@article{BreiterFoersterSkoda2006, author = {Breiter, Karel and F{\"o}rster, Hans-J{\"u}rgen and Skoda, Radek}, title = {Extreme P-, Bi-, Nb-, Sc-, U- and F-rich zircon from fractionated perphosphorous granites: the peraluminous Podlesi granite system, Czech Republic}, issn = {0024-4937}, doi = {10.1016/j.lithos.2005.08.011}, year = {2006}, abstract = {The strongly peraluminous and P-rich, protolithionite and zinnwaldite leucogranites from Podlesi, western Krusne Hory Mts., Czech Republic, contain accessory zircon with extraordinary enrichment of several elements, which constitute trace elements in common zircon. Elements showing a not yet reported anomalous enrichment include P (up to 20.2 wt.\% P2O5; equivalent to 0.60 apfu, formula calculated on the basis of 4 oxygen atoms), Bi (up to 9.0 wt.\% Bi2O3; 0.086 apfu), Nb (up to 6.7 wt.\% Nb2O5, 0.12 apfu), Sc (up to 3.45 wt.\% Sc2O3; 0.10 apfu), U (up to 14.8 wt.\% UO2; 0.12 apfu) and F (up to 3.81 wt.\% F; 0.42 apfu). Strong enrichment of P preferentially involved the berlinite-type substitution (2 Si4+ double left right arrow P5+ + Al3+) implying that significant Al may enter the Si position in zircon. Incorporation of other exotic elements is primarily governed by the xenotime (Si4++Zr4+ double left right arrow P5++Y3+), pretulite (Sc3++P5+ double left right arrow Zr4++Si4+), brabantite-type (Ca2++(U, Th)(4+)+2P(5+) double left right arrow 2Zr(4+)+2Si(4+)), and ximengite-type (Bi3++P5+double left right arrow Zr4++Si4+) substitution reactions. One part of the anomalous zircons formed late-magmatically, from a strongly peraluminous, P-F-U-rich hydrous residual melt that gave rise to the zinnwaldite granite. Interaction with aggressive residual fluids and metamictization have further aided in element enrichment or depletion, particularly in altered parts of zircon contained in the protolithionite granite. Most of the zircon from F-rich greisens have a composition close to endmember ZrSiO4 and are chemically distinct from zircon in its granite parent. This discrepancy implies that at Podlesi, granitic zircon became unstable and completely dissolved during greisenization. Part of the mobilized elements was reprecipitated in newly grown, hydrothermal zircon.}, language = {en} } @article{FuchsFoersterBrauneetal.2018, author = {Fuchs, Sven and F{\"o}rster, Hans-J{\"u}rgen and Braune, K. and F{\"o}rster, A.}, title = {Calculation of Thermal Conductivity of Low-Porous, Isotropic Plutonic Rocks of the Crust at Ambient Conditions From Modal Mineralogy and Porosity}, series = {Journal of geophysical research : Solid earth}, volume = {123}, journal = {Journal of geophysical research : Solid earth}, number = {10}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9313}, doi = {10.1029/2018JB016287}, pages = {8602 -- 8614}, year = {2018}, abstract = {Thermal conductivity (lambda) is an essential physical property of minerals and rocks and fundamental in constraining the thermal field of the lithosphere. In case that adequate samples to measure lambda are not available, it could be indirectly inferred from calculation. One of the most widely applied indirect methods for rocks involve modal mineralogy and porosity as parameters that are incorporated into mathematical mean or mixing models. Robust inferences from these approaches for crystalline rocks were impeded by a small number of studied samples or restriction to certain rock types. We employ this method and examine its applicability to low-porosity plutonic rocks by calculating bulk thermal conductivity lambda(b) for 45 samples covering the entire range from gabbro/diorite to granite. We show that the use of the harmonic-mean model for both rock matrix and porosity provided a good match between lambda(b.meas) and lambda(b.calc) of <10\% deviation (2 sigma), with relative and absolute errors amounting to 1.49.7\% and 4.44.9\%, respectively. The results of our study constitute a big step forward to a robust conclusion on the overall applicability of the harmonic-mean model for inferring lambda(b) of isotropic, low-porosity, mafic to silicic plutonic and metamorphic rocks with an acceptable magnitude of error. Drill cuttings and enclaves form particularly interesting objects for application of this method, as they are poorly suited for direct measurement. Well-derived lambda values for those rocks would permit to calculate heat flow and to model more profoundly the thermal state of the deeper lithosphere.}, language = {en} } @article{Foerster2006, author = {F{\"o}rster, Hans-J{\"u}rgen}, title = {Composition and origin of intermediate solid solutions in the system thorite-xenotime-zircon-coffinite}, issn = {0024-4937}, doi = {10.1016/j.lithos.2005.08.003}, year = {2006}, abstract = {A comprehensive survey of the accessory-mineral assemblages in Variscan granites of the German Erzgebirge and Pan-African granites from Jordan revealed the occurrence of intermediate solid solutions of the tetragonal thorite- xenotime-zircon-coffinite mineral group with partially novel compositions. These solid solutions preferentially formed in evolved and metasomatically altered, P-poor leucogranites of either I- or A-type affinity. Thorite from the Erzgebirge contained up to 18-8 Wt-\% Y2O3, 16.1 wt.\% ZrO2, and 23.3 Wt-\% UO2. Xenotime and zircon have incorporated Th in abundances up to 36.3 wt.\% and 41.8 wt.\% ThO2, respectively. Extended compositional gradation with only minor gaps is confined to hydrated members of this mineral group, and is observed to exist between thorite and xenotime, thorite and coffinite, and Y-HREE-bearing thorite and zircon. Complex, hydrous solid solutions containing elevated abundances of three or more of the endmembers are subordinate. Previously reported intermediate solid solutions between anhydrous zircon and xenotime, and anhydrous zircon and thorite, are not observed and are in conflict with experimental work demonstrating very limited miscibility between anhydrous species of endmember composition. The majority of hydrous intermediate solid solutions in the Th-Y-Zr-U system are likely thermodynamically unstable. Instead, they are probably metastable responses to unusual physico-chemical conditions involving various parameters and conditions, the relative importance of which is incompletely known. Leaching and dissolution of preexisting accessory phases during interaction with F-bearing hydrous fluids enriched in Th, Y(HREE), Zr, and/or U, and common deposition of the various elements at disequilibrium (supersaturation) seems to play a key role, but other processes may be of similar importance. Experimental work involving hydrous conditions and complex systems composed of more than two endmembers are needed to shed light into the stability relations of the chemically uncommon compositions treated in this study.}, language = {en} } @article{Foerster2005, author = {F{\"o}rster, Hans-J{\"u}rgen}, title = {Mineralogy of the U-Se-polymetallic deposit Niederschlema-Alberoda, Erzgebirge, Germany : IV. The continuous clausthalite-galena solid-solution series}, year = {2005}, abstract = {In a sample from the Niederschlema-Alberoda U-Se-polymetallic deposit, western Erzgebirge, Germany, the entire PbSe-PbS solid-solution series was observed associated with uraninite, coffinite, hematite, acanthite, sphalerite, chalcopyrite, pyrite, and lollingite. Early deposited, Se-rich members of the Pb(Se, S) series occur as fracture fillings inside spherical uraninite or on its surface or form anhedral to subhedral grains precipitated in the immediate neighbourhood of the U minerals. Later crystallized, S-rich members of the series are affiliated with the sulfide minerals. The solid-solution series covers the range PbS1.00-Pb(S0.04Se0.96)(\&USigma; 1.00) virtually free of gaps, consistent with a temperature of formation of \&GE; 100° C. The PbSe-PbS solid solutions were likely deposited from hydrothermal fluids that became successively depleted in Se and enriched in S. The fugacities of selenium and sulfur covered the range -17 < logfSe(2) < -26 and -17 < logfS(2) < -22, respectively, implying fSe(2)/fS(2) \&LE; 1. The spherical texture of the uraninite, as well as its U-Th-total Pb age (192 ± 21 Ma), imply deposition of the Pb(Se, S) series during the Jurassic, contemporaneous with the formation of the bulk of the other selenium minerals. The electron-microprobe data from this study confirm earlier inferences on complete miscibility between clausthalite and galena deduced from X-ray patterns of PbSe-PbS solid solutions from different uranium-vanadium deposits of the Colorado Plateau (COLEMAN 1959). In Niederschlema-Alberoda, the entire clausthalite-galena series occurs in a single section}, language = {en} } @article{Foerster2004, author = {F{\"o}rster, Hans-J{\"u}rgen}, title = {Mineralogy of the Niederschlema-Alberoda U-Se-polymetallic deposit, Erzgebirge, Germany : II: Hessite, Ag2Te, and native Te (?), the first tellurium minerals}, year = {2004}, abstract = {Hessite, Ag2Te, and native tellurium (?) constitute two, previously unknown tellurium species within the complex mineral assemblage at Niederschlema-Alberoda, Erzgebirge, Germany. Hessite is always intimately associated with clausthalite and has a composition close to ideal stoichiometry. The mean empirical formula is (Ag1.98Sb0.01)(1.99)(Te0.96Se0.05)(1.01). Paragenetic relations and thermodynamic data suggest that hessite crystallized in equilibrium with clausthalite, berzelianite, and tiemannite under conditions of almost identical, high fugacitities of Se-2 and Te-2, which very locally were approached in the main selenide stage of Jurassic age. Native tellurium (?) formed as replacement product of hessite. Niederschlema-Alberoda provides the first record of hessite from an uranium deposit worldwide. Hessite and native Te are the first tellurium minerals reported from the Erzgebirge metallogenic province}, language = {en} } @article{FoersterFoersterOberhaenslietal.2010, author = {F{\"o}rster, Hans-J{\"u}rgen and F{\"o}rster, Andrea and Oberh{\"a}nsli, Roland and Stromeyer, Dietrich}, title = {Lithospheric composition and thermal structure of the Arabian Shield in Jordan}, issn = {0040-1951}, doi = {10.1016/j.tecto.2008.11.014}, year = {2010}, abstract = {In this paper, a unique set of samples from the uppermost crust down to the lithospheric mantle of Jordan is analyzed for composition and petrophysical properties (density. thermal conductivity, radiogenic heat production) These data, covering a vertical section of almost 65 km. are used in conjunction with surface heat flow to generate a detailed and comprehensive lithospheric thermal model that reflects the conditions of the Arabian Shield (AS) prior to the post- Oligocene onset of lithosphere thinning and Voluminous basaltic volcanism. The pre-Miocene model geotherms, based on conductive surface heat flows of 55 and 60 mW m(-2). (a) meet the range of lithosphere-asthenosphere boundary depths of 110-160 km known from seismology, (b) conform to results of thermomechanical models on the on.-in of the Dead Sea basin that started in Miocene time. and (c) are consistent with typical xenolith-derived geotherms for terranes of similar age and lithospheric thickness. Moho temperatures (at depths between 35 and 40 km) of the AS in pre-Miocene times were most likely in the order of 530-650 degrees C, with mantle heat flows averaging between 24 and 29 mW m(-2) Results contradict former views of the late Proterozoic/early Cambrian-stabilized AS being an anomalously cold terrane A "cold" thermal structure inferred from previously measured low surface heat flows (generally <= 45 mW m(-2)) is inconsistent with the thickness, composition, and petrophysical properties of the stable lithosphere of the shield.}, language = {en} } @article{FoersterRhede2006, author = {F{\"o}rster, Hans-J{\"u}rgen and Rhede, Dieter}, title = {The Be-Ta-rich granite of Seiffen (eastern Erzgebirge, Germany)}, series = {Neues Jahrbuch f{\"u}r Mineralogie : Abhandlungen}, volume = {182}, journal = {Neues Jahrbuch f{\"u}r Mineralogie : Abhandlungen}, number = {3}, publisher = {Schweizerbart}, address = {Stuttgart}, issn = {0077-7757}, doi = {10.1127/0077-7757/2006/0055}, pages = {307 -- 321}, year = {2006}, abstract = {The mildly peraluminous granite of Seiffen, in the eastern Erzgebirge of Germany, is exposed by drillcores and associated with an abandoned Sri mine. The granite is of Stefanian age, with overlapping Th-U-total Pb monazite (302 +/- 4 Ma) and K-Ar siderophyllite ages (301 +/- 5 Ma). It is among the youngest granites in the Erzgebirge, emplaced in an extensional setting. The medium-grained, equigranular granite classifies as high-F, low-P Li-mica granite of A-type affinity. It is spatially associated with a high-Si rhyolitic microgranite, documenting the shallow intrusion level of this igneous association. Zircon, monazite-(Ce), and xenotime-(Y) constitute important radioactive accessory minerals in the granite, hosting the major proportions (> 80-90\%) of the bulk-rock budgets of the REE, Y, and Th. A significant percentage of U (40-50\%) may reside within unidentified phases or precipitated along grain boundaries. The most uncommon accessory phase is late-magmatic ytterbian xenotime-(Y) containing up to 11.2 wt\% Yb2O3, in addition to 7.3 wt\% Er2O3 and 7.9 wt\% Dy2O3. The Seiffen granite (epsilon(Nd(300)) = -4.6) is geochemically evolved and rich in Sri (23-63 ppm) and W (11-14 ppm). It contains elevated to high concentrations of incompatible lithophile elements such as F, Li, Ga, Rb, Y, Nb, Cs, REE, Th, and U, thus having much in common chemically with subvolcanic ongonites. The most prominent compositional feature is the strong enrichment (in ppm) in Be (51-55) and Ta (23-28). The granite exhibits flat chondrite-normalized REE patterns (La-N/Lu-N = 1.35-1.48) and a moderate negative Eu anomaly (Eu/Eu* = 0.12-0.13). Indications for alteration-induced, postmagmatic disturbances of initial elemental abundances are weak and mainly relate to the ore-forming elements Sri and U.}, language = {en} } @article{FoersterRhede2004, author = {F{\"o}rster, Hans-J{\"u}rgen and Rhede, Dieter}, title = {Mineralogy of the Niederschlema-Alberoda U-Se-polymetallic deposit, Erzgebirge, Germany : III. First indication of complete miscibility between tennantite and giraudite}, year = {2004}, language = {en} } @article{FoersterRhedeTischendorf2004, author = {F{\"o}rster, Hans-J{\"u}rgen and Rhede, Dieter and Tischendorf, Gerhard}, title = {Mineralogy of the Niederschlema-Alberoda U-Se-polymetallic deposit, Erzgebirge, Germany : I. Jolliffeite, NiAsSe, the rare Se-dominant analogue of gersdorffite}, year = {2004}, abstract = {The Niederschlema-Alberoda uranium deposit, in the Erzgebirge region of Germany, contains an uncommon assemblage of metallic minerals, in particular selenides, sulfides, arsenides, tellurides, and native elements, in addition to uraninite and coffinite. The complex mineralogy resulted from the superposition of several mineralizing events over the time interval from the Permian to the Cretaceous; these events introduced and redeposited a great variety of metallic elements within the hydrothermal uranium deposit (Pb, Ag, Cu, Hg, Tl, Bi, Co, Ni, As, Sb, Se, S, Te). One of the exotic minerals is jolliffeite, an arsenoselenide with end-member composition NiAsSe, so far only known from Lake Athabasca, Saskatchewan, Canada. A single, small, anhedral grain of jolliffeite from Niederschlema-Alberoda is included and partly replaced by sulfurian eskebornite. Associated minerals comprise hematite, Ni-Co-Se-bearing lollingite, clausthalite, tiemannite, mercurian hakite-giraudite solid solutions, sulfurian berzelianite, sulfurian umangite, hessite, Ni-Co-As-bearing pyrite, and Se-rich chalcopyrite. The sulfurian jolliffeite has the empirical formula (Ni0.85Cu0.09Co0.05Fe0.02Ag0.01)Sigma(1.02)As(0.98)(Se0.77S0.23)(Sigma1. 00) and differs from type jolliffeite mainly by substantial substitution of Cu (2.6-3.3 wt.\%) for Ni and S (3.2-4.1 wt.\%) for Se. Substantial S-for-Se substitution in jolliffeite implies extensive and probably complete miscibility between NiAsSe and its S-dominant analogue, gersdorffite-Pa3 (NiAsS). We suggest that a localized accumulation of Ni and As in the Se-(S)-bearing hydrothermal fluid gave rise to the crystallization of jolliffeite at some rare locations at a late stage of formation of the Jurassic selenide assemblage}, language = {en} } @article{FoersterRomerGottesmannetal.2009, author = {F{\"o}rster, Hans-J{\"u}rgen and Romer, Rolf L. and Gottesmann, B{\"a}rbel and Tischendorf, Gerhard and Rhede, Dieter}, title = {Are the granites of the Aue-Schwarzenberg Zone (Erzgebirge, Germany) a major source for metalliferous ore deposits? : a geochemical, Sr-Nd-Pb isotopic, and geochronological study}, issn = {0077-7757}, doi = {10.1127/0077-7757/2009/0138}, year = {2009}, abstract = {The Aue-Schwarzenberg Granite Zone (ASGZ), in the western Erzgebirge of Germany, is composed of small, late- Variscan F-poor biotite and two-mica granites. The biotite granites (Aue granite suite, Beierfeld, Bernsbach) are weakly to mildly peraluminous (A/CNK = 1.07-1.14; 70-76 wt\% SiO2), display similar Sr-87/Sr-86 initial ratios (0.7065-0.7077; t = 325 Ma), and exhibit a narrow range in epsilon Nd-325 (-2.6 to -3.5). They are closely affiliated compositionally with the biotite granites in the distant, more voluminous Nejdek massif (Czech Republic). The two-mica granites (Schwarzenberg granite suite, Lauter) are Si-rich (74-77 wt\% SiO2) and mildly to strongly peraluminous (A/CNK = 1.17- 1.26). The granites from Schwarzenberg Lire distinctly higher in their Sr(i)ratios (0.709-0.713; t = 325 Ma) and possess lower values of epsilon Nd-325 (-4.9 to -5.2) relative to the biotite granites. The Lauter granites have a Nd-isotopic composition between -3.6 and -4.0 (t = 325 Ma). Mean Th-U-total Pb uraninite ages (Ma +/- 2 sigma) obtained for the granites from the Aue Suite (324.3 +/- 3. 1), Beierfeld (323.7 +/- 3.1), Bernsbach (320.7 +/- 2.9), Schwarzenberg (323.3 +/- 2.4), and the Kirchberg granite al Burkersdorf (322.7 +/- 3.5) indicate that magmatism in the ASGZ commenced in the Namurian and took place early within the major episode of granite formation in the Erzgebirge-Vogtland zone (327-318 Ma). Geochemical and mineralogical patterns of variably altered samples imply that the ASGZ granites are unlikely to have significantly contributed to the formation of spatially associated metalliferous ore deposits (Sn, W, Mo, Ph, Zn, Bi, Co, Ni), except for uranium. In particular the Aue granite suite should have served as major Source for U accumulated in the economically important post-granitic deposits of Schneeberg and Schlema-Alberoda.}, language = {en} }