@article{ShainyanKirpichenkoKleinpeter2012, author = {Shainyan, Bagrat A. and Kirpichenko, Svetlana V. and Kleinpeter, Erich}, title = {Synthesis and conformational properties of 1,3-dimethyl-3-phenyl-1,3-azasilinane low temperature dynamic NMR and computational study}, series = {Arkivoc : free online journal of organic chemistry}, journal = {Arkivoc : free online journal of organic chemistry}, number = {24}, publisher = {ARKAT}, address = {Gainesville}, issn = {1551-7004}, pages = {175 -- 185}, year = {2012}, abstract = {1,3-Dimethyl-3-phenyl-1,3-azasilinane was synthesized and its conformational behavior was studied by the low temperature NMR spectroscopy and quantum chemical calculations. The compound was shown to exist as an equilibrium mixture of the PhaxMeeq and PheqMeax chair conformers with the N-methyl substituent in equatorial position. The barrier to ring inversion was also determined.}, language = {en} }