@article{vonKlitzingStehlPogrzebaetal.2017, author = {von Klitzing, Regine and Stehl, Dimitrij and Pogrzeba, Tobias and Schoma{\"a}cker, Reinhard and Minullina, Renata and Panchal, Abhishek and Konnova, Svetlana and Fakhrullin, Rawil and Koetz, Joachim and Moehwald, Helmuth and Lvov, Yuri}, title = {Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins}, series = {Advanced materials interfaces}, volume = {4}, journal = {Advanced materials interfaces}, number = {1}, publisher = {Wiley}, address = {Hoboken}, issn = {2196-7350}, doi = {10.1002/admi.201600435}, pages = {8}, year = {2017}, abstract = {Halloysites as tubular alumosilicates are introduced as inexpensive natural nanoparticles to form and stabilize oil-water emulsions. This stabilized emulsion is shown to enable efficient interfacial catalytic reactions. Yield, selectivity, and product separation can be tremendously enhanced, e.g., for the hydroformylation reaction of dodecene to tridecanal. In perspective, this type of formulation may be used for oil spill dispersions. The key elements of the described formulations are clay nanotubes (halloysites) which are highly anisometric, can be filled by helper molecules, and are abundantly available in thousands of tons, making this technology scalable for industrial applications.}, language = {en} }