activity normalized to total cell abundance ranges over five orders of magnitude and varies, dependent upon the predominant terminal electron acceptor. Lowest per-cell potential rates characterize the zone of nitrate reduction and highest per-cell potential rates occur in the methanogenic zone. Possible reasons for this relationship to predominant electron acceptor include (i) increasing importance of fermentation in successively deeper biogeochemical zones and (ii) adaptation of H(2)ases to successively higher concentrations of H-2 in successively deeper zones.}, language = {en} } @phdthesis{Bojahr2016, author = {Bojahr, Andre}, title = {Hypersound interaction studied by time-resolved inelastic light and x-ray scattering}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-93860}, school = {Universit{\"a}t Potsdam}, pages = {xxiii, 201}, year = {2016}, abstract = {This publications-based thesis summarizes my contribution to the scientific field of ultrafast structural dynamics. It consists of 16 publications, about the generation, detection and coupling of coherent gigahertz longitudinal acoustic phonons, also called hypersonic waves. To generate such high frequency phonons, femtosecond near infrared laser pulses were used to heat nanostructures composed of perovskite oxides on an ultrashort timescale. As a consequence the heated regions of such a nanostructure expand and a high frequency acoustic phonon pulse is generated. To detect such coherent acoustic sound pulses I use ultrafast variants of optical Brillouin and x-ray scattering. Here an incident optical or x-ray photon is scattered by the excited sound wave in the sample. The scattered light intensity measures the occupation of the phonon modes. The central part of this work is the investigation of coherent high amplitude phonon wave packets which can behave nonlinearly, quite similar to shallow water waves which show a steepening of wave fronts or solitons well known as tsunamis. Due to the high amplitude of the acoustic wave packets in the solid, the acoustic properties can change significantly in the vicinity of the sound pulse. This may lead to a shape change of the pulse. I have observed by time-resolved Brillouin scattering, that a single cycle hypersound pulse shows a wavefront steepening. I excited hypersound pulses with strain amplitudes until 1\% which I have calibrated by ultrafast x-ray diffraction (UXRD). On the basis of this first experiment we developed the idea of the nonlinear mixing of narrowband phonon wave packets which we call "nonlinear phononics" in analogy with the nonlinear optics, which summarizes a kaleidoscope of surprising optical phenomena showing up at very high electric fields. Such phenomena are for instance Second Harmonic Generation, four-wave-mixing or solitons. But in case of excited coherent phonons the wave packets have usually very broad spectra which make it nearly impossible to look at elementary scattering processes between phonons with certain momentum and energy. For that purpose I tested different techniques to excite narrowband phonon wave packets which mainly consist of phonons with a certain momentum and frequency. To this end epitaxially grown metal films on a dielectric substrate were excited with a train of laser pulses. These excitation pulses drive the metal film to oscillate with the frequency given by their inverse temporal displacement and send a hypersonic wave of this frequency into the substrate. The monochromaticity of these wave packets was proven by ultrafast optical Brillouin and x-ray scattering. Using the excitation of such narrowband phonon wave packets I was able to observe the Second Harmonic Generation (SHG) of coherent phonons as a first example of nonlinear wave mixing of nanometric phonon wave packets.}, language = {en} } @article{Simić2016, author = {Simić, Dijana}, title = {I am complicated}, series = {Grenzr{\"a}ume - Grenzbewegungen : Ergebnisse der Arbeitstreffen des Jungen Forums Slavistische Literaturwissenschaft in Basel 2013 und Frankfurt (Oder) und Słubice 2014 ; Bd. 1}, volume = {1}, journal = {Grenzr{\"a}ume - Grenzbewegungen : Ergebnisse der Arbeitstreffen des Jungen Forums Slavistische Literaturwissenschaft in Basel 2013 und Frankfurt (Oder) und Słubice 2014 ; Bd. 1}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-358-9}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-92591}, pages = {129 -- 142}, year = {2016}, language = {de} }