@phdthesis{Borghini2020,
  author    = {Borghini, Alessia},
  title     = {Melt inclusions in mafic rocks as witnesses of metasomatism in the Bohemian Massif},
  doi       = {10.25932/publishup-47363},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-473639},
  school      = {Universit{\"a}t Potsdam},
  pages     = {205},
  year      = {2020},
  abstract  = {Orogenic peridotites represent portions of upper subcontinental mantle now incorporated in mountain belts. They often contain layers, lenses and irregular bodies of pyroxenite and eclogite. The origin of this heterogeneity and the nature of these layers is still debated but it is likely to involve processes such as transient melts coming from the crust or the mantle and segregating in magma conduits, crust-mantle interaction, upwelling of the asthenosphere and metasomatism. All these processes occur in the lithospheric mantle and are often related with the subduction of crustal rocks to mantle depths. In fact, during subduction, fluids and melts are released from the slab and can interact with the overlying mantle, making the study of deep melts in this environment crucial to understand mantle heterogeneity and crust-mantle interaction. The aim of this thesis is precisely to better constrain how such processes take place studying directly the melt trapped as primary inclusions in pyroxenites and eclogites. The Bohemian Massif, crystalline core of the Variscan belt, is targeted for these purposes because it contains orogenic peridotites with layers of pyroxenite and eclogite and other mafic rocks enclosed in felsic high pressure and ultra-high pressure crustal rocks. Within this Massif mafic rocks from two areas have been selected: the garnet clinopyroxenite in orogenic peridotite of the Granulitgebirge and the ultra-high pressure eclogite in the diamond-bearing gneisses of the Erzgebirge. In both areas primary melt inclusions were recognized in the garnet, ranging in size between 2-25 µm and with different degrees of crystallization, from glassy to polycrystalline. They have been investigated with Micro Raman spectroscopy and EDS mapping and the mineral assemblage is kumdykolite, phlogopite, quartz, kokchetavite, phase with a main Raman peak at 430 cm-1, phase with a main Raman peak at 412 cm-1, white mica and calcite with some variability in relative abundance depending on the case study. In the Granulitgebirge osumilite and pyroxene are also present, whereas calcite is one of the main phases in the Erzgebirge. The presence of glass and the mineral assemblage in the nanogranitoids suggest that they were former droplets of melt trapped in the garnet while it was growing. Glassy inclusions and re-homogenized nanogranitoids show a silicate melt that is granitic, hydrous, high in alkalis and weakly peraluminous. The melt is also enriched in both case studies in Cs, Pb, Rb, U, Th, Li and B suggesting the involvement of crustal component, i.e. white mica (main carrier of Cs, Pb, Rb, Li and B), and a fluid (Cs, Th and U) in the melt producing reaction. The whole rock in both cases mainly consists of garnet and clinopyroxene with, in Erzgebirge samples, the additional presence of quartz both in the matrix and as a polycrystalline inclusion in the garnet. The latter is interpreted as a quartz pseudomorph after coesite and occurs in the same microstructural position as the melt inclusions. Both rock types show a crustal and subduction zone signature with garnet and clinopyroxene in equilibrium. Melt was likely present during the metamorphic peak of the rock, as it occurs in garnet. Our data suggest that the processes most likely responsible for the formation of the investigated rocks in both areas is a metasomatic reaction between a melt produced in the crust and mafic layers formerly located in the mantle wedge for the Granulitgebirge and in the subducted continental crust itself in the Erzgebirge. Thus metasomatism in the first case took place in the mantle overlying the slab, whereas in the second case metasomatism took place in the continental crust that already contained, before subduction, mafic layers. Moreover, the presence of former coesite in the same microstructural position of the melt inclusions in the Erzgebirge garnets suggest that metasomatism took place at ultra-high pressure conditions. Summarizing, in this thesis we provide new insights into the geodynamic evolution of the Bohemian Massif based on the study of melt inclusions in garnet in two different mafic rock types, combining the direct microstructural and geochemical investigation of the inclusions with the whole-rock and mineral geochemistry. We report for the first time data, directly extracted from natural rocks, on the metasomatic melt responsible for the metasomatism of several areas of the Bohemian Massif. Besides the two locations here investigated, belonging to the Saxothuringian Zone, a signature similar to the investigated melt is clearly visible in pyroxenite and peridotite of the T-7 borehole (again Saxothuringian Zone) and the durbachite suite located in the Moldanubian Zone.},
  language  = {en}
}
@misc{BorghiniFerreroO'Brienetal.2019,
  author    = {Borghini, Alessia and Ferrero, Silvio and O'Brien, Patrick J. and Laurent, Oscar and G{\"u}nter, Christina and Ziemann, Martin Andreas},
  title     = {Cryptic metasomatic agent measured in situ in Variscan mantle rocks},
  series = {Postprints der Universit{\"a}t Potsdam : Mathematisch Naturwissenschaftliche Reihe},
  journal   = {Postprints der Universit{\"a}t Potsdam : Mathematisch Naturwissenschaftliche Reihe},
  number    = {976},
  issn      = {1866-8372},
  doi       = {10.25932/publishup-47459},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-474592},
  pages     = {207 -- 234},
  year      = {2019},
  abstract  = {Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschm{\"u}hle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Star{\´e}, Česk{\´e} Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.},
  language  = {en}
}
@article{BorghiniFerreroO’Brienetal.2019,
  author    = {Borghini, Alessia and Ferrero, Silvio and O'Brien, Patrick J. and Laurent, Oscar and G{\"u}nter, Christina and Ziemann, Martin Andreas},
  title     = {Cryptic metasomatic agent measured in situ in Variscan mantle rocks},
  volume    = {38},
  publisher = {Wiley-Blackwell},
  address   = {Oxford [u.a.]},
  issn      = {1525-1314},
  doi       = {10.1111/jmg.12519},
  pages     = {207 -- 234},
  year      = {2019},
  abstract  = {Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschm{\"u}hle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Star{\´e}, Česk{\´e} Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.},
  language  = {en}
}
@article{BorghiniFerreroWunderetal.2018,
  author    = {Borghini, Alessia and Ferrero, Silvio and Wunder, Bernd and Laurent, Oscar and Ziemann, Martin Andreas},
  title     = {Granitoid melt inclusions in orogenic peridotite and the origin of garnet clinopyroxenite},
  series = {Geology},
  volume    = {46},
  journal   = {Geology},
  number    = {11},
  publisher = {American Institute of Physics},
  address   = {Boulder},
  issn      = {0091-7613},
  doi       = {10.1130/G45316.1},
  pages     = {1007 -- 1010},
  year      = {2018},
  abstract  = {Granitic melt inclusions were found in layers of garnet clinopyroxenites from orogenic peridotites hosted in high-pressure felsic granulites of the Granulitgebirge, central Europe. The inclusions are both glassy and crystallized, and occur as clusters in the garnet. Microstructural features suggest that the inclusions formed while garnet was growing as a peritectic phase, likely alongside clinopyroxene. The chemistry of the melt, in particular its trace element signature, shows a crustal contribution, probably due to the involvement of phengite in the melt-producing reaction, most likely in the presence of a fluid. The presence of a granitoid melt in mantle rocks may be the result of localized melting of a phengite-bearing protolith either already present in the peridotites or, more likely, within the local deeply subducted crustal units. In the latter case, the melt would have infiltrated the peridotites and generated pyroxenite via metasomatism. In either case, the presence of granitoid inclusions in orogenic peridotite provides direct evidence for a genetic connection between a high-pressure crustal melt and garnet pyroxenites. The in situ characterization of these remnants of natural melt provides direct quantitative constraints on (one of) the agents responsible for the interaction between crust and mantle.},
  language  = {en}
}
@article{FerreroBorghiniWunderetal.2018,
  author    = {Ferrero, Silvio and Borghini, Alessia and Wunder, Bernd and Walle, Markus and G{\"u}nter, Christina and Ziemann, Martin Andreas},
  title     = {A treasure chest full of nanogranitoids},
  series = {Metamorphic Geology: Microscale to Mountain Belts},
  volume    = {478},
  journal   = {Metamorphic Geology: Microscale to Mountain Belts},
  publisher = {Geological Soc Publishing House},
  address   = {Bath},
  isbn      = {978-1-78620-400-4},
  issn      = {0305-8719},
  doi       = {10.1144/SP478.19},
  pages     = {13 -- 38},
  year      = {2018},
  abstract  = {The central European Bohemian Massif has undergone over two centuries of scientific investigation which has made it a pivotal area for the development and testing of modern geological theories. The discovery of melt inclusions in high-grade rocks, either crystallized as nanogranitoids or as glassy inclusions, prompted the re-evaluation of the area with an 'inclusionist' eye. Melt inclusions have been identified in a wide range of rocks, including felsic/perpotassic granulites, migmatites, eclogites and garnet clinopyroxenites, all the result of melting events albeit over a wide range of pressure/temperature conditions (800-1000°C/0.5-5 GPa). This contribution provides an overview of such inclusions and discusses the qualitative and quantitative constraints they provide for melting processes, and the nature of melts and fluids involved in these processes. In particular, data on trace-element signatures of melt inclusions trapped at mantle depths are presented and discussed. Moreover, experimental re-homogenization of nanogranitoids provided microstructural criteria allowing assessment of the conditions at which melt and host are mutually stable during melting. Overall this work aims to provide guidelines and suggestions for petrologists wishing to explore the fascinating field of melt inclusions in metamorphic terranes worldwide, based on the newest discoveries from the still-enigmatic Bohemian Massif.},
  language  = {en}
}