@article{BurekDenglerEmmerlingetal.2019,
  author    = {Burek, Katja and Dengler, Joachim and Emmerling, Franziska and Feldmann, Ines and Kumke, Michael Uwe and Stroh, Julia},
  title     = {Lanthanide Luminescence Revealing the Phase Composition in Hydrating Cementitious Systems},
  series = {ChemistryOpen},
  volume    = {8},
  journal   = {ChemistryOpen},
  number    = {12},
  publisher = {Wiley-VCH-Verl.},
  address   = {Weinheim},
  issn      = {2191-1363},
  doi       = {10.1002/open.201900249},
  pages     = {1441 -- 1452},
  year      = {2019},
  abstract  = {The hydration process of Portland cement in a cementitious system is crucial for development of the high-quality cement-based construction material. Complementary experiments of X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and time-resolved laser fluorescence spectroscopy (TRLFS) using europium (Eu(III)) as an optical probe are used to analyse the hydration process of two cement systems in the absence and presence of different organic admixtures. We show that different analysed admixtures and the used sulphate carriers in each cement system have a significant influence on the hydration process, namely on the time-dependence in the formation of different hydrate phases of cement. Moreover, the effect of a particular admixture is related to the type of sulphate carrier used. The quantitative information on the amounts of the crystalline cement paste components is accessible via XRD analysis. Distinctly different morphologies of ettringite and calcium-silicate-hydrates (C-S-H) determined by SEM allow visual conclusions about formation of these phases at particular ageing times. The TRLFS data provides information about the admixture influence on the course of the silicate reaction. The dip in the dependence of the luminescence decay times on the hydration time indicates the change in the structure of C-S-H in the early hydration period. Complementary information from XRD, SEM and TRLFS provides detailed information on distinct periods of the cement hydration process.},
  language  = {en}
}
@article{BurekKrauseSchwotzeretal.2018,
  author    = {Burek, Katja and Krause, Felix and Schwotzer, Matthias and Nefedov, Alexei and S{\"u}ssmuth, Julia and Haubitz, Toni and Kumke, Michael Uwe and Thissen, Peter},
  title     = {Hydrophobic Properties of Calcium-Silicate Hydrates Doped with Rare-Earth Elements},
  series = {ACS sustainable chemistry \& engineering},
  volume    = {6},
  journal   = {ACS sustainable chemistry \& engineering},
  number    = {11},
  publisher = {American Chemical Society},
  address   = {Washington},
  issn      = {2168-0485},
  doi       = {10.1021/acssuschemeng.8b03244},
  pages     = {14669 -- 14678},
  year      = {2018},
  abstract  = {In this study, the apparent relationship between the transport process and the surface chemistry of the Calcium-Silicate Hydrate (CSH) phases was investigated. For this purpose, a method was developed to synthesize ultrathin CSH phases to be used as a model substrate with the specific modification of their structure by introducing europium (Eu(III)). The structural and chemical changes during this Eu(III)-doping were observed by means of infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), and time-resolved laser fluorescence spectroscopy (TRLFS). These alterations of the CSH phases led to significant changes in the surface chemistry and consequently to considerable variations in the interaction with water, as evidenced by measurements of the contact angles on the modified model substrates. Our results provide the basis for a more profound molecular understanding of reactive transport processes in cement-based systems. Furthermore, these results broaden the perspective of improving the stability of cement-based materials, which are subjected to the impact of aggressive aqueous environments through targeted modifications of the CSH phases.},
  language  = {en}
}