@article{SchmidtHoelter2009,
  author    = {Schmidt, Bernd and Hoelter, Frank},
  title     = {A stereodivergent synthesis of all stereoisomers of centrolobine : control of selectivity by a protecting-group manipulation},
  issn      = {0947-6539},
  doi       = {10.1002/chem.200902053},
  year      = {2009},
  abstract  = {All stereoisomers of the natural product centrolobine are selectively synthesized, by starting from a common precursor. Key steps are an enantioselective allylation with enantiomerically pure allylsilanes, a tandem ring-closing metathesis-isomerization reaction, and a Heck reaction by using an arene diazonium salt. By choosing appropriate conditions for the final deprotection step, either the cis-configured centrolobines or their epimers are selectively obtained.},
  language  = {en}
}