@article{JonesWiesner2022, author = {Jones, Chris and Wiesner, Karoline}, title = {Clarifying how degree entropies and degree-degree correlations relate to network robustness}, series = {Entropy : an international and interdisciplinary journal of entropy and information studies}, volume = {24}, journal = {Entropy : an international and interdisciplinary journal of entropy and information studies}, number = {9}, publisher = {MDPI}, address = {Basel}, issn = {1099-4300}, doi = {10.3390/e24091182}, pages = {13}, year = {2022}, abstract = {It is often claimed that the entropy of a network's degree distribution is a proxy for its robustness. Here, we clarify the link between degree distribution entropy and giant component robustness to node removal by showing that the former merely sets a lower bound to the latter for randomly configured networks when no other network characteristics are specified. Furthermore, we show that, for networks of fixed expected degree that follow degree distributions of the same form, the degree distribution entropy is not indicative of robustness. By contrast, we show that the remaining degree entropy and robustness have a positive monotonic relationship and give an analytic expression for the remaining degree entropy of the log-normal distribution. We also show that degree-degree correlations are not by themselves indicative of a network's robustness for real networks. We propose an adjustment to how mutual information is measured which better encapsulates structural properties related to robustness.}, language = {en} } @article{HenkelFolman2022, author = {Henkel, Carsten and Folman, Ron}, title = {Internal decoherence in nano-object interferometry due to phonons}, series = {AVS Quantum Science}, volume = {4}, journal = {AVS Quantum Science}, number = {2}, publisher = {AIP Publishing}, address = {Melville}, issn = {2639-0213}, doi = {10.1116/5.0080503}, pages = {9}, year = {2022}, abstract = {We discuss the coherent splitting and recombining of a nanoparticle in a mesoscopic "closed-loop" Stern-Gerlach interferometer in which the observable is the spin of a single impurity embedded in the particle. This spin, when interacting with a pulsed magnetic gradient, generates the force on the particle. We calculate the internal decoherence, which arises as the displaced impurity excites internal degrees of freedom (phonons) that may provide WelcherWeg information and preclude interference. We estimate the constraints this decoherence channel puts on future interference experiments with massive objects. We find that for a wide range of masses, forces, and temperatures, phonons do not inhibit Stern-Gerlach interferometry with micro-scale objects. However, phonons do constitute a fundamental limit on the splitting of larger macroscopic objects if the applied force induces phonons.}, language = {en} } @article{KlugeLevermannSchewe2022, author = {Kluge, Lucas and Levermann, Anders and Schewe, Jacob}, title = {Radiation model for migration with directional preferences}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {106}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {6}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.106.064138}, pages = {10}, year = {2022}, abstract = {The radiation model is a parameter-free model of human mobility that has been applied primarily for short-distance moves, such as commuting. When applied to migration, it underestimates the number of long-range moves, such as between different US states. Here we show that it additionally suffers from a conceptual inconsistency that can have substantial numerical effects on long-distance moves. We propose a modification of the radiation model that introduces a dependence on the angle between any two alternative potential destinations, accounting for the possibility that migrants may have preferences about the approximate direction of their move. We demonstrate that this modification mitigates the conceptual inconsistency and improves the model fit to observational migration data, without introducing any fitting parameters.}, language = {en} } @article{PauzonMishurovaFischeretal.2022, author = {Pauzon, Camille and Mishurova, Tatiana and Fischer, Marie and Ahlstr{\"o}m, Johan and Fritsch, Tilman and Bruno, Giovanni and Hryha, Eduard}, title = {Impact of contour scanning and helium-rich process gas on performances of Alloy 718 lattices produced by laser powder bed fusion}, series = {Materials \& Design}, volume = {215}, journal = {Materials \& Design}, publisher = {Elsevier}, address = {Oxford}, issn = {0264-1275}, doi = {10.1016/j.matdes.2022.110501}, pages = {12}, year = {2022}, abstract = {Contour scanning and process gas type are process parameters typically considered achieving second order effects compared to first order factors such as laser power and scanning speed. The present work highlights that contour scanning is crucial to ensure geometrical accuracy and thereby the high performance under uniaxial compression of complex Alloy 718 lattice structures. Studies of X-ray computed tomography visualizations of as-built and compression-strained structures reveal the continuous and smooth bending and compression of the walls, and the earlier onset of internal contact appearance in the denser lattices printed with contour. In contrast, the effect of addition of He to the Ar process gas appears to have limited influence on the mechanical response of the lattices and their microstructure as characterized by electron backscattered diffraction. However, the addition of He proved to significantly enhance the cooling rate and to reduce the amount of the generated spatters as evidenced by in situ monitoring of the process emissions, which is very promising for the process stability and powder reusability during laser powder bed fusion.}, language = {en} } @article{VazdaCruzMascarenhasBuechneretal.2022, author = {Vaz da Cruz, Vinicius and Mascarenhas, Eric J. and B{\"u}chner, Robby and Jay, Raphael M. and Fondell, Mattis and Eckert, Sebastian and Foehlisch, Alexander}, title = {Metal-water covalency in the photo-aquated ferrocyanide complex as seen by multi-edge picosecond X-ray absorption}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {24}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, number = {45}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/d2cp04084k}, pages = {27819 -- 27826}, year = {2022}, abstract = {In this work, we investigate the photo-aquation reaction of the ferrocyanide anion with multi-edge picosecond soft X-ray spectroscopy. Combining the information of the iron L-edge with nitrogen and oxygen K-edges, we carry out a complete characterization of the bonding channels in the [Fe(CN)(5)(H2O)](3-) photo-product. We observe clear spectral signatures of covalent bonding between water and the metal, reflecting the mixing of the Fe d(z)(2) orbital with the 3a(1) and 4a(1) orbitals of H2O. Additional fingerprints related to the symmetry reduction and the resulting loss in orbital degeneracy are also reported. The implications of the elucidated fingerprints in the context of future ultra-fast experiments are also discussed.}, language = {en} } @article{BohdanWeidlMorrisetal.2022, author = {Bohdan, Artem and Weidl, Martin S. and Morris, Paul J. and Pohl, Martin}, title = {The electron foreshock at high-Mach-number non-relativistic oblique shocks}, series = {Physics of plasmas}, volume = {29}, journal = {Physics of plasmas}, number = {5}, publisher = {AIP Publishing}, address = {Melville}, issn = {1070-664X}, doi = {10.1063/5.0084544}, pages = {13}, year = {2022}, abstract = {In the Universe, matter outside of stars and compact objects is mostly composed of collisionless plasma. The interaction of a supersonic plasma flow with an obstacle results in collisionless shocks that are often associated with intense nonthermal radiation and the production of cosmic ray particles. Motivated by simulations of non-relativistic high-Mach-number shocks in supernova remnants, we investigate the instabilities excited by relativistic electron beams in the extended foreshock of oblique shocks. The phase-space distributions in the inner and outer foreshock regions are derived with a particle-in-cell simulation of the shock and used as initial conditions for simulations with periodic boundary conditions to study their relaxation toward equilibrium. We find that the observed electron-beam instabilities agree very well with the predictions of a linear dispersion analysis: the electrostatic electron-acoustic instability dominates in the outer region of the foreshock, while the denser electron beams in the inner foreshock drive the gyroresonant oblique-whistler instability.}, language = {en} } @article{KamlahVermaDierckeetal.2021, author = {Kamlah, Robert and Verma, Meetu and Diercke, Andrea and Denker, Carsten}, title = {Wavelength dependence of image quality metrics and seeing parameters and their relation to adaptive optics performance}, series = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, volume = {296}, journal = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, number = {2}, publisher = {Springer Science + Business Media B.V}, address = {Dordrecht [u.a.]}, issn = {1573-093X}, doi = {10.1007/s11207-021-01771-y}, pages = {29}, year = {2021}, abstract = {Ground-based solar observations are severely affected by Earth's turbulent atmosphere. As a consequence, observed image quality and prevailing seeing conditions are closely related. Partial correction of image degradation is nowadays provided in real time by adaptive optics (AO) systems. In this study, different metrics of image quality are compared with parameters characterizing the prevailing seeing conditions, i.e. Median Filter Gradient Similarity (MFGS), Median Filter Laplacian Similarity (MFLS), Helmli-Scherer mean, granular rms-contrast, differential image motion, and Fried-parameter r(0). The quiet-Sun observations at disk center were carried out at the Vacuum Tower Telescope (VTT), Observatorio del Teide (OT), Izana, Tenerife, Spain. In July and August 2016, time series of short-exposure images were recorded with the High-resolution Fast Imager (HiFI) at various wavelengths in the visible and near-infrared parts of the spectrum. Correlation analysis yields the wavelength dependence of the image quality metrics and seeing parameters, and Uniform Manifold Approximation and Projection (UMAP) is employed to characterize the seeing on a particular observing day. In addition, the image quality metrics and seeing parameters are used to determine the field dependence of the correction provided by the AO system. Management of high-resolution imaging data from large-aperture, ground-based telescopes demands reliable image quality metrics and meaningful characterization of prevailing seeing conditions and AO performance. The present study offers guidance on how retrieving such information ex post facto.}, language = {en} } @article{MeyerMeliani2022, author = {Meyer, Dominique M.-A. and Meliani, Zakaria}, title = {Pulsar wind nebulae of runaway massive stars}, series = {Monthly notices of the Royal Astronomical Society. Letters}, volume = {515}, journal = {Monthly notices of the Royal Astronomical Society. Letters}, number = {1}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {1745-3933}, doi = {10.1093/mnrasl/slac062}, pages = {L29 -- L33}, year = {2022}, abstract = {A significant fraction of massive stars move at speed through the interstellar medium of galaxies. After their death as core-collapse supernovae, a possible final evolutionary state is that of a fast-rotating magnetized neutron star, shaping its circumstellar medium into a pulsar wind nebula. Understanding the properties of pulsar wind nebulae requires knowledge of the evolutionary history of their massive progenitors. Using two-dimensional magnetohydrodynamical simulations, we demonstrate that, in the context of a runaway high-mass red-supergiant supernova progenitor, the morphology of its subsequent pulsar wind nebula is strongly affected by the wind of the defunct progenitor star pre-shaping the stellar surroundings throughout its entire past life. In particular, pulsar wind nebulae of obscured runaway massive stars harbour asymmetries as a function of the morphology of the progenitor's wind-blown cavity, inducing projected asymmetric up-down synchrotron emission.}, language = {en} } @article{YochelisFlemmingBeta2022, author = {Yochelis, Arik and Flemming, Sven and Beta, Carsten}, title = {Versatile patterns in the actin cortex of motile cells}, series = {Physical review letters}, volume = {129}, journal = {Physical review letters}, number = {8}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.129.088101}, pages = {6}, year = {2022}, abstract = {Self-organized patterns in the actin cytoskeleton are essential for eukaryotic cellular life. They are the building blocks of many functional structures that often operate simultaneously to facilitate, for example, nutrient uptake and movement of cells. However, identifying how qualitatively distinct actin patterns can coexist remains a challenge. Using bifurcation theory of a mass conserved activator-inhibitor system, we uncover a generic mechanism of how different actin waves-traveling waves and excitable pulses- organize and simultaneously emerge. Live-cell imaging experiments indeed reveal that narrow, planar, and fast-moving excitable pulses may coexist with ring-shaped macropinocytic actin waves in the cortex of motile amoeboid cells.}, language = {en} } @article{SavchenkoLomadzeSanteretal.2022, author = {Savchenko, Vladyslav and Lomadze, Nino and Santer, Svetlana and Guskova, Olga}, title = {Spiropyran/merocyanine amphiphile in various solvents}, series = {International journal of molecular sciences}, volume = {23}, journal = {International journal of molecular sciences}, number = {19}, publisher = {MDPI}, address = {Basel}, issn = {1422-0067}, doi = {10.3390/ijms231911535}, pages = {24}, year = {2022}, abstract = {This joint experimental-theoretical work focuses on molecular and photophysical properties of the spiropyran-containing amphiphilic molecule in organic and aqueous solutions. Being dissolved in tested organic solvents, the system demonstrates positive photochromism, i.e., upon UV stimulus the colorless spiropyran form is transformed into colorful merocyanine isomer. However, the aqueous solution of the amphiphile possesses a negative photochromism: the orange-red merocyanine form becomes thermodynamically more stable in water, and both UV and vis stimuli lead to the partial or complete photobleaching of the solution. The explanation of this phenomenon is given on the basis of density functional theory calculations and classical modeling including thermodynamic integration. The simulations reveal that stabilization of merocyanine in water proceeds with the energy of ca. 70 kJ mol-1, and that the Helmholtz free energy of hydration of merocyanine form is 100 kJ mol-1 lower as compared to the behavior of SP isomer in water. The explanation of such a difference lies in the molecular properties of the merocyanine: after ring-opening reaction this molecule transforms into a zwitterionic form, as evidenced by the electrostatic potential plotted around the opened form. The presence of three charged groups on the periphery of a flat conjugated backbone stimulates the self-assembly of merocyanine molecules in water, ending up with the formation of elongated associates with stack-like building blocks, as shown in molecular dynamics simulations of the aqueous solution with the concentration above critical micelle concentration. Our quantitative evaluation of the hydrophilicity switching in spiropyran/merocyanine containing surfactants may prompt the search for new systems, including colloidal and polymeric ones, aiming at remote tuning of their morphology, which could give new promising shapes and patterns for the needs of modern nanotechnology.}, language = {en} }