@article{TiseanuKumkeParvulescuetal.2008, author = {Tiseanu, Carmen and Kumke, Michael Uwe and Parvulescu, Vasile Ion and Geßner, Andre and Gagea, Bogdan and Martens, Johan}, title = {Europium(3+) : an efficient luminescence probe for the Si to Al ratio and silylation effect in the microporous- mesoporous Zeogrid materials}, doi = {10.1021/Jp711337h}, year = {2008}, language = {en} } @article{TiseanuLorenzFonfriaGessneretal.2009, author = {Tiseanu, Carmen and Lorenz-Fonfria, Victor A. and Geßner, Andr{\´e} and Kumke, Michael Uwe and Gagea, Bogdan}, title = {Comparative luminescence study of terbium-exchanged zeolites silylated with alkoxysilanes}, issn = {0957-4522}, doi = {10.1007/s10854-008-9597-1}, year = {2009}, abstract = {Terbium-exchanged ZSM-5, MOR and (H)BEA zeolites were silylated with phenyl-, vinyl- and hexadecyl trimethoxysilanes via a post-synthesis grafting. All samples were investigated by means of PXRD, FT-IR, TGA, physical adsorption, DR-UV-Vis and time-resolved photoluminescence spectroscopy. From the comparison of the photoluminescence decays of terbium-exchanged in parent (non-silylated) and silylated zeolites, it resulted that the silylation efficiency of the various alkoxysilanes is determined by the type of zeolite and follows the sequences: phenyl > vinyl > hexadecyl > parent for ZSM-5, hexadecyl a parts per thousand phenyl a parts per thousand vinyl > parent for MOR and hexadecyl > phenyl a parts per thousand vinyl > a parts per thousand parent for BEA zeolites, respectively.}, language = {en} } @article{TiseanuGessnerKumkeetal.2008, author = {Tiseanu, Carmen and Geßner, Andre and Kumke, Michael Uwe and Gagea, Bogdan and Parvulescu, Vasile Ion and Martens, Johan}, title = {Photoluminescence spectra and dynamics of lanthanide-doped microporous materials}, doi = {10.1016/j.jlumin.2007.10.018}, year = {2008}, abstract = {A series of terbium- and europium-exchanged microporous-mesoporous zeolite Socony Mobil Five (MFI)-type materials such as Zeotile-1 and Zeogrid with varying Si/Al ratios was investigated using FTIR, PXRD, adsorption- desorption isotherms of N-2 at 77 K and time-resolved luminescence spectroscopy. Silylation of the lanthanides-exchanged Zeotile-1 and Zeogrid with hexadecyl trimethoxysilanes via post-synthesis grafting was also studied. The results showed that the lanthanide's photoluminescence spectra and decays were modified due to silylation. The different silylation effects in Zeotile-1 and Zeogrid were correlated with the textural properties of the investigated materials. (C) 2007 Elsevier B.V. All rights reserved.}, language = {en} }