@article{UhlemannGloeStephanetal.1994, author = {Uhlemann, Erhard and Gloe, Karsten and Stephan, Holger and Heitzsch, Olaf and Bukowsky, Heinz and Pollex, Rolf and Weber, Erwin}, title = {Preorganized endo-dicarboxylic host macrocycles having superior extraction selectivity for small alkaline earth metal ions}, year = {1994}, language = {en} } @article{UhlemannBukowskyKlaeui1996, author = {Uhlemann, Erhard and Bukowsky, Heinz and Kl{\"a}ui, Wolfgang}, title = {Extraction of alkali metal, magnesium and calcium ions with Cyclopentadienyl-Tris(diethylphosphito-P)cobaltate(- 1)}, year = {1996}, language = {en} } @article{MicklerBukowskyHoldt2002, author = {Mickler, Wulfhard and Bukowsky, Heinz and Holdt, Hans-J{\"u}rgen}, title = {Separation of Palladium(II) with immobilized Maleonitrile-Dithiocrown ethers}, year = {2002}, abstract = {Especially sulphur containing compounds are suitable for the separation of noble metals. 1,2-Dithioethenes are weak chelate-forming ligands and in the case of bis(methylthio)maleo-nitrile the donor power of both of the sulphur atoms is further decreased by the electron withdrawing effect of the cyanogroups. Crowned dithiomaleonitrile are macrocyclic chelate ligands which extract Pd(II) at sufficient rate in a very good yields. The synthesis of the immobilised ligands proceeds from the 2-allyloxy-1,2-propanediol forming the dicar-bon acid which is reduced to the diole. With the help of thionylchloride the dichloro compound is synthe-sized forming the macrocycle together with a dithiolate (1,2-disodium-1,2-dicyanethene-1,2-dithiolate, 1,2-disodium-4-methylbenzene-1,2-dithiolate) at high dilution conditions. The allylsubstituted crown ether is sillylated and the resulting alkoxysilane is immobilised onto activated silica gel. The extraction results with crown ethers are compared with that achieved with the help of substituted ß- diketones and 4-acyl-5-pyrazolones. By modification of the cavity of the macrocyclus the extraction rate increases from the acyclic compound through maleonitrile-dithio-21-crown-7, maleonitrile-dithio-15-crown-5 and maleonitrile-18-crown-6. The best results can be observed at the maleonitrile-dithio-12-crown-4. The rise of the function log D= f(log L) gives the composition of the extracted compounds as 1:1. The separa-tion is unsatisfactory in the case of Ag(I), Hg(II), Pt(II), Tl (I) and the most 3d-elements. Summarizing, a very good separation of palladium from the examined elements can be specified. Additional to the extraction experiments, as well as the crystal structures and by UV spectroscopy the for- mation constants of selected chelates were determined.}, language = {en} } @article{KuehlingBukowskyKraudelt2001, author = {K{\"u}hling, Matthias and Bukowsky, Heinz and Kraudelt, Heide}, title = {Heavy metal contents of chicken and red toads}, year = {2001}, language = {en} } @article{KnoescheBukowsky1996, author = {Kn{\"o}sche, R{\"u}diger and Bukowsky, Heinz}, title = {Zur Schwermetallakkumulation in Dactylis glomerata auf Rieselfeldb{\"o}den}, isbn = {3-7983-1680-5}, year = {1996}, language = {de} } @article{GrunewaldBukowskySchade1996, author = {Grunewald, Karsten and Bukowsky, Heinz and Schade, Werner}, title = {Schwermetalle und deren Bindung in B{\"o}den und Substraten des Rieselfeldgebietes s{\"u}dlich Berlin}, year = {1996}, language = {de} } @article{GrunewaldBlumensteinBukowskyetal.1995, author = {Grunewald, Karsten and Blumenstein, Oswald and Bukowsky, Heinz and Schade, Werner}, title = {Schadstoffe in Vorflutsedimenten des Rieselfeldgebietes s{\"u}dlich von Berlin}, year = {1995}, language = {de} } @article{GrunewaldBarschBechmannetal.1995, author = {Grunewald, Karsten and Barsch, Heiner and Bechmann, Wolfgang and Bukowsky, Heinz}, title = {Methodische Ans{\"a}tze zur Erkundung großfl{\"a}chiger Bodenkontaminationen in Lockersedimenten}, year = {1995}, language = {de} } @article{BurhenneBukowskySchneider1997, author = {Burhenne, Matthias and Bukowsky, Heinz and Schneider, Ingo}, title = {Schwermetalle in B{\"o}den der Rieselfelder Berlin-S{\"u}d}, year = {1997}, language = {de} } @article{BlumensteinSchubertBechmannetal.1997, author = {Blumenstein, Oswald and Schubert, Rudolf and Bechmann, Wolfgang and Bukowsky, Heinz and Dautz, J. and Kopp, Ingo and Kn{\"o}sche, R{\"u}diger and Portmann, H. - D. and Schachtzabel, Hartmut and Schneider, I. and Tessmann, J.}, title = {Erste Ergebnisse einer Fallstudie zur Stoffdynamik in naturschutzrelevanten B{\"o}den der D{\"o}beritzer Heide}, series = {Brandenburgische Umwelt-Berichte : BUB ; Schriftenreihe der Mathematisch-Naturwissenschaftlichen Fakult{\"a}t der Universit{\"a}t Potsdam}, volume = {1}, journal = {Brandenburgische Umwelt-Berichte : BUB ; Schriftenreihe der Mathematisch-Naturwissenschaftlichen Fakult{\"a}t der Universit{\"a}t Potsdam}, issn = {1434-2375}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-2690}, pages = {65 -- 77}, year = {1997}, language = {de} }