@article{VidadalaPimpalpalleLinkeretal.2011, author = {Vidadala, Srinivasa Rao and Pimpalpalle, Tukaram M. and Linker, Torsten and Hotha, Srinivas}, title = {Gold-Catalyzed reactions of 2-C-Branched carbohydrates mild glycosidations and selective anomerizations}, series = {European journal of organic chemistry}, journal = {European journal of organic chemistry}, number = {13}, publisher = {Wiley-Blackwell}, address = {Malden}, issn = {1434-193X}, doi = {10.1002/ejoc.201100134}, pages = {2426 -- 2430}, year = {2011}, abstract = {2-C-branched methyl glycosides react with various alcohols under gold catalysis to transglycosylated products. The method is applicable for the convenient synthesis of disaccharides. Without nucleophile a selective anomerization occurs, giving first access to alpha-configured 2-C-nitromethyl glycosides. The results are interesting for the mechanism of gold-catalyzed glycosidations.}, language = {en} }