@article{MarsatHeydenreichKleinpeteretal.2011,
  author    = {Marsat, Jean-Noel and Heydenreich, Matthias and Kleinpeter, Erich and Berlepsch, Hans V. and Boettcher, Christoph and Laschewsky, Andr{\´e}},
  title     = {Self-Assembly into multicompartment micelles and selective solubilization by Hydrophilic-Lipophilic-Fluorophilic block copolymers},
  series = {Macromolecules : a publication of the American Chemical Society},
  volume    = {44},
  journal   = {Macromolecules : a publication of the American Chemical Society},
  number    = {7},
  publisher = {American Chemical Society},
  address   = {Washington},
  issn      = {0024-9297},
  doi       = {10.1021/ma200032j},
  pages     = {2092 -- 2105},
  year      = {2011},
  abstract  = {Amphiphilic linear ternary block copolymers (ABC) were synthesized in three consecutive steps by the reversible addition fragmentation chain transfer (RAFT) method. Using oligo(ethylene oxide) monomethyl ether acrylate, benzyl acrylate, and 1H,1H-perfluorobutyl acrylate monomers, the triblock copolymers consist of a hydrophilic (A), a lipophilic (B), and a fluorophilic (C) block. The block sequence of the triphilic copolymers was varied systematically to provide all possible variations: ABC, ACB, and BAC. All blocks have glass transition temperatures below 0 degrees C. Self-assembly into spherical micellar aggregates was observed in aqueous solution, where hydrophobic cores undergo local phase separation into various ultrastructures as shown by cryogenic transmission electron microscopy (cryo-TEM). Selective solubilization of substantial quantities of hydrocarbon and fluorocarbon low molar mass compounds by the lipophilic and fluorophilic block, respectively, is demonstrated.},
  language  = {en}
}
@article{MarsatStahlhutLaschewskyetal.2013,
  author    = {Marsat, Jean-Noel and Stahlhut, Frank and Laschewsky, Andr{\´e} and von Berlepsch, Hans and B{\"o}ttcher, Christoph},
  title     = {Multicompartment micelles from silicone-based triphilic block copolymers},
  series = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft},
  volume    = {291},
  journal   = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft},
  number    = {11},
  publisher = {Springer},
  address   = {New York},
  issn      = {0303-402X},
  doi       = {10.1007/s00396-013-3001-2},
  pages     = {2561 -- 2567},
  year      = {2013},
  abstract  = {An amphiphilic linear ternary block copolymer was synthesised in three consecutive steps via reversible addition-fragmentation chain transfer polymerisation. Oligo(ethylene glycol) monomethyl ether acrylate was engaged as a hydrophilic building block, while benzyl acrylate and 3-tris(trimethylsiloxy)silyl propyl acrylate served as hydrophobic building blocks. The resulting "triphilic" copolymer consists thus of a hydrophilic (A) and two mutually incompatible "soft" hydrophobic blocks, namely, a lipophilic (B) and a silicone-based (C) block, with all blocks having glass transition temperatures well below 0 A degrees C. The triphilic copolymer self-assembles into spherical multicompartment micellar aggregates in aqueous solution, where the two hydrophobic blocks undergo local phase separation into various ultrastructures as evidenced by cryogenic transmission electron microscopy. Thus, a silicone-based polymer block can replace the hitherto typically employed fluorocarbon-based hydrophobic blocks in triphilic block copolymers for inducing multicompartmentalisation.},
  language  = {en}
}
@phdthesis{Marsat2009,
  author    = {Marsat, Jean-Noel},
  title     = {Synthesis and study of multicompartment micelles},
  address   = {Potsdam},
  pages     = {98 Bl. : Ill., graph. Darst.},
  year      = {2009},
  language  = {en}
}