@article{LitwinskiTannertJesorkaetal.2006, author = {Litwinski, Christian and Tannert, Sebastian and Jesorka, Aldo and Katterle, Martin and Roder, Beate}, title = {Photophysical properties of gallium hydroxyl tetratolylporphyrin and 13(2)-demethoxycarbonyl-(gallium hydroxyl)- methyl-pheophorbide alpha}, issn = {0009-2614}, doi = {10.1016/j.cplett.2005.10.131}, year = {2006}, abstract = {Two metal tetrapyrroles containing gallium, gallium hydroxyl tetratolylporphyrin and 13(2)-demethoxycarbonyl- (gallium hydroxyl)methyl pheophorbide a (Ga-(OH)-chlorin), were synthesized from their respective free bases using Ga(III)-acetylacetonate in a phenol melt. Their photophysical properties were investigated and the quantum yields of different monomolecular deactivation processes were determined. For Ga-(OH)-porphyrin S-2-fluorescence was observed and quantified. In contrast. for Ga-(OH)-chlorin no S-2-fluorescence was observed. Both compounds should be useful as efficient photosensitizers in photodynamic therapy.}, language = {en} }