@article{ChristImmenhauserAmouretal.2012, author = {Christ, Nicolas and Immenhauser, Adrian and Amour, Frederic and Mutti, Maria and Preston, Rosalind and Whitaker, Fiona F. and Peterh{\"a}nsel, Arndt and Egenhoff, Sven O. and Dunn, Paul A. and Agar, Susan M.}, title = {Triassic Latemar cycle tops - Subaerial exposure of platform carbonates under tropical arid climate}, series = {Sedimentary geology : international journal of applied and regional sedimentology}, volume = {265}, journal = {Sedimentary geology : international journal of applied and regional sedimentology}, number = {28}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0037-0738}, doi = {10.1016/j.sedgeo.2012.02.008}, pages = {1 -- 29}, year = {2012}, abstract = {The Triassic Latemar platform in the Dolomites, Italy, is the site of several ongoing controversies. Perhaps the most interesting debate focuses on apparent cyclic deposition within the Latemar platform, whose nature and duration are still open to debate. Further disagreement concerns the lack of meteoric diagenesis-related isotope shifts at cycle tops that bear circumstantial petrographic evidence for subaerial emergence. Here, an evaluation of the nature of Latemar cycle tops is presented combining evidence from previous work and new field, petrographic and geochemical data. Cycle tops are ranked according to increasing exposure duration and spatial extent: type I surfaces lacking unequivocal evidence of prolonged supratidal conditions; type II dolomite caps formed in warm, evaporitic, intertidal lagoonal waters followed by exposure of perhaps intermediate duration; type III clastic-rich, red calcareous horizons with some showing platform-wide extent, representing prolonged supratidal conditions, and type IV discontinuities in tepee belts, genetically related to type II and III surfaces, but likely representing shorter-lived exposure stages. Petrographic and geochemical criteria indicate that most diagenesis occurred in the shallow marine and burial domain whilst an extensive meteoric overprint of cycle tops is lacking. This is underlined by the scarcity of meteoric diagenetic fabrics such as gravitational cements that, where present, are here interpreted as marine-vadose in origin. The scarcity of carbon and oxygen isotope signatures commonly assigned to subaerial exposure stages is best explained in the context of mid-Triassic climate. The low latitude, tropical but arid setting of the Latemar, situated in the western extension of the Tethys ocean, its isolation from nearby continental areas and overall short-term emergence episodes are in agreement with a limited degree of meteoric alteration of most cycle tops. High amounts of aeolian clastic material beneath some cycle tops, along with high Fe and Mn elemental abundances argue for intermittent subaerial conditions. This study proposes an enhancement of the classical Allan and Matthews (1982) isotope model for subaerial exposure under strongly arid climates. As the subaerial exposure nature of Latemar cycle tops, and therefore eustasy as the cause for cyclicity, have been previously challenged due to the lack of meteoric-induced isotopic signatures, the outcome of this study is of significance for the ongoing Latemar stratigraphic controversy.}, language = {en} } @phdthesis{MarcanoRomero2008, author = {Marcano Romero, Gabriela Helena}, title = {Investigations on sedimentology and early diagenesis in shallow-water warm-temperate to tropical miocene carbonates : a case study from Northern Sardinia, Italy}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-29207}, school = {Universit{\"a}t Potsdam}, year = {2008}, abstract = {This study investigated the warm-temperate to tropical shallow-water Miocene carbonates of the Perfugas basin (Anglona area), northern Sardinia, Italy (Central Mediterranean). The aim of this study was to identify and document the existence and significance of early diagenesis in this carbonate system, especially the diagenetic history, which reflects the diagenetic potential in terms of skeletal mineralogy. The motivation behind the present study was to investigate the role that early cementation has over facies stabilization linked to differences in biotic associations in shallow-water settings. Principal to this was to unravel the amount, kind and distribution of early cements in this type of carbonates, in order to complement previous studies, and hence acquire a more global perspective on non-tropical carbonate settings. The shallow-buried Sedini Limestone Unit was investigated for variations on early diagenetic features, as well as for the type of biotic association, and oxygen and carbon stable isotope stratigraphy. Results showed, that particularly at the Perfugas basin (< 15 km2), which evolves in time from a ramp into a steep-flanked platform, shallow-water facies are characterized by a "transitional" type of biotic association. The biotic assemblages change gradually over time from a heterozoan-rich into a photozoan-rich depositional system. This transition implies a change in the depositional environmental control factors such as temperature. It is considered that sedimentation took place under warm-temperate waters, which shifted to more warmer or tropical waters through time. Moreover, it was noticed that along with these changes, marine early syn-depositional cements (high-Mg calcite), with particular fabrics (e.g. fibrous), gradually contributed to the early lithification of rocks, favoring a steepening of the platform relief. The major controls for the shift of the depositional geometry was triggered by the change of the type of biotic associations (carbonate factory), related with the shift towards warmer conditions, and the development of early marine cementation. The identification of the amount and distribution of different cement phases, porosities and early diagenetic features, within facies and stratigraphy, showed that diagenesis is differential along depth, and within the depositional setting. High-Mg calcite cements (micrite, fibrous and syntaxial inclusion-rich) are early syn-depositional, facies-related (shallow-water), predominant at the platform phase, and marine in origin. Low-Mg calcite cements (bladed, syntaxial inclusionpoor and blocky) are early to late post-depositional, non-facies related (shallow- to deep-water) and shallow-burial marine in origin. However, a particular difference exists when looking at the amount and distribution of low-Mg calcite bladed cements. They become richer in shallow-water facies at the platform phase, suggesting that the enrichment of bladed cementation is linked to the appearance of metastable grains (e.g. aragonite). In both depositional profiles, the development of secondary porosity is the product of fabric-selective dissolution of grains (aragonite, high-Mg calcite) and/or cements (syntaxial inclusion-rich). However, stratigraphy and stable isotopes (oxygen and carbon), indicate that the molds found at shallower facies located beneath, and close to stratigraphic boundaries, have been produced by the infiltration of meteoric-derived water, which caused recrystallization without calcite cementation. Away from these stratigraphic locations, shallow- and deep-water facies show molds, and recrystallization, as well as low-Mg calcite cementation, interpreted as occurring during burial of these sediments by marine waters. The main cement source is suggested to be aragonite. Our results indicate that the Sedini Limestone Unit was transformed in three different diagenetic environments (marine, meteoric and shallow-burial marine); however, the degree of transformation in each diagenetic environment differs in the heterozoan-dominated ramp from the photozoan-dominated platform. It is suggested that the sediments from the ramp follow a diagenetic pathway similar to their heterozoan counterparts (i.e. lack of marine cementation, and loss of primary porosity by compaction), and the sediments from the platform follow a diagenetic pathway similar to their photozoan counterparts (i.e. marine cementation occluding primary porosity). However, in this carbonate setting, cements are Mg-calcite, no meteoric cementation was produced, and secondary porosity at shallow-water facies of the platform phase is mostly open and preserved. Despite the temporal and transitional change in biotic associations, ramp and platform facies (shallow- to deep-water facies) showed an oxygen isotope record overprinted by diagenesis. Oxygen primary marine signatures were not found. It is believed that burial diagenesis (recrystallization and low-Mg calcite cementation) was the main reason. This was unexpected at the ramp, since heterozoan-rich carbonates can hold isotope values close to primary marine signals due to their low-Mg calcite original composition. Ramp and platform facies (shallow- to deep-water facies) showed a carbon isotope record that was less affected by diagenesis. However, only at deep-water facies, did the carbon record show positive values comparable with carbon primary marine signals. The positive carbon values were noticed with major frequency at the platform deep-water facies. Moreover, these values usually showed a covariant trend with the oxygen isotope record; even that the latter did not hold positive values. The main conclusion of this work is that carbonates, deposited under warm-temperate to tropical conditions, have a unique facies, diagenesis and chemostratigraphic expression, which is different from their cool-water heterozoan or warm-water photozoan counterparts, reflecting the "transitional" nature of biotic association.}, language = {en} }