@article{SauterKratzLendlein2013, author = {Sauter, Tilman and Kratz, Karl and Lendlein, Andreas}, title = {Pore-size distribution controls shape-memory properties on the macro- and microscale of polymeric foams}, series = {Macromolecular chemistry and physics}, volume = {214}, journal = {Macromolecular chemistry and physics}, number = {11}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1352}, doi = {10.1002/macp.201300062}, pages = {1184 -- 1188}, year = {2013}, abstract = {Open porous foams with identical foam density but different pore-size distributions (bimodal or monomodal) are prepared from a shape-memory polyetherurethane (PEU) by thermally induced phase separation. The shape-memory effect of the two PEU foams is explored by cyclic thermomechanical compression tests and microstructural analysis. The obtained results reveal that the PEU foam with a bimodal pore-size distribution exhibits an increased shape-recovery under stress-free conditions, both on the macro- (foam level) as well as the microscale (pore level). While bimodal pore-size distributions induce microscale bending during compression, buckling occurs in foams with monomodal pore-size distributions, leading to both a reduced and delayed shape recovery.}, language = {en} }