@article{MaiLindeLinker2020,
  author    = {Mai-Linde, Yasemin and Linker, Torsten},
  title     = {Radical clock probes to determine carbohydrate radical stabilities},
  series = {Organic letters},
  volume    = {22},
  journal   = {Organic letters},
  number    = {4},
  publisher = {American Chemical Society},
  address   = {Washington},
  issn      = {1523-7060},
  doi       = {10.1021/acs.orglett.0c00111},
  pages     = {1525 -- 1529},
  year      = {2020},
  abstract  = {Carbohydrate radical stabilities in the 1- and 2-position have been determined by a radical clock approach, starting from cyclopropanated sugars with xanthates as precursors. Various hexoses and pentoses afforded 1-deoxy sugars as main products, indicating that anomeric radicals are more stable than radicals in the 2-position. An additional influence of the configurations on radical stabilities has been observed. Our results should be interesting for the understanding of 1,2-radical rearrangements in carbohydrate chemistry and offer an easy access to deoxy-vinyl sugars.},
  language  = {en}
}