@article{AwadConradKochetal.2010,
  author    = {Awad, Duha Jawad and Conrad, Franziska and Koch, Andreas and Schilde, Uwe and Poeppl, Andreas and Strauch, Peter},
  title     = {1,10-phenanthroline-dithiolate mixed ligand transition metal complexes : synthesis, characterization and EPR spectroscopy},
  issn      = {0020-1693},
  doi       = {10.1016/j.ica.2010.01.021},
  year      = {2010},
  abstract  = {A series of new N2S2 mixed ligand transition metal complexes, where N-2 is phenanthroline and S-2 is 1,2- dithiooxalate (dto) or 1,2-dithiosquarate (dtsq), has been synthesized and characterized. IR spectra reveal that the 1,2- dithiolate ligands are coordinated via the sulfur atoms forming a N2S2 coordination sphere. The copper(II) complex [Cu(phen)(dto)] was studied by EPR spectroscopy as a diamagnetically diluted powder. The diamagnetic dilution resulted from doping of the copper complex into the isostructural host lattice of the nickel complex [Ni(phen)(dto)]. The electronic situation in the frontier orbitals of the copper complex calculated from the experimental data is compared to the results of EHT and DFT calculations. Furthermore, one side product, chlorobis(1,10-phenanthroline)copper(I) ethanol solvate hydrate [(phen)(2)CuCl]center dot C2H5OH center dot H2O, was formed by a reduction process and characterized by X-ray diffraction. In the crystal packing one-dimensional columns of dimers are formed, stabilized by significant pi-pi interactions.},
  language  = {en}
}
@article{WenzelWehseSchildeetal.2004,
  author    = {Wenzel, Barbara and Wehse, Burkhard and Schilde, Uwe and Strauch, Peter},
  title     = {1,2-Dithioquadratato- und 1,2-Dithiooxalatoindate(III) = 1,2-dithiosquarato- and 1,2-dithiooxalatoindates(III)},
  year      = {2004},
  abstract  = {Indium(III) chloride forms in water with potassium 1,2-dithiooxalate (dto) and potassium 1,2-dithiosquarate (dtsq) stable coordination compounds. Due to the higher bridging ability of the 1,2-dithiooxalate ligand in all cases only thiooxalate bridged binuclear complexes were found. From 1,2-dithioquadratate with an identical donor atom set mononuclear trischelates could be isolated. Five crystalline complexes, (BzlMe(3)N)(4)[(dto)(2)In(dto)In(dto)(2)] (1), (BzlPh(3)P)(4)[(dto)(2)In(dto)In(dto)(2)] (2), (BzlMe(3)N)(3)[In(dtsq)(3)] (3), (Bu4N)(3)[In(dtsq)(3)] (4) and (Ph4P)[In(dtsq)(2)(DMF)(2)] (5), have been isolated and characterized by X-ray analyses. Due to the type of the complex and the cations involved these compounds crystallize in different space groups with the following parameters: 1, monoclinic in P2(1)/c with a = 14.4035(5) Angstrom, b = 10.8141(5) Angstrom, c = 23.3698(9) Angstrom, beta = 124.664(2)degrees, and Z = 2; 2, triclinic in P (1) over bar with a = 11.3872(7) Angstrom, b = 13.6669(9) Angstrom, c = 17.4296(10) Angstrom, alpha = 88.883(5)degrees, beta = 96.763(1)degrees, gamma = 74.587(5)degrees, and Z = 1; 3, hexagonal in R3 with a = 20.6501(16) Angstrom, b = 20.6501(16) Angstrom, c = 19.0706(13) Angstrom and Z = 6; 4, monoclinic in P21/c with a = 22.7650(15) Angstrom, b = 20.4656(10) Angstrom, c = 14.4770(9) Angstrom, P},
  language  = {de}
}
@article{AwadConradKochetal.2010,
  author    = {Awad, Duha Jawad and Conrad, Franziska and Koch, Andreas and Friedrich, Alwin and Poeppl, Andreas and Strauch, Peter},
  title     = {2,2'-Bipyridin-1,2-dithiolat Gemischtligand-Komplexe : Systhese, Charakterisierung und EPR-Spektroskopie},
  issn      = {0932-0776},
  year      = {2010},
  abstract  = {A series of new 2 2'-bipyridine/1 2-dithiolate transition metal complexes has been synthesised and characterised As 1,2-dithiolate ligands 1,2 dithiooxalate (dto) and 1 2-dithiosquarate (dtsq) were used It follows from the IR spectra that the multidentate dithiolate ligands coordinate exclusively via their sulfur atoms forming an MN2S2 coordination sphere The central metal ions (M) are Cu2+ Ni2+ Pd2+ Pt2+, and Zn2+ The complex [Cu-II(bpy)(dto)] could be studied by EPR spectroscopy and was measured as powder diamagnetically diluted in the isostructural [Ni-II(bpy)(dto)] host structure The spin density contribution calculated from the experimental parameters is compared with the electronic situation in the frontier orbitals namely in the semi occupied SOMO of the copper complex derived from quantum chemical calculations on different levels (EHT and DFT)},
  language  = {de}
}
@article{StrehmelRexhausenStrauch2010,
  author    = {Strehmel, Veronika and Rexhausen, Hans and Strauch, Peter},
  title     = {2,2,6,6-Tetramethylpiperidine-1-yloxyl bound to the imidazolium ion by an acetamido group for investigation of ionic liquids},
  issn      = {0040-4039},
  doi       = {10.1016/j.tetlet.2009.11.124},
  year      = {2010},
  abstract  = {New spin probes bearing the 2,2,6,6-tetramethylpiperidine-1-yloxyl covalently bound to the imidazolium ion via a methylene spacer and an amide group are synthesized. If the anion is bis(trifluoromethylsulfonylimide) instead of iodide, the new spin probe has a similar structure as that of an ionic liquid. Nevertheless, the new spin probes are useful tools to investigate ionic liquids.},
  language  = {en}
}
@article{AwadSchildeStrauch2011,
  author    = {Awad, Duha Jawad and Schilde, Uwe and Strauch, Peter},
  title     = {4,4 '-Bis(tert-butyl)-2,2 '-bipyridinedichlorometal(II) - Synthesis, structure and EPR spectroscopy},
  series = {Inorganica chimica acta : the international inorganic chemistry journal},
  volume    = {365},
  journal   = {Inorganica chimica acta : the international inorganic chemistry journal},
  number    = {1},
  publisher = {Elsevier},
  address   = {Lausanne},
  issn      = {0020-1693},
  doi       = {10.1016/j.ica.2010.08.035},
  pages     = {127 -- 132},
  year      = {2011},
  abstract  = {Due to the better solubility of the 4,4'-substituted bipyridine ligand a series of 4,4'0-bis(tert-butyl)-2,2'-bipyridinedichlorometal(II) complexes, [M(tbbpy)Cl(2)], with M = Cu, Ni, Zn, Pd, Pt was synthesised and characterised. The blue copper complex 4,4'-bis(tert-butyl)-2,2'-bipyridinedichlorocopper(II) was isolated in two different polymorphic forms, as prisms 1 with a solvent inclusion and solvent-free as needles 2. Both structures were determined by X-ray structure analysis. They crystallise in the monoclinic space group P2(1)/c with four molecules in the unit cell, but with different unit cells and packing motifs. Whereas in the prisms 1, with the unit cell parameters a = 12.1613(12), b = 10.6363(7), c = 16.3074(15) angstrom, eta = 94.446(8)degrees, the packing is dominated by intra-and intermolecular hydrogen bonds, in the needles 2, with a = 7.738(1), b = 18. 333(2), c = 13.291(3) angstrom, beta = 97.512(15)degrees, only intramolecular hydrogen bonds appear and the complex molecules are arranged in columns which are stabilised by p-p-stacking interactions. In both complexes the copper has a tetrahedrally distorted coordination sphere. These copper complexes were also studied by EPR spectroscopy in solution, as frozen glass and diamagnetically diluted powder with the analogue [Pd(tbbpy)Cl(2)] as host lattice.},
  language  = {en}
}
@misc{KoenigKellingSchildeetal.2017,
  author    = {K{\"o}nig, Jana and Kelling, Alexandra and Schilde, Uwe and Strauch, Peter},
  title     = {[µ2-O,O′,Oʺ,Oʺ′-Bis(1,2-dithiooxalato-S,S′)nickel(II)]bis[-O,O′-bis(1,2-dithiooxalato-S,S′)-nickel(II)pentaquaholmium(III)]hydrate, [Ho2Ni3(dto)6(H2O)10]},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-400598},
  pages     = {5},
  year      = {2017},
  abstract  = {Planar bis(1,2-dithiooxalato)nickelate(II), [Ni(dto)]2- reacts in aqueous solutions with lanthanide ions (Ln3+) to form pentanuclear, hetero-bimetallic complexes of the general composition [{Ln(H2O)n}2{Ni(dto)2}3]·xH2O. (n = 4 or 5; x = 9-12). The complex [{Ho(H2O)5}2{Ni(dto)2}3]·10H2O, Ho2Ni3, was synthesized and characterized by single crystal X-ray structure analysis and powder diffraction. The Ho2Ni3 complex crystallizes as monoclinic crystals in the space group P21/c. The channels and cavities, appearing in the crystal packing of the complex molecules, are occupied by a varying amount of non-coordinated water molecules.},
  language  = {en}
}
@article{ThielZehbeRoesneretal.2013,
  author    = {Thiel, Kerstin and Zehbe, Rolf and Roesner, Jer{\^o}m{\´e} and Strauch, Peter and Enthaler, Stephan and Thomas, Arne},
  title     = {A polymer analogous reaction for the formation of imidazolium and NHC based porous polymer networks},
  doi       = {10.1039/C2PY20947K},
  year      = {2013},
  abstract  = {A polymer analogous reaction was carried out to generate a porous polymeric network with N-heterocyclic carbenes (NHC) in the polymer backbone. Using a stepwise approach, first a polyimine network is formed by polymerization of the tetrafunctional amine tetrakis(4-aminophenyl)methane. This polyimine network is converted in the second step into polyimidazolium chloride and finally to a polyNHC network. Furthermore a porous Cu(II)-coordinated polyNHC network can be generated. Supercritical drying generates polymer networks with high permanent surface areas and porosities which can be applied for different catalytic reactions. The catalytic properties were demonstrated for example in the activation of CO2 or in the deoxygenation of sulfoxides to the corresponding sulfides.},
  language  = {en}
}
@article{ThielZehbeRoeseretal.2013,
  author    = {Thiel, Kerstin and Zehbe, Rolf and R{\"o}ser, Jerome and Strauch, Peter and Enthaler, Stephan and Thomas, Arne},
  title     = {A polymer analogous reaction for the formation of imidazolium and NHC based porous polymer networks},
  series = {Polymer Chemistry},
  volume    = {4},
  journal   = {Polymer Chemistry},
  number    = {6},
  publisher = {Royal Society of Chemistry},
  address   = {Cambridge},
  issn      = {1759-9954},
  doi       = {10.1039/c2py20947k},
  pages     = {1848 -- 1856},
  year      = {2013},
  abstract  = {A polymer analogous reaction was carried out to generate a porous polymeric network with N-heterocyclic carbenes (NHC) in the polymer backbone. Using a stepwise approach, first a polyimine network is formed by polymerization of the tetrafunctional amine tetrakis(4-aminophenyl)methane. This polyimine network is converted in the second step into polyimidazolium chloride and finally to a polyNHC network. Furthermore a porous Cu(II)-coordinated polyNHC network can be generated. Supercritical drying generates polymer networks with high permanent surface areas and porosities which can be applied for different catalytic reactions. The catalytic properties were demonstrated for example in the activation of CO2 or in the deoxygenation of sulfoxides to the corresponding sulfides.},
  language  = {en}
}
@misc{ThielZehbeRoeseretal.2013,
  author    = {Thiel, Kerstin and Zehbe, Rolf and Roeser, Jer{\^o}m{\´e} and Strauch, Peter and Enthaler, Stephan and Thomas, Arne},
  title     = {A polymer analogous reaction for the formation of imidazolium and NHC based porous polymer networks},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-95118},
  pages     = {1848 -- 1856},
  year      = {2013},
  abstract  = {A polymer analogous reaction was carried out to generate a porous polymeric network with N-heterocyclic carbenes (NHC) in the polymer backbone. Using a stepwise approach, first a polyimine network is formed by polymerization of the tetrafunctional amine tetrakis(4-aminophenyl)methane. This polyimine network is converted in the second step into polyimidazolium chloride and finally to a polyNHC network. Furthermore a porous Cu(II)-coordinated polyNHC network can be generated. Supercritical drying generates polymer networks with high permanent surface areas and porosities which can be applied for different catalytic reactions. The catalytic properties were demonstrated for example in the activation of CO2 or in the deoxygenation of sulfoxides to the corresponding sulfides.},
  language  = {en}
}
@article{NeumannNoeskeBachetal.2011,
  author    = {Neumann, Mike and Noeske, Robert and Bach, Grete and Glaubauf, Thomas and Bartoszek, Michael and Strauch, Peter},
  title     = {A procedure for rapid determination of the silicon content in plant materials},
  series = {Zeitschrift f{\"u}r Naturforschung : B, Chemical sciences},
  volume    = {66},
  journal   = {Zeitschrift f{\"u}r Naturforschung : B, Chemical sciences},
  number    = {3},
  publisher = {De Gruyter},
  address   = {T{\"u}bingen},
  issn      = {0932-0776},
  pages     = {289 -- 294},
  year      = {2011},
  abstract  = {An efficient, reliable and low-cost procedure to determine the silicon content in plant material is presented which allows to monitor the agricultural aspects like growth and yield. The presented procedure consists of a hydrochloric acid pre-treatment and a subsequent thermal oxidation. The method is compared to other processes like dissolution in hydrofluoric acid combined with ICP OES, energy-dispersive X-ray fluorescence spectroscopy (EDXRF) or aqua regia treatment.},
  language  = {en}
}