@article{FrickSchuesslerSommeretal.2018,
  author    = {Frick, Daniel Alexander and Sch{\"u}ßler, Jan Arne and Sommer, Michael and von Blanckenburg, Friedhelm},
  title     = {Laser Ablation In Situ Silicon Stable Isotope Analysis of Phytoliths},
  series = {Geostandards and geoanalytical research},
  volume    = {43},
  journal   = {Geostandards and geoanalytical research},
  number    = {1},
  publisher = {Wiley},
  address   = {Hoboken},
  issn      = {1639-4488},
  doi       = {10.1111/ggr.12243},
  pages     = {77 -- 91},
  year      = {2018},
  abstract  = {Silicon is a beneficial element for many plants and is deposited in plant tissue as amorphous bio-opal called phytoliths. The biochemical processes of silicon uptake and precipitation induce isotope fractionation: the mass-dependent shift in the relative abundances of the stable isotopes of silicon. At the bulk scale, delta Si-30 ratios span from -2 to +6 parts per thousand. To further constrain these variations in situ, at the scale of individual phytolith fragments, we used femtosecond laser ablation multi-collector inductively coupled plasma-mass spectrometry (fsLA-MC-ICP-MS). A variety of phytoliths from grasses, trees and ferns were prepared from plant tissue or extracted from soil. Good agreement between phytolith delta Si-30 ratios obtained by bulk solution MC-ICP-MS analysis and in situ isotope ratios from fsLA-MC-ICP-MS validates the method. Bulk solution analyses result in at least twofold better precision for delta Si-30 (2s on reference materials <= 0.11 parts per thousand) over that found for the means of in situ analyses (2s typically <= 0.24 parts per thousand). We find that bushgrass, common reed and horsetail show large internal variations up to 2 parts per thousand in delta Si-30, reflecting the various pathways of silicon from soil to deposition. Femtosecond laser ablation provides a means to identify the underlying processes involved in the formation of phytoliths using silicon isotope ratios.},
  language  = {en}
}
@article{FunkBusseSiegmundetal.2022,
  author    = {Funk, Roger and Busse, Jaqueline and Siegmund, Nicole and Sommer, Michael and Iturri, Laura Antonela and Panebianco, Juan E. and Avecilla, Fernando and Buschiazzo, Daniel},
  title     = {Phytoliths in particulate matter released by wind erosion on arable land in La Pampa, Argentina},
  series = {Frontiers in environmental science},
  volume    = {10},
  journal   = {Frontiers in environmental science},
  publisher = {Frontiers Media},
  address   = {Lausanne},
  issn      = {2296-665X},
  doi       = {10.3389/fenvs.2022.969898},
  pages     = {10},
  year      = {2022},
  abstract  = {Silicon (Si) is considered a beneficial element in plant nutrition, but its importance on ecosystems goes far beyond that. Various forms of silicon are found in soils, of which the phytogenic pool plays a decisive role due to its good availability. This Si returns to the soil through the decomposition of plant residues, where they then participate in the further cycle as biogenic amorphous silica (bASi) or so-called phytoliths. These have a high affinity for water, so that the water holding capacity and water availability of soils can be increased even by small amounts of ASi. Agricultural land is a considerable global dust source, and dust samples from arable land have shown in cloud formation experiments a several times higher ice nucleation activity than pure mineral dust. Here, particle sizes in the particulate matter fractions (PM) are important, which can travel long distances and reach high altitudes in the atmosphere. Based on this, the research question was whether phytoliths could be detected in PM samples from wind erosion events, what are the main particle sizes of phytoliths and whether an initial quantification was possible.Measurements of PM concentrations were carried out at a wind erosion measuring field in the province La Pampa, Argentina. PM were sampled during five erosion events with Environmental Dust Monitors (EDM). After counting and classifying all particles with diameters between 0.3 and 32 mu m in the EDMs, they are collected on filters. The filters were analyzed by Scanning Electron Microscopy and Energy Dispersive X-Ray analysis (SEM-EDX) to investigate single or ensembles of particles regarding composition and possible origins.The analyses showed up to 8.3 per cent being phytoliths in the emitted dust and up to 25 per cent of organic origin. Particles of organic origin are mostly in the coarse dust fraction, whereas phytoliths are predominately transported in the finer dust fractions. Since phytoliths are both an important source of Si as a plant nutrient and are also involved in soil C fixation, their losses from arable land via dust emissions should be considered and its specific influence on atmospheric processes should be studied in detail in the future.},
  language  = {en}
}