@phdthesis{Ide2008,
  author    = {Ide, Andreas Hans Peter},
  title     = {Self-Structuring of functionalized micro- and mesoporous organosilicas using boron-silane-precursors},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-23717},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {The structuring of porous silica materials at the nanometer scale and their surface functionalization are important issues of current materials research. Many innovations in chromatography, catalysis and electronic devices benefit from this knowledge. The work at hand is dedicated to the targeted design of functional organosilica materials. In this context a new precursor concept based on boron-silanes is presented. These precursors combine the properties of a structure directing group and a silica source by covalent borane linkage. Formation of the precursor is easily realized by a sequential two-step hydroboration, firstly on bis(triethoxysilyl)ethene, and secondly on an unsaturated structure directing moiety such as alkenes or polymers. The so prepared precursors self-organize when hydrolysis of their inorganic moiety takes place via an aggregation of their organic side chains into hydrophobic domains. In this way, the additional use of a surfactant as a template is not necessary. Chemical cleavage of these moieties (e.g. by ammonolysis or oxidative saponification) yields an organosilica where all functionalities are exclusively located at the pore wall and therefore accessible. The accessibility of the functionalities is a vital point for applications and is not necessarily granted for common silica functionalization approaches. Further advantages of the boron-silane concept are the possibility to introduce a variety of surface functionalities by heterolytic cleavage of the boron linker and the control of the pore morphology. For that purpose the covalent linkage of different alkyl groups and polymers was studied. Another aspect is the access to chiral boron silane precursors yielding functionalized mesoporous organosilica with chiral functionalities exclusively located at the pore walls after condensation and removal of the structure directing moiety. These materials possess great potential for applications documented by preliminary investigations on chiral resolution of a racemic mixture by HPLC and asymmetric catalysis. In the course of this work valuable insights into the targeted structuring and surface functionalization of organosilicas were gained. A promising outlook for further investigations is the extension of this concept by altering the structure directing moieties of the precursor. That way the morphology of the final organosilica might be controlled by for example mesogens. Furthermore, the use of the boron linker enables the introduction of multiple functionalities into organosilicas, making the obtained material unique in its performance.},
  language  = {en}
}
@phdthesis{Groenewolt2004,
  author    = {Groenewolt, Matthijs},
  title     = {Mesostrukturierte Materialien durch Neue Templatsysteme und Nutzung Mesopor{\"o}ser Silikate als Nano-Reaktoren},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-2515},
  school      = {Universit{\"a}t Potsdam},
  year      = {2004},
  abstract  = {In dieser Arbeit wird ein chemisches Abgussverfahren f{\"u}r selbstorganisierte Strukturen in L{\"o}sung verwendet, das es erm{\"o}glicht definierte por{\"o}se Materialien mit Strukturierung auf der Nanometerskala herzustellen. {\"A}hnlich wie beim Gussverfahren von Werkst{\"u}cken wird die Vorlage durch ein geeignetes Material abgebildet. Durch Entfernen dieser Vorlage erh{\"a}lt man ein por{\"o}ses (mit Hohlr{\"a}umen durchsetztes) Negativ derselben. Die auf diese Weise erhaltenen Materialien sind in mehrerer Hinsicht interessant: So lassen sich aus ihrer Morphologie R{\"u}ckschl{\"u}sse {\"u}ber die Natur der selbstorganisierten Strukturen erhalten, da der hier verwendete Abbildungsprozess selbst kleinste strukturelle Details erfasst. Die Hohlr{\"a}ume der synthetisierten por{\"o}sen Stoffe hingegen k{\"o}nnen als winzige Reaktionsgef{\"a}ße, sogenannte \"Nano-Reaktoren\" verwendet werden. Dies erm{\"o}glicht sowohl die Synthese von Nano-Partikeln, die auf anderem Wege nicht zug{\"a}nglich sind, als auch die M{\"o}glichkeit Einfl{\"u}sse der r{\"a}umlichen Restriktion auf die Reaktion zu untersuchen. Besonders r{\"a}umlich ausgedehnte Strukturen sollten hierbei Auff{\"a}lligkeiten zeigen. Somit ist die Gliederung der Arbeit vorgegeben: - Die Herstellung und Charakterisierung von por{\"o}sen Stoffen und selbstorganisierten Strukturen - Ihre Verwendung als \"Nano-Reaktor\"},
  subject      = {Nanopartikel},
  language  = {de}
}