@article{StarkeKammerGrunwaldetal.2008, author = {Starke, Ines and Kammer, Stefan and Grunwald, Nicolas and Schilde, Uwe and Holdt, Hans-J{\"u}rgen and Kleinpeter, Erich}, title = {Complexation of diazaperylene and bisisoquinoline with transition metal ions in the gas phase studied by electrospray ionization mass spectrometry}, year = {2008}, abstract = {The complex formation of the ligands 1,12-diazaperylene (dap), 1,1-bisisoquinoline (bis), 2,2-bipyridine (bpy) and 1,10-phenanthroline (phen) with transition metal ions (M = Fe, Co, Ni, Cu, Zn, Ru, Os, Re, Pd, Pt, Ag and Cd) in the gas phase has been studied by electrospray ionization mass spectrometry. With the exception of Ru, Os, Fe, Ni and Cu, singly charged complexes [MLn]+ (n = 1,2) were observed. The complexes of dap and bis with Ru, Os, Fe and Ni ions, and the mixed ligand complexes with bpy and phen, are preferably of the doubly charged type [ML3]2+. In addition, collision- induced dissociation (CID) measurements were employed to evaluate the relative stabilities of these complexes. The CID experiments of mixed-ligand complexes which contain both dap and phen or dap and bpy exhibit preferential elimination of bpy, indicating that bpy is a weaker ligand than phen and dap.}, language = {en} } @article{KammerMuellerGrunwaldetal.2006, author = {Kammer, Stefan and M{\"u}ller, Holger and Grunwald, Nicolas and Bellin, Anja and Kelling, Alexandra and Schilde, Uwe and Mickler, Wulfhard and Dosche, Carsten and Holdt, Hans-J{\"u}rgen}, title = {Supramolecular assemblies with honeycomb structures by pi-pi stacking of octahedral metal complexes of 1,12- diazaperylene}, issn = {1343-1948}, doi = {10.1002/ejic.200600092}, year = {2006}, abstract = {Homoleptic Ni-II and Fe-II complexes of the "large-surface" phenanthroline-type ligand 1,12-diazaperylene (dap), [Ni(dap)(3)](BF4)(2) (1) and [Fe(dap)(3)](PF6)(2) (2), respectively, were synthesized. In the crystal structure the complex cation [M(dap)(3)](2+) (M = Ni, Fe) exhibits C-3 symmetry and interacts with three other cations by pi-pi stacking. It forms a new metalla-supramolecular assembly with a honeycomb structure containing nanochannels running parallel to the crystallographic c axis. Aggregation by pi-pi stacking between metal complexes of "large-surface" ligands should give new perspectives for inorganic supramolecular chemistry.}, language = {en} } @misc{GrunwaldKellingHoldtetal.2017, author = {Grunwald, Nicolas and Kelling, Alexandra and Holdt, Hans-J{\"u}rgen and Schilde, Uwe}, title = {The crystal structure of 1,1′-bisisoquinoline, C18H12N2}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-401952}, pages = {3}, year = {2017}, abstract = {C18H12N2, tetragonal, I41/a (no. 88), a=13.8885(6) {\AA}, c=13.6718(6) {\AA}, V =2637.2(3) {\AA}3, Z =8, Rgt(F)=0.0295, wRref(F2)=0.0854, T =210 K. CCDC no.: 631823}, language = {en} } @article{GrunwaldKellingHoldtetal.2017, author = {Grunwald, Nicolas and Kelling, Alexandra and Holdt, Hans-J{\"u}rgen and Schilde, Uwe}, title = {The crystal structure of 1,1′-bisisoquinoline, C18H12N2}, series = {Zeitschrift f{\"u}r Kristallographie : international journal for structural, physical and chemical aspects of crystalline materials. New crystal structures}, volume = {232}, journal = {Zeitschrift f{\"u}r Kristallographie : international journal for structural, physical and chemical aspects of crystalline materials. New crystal structures}, number = {5}, publisher = {de Gruyter}, address = {Berlin}, doi = {10.1515/ncrs-2017-0088}, pages = {839 -- 841}, year = {2017}, abstract = {C18H12N2, tetragonal, I41/a (no. 88), a=13.8885(6) {\AA}, c=13.6718(6) {\AA}, V =2637.2(3) {\AA}3, Z =8, Rgt(F)=0.0295, wRref(F2)=0.0854, T =210 K. CCDC no.: 631823}, language = {en} } @article{GrunwaldKellingHoldtetal.2017, author = {Grunwald, Nicolas and Kelling, Alexandra and Holdt, Hans-J{\"u}rgen and Schilde, Uwe}, title = {The crystal structure of 1,1\&\#8242;-bisisoquinoline, C18H12N2}, series = {Zeitschrift f{\"u}r Kristallographie : international journal for structural, physical and chemical aspects of crystalline materials ; New crystal structures}, volume = {232}, journal = {Zeitschrift f{\"u}r Kristallographie : international journal for structural, physical and chemical aspects of crystalline materials ; New crystal structures}, publisher = {De Gruyter}, address = {Berlin}, issn = {1433-7266}, doi = {10.1515/ncrs-2017-0088}, pages = {839 -- 841}, year = {2017}, abstract = {C18H12N2, tetragonal, I4(1)/a (no. 88), a = 13.8885(6) angstrom, c = 13.6718(6) angstrom, V = 2637.2(3) angstrom(3), Z = 8, R-gt(F) = 0.0295, wR(ref)(F-2) = 0.0854, T = 210 K.}, language = {en} }