@article{BalischewskiBehrensZehbeetal.2020, author = {Balischewski, Christian and Behrens, Karsten and Zehbe, Kerstin and G{\"u}nter, Christina and Mies, Stefan and Sperlich, Eric and Kelling, Alexandra and Taubert, Andreas}, title = {Ionic liquids with more than one metal}, series = {Chemistry - a European journal}, volume = {26}, journal = {Chemistry - a European journal}, number = {72}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0947-6539}, doi = {10.1002/chem.202003097}, pages = {17504 -- 17513}, year = {2020}, abstract = {Thirteen N-butylpyridinium salts, including three monometallic [C4Py](2)[MCl4], nine bimetallic [C4Py](2)[(M1-xMxCl4)-M-a-Cl-b] and one trimetallic compound [C4Py](2)[(M1-y-zMyMz (c) Cl4)-M-a-M-b] (M=Co, Cu, Mn; x=0.25, 0.50 or 0.75 and y=z=0.33), were synthesized and their structure and thermal and electrochemical properties were studied. All compounds are ionic liquids (ILs) with melting points between 69 and 93 degrees C. X-ray diffraction proves that all ILs are isostructural. The conductivity at room temperature is between 10(-4) and 10(-8) S cm(-1). Some Cu-based ILs reach conductivities of 10(-2) S cm(-1), which is, however, probably due to IL dec. This correlates with the optical bandgap measurements indicating the formation of large bandgap semiconductors. At elevated temperatures approaching the melting points, the conductivities reach up to 1.47x10(-1) S cm(-1) at 70 degrees C. The electrochemical stability windows of the ILs are between 2.5 and 3.0 V.}, language = {en} } @misc{BarboliniWoutersenDupontNivetetal.2020, author = {Barbolini, Natasha and Woutersen, Amber and Dupont-Nivet, Guillaume and Silvestro, Daniele and Tardif-Becquet, Delphine and Coster, Pauline M. C. and Meijer, Niels and Chang, Cun and Zhang, Hou-Xi and Licht, Alexis and Rydin, Catarina and Koutsodendris, Andreas and Han, Fang and Rohrmann, Alexander and Liu, Xiang-Jun and Zhang, Y. and Donnadieu, Yannick and Fluteau, Frederic and Ladant, Jean-Baptiste and Le Hir, Guillaume and Hoorn, M. Carina}, title = {Cenozoic evolution of the steppe-desert biome in Central Asia}, series = {Science Advances}, volume = {6}, journal = {Science Advances}, number = {41}, publisher = {American Association for the Advancement of Science}, address = {Washington}, issn = {2375-2548}, doi = {10.1126/sciadv.abb8227}, pages = {16}, year = {2020}, abstract = {The origins and development of the arid and highly seasonal steppe-desert biome in Central Asia, the largest of its kind in the world, remain largely unconstrained by existing records. It is unclear how Cenozoic climatic, geological, and biological forces, acting at diverse spatial and temporal scales, shaped Central Asian ecosystems through time. Our synthesis shows that the Central Asian steppe-desert has existed since at least Eocene times but experienced no less than two regime shifts, one at the Eocene-Oligocene Transition and one in the mid-Miocene. These shifts separated three successive "stable states," each characterized by unique floral and faunal structures. Past responses to disturbance in the Asian steppe-desert imply that modern ecosystems are unlikely to recover their present structures and diversity if forced into a new regime. This is of concern for Asian steppes today, which are being modified for human use and lost to desertification at unprecedented rates.}, language = {en} } @article{BaroniFrancke2020, author = {Baroni, Gabriele and Francke, Till}, title = {An effective strategy for combining variance- and distribution-based global sensitivity analysis}, series = {Environmental modelling \& software with environment data news}, volume = {134}, journal = {Environmental modelling \& software with environment data news}, publisher = {Elsevier}, address = {Oxford}, issn = {1364-8152}, doi = {10.1016/j.envsoft.2020.104851}, pages = {14}, year = {2020}, abstract = {We present a new strategy for performing global sensitivity analysis capable to estimate main and interaction effects from a generic sampling design. The new strategy is based on a meaningful combination of varianceand distribution-based approaches. The strategy is tested on four analytic functions and on a hydrological model. Results show that the analysis is consistent with the state-of-the-art Saltelli/Jansen formula but to better quantify the interaction effect between the input factors when the output distribution is skewed. Moreover, the estimation of the sensitivity indices is much more robust requiring a smaller number of simulations runs. Specific settings and alternative methods that can be integrated in the new strategy are also discussed. Overall, the strategy is considered as a new simple and effective tool for performing global sensitivity analysis that can be easily integrated in any environmental modelling framework.}, language = {en} } @phdthesis{Barrionuevo2020, author = {Barrionuevo, Mat{\´i}as}, title = {The role of the upper plate in the Andean tectonic evolution (33-36°S): insights from structural geology and numerical modeling}, doi = {10.25932/publishup-51590}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-515909}, school = {Universit{\"a}t Potsdam}, pages = {148, S2}, year = {2020}, abstract = {Los Andes Centrales del Sur (33-36°S) son un gran laboratorio para el estudio de los procesos de deformaci{\´o}n orog{\´e}nica, donde las condiciones de borde, como la geometr{\´i}a de la placa subductada, imponen un importante control sobre la deformaci{\´o}n andina. Por otro lado, la Placa Sudamericana presenta una serie de heterogeneidades que tambi{\´e}n imparten un control sobre el modo de deformaci{\´o}n. El objetivo de esta tesis es probar el control de este {\´u}ltimo factor sobre la construcci{\´o}n del sistema orog{\´e}nico andino. A partir de la integraci{\´o}n de la informaci{\´o}n superficial y de subsuelo en el {\´a}rea sur (34°-36°S), se estudi{\´o} la evoluci{\´o}n de la deformaci{\´o}n andina sobre el segmento de subducci{\´o}n normal. Se desarroll{\´o} un modelo estructural que eval{\´u}a el estado de esfuerzos desde el Mioceno hasta la actualidad, el rol de estructuras previas y su influencia en la migraci{\´o}n de fluidos. Con estos datos y publicaciones previas de la zona norte del {\´a}rea de estudio (33°-34ºS), se realiz{\´o} un modelado num{\´e}rico geodin{\´a}mico para probar la hip{\´o}tesis del papel de las heterogeneidades de la placa superior en la evoluci{\´o}n andina. Se utilizaron dos c{\´o}digos (LAPEX-2D y ASPECT) basados en elementos finitos/diferencias finitas, que simulan el comportamiento de materiales con reolog{\´i}as elastoviscopl{\´a}sticas bajo deformaci{\´o}n. Los resultados del modelado sugieren que la deformaci{\´o}n contraccional de la placa superior est{\´a} significativamente controlada por la resistencia de la lit{\´o}sfera, que est{\´a} definida por la composici{\´o}n de la corteza superior e inferior y por la proporci{\´o}n del manto litosf{\´e}rico, que a su vez est{\´a} definida por eventos tect{\´o}nicos previos. Estos eventos previos tambi{\´e}n definieron la composici{\´o}n de la corteza y su geometr{\´i}a, que es otro factor que controla la localizaci{\´o}n de la deformaci{\´o}n. Con una composici{\´o}n de corteza inferior m{\´a}s f{\´e}lsica, la deformaci{\´o}n sigue un modo de cizalla pura mientras que las composiciones m{\´a}s m{\´a}ficas provocan un modo de deformaci{\´o}n tipo cizalla simple. Por otro lado, observamos que el espesor inicial de la lit{\´o}sfera controla la localizaci{\´o}n de la deformaci{\´o}n, donde zonas con lit{\´o}sfera m{\´a}s fina es propensa a concentrar la deformaci{\´o}n. Un l{\´i}mite lit{\´o}sfera-asten{\´o}sfera asim{\´e}trico, como resultado del flujo de la cu{\~n}a mant{\´e}lica tiende a generar despegues vergentes al E.}, language = {en} } @misc{BenDorNeugebauerEnzeletal.2020, author = {Ben Dor, Yoav and Neugebauer, Ina and Enzel, Yehouda and Schwab, Markus J. and Tjallingii, Rik and Erel, Yigal and Brauer, Achim}, title = {Reply to comment on: Ben Dor, Yoav et al. : Varves of the Dead Sea sedimentary record. - In: Quaternary science reviews : the international multidisciplinary research and review journal. - 215 (2019), S. 173 - 184. - (ISSN: 0277-3791). - https://doi.org/10.1016/j.quascirev.2019.04.011}, series = {Quaternary science reviews : the international multidisciplinary research and review journal}, volume = {231}, journal = {Quaternary science reviews : the international multidisciplinary research and review journal}, publisher = {Elsevier}, address = {Amsterdam [u.a.]}, issn = {0277-3791}, doi = {10.1016/j.quascirev.2019.106063}, pages = {5}, year = {2020}, abstract = {In the comment on "Varves of the Dead Sea sedimentary record." Quaternary Science Reviews 215 (Ben Dor et al., 2019): 173-184. by R. Bookman, two recently published papers are suggested to prove that the interpretation of the laminated sedimentary sequence of the Dead Sea, deposited mostly during MIS2 and Holocene pluvials, as annual deposits (i.e., varves) is wrong. In the following response, we delineate several lines of evidence which coalesce to demonstrate that based on the vast majority of evidence, including some of the evidence provided in the comment itself, the interpretation of these sediments as varves is the more likely scientific conclusion. We further discuss the evidence brought up in the comment and its irrelevance and lack of robustness for addressing the question under discussion.}, language = {en} } @article{BentzKwiatekMartinezGarzonetal.2020, author = {Bentz, Stephan and Kwiatek, Grzegorz and Martinez-Garzon, Patricia and Bohnhoff, Marco and Dresen, Georg}, title = {Seismic moment evolution during hydraulic stimulations}, series = {Geophysical research letters}, volume = {47}, journal = {Geophysical research letters}, number = {5}, publisher = {American Geophysical Union}, address = {Washington}, issn = {0094-8276}, doi = {10.1029/2019GL086185}, pages = {9}, year = {2020}, abstract = {Analysis of past and present stimulation projects reveals that the temporal evolution and growth of maximum observed moment magnitudes may be linked directly to the injected fluid volume and hydraulic energy. Overall evolution of seismic moment seems independent of the tectonic stress regime and is most likely governed by reservoir specific parameters, such as the preexisting structural inventory. Data suggest that magnitudes can grow either in a stable way, indicating the constant propagation of self-arrested ruptures, or unbound, for which the maximum magnitude is only limited by the size of tectonic faults and fault connectivity. Transition between the two states may occur at any time during injection or not at all. Monitoring and traffic light systems used during stimulations need to account for the possibility of unstable rupture propagation from the very beginning of injection by observing the entire seismicity evolution in near-real time and at high resolution for an immediate reaction in injection strategy. Plain Language Summary Predicting and controlling the size of earthquakes caused by fluid injection is currently the major concern of many projects associated with geothermal energy production. Here, we analyze the magnitude and seismic moment evolution with injection parameters for prominent geothermal and scientific projects to date. Evolution of seismicity seems to be largely independent of the tectonic stress background and seemingly depends on reservoir specific characteristics. We find that the maximum observed magnitudes relate linearly to the injected volume or hydraulic energy. A linear relation suggests stable growth of induced ruptures, as predicted by current models, or rupture growth may no longer depend on the stimulated volume but on tectonics. A system may change between the two states during the course of fluid injection. Close-by and high-resolution monitoring of seismic and hydraulic parameters in near-real time may help identify these fundamental changes in ample time to change injection strategy and manage maximum magnitudes.}, language = {en} } @phdthesis{Biedermann2020, author = {Biedermann, Nicole}, title = {Carbonate-silicate reactions at conditions of the Earth's mantle and the role of carbonates as possible trace-element carriers}, doi = {10.25932/publishup-48277}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-482772}, school = {Universit{\"a}t Potsdam}, pages = {xvii, 127}, year = {2020}, abstract = {Carbonates play a key role in the chemistry and dynamics of our planet. They are directly connected to the CO2 budget of our atmosphere and have a great impact on the deep carbon cycle. Moreover, recent studies have shown that carbonates are stable along the geothermal gradient down to Earth's lower mantle conditions, changing their crystal structure and related properties. Subducted carbonates may also react with silicates to form new phases. These reactions will redistribute elements, such as calcium (Ca), magnesium (Mg), iron (Fe) and carbon in the form of carbon dioxide (CO2), but also trace elements, that are carried by the carbonates. The trace elements of most interest are strontium (Sr) and rare earth elements (REE) which have been found to be important constituents in the composition of the primitive lower mantle and in mineral inclusions found in super-deep diamonds. However, the stability of carbonates in presence of mantle silicates at relevant temperatures is far from being well understood. Related to this, very little is known about distribution processes of trace elements between carbonates and mantle silicates. To shed light on these processes, we studied reactions between Sr- and REE-containing CaCO3 and Mg/Fe-bearing silicates of the system (Mg,Fe)2SiO4 - (Mg,Fe)SiO3 at high pressure and high temperature using synchrotron radiation based μ-X-ray diffraction (μ-XRD) and μ-X-ray fluorescence (μ-XRF) with μm-resolution in a laser-heated diamond anvil cell. X-ray diffraction is used to derive the structural changes of the phase reactions whereas X-ray fluorescence gives information on the chemical changes in the sample. In-situ experiments at high pressure and high temperature were performed at beamline P02.2 at PETRA III (Hamburg, Germany) and at beamline ID27 at ESRF (Grenoble, France). In addition to μ-XRD and μ-XRF, ex-situ measurements were made on the recovered sample material using transmission electron microscopy (TEM) and provided further insights into the reaction kinetics of carbonate-silicate reactions. Our investigations show that CaCO3 is unstable in presence of mantle silicates above 1700 K and a reaction takes place in which magnesite plus CaSiO3-perovskite are formed. In addition, we observed that a high content of iron in the carbonate-silicate system favours dolomite formation during the reaction. The subduction of natural carbonates with significant amounts of Sr leads to a comprehensive investigation of the stability not only of CaCO3 phases in contact with mantle silicates but also of SrCO3 (and of Sr-bearing CaCO3). We found that SrCO3 reacts with (Mg,Fe)SiO3-perovskite to form magnesite and gained evidence for the formation of SrSiO3-perovskite. To complement our study on the stability of SrCO3 at conditions of the Earth's lower mantle, we performed powder X-ray diffraction and single crystal X-ray diffraction experiments at ambient temperature and up to 49 GPa. We observed a transformation from SrCO3-I into a new high-pressure phase SrCO3-II at around 26 GPa with Pmmn crystal structure and a bulk modulus of 103(10) GPa. This information is essential to fully understand the phase behaviour and stability of carbonates in the Earth's lower mantle and to elucidate the possibility of introducing Sr into mantle silicates by carbonate-silicate reactions. Simultaneous recording of μ-XRD and μ-XRF in the μm-range over the heated areas provides spatial information not only about phase reactions but also on the elemental redistribution during the reactions. A comparison of the spatial intensity distribution of the XRF signal before and after heating indicates a change in the elemental distribution of Sr and an increase in Sr-concentration was found around the newly formed SrSiO3-perovskite. With the help of additional TEM analyses on the quenched sample material the elemental redistribution was studied at a sub-micrometer scale. Contrary to expectations from combined μ-XRD and μ-XRF measurements, we found that La and Eu were not incorporated into the silicate phases, instead they tend to form either isolated oxide phases (e.g. Eu2O3, La2O3) or hydroxyl-bastn{\"a}site (La(CO3)(OH)). In addition, we observed the transformation from (Mg,Fe)SiO3-perovskite to low-pressure clinoenstatite during pressure release. The monoclinic structure (P21/c) of this phase allows the incorporation of Ca as shown by additional EDX analyses and, to a minor extent, Sr too. Based on our experiments, we can conclude that a detection of the trace elements in-situ at high pressure and high temperature remains challenging. However, our first findings imply that silicates may incorporate the trace elements provided by the carbonates and indicate that carbonates may have a major effect on the trace element contents of mantle phases.}, language = {en} } @phdthesis{Borghini2020, author = {Borghini, Alessia}, title = {Melt inclusions in mafic rocks as witnesses of metasomatism in the Bohemian Massif}, doi = {10.25932/publishup-47363}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-473639}, school = {Universit{\"a}t Potsdam}, pages = {205}, year = {2020}, abstract = {Orogenic peridotites represent portions of upper subcontinental mantle now incorporated in mountain belts. They often contain layers, lenses and irregular bodies of pyroxenite and eclogite. The origin of this heterogeneity and the nature of these layers is still debated but it is likely to involve processes such as transient melts coming from the crust or the mantle and segregating in magma conduits, crust-mantle interaction, upwelling of the asthenosphere and metasomatism. All these processes occur in the lithospheric mantle and are often related with the subduction of crustal rocks to mantle depths. In fact, during subduction, fluids and melts are released from the slab and can interact with the overlying mantle, making the study of deep melts in this environment crucial to understand mantle heterogeneity and crust-mantle interaction. The aim of this thesis is precisely to better constrain how such processes take place studying directly the melt trapped as primary inclusions in pyroxenites and eclogites. The Bohemian Massif, crystalline core of the Variscan belt, is targeted for these purposes because it contains orogenic peridotites with layers of pyroxenite and eclogite and other mafic rocks enclosed in felsic high pressure and ultra-high pressure crustal rocks. Within this Massif mafic rocks from two areas have been selected: the garnet clinopyroxenite in orogenic peridotite of the Granulitgebirge and the ultra-high pressure eclogite in the diamond-bearing gneisses of the Erzgebirge. In both areas primary melt inclusions were recognized in the garnet, ranging in size between 2-25 µm and with different degrees of crystallization, from glassy to polycrystalline. They have been investigated with Micro Raman spectroscopy and EDS mapping and the mineral assemblage is kumdykolite, phlogopite, quartz, kokchetavite, phase with a main Raman peak at 430 cm-1, phase with a main Raman peak at 412 cm-1, white mica and calcite with some variability in relative abundance depending on the case study. In the Granulitgebirge osumilite and pyroxene are also present, whereas calcite is one of the main phases in the Erzgebirge. The presence of glass and the mineral assemblage in the nanogranitoids suggest that they were former droplets of melt trapped in the garnet while it was growing. Glassy inclusions and re-homogenized nanogranitoids show a silicate melt that is granitic, hydrous, high in alkalis and weakly peraluminous. The melt is also enriched in both case studies in Cs, Pb, Rb, U, Th, Li and B suggesting the involvement of crustal component, i.e. white mica (main carrier of Cs, Pb, Rb, Li and B), and a fluid (Cs, Th and U) in the melt producing reaction. The whole rock in both cases mainly consists of garnet and clinopyroxene with, in Erzgebirge samples, the additional presence of quartz both in the matrix and as a polycrystalline inclusion in the garnet. The latter is interpreted as a quartz pseudomorph after coesite and occurs in the same microstructural position as the melt inclusions. Both rock types show a crustal and subduction zone signature with garnet and clinopyroxene in equilibrium. Melt was likely present during the metamorphic peak of the rock, as it occurs in garnet. Our data suggest that the processes most likely responsible for the formation of the investigated rocks in both areas is a metasomatic reaction between a melt produced in the crust and mafic layers formerly located in the mantle wedge for the Granulitgebirge and in the subducted continental crust itself in the Erzgebirge. Thus metasomatism in the first case took place in the mantle overlying the slab, whereas in the second case metasomatism took place in the continental crust that already contained, before subduction, mafic layers. Moreover, the presence of former coesite in the same microstructural position of the melt inclusions in the Erzgebirge garnets suggest that metasomatism took place at ultra-high pressure conditions. Summarizing, in this thesis we provide new insights into the geodynamic evolution of the Bohemian Massif based on the study of melt inclusions in garnet in two different mafic rock types, combining the direct microstructural and geochemical investigation of the inclusions with the whole-rock and mineral geochemistry. We report for the first time data, directly extracted from natural rocks, on the metasomatic melt responsible for the metasomatism of several areas of the Bohemian Massif. Besides the two locations here investigated, belonging to the Saxothuringian Zone, a signature similar to the investigated melt is clearly visible in pyroxenite and peridotite of the T-7 borehole (again Saxothuringian Zone) and the durbachite suite located in the Moldanubian Zone.}, language = {en} } @misc{Braun2020, author = {Braun, Jean}, title = {Response to comment by Japsen et al. on "A review of numerical modeling studies of passive margin escarpments leading to a new analytical expression for the rate of escarpment migration velocity"}, series = {Gondwana research : international geoscience journal ; official journal of the International Association for Gondwana Research}, volume = {65}, journal = {Gondwana research : international geoscience journal ; official journal of the International Association for Gondwana Research}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1342-937X}, doi = {10.1016/j.gr.2018.10.003}, pages = {174 -- 176}, year = {2020}, language = {en} } @article{BrillPassuniPinedaEspichanCuyaetal.2020, author = {Brill, Fabio Alexander and Passuni Pineda, Silvia and Espichan Cuya, Bruno and Kreibich, Heidi}, title = {A data-mining approach towards damage modelling for El Nino events in Peru}, series = {Geomatics, natural hazards and risk}, volume = {11}, journal = {Geomatics, natural hazards and risk}, number = {1}, publisher = {Routledge, Taylor \& Francis Group}, address = {Abingdon}, issn = {1947-5705}, doi = {10.1080/19475705.2020.1818636}, pages = {1966 -- 1990}, year = {2020}, abstract = {Compound natural hazards likeEl Ninoevents cause high damage to society, which to manage requires reliable risk assessments. Damage modelling is a prerequisite for quantitative risk estimations, yet many procedures still rely on expert knowledge, and empirical studies investigating damage from compound natural hazards hardly exist. A nationwide building survey in Peru after theEl Ninoevent 2017 - which caused intense rainfall, ponding water, flash floods and landslides - enables us to apply data-mining methods for statistical groundwork, using explanatory features generated from remote sensing products and open data. We separate regions of different dominant characteristics through unsupervised clustering, and investigate feature importance rankings for classifying damage via supervised machine learning. Besides the expected effect of precipitation, the classification algorithms select the topographic wetness index as most important feature, especially in low elevation areas. The slope length and steepness factor ranks high for mountains and canyons. Partial dependence plots further hint at amplified vulnerability in rural areas. An example of an empirical damage probability map, developed with a random forest model, is provided to demonstrate the technical feasibility.}, language = {en} }