@phdthesis{Ott2018, author = {Ott, Florian}, title = {Late Glacial and Holocene climate and environmental evolution in the southern Baltic lowlands derived from varved lake sediments}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-414805}, school = {Universit{\"a}t Potsdam}, pages = {xix, 241}, year = {2018}, abstract = {Holocene climate variability is generally characterized by low frequency changes than compared to the last glaciations including the Lateglacial. However, there is vast evidence for decadal to centennial scale oscillations and millennial scale climate trends, which are within and beyond a human lifetime perception, respectively. Within the Baltic realm, a transitional zone between oceanic and continental climate influence, the impact of Holocene and Lateglacial climate and environmental change is currently partly understood. This is mainly attributed to the scarcity of well-dated and high-resolution sediment records and to the lacking continuity of already investigated archives. The aim of this doctoral thesis is to reconstruct Holocene and Late Glacial climate variability on local to (over)regional scales based on varved (annually laminated) sediments from Lake Czechowskie down to annual resolution. This project was carried out within the Virtual Institute for Integrated Climate and Landscape Evolution Analyses (ICLEA) and funded by the Helmholtz Association and the Helmholtz Climate Initiative REKLIM (Regional Climate Change). ICLEA intended to gain a better understanding of climate variability and landscape evolution processes in the Northern Central European lowlands since the last deglaciation. REKLIM Topic 8 "Abrupt climate change derived from proxy data" aims at identifying spatiotemporal patterns of climate variability between e.g. higher and lower latitudes. The main aim of this thesis was (i) to establish a robust chronology based on a multiple dating approach for Lake Czechowskie covering the Late Glacial and Holocene and for the Trzechowskie palaeolake for the Lateglacial, respectively, (ii) to reconstruct past climatic and environmental conditions on centennial to multi-millennial time scales and (iii) to distinguish between local to regional different sediments responses to climate change. Addressing the first aim, the Lake Czechowskie chronology has been established by a multiple dating approach comprising information from varve counting, tephrochronology, AMS 14C dating of terrestrial plant remains, biostratigraphy and 137Cs activity concentration measurements. Those independent age constraints covering the Lateglacial and the entire Holocene and have been further implemented in a Bayesian age model by using OxCal v.4.2. Thus, even within non-varved sediment intervals, robust chronological information has been used for absolute age determination. The identification of five cryptotephras, of which three are used as unambiguous isochrones, is furthermore a significant improvement of the Czechowskie chronology and currently unique for the Holocene within Poland. The first findings of coexisting early Holocene H{\"a}sseldalen and Askja-S cryptotephras within a varved sequence even allowed differential dating between both volcanic ashes and stimulated the discussion of revising the absolute ages of the Askja-S tephra. The Trzechowskie palaeolake chronology has been established by a multiple dating approach comprising varve counting, tephrochronology, AMS 14C dating of terrestrial plant remains and biostratigraphy, covers the Lateglacial period (Aller{\o}d and Younger Dryas) and has been implemented in OxCal v.4.2. Those age constraints allowed regional correlation to other high-resolution climate archives and identifying leads and lags of proxy responses at the onset of the Younger Dryas. The second aim has been accomplished by detailed micro-facies and geochemical analyses of the Czechowskie sediments for the entire Holocene. Thus, especially micro-facies changes had been linked to enhanced productivity at Lake Czechowskie. Most prominent changes have been recorded at 7.3, 6.5, 4.3 and 2.8 varve kyrs BP and are linked to a stepwise increasing influence of Atlantic air masses. Especially, the mid-Holocene change, which had been widely reported from palaeohydrological records in low latitudes, has been identified and linked to large scale reorganization of atmospheric circulation patterns. Thus, especially long-term changes of climatic and environmental boundary conditions are widely recorded by the Czechowskie sediments. The pronounced response to (multi)millennial scale changes is further corroborated by the lack of clear sediment responses to early Holocene centennial scale climate oscillations (e.g. the Preboreal Oscillation). However, decadal scale changes at Lake Czechowskie during the most recent period (last 140 years) have been investigated in a lake comparison study. To fulfill the third aim of the doctoral thesis, three lakes in close vicinity to each other have been investigated in order to better distinguish how local, site-specific parameters, may superimpose regional climate driven changes. All lakes haven been unambiguously linked by the Askja AD1875 cryptotephra and independent varve chronologies. As a result, climate warming has only been recorded by sedimentation changes at the smallest and best sheltered lake (Głęboczek), whereas the largest lake (Czechowskie) and the shallowest lake (Jelonek) showed attenuated and less clear sediment responses, respectively. The different responses have been linked to morphological lake characteristics (lake size and depth, catchment area). This study highlights the potential of high-resolution lake comparison for robust proxy based climate reconstructions. In summary, the doctoral thesis presents a high-resolution sediment record with an underlying age model, which is prerequisite for unprecedented age control down to annual resolution. Sediment proxy based climate reconstructions demonstrate the importance of the Czechowskie sediments for better understanding climate variability in the southern Baltic realm. Case studies showed the clear response on millennial time scale, while decadal scale fluctuations are either less well expressed or superimposed by local, site-specific parameters. The identification of volcanic ash layers is not only used for unambiguous isochrones, those are key tie lines for local to supra regional archive synchronization and establish the Lake Czechowskie as a key climate archive.}, language = {en} } @book{LudwigMarxTaschetal.2018, author = {Ludwig, Joachim and Marx, Silvia and Tasch, Markus and Utech, Henry}, title = {d.art}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-413642}, publisher = {Universit{\"a}t Potsdam}, pages = {149}, year = {2018}, abstract = {Der Konzeptband dokumentiert den Aufbau und die Durchf{\"u}hrung der p{\"a}dagogischen Weiterbildung „d.art". Der Band richtet sich an zuk{\"u}nftige Weiterbildungsanbietende und Weiterbildende, die {\"a}hnliche p{\"a}dagogische Weiterbildungen durchf{\"u}hren wollen. Das vom BMBF (Bundesministerium f{\"u}r Bildung und Forschung) gef{\"o}rderte Projekt umfasste zwei Teilprojekte: erstens die Entwicklung eines Konzepts f{\"u}r die p{\"a}dagogische Weiterbildung von Kunstschaffenden und zweitens die Evaluation der Bildungs- und Lernprozesse, welche die Kunstschaffenden im Verlauf der Weiterbildung durchliefen. Es werden Anregungen und Begr{\"u}ndungen f{\"u}r eine p{\"a}dagogische Weiterbildung von Kunstschaffenden geboten, mit der die Qualit{\"a}t {\"a}sthetischer Bildungsprojekte steigt. Die Professur f{\"u}r Erwachsenenbildung an der Universit{\"a}t Potsdam (Prof. Dr. Joachim Ludwig) hat mit insgesamt 41 Brandenburger und Berliner K{\"u}nstler*innen (KuK) aller Kunstsparten in drei Weiterbildungsdurchg{\"a}ngen (2014-2017) dieses Konzept erprobt und entwickelt. Die KuK planen im Rahmen der Weiterbildung außerunterrichtliche Angebote {\"a}sthetischer Bildung an Ganztagsschulen, f{\"u}hren zwei Praxisprojekte durch und reflektieren in den Workshops ihre Erfahrungen. Eine Didaktik vom Standpunkt der Lernenden ist die Leitidee der Weiterbildung. Die Selbstbildungsprozesse der KuK werden in dieser Weiterbildung zum Ausgangspunkt gemacht, unterst{\"u}tzt und begleitet. Aus der Perspektive der Weiterbildungsanbietenden standen vier Themenfelder im Vordergrund, die mit den Anliegen der KuK gekoppelt wurden. Dabei f{\"a}llt auf, dass methodische Fragen weitgehend ausgespart wurden. Dies war m{\"o}glich, weil KuK eigene {\"a}sthetische Weltzug{\"a}nge anbieten k{\"o}nnen. Stattdessen wurde die p{\"a}dagogische Beziehung mit ihren grundlegenden Spannungsverh{\"a}ltnissen in den Vordergrund gestellt. Im ersten Teil des Bandes werden der Weiterbildungsverlauf, die Inhalte der vier Themenfelder (k{\"u}nstlerisches Selbstverst{\"a}ndnis, {\"a}sthetische Bildung, didaktische Herausforderungen, Schule als Projektraum) und die Lernbegleitungsformate detailliert vorgestellt. Im zweiten Teil werden ausf{\"u}hrliche bildungs- und lerntheoretische Grundlagen beschrieben, auf denen das Konzept aufbaut.}, language = {de} } @phdthesis{Platz2018, author = {Platz, Anna}, title = {Novel pre-stack data confinement and selection for magnetotelluric data processing and its application to data of the Eastern Karoo Basin, South Africa}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-415087}, school = {Universit{\"a}t Potsdam}, pages = {xx, 1131}, year = {2018}, abstract = {Magnetotellurics (MT) is a geophysical method that is able to image the electrical conductivity structure of the subsurface by recording time series of natural electromagnetic (EM) field variations. During the data processing these time series are divided into small segments and for each segment spectral values are computed which are typically averaged in a statistical manner to obtain MT transfer functions. Unfortunately, the presence of man-made EM noise sources often deteriorates a significant amount of the recorded time series resulting in disturbed transfer functions. Many advanced processing techniques, e.g. robust statistics, pre-stack data selection or remote reference, have been developed to tackle this problem. The first two techniques reduce the amount of outliers and noise in the data whereas the latter approach removes noise by using data from another MT station. However, especially in populated regions the data processing is still quite challenging even with these approaches. In this thesis, I present two novel pre-stack data confinement and selection criteria for the detection of outliers and noise affected data based on (i) a distance measure of each data segment with regard to the entire sample distribution and (ii) the evaluation of the magnetic polarisation direction of all segments. The first criterion is able to remove data points that scatter around the desired MT distribution and furthermore it can, under some circumstances, even reject complete data cluster originating from noise sources. The second criterion eliminates data points caused by a strongly polarised magnetic signal. Both criteria have been successfully applied to many stations with different noise contaminations showing that they can significantly improve the transfer function estimation. The novel criteria were used to evaluate a MT data set from the Eastern Karoo Basin in South Africa. The corresponding field experiment is part of an extensive research programme to collect information of the current e.g. geological setting in this region prior to a potential shale gas exploitation. The aim was to investigate whether a three-dimensional (3D) inversion of the newly measured data fosters a more realistic mapping of physical properties of the target horizon. For this purpose, a comprehensive 3D model was derived by using all available data. In a second step, I analysed parameters of the target horizon, e.g. its conductivity, that are proxies for physical properties such as thermal maturity and porosity.}, language = {en} } @masterthesis{Haug2018, type = {Bachelor Thesis}, author = {Haug, Frederik}, title = {Verbrannte Erde}, series = {WeltTrends Thesis}, journal = {WeltTrends Thesis}, number = {21}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-434-0}, issn = {1866-0738}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-411237}, school = {Universit{\"a}t Potsdam}, pages = {74}, year = {2018}, abstract = {Innerhalb des {\"o}ffentlichen und politischen Diskurses in Deutschland nehmen die Verbrechen in den ehemaligen Kolonien des Deutschen Kaiserreichs einen kaum wahrnehmbaren Platz ein. R{\"u}ckt der V{\"o}lkermord an den Herero und Nama in Deutsch-S{\"u}dwestafrika seit ein paar Jahren vermehrt ins Licht der {\"O}ffentlichkeit, so sind die Kolonialkriege in Deutsch-Ostafrika, die mehrere Hunderttausend Afrikaner das Leben kosteten, nahezu vergessen. Frederik Haug analysiert den erinnerungspolitischen Umgang der Bundesregierung mit den Verbrechen, die die deutsche „Schutztruppe" in Ostafrika vor {\"u}ber einem Jahrhundert ver{\"u}bte. Er untersucht dabei sowohl die Charakteristika dieser Haltung als auch die Gr{\"u}nde f{\"u}r eine solche Positionierung.}, language = {de} } @inproceedings{SeegererRomeikeTillmannetal.2018, author = {Seegerer, Stefan and Romeike, Ralf and Tillmann, Alexander and Kr{\"o}mker, Detlef and Horn, Florian and Gattinger, Thorsten and Weicker, Karsten and Schmitz, Dennis and Moldt, Daniel and R{\"o}pke, Ren{\´e} and Larisch, Kathrin and Schroeder, Ulrik and Keverp{\"u}tz, Claudia and K{\"u}ppers, Bastian and Striewe, Michael and Kramer, Matthias and Grillenberger, Andreas and Frede, Christiane and Knobelsdorf, Maria and Greven, Christoph}, title = {Hochschuldidaktik der Informatik HDI 2018}, series = {Commentarii informaticae didacticae (CID)}, booktitle = {Commentarii informaticae didacticae (CID)}, number = {12}, editor = {Bergner, Nadine and R{\"o}pke, Ren{\´e} and Schroeder, Ulrik and Kr{\"o}mker, Detlef}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-435-7}, issn = {1868-0844}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-413542}, pages = {161}, year = {2018}, abstract = {Die 8. Fachtagung f{\"u}r Hochschuldidaktik der Informatik (HDI) fand im September 2018 zusammen mit der Deutschen E-Learning Fachtagung Informatik (DeLFI) unter dem gemeinsamen Motto „Digitalisierungswahnsinn? - Wege der Bildungstransformationen" in Frankfurt statt. Dabei widmet sich die HDI allen Fragen der informatischen Bildung im Hochschulbereich. Schwerpunkte bildeten in diesem Jahr u. a.: - Analyse der Inhalte und anzustrebenden Kompetenzen in Informatikveranstaltungen - Programmieren lernen \& Einstieg in Softwareentwicklung - Spezialthemen: Data Science, Theoretische Informatik und Wissenschaftliches Arbeiten Die Fachtagung widmet sich ausgew{\"a}hlten Fragestellungen dieser Themenkomplexe, die durch Vortr{\"a}ge ausgewiesener Experten und durch eingereichte Beitr{\"a}ge intensiv behandelt werden.}, language = {de} } @misc{PaesslerAndressDuranCasasetal.2018, author = {P{\"a}ßler, Ulrich and Andress, Reinhard and Dur{\´a}n Casas, Vicente and Ette, Ottmar and H{\"u}lsenberg, Dagmar and Schmuck, Thomas and Sundermann, Werner}, title = {HiN : Alexander von Humboldt im Netz}, series = {HIN : Alexander von Humboldt im Netz ; international review for Humboldtian studies}, volume = {XIX}, journal = {HIN : Alexander von Humboldt im Netz ; international review for Humboldtian studies}, number = {36}, editor = {Ette, Ottmar and Knobloch, Eberhard}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {2568-3543}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-410919}, pages = {109}, year = {2018}, abstract = {Inhalt: -Ulrich P{\"a}ßler: Die edition humboldt digital. Dokumente zur Neuausgabe der Ideen zu einer Geographie der Pflanzen (1825-1826) -Reinhard Andress: Eduard Dorsch and his unpublished poem on the occasion of Humboldt's 100th birthday -Vicente Dur{\´a}n Casas: Immanuel Kant, Alexander von Humboldt and the Tequendama Fall. Two Prussians linked by Geography -Ottmar Ette: Languages about Languages: Two Brothers and one Humboldtian Science -Dagmar H{\"u}lsenberg: Alexander von Humboldts Erl{\"a}uterungen zu {\"O}fen f{\"u}r die Herstellung von Keramik- und Glaserzeugnissen -Thomas Schmuck: Missgl{\"u}ckte Begegnung. Der kurze Briefwechsel zwischen Leopold von Buch und Goethe -Werner Sundermann: Alexander von Humboldt und das Persische}, language = {de} } @phdthesis{Muench2018, author = {M{\"u}nch, Thomas}, title = {Interpretation of temperature signals from ice cores}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-414963}, school = {Universit{\"a}t Potsdam}, pages = {xxi, 197}, year = {2018}, abstract = {Earth's climate varies continuously across space and time, but humankind has witnessed only a small snapshot of its entire history, and instrumentally documented it for a mere 200 years. Our knowledge of past climate changes is therefore almost exclusively based on indirect proxy data, i.e. on indicators which are sensitive to changes in climatic variables and stored in environmental archives. Extracting the data from these archives allows retrieval of the information from earlier times. Obtaining accurate proxy information is a key means to test model predictions of the past climate, and only after such validation can the models be used to reliably forecast future changes in our warming world. The polar ice sheets of Greenland and Antarctica are one major climate archive, which record information about local air temperatures by means of the isotopic composition of the water molecules embedded in the ice. However, this temperature proxy is, as any indirect climate data, not a perfect recorder of past climatic variations. Apart from local air temperatures, a multitude of other processes affect the mean and variability of the isotopic data, which hinders their direct interpretation in terms of climate variations. This applies especially to regions with little annual accumulation of snow, such as the Antarctic Plateau. While these areas in principle allow for the extraction of isotope records reaching far back in time, a strong corruption of the temperature signal originally encoded in the isotopic data of the snow is expected. This dissertation uses observational isotope data from Antarctica, focussing especially on the East Antarctic low-accumulation area around the Kohnen Station ice-core drilling site, together with statistical and physical methods, to improve our understanding of the spatial and temporal isotope variability across different scales, and thus to enhance the applicability of the proxy for estimating past temperature variability. The presented results lead to a quantitative explanation of the local-scale (1-500 m) spatial variability in the form of a statistical noise model, and reveal the main source of the temporal variability to be the mixture of a climatic seasonal cycle in temperature and the effect of diffusional smoothing acting on temporally uncorrelated noise. These findings put significant limits on the representativity of single isotope records in terms of local air temperature, and impact the interpretation of apparent cyclicalities in the records. Furthermore, to extend the analyses to larger scales, the timescale-dependency of observed Holocene isotope variability is studied. This offers a deeper understanding of the nature of the variations, and is crucial for unravelling the embedded true temperature variability over a wide range of timescales.}, language = {en} } @article{Hennemann2018, author = {Hennemann, Anja}, title = {Evidentiality and (Inter-) Subjectivity as (Non-) Competing Dimensions}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-414996}, year = {2018}, abstract = {The present paper discusses the relationship between evidentiality and (inter-) subjectivity and argues that the two semantic-functional categories need not be mutually exclusive. In the use of certain means of expression and in certain contexts, both evidentiality and (inter-) subjectivity may be conveyed simultaneously. I thereby differentiate between two meanings of intersubjectivity, namely 'intersubjectivity1' and 'intersubjectivity2'. Intersubjectivity1 refers to the notion of common or general knowledge: certain means of expression are seen as being intersubjectively used when the speaker shares or assumes sharing knowledge with the interlocutor. Intersubjectivity2 is related to particular discourse functions of certain means of expression in interactional settings, paying attention to the speaker-hearer constellation. In order to substantiate the theoretical part of the paper, I then present a qualitative analysis of Portuguese, Spanish and English examples, which are taken from the Corpus do Portugu{\^e}s, Corpus del Espa{\~n}ol and the Corpus of Contemporary American English.}, language = {en} } @phdthesis{Lee2018, author = {Lee, Hui-Chun}, title = {Toward ultimate control of polymerization and catalytic property}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-414973}, school = {Universit{\"a}t Potsdam}, pages = {vii, iii, 150}, year = {2018}, abstract = {Reversible-deactivation radical polymerization (RDRP) is without any doubt one of the most prevalent and powerful strategies for polymer synthesis, by which well-defined living polymers with targeted molecular weight (MW), low molar dispersity (Ɖ) and diverse morphologies can be prepared in a controlled fashion. Atom transfer radical polymerization (ATRP) as one of the most extensive studied types of RDRP has been particularly emphasized due to the high accessibility to hybrid materials, multifunctional copolymers and diverse end group functionalities via commercially available precursors. However, due to catalyst-induced side reactions and chain-chain coupling termination in bulk environment, synthesis of high MW polymers with uniform chain length (low Ɖ) and highly-preserved chain-end fidelity is usually challenging. Besides, owing to the inherited radical nature, the control of microstructure, namely tacticity control, is another laborious task. Considering the applied catalysts, the utilization of large amounts of non-reusable transition metal ions which lead to cumbersome purification process, product contamination and complicated reaction procedures all delimit the scope ATRP techniques. Metal-organic frameworks (MOFs) are an emerging type of porous materials combing the properties of both organic polymers and inorganic crystals, characterized with well-defined crystalline framework, high specific surface area, tunable porous structure and versatile nanochannel functionalities. These promising properties of MOFs have thoroughly revolutionized academic research and applications in tremendous aspects, including gas processing, sensing, photoluminescence, catalysis and compartmentalized polymerization. Through functionalization, the microenvironment of MOF nanochannel can be precisely devised and tailored with specified functional groups for individual host-guest interactions. Furthermore, properties of high transition metal density, accessible catalytic sites and crystalline particles all indicate MOFs as prominent heterogeneous catalysts which open a new avenue towards unprecedented catalytic performance. Although beneficial properties in catalysis, high agglomeration and poor dispersibility restrain the potential catalytic capacity to certain degree. Due to thriving development of MOF sciences, fundamental polymer science is undergoing a significant transformation, and the advanced polymerization strategy can eventually refine the intrinsic drawbacks of MOF solids reversely. Therefore, in the present thesis, a combination of low-dimensional polymers with crystalline MOFs is demonstrated as a robust and comprehensive approach to gain the bilateral advantages from polymers (flexibility, dispersibility) and MOFs (stability, crystallinity). The utilization of MOFs for in-situ polymerizations and catalytic purposes can be realized to synthesize intriguing polymers in a facile and universal process to expand the applicability of conventional ATRP methodology. On the other hand, through the formation of MOF/polymer composites by surface functionalization, the MOF particles with environment-adjustable dispersibility and high catalytic property can be as-prepared. In the present thesis, an approach via combination of confined porous textures from MOFs and controlled radical polymerization is proposed to advance synthetic polymer chemistry. Zn2(bdc)2(dabco) (Znbdc) and the initiator-functionalized Zn MOFs, ZnBrbdc, are utilized as a reaction environment for in-situ polymerization of various size-dependent methacrylate monomers (i.e. methyl, ethyl, benzyl and isobornyl methacrylate) through (surface-initiated) activators regenerated by electron transfer (ARGET/SI-ARGET) ATRP, resulting in polymers with control over dispersity, end functionalities and tacticity with respect to distinct molecular size. While the functionalized MOFs are applied, due to the strengthened compartmentalization effect, the accommodated polymers with molecular weight up to 392,000 can be achieved. Moreover, a significant improvement in end-group fidelity and stereocontrol can be observed. The results highlight a combination of MOFs and ATRP is a promising and universal methodology to synthesize versatile well-defined polymers with high molecular weight, increment in isotactic trial and the preserved chain-end functionality. More than being a host only, MOFs can act as heterogeneous catalysts for metal-catalyzed polymerizations. A Cu(II)-based MOF, Cu2(bdc)2(dabco), is demonstrated as a heterogeneous, universal catalyst for both thermal or visible light-triggered ARGET ATRP with expanded monomer range. The accessible catalytic metal sites enable the Cu(II) MOF to polymerize various monomers, including benzyl methacrylate (BzMA), styrene, methyl methacrylate (MMA), 2-(dimethylamino)ethyl methacrylate (DMAEMA) in the fashion of ARGET ATRP. Furthermore, due to the robust frameworks, surpassing the conventional homogeneous catalyst, the Cu(II) MOF can tolerate strongly coordinating monomers and polymerize challenging monomers (i.e. 4-vinyl pyridine, 2-vinyl pyridine and isoprene), in a well-controlled fashion. Therefore, a synthetic procedure can be significantly simplified, and catalyst-resulted chelation can be avoided as well. Like other heterogeneous catalysts, the Cu(II) MOF catalytic complexes can be easily collected by centrifugation and recycled for an arbitrary amount of times. The Cu(II) MOF, composed of photostimulable metal sites, is further used to catalyze controlled photopolymerization under visible light and requires no external photoinitiator, dye sensitizer or ligand. A simple light trigger allows the photoreduction of Cu(II) to the active Cu(I) state, enabling controlled polymerization in the form of ARGET ATRP. More than polymerization application, the synergic effect between MOF frameworks and incorporated nucleophilic monomers/molecules is also observed, where the formation of associating complexes is able to adjust the photochemical and electrochemical properties of the Cu(II) MOF, altering the band gap and light harvesting behavior. Owing to the tunable photoabsorption property resulting from the coordinating guests, photoinduced Reversible-deactivation radical polymerization (PRDRP) can be achieved to further simplify and fasten the polymerization. More than the adjustable photoabsorption ability, the synergistic strategy via a combination of controlled/living polymerization technique and crystalline MOFs can be again evidenced as demonstrated in the MOF-based heterogeneous catalysts with enhanced dispersibility in solution. Through introducing hollow pollen pivots with surface immobilized environment-responsive polymer, PDMAEMA, highly dispersed MOF nanocrystals can be prepared after associating on polymer brushes via the intrinsic amine functionality in each DMAEMA monomer. Intriguingly, the pollen-PDMAEMA composite can serve as a "smart" anchor to trap nanoMOF particles with improved dispersibility, and thus to significantly enhance liquid-phase photocatalytic performance. Furthermore, the catalytic activity can be switched on and off via stimulable coil-to-globule transition of the PDMAEMA chains exposing or burying MOF catalytic sites, respectively.}, language = {en} } @book{OPUS4-40576, title = {www.BrAnD2.Wissen.}, number = {10}, editor = {H{\"o}mke, Nicola}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-424-1}, issn = {1860-5206}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-405764}, publisher = {Universit{\"a}t Potsdam}, pages = {248}, year = {2018}, abstract = {Mit „Wissen" kommt der zweite Durchgang des insgesamt dreij{\"a}hrigen Brandenburger Antike-Denkwerks zum Abschluss, das der Zusammenarbeit zwischen der Klassischen Philologie der Universit{\"a}t Potsdam und ausgew{\"a}hlten Brandenburger Gymnasien dient und von der Robert Bosch Stiftung gef{\"o}rdert wird. Der vorliegende Band enth{\"a}lt zum einen die beiden Impulsvortr{\"a}ge vom Potsdamer Lateintag im Oktober 2017: Prof. Dr. Claudia Tiersch zeigt, inwiefern sich im antiken Rom Raumwissen als Raumpolitik offenbarte, und Frau PD Dr. Nicola H{\"o}mke beleuchtet den Streit um die „richtige" Wissensvermittlung an r{\"o}mische Sch{\"u}ler in der ausgehenden Republik. Zum anderen sind die fantasievollen Ergebnisse dokumentiert, die die Sch{\"u}ler zusammen mit ihren studentischen Mentoren in der mehrmonatigen Projektphase zum Thema „Wissen" erarbeiteten und auf einem eigenen Sch{\"u}lerkongress im M{\"a}rz 2018 pr{\"a}sentierten.}, language = {de} }