@article{GlatzelNoackSchanzenbachetal.2020, author = {Glatzel, Julia and Noack, Sebastian and Schanzenbach, Dirk and Schlaad, Helmut}, title = {Anionic polymerization of dienes in 'green' solvents}, series = {Polymer international}, volume = {70}, journal = {Polymer international}, number = {2}, publisher = {Wiley}, address = {Hoboken}, issn = {0959-8103}, doi = {10.1002/pi.6152}, pages = {181 -- 184}, year = {2020}, abstract = {Isoprene and beta-myrcene were polymerized by anionic polymerization in bulk and in the 'green' ether solvents cyclopentyl methyl ether and 2-methyltetrahydrofuran and, for comparison, in cyclohexane and tetrahydrofuran. The polydienes produced in bulk and in cyclohexane contained high amounts of 1,4 units (>90\%) whereas those produced in ether solvents were rich in 1,2 and 3,4 units (36\%-86\%). Comparison of the microstructures and glass transition temperatures of the polydienes obtained in the various solvents suggests that conventionally used solvents can be substituted by environmentally more friendly alternatives.}, language = {en} }