@article{ShainyanTolstikovaSchilde2012, author = {Shainyan, Bagrat A. and Tolstikova, Ljudmila L. and Schilde, Uwe}, title = {Simple methods for the preparation of N-triflyl guanidines and the structure of compounds with the CF3SO2N=C-N fragment}, series = {Journal of fluorine chemistry}, volume = {135}, journal = {Journal of fluorine chemistry}, number = {1}, publisher = {Elsevier}, address = {Lausanne}, issn = {0022-1139}, doi = {10.1016/j.fluchem.2011.12.004}, pages = {261 -- 264}, year = {2012}, abstract = {Two novel and simple approaches to N-triflyl guanidines are elaborated. Owing to very strong conjugation the formally double C=N bond of TIN=C(NHR)(2) is longer than the formally single N-C bonds. Energetic effect of the triflylgroup on the conjugation in the N-C=N moiety is estimated to be >= 150 kcal/mol.}, language = {en} } @misc{Laschewsky2012, author = {Laschewsky, Andr{\´e}}, title = {Recent trends in the synthesis of polyelectrolytes}, series = {Current opinion in colloid \& interface science : current chemistry}, volume = {17}, journal = {Current opinion in colloid \& interface science : current chemistry}, number = {2}, publisher = {Elsevier}, address = {London}, issn = {1359-0294}, doi = {10.1016/j.cocis.2011.08.001}, pages = {56 -- 63}, year = {2012}, abstract = {Recent developments in the synthesis of polyelectrolytes are highlighted, with respect to the nature of the ionic groups, the polymer backbones, synthetic methods, and additional functionality given to the polyelectrolytes. In fact, the synthesis of new polyelectrolytes is mostly driven by material aspects, currently. The article pays particular attention to strong polyelectrolytes, and the new methods of controlled polymerization. These methods and the so-called click reactions have enabled novel designs of polyelectrolytes. Nevertheless, the polymerization of unprotected ionic monomers is still challenging and limits the synthetic possibilities. The structural aspects are complemented by considerations with respect to the aspired uses of the new polyelectrolytes.}, language = {en} }