@article{MeshcheryakovMoskalikKellingetal.2008,
  author    = {Meshcheryakov, Vladimir I. and Moskalik, Mikail Yu. and Kelling, Alexandra and Schilde, Uwe and Ushakov, Igor A. and Shainyan, Bagrat A.},
  title     = {Oxymethylation of trifluoromethanesulfonamide with paraformaldehyde in ethyl acetate},
  issn      = {1070-4280},
  doi       = {10.1134/S1070428008020206},
  year      = {2008},
  abstract  = {Acid-catalyzed reaction of trifluoromethanesulfonamide with paraformaldehyde in ethyl acetate led to the formation of oxymethylated products that did not form in the reaction carried out in sulfuric acid. Following products were obtained: 5-trifluoromethylsulfonyl-1,3-dioxazinane, 3,7-bis-(trifluoromethylsulfonyl)-1,5,3,7-dioxadiazocane, and a complex of trifluoromethanesulfonamide with 2,4,8,10-tetraoxospiro[5,5]undecene, 1:1. The spiroring resulted from the cyclization of pentaerythritol under the action of formaldehyde. The pentaerythritol formed in its turn by oxymethylation of the methyl group of ethyl acetate with paraformaldehyde followed by the reduction of the COOEt group into CH2 OH by the formaldehyde.},
  language  = {en}
}
@article{ZehmFudickarHansetal.2008,
  author    = {Zehm, Daniel and Fudickar, Werner and Hans, Melanie and Schilde, Uwe and Kelling, Alexandra and Linker, Torsten},
  title     = {9,10-Diarylanthracenes as molecular switches : syntheses, properties, isomerisations and their reactions with singlet oxygen},
  issn      = {0947-6539},
  year      = {2008},
  abstract  = {A series of 9,10-diarylanthracenes with various substituents at the ortho positions have been synthesised by palladium-catalysed cross-coupling reactions. Such compounds exhibit interesting physical properties and can be applied as molecular switches. Despite the high steric demand of the substituents, products were formed in moderate-to-good yields. In some cases, microwave conditions further improved yields. Bis-coupling afforded two isomers (syn and anti) that do not interconvert at room temperature. These products were easily separated and their relative stereochemistries were unequivocally assigned by NMR spectroscopy and X-ray analysis. The syn and anti isomers exhibit different physical properties (e.g., melting points and solubilities) and interconversion by rotation around the aryl-aryl axis commences at <100 °C for fluoro-substituted diarylanthracenes and at >300 °C for alkyl- or alkoxy-substituted diarylanthracenes. The reactions with singlet oxygen were studied separately and revealed different reactivities and reaction pathways. The yields and reactivities depend on the size and electronic nature of the substituents. The anti isomers form the same 9,10-endoperoxides as the syn species, occasionally accompanied by unexpected 1,4-endoperoxides as byproducts. Thermolysis of the endoperoxides exclusively yielded the syn isomers. The interesting rotation around the aryl-aryl axis allows the application of 9,10-diarylanthracenes as molecular switches, which are triggered by light and air under mild conditions. Finally, the oxygenation and thermolysis sequence provides a simple, synthetic access to a single stereoisomer (syn) from an unselective coupling step.},
  language  = {en}
}
@article{HahnKellingSchildeetal.2008,
  author    = {Hahn, Simone and Kelling, Alexandra and Schilde, Uwe and Holdt, Hans-J{\"u}rgen},
  title     = {Crystal structure of bis(2-ethylthiomethylpyridine)platinum(II) hexachloroplatinate, [Pt(C8H11NS)2][PtCl6]},
  issn      = {1433-7266},
  doi       = {10.1524/ncrs.2008.0216},
  year      = {2008},
  abstract  = {C16H22Cl6N2Pt2S2, orthorhombic, Pbca (no. 61), a = 15.5660(8) angstrom, b = 17.4892(9) angstrom, c = 18.161 (1) angstrom, V = 4944. 1 angstrom(3), Z = 8, R-gt(F) = 0.030, wR(ref)(F-2) = 0.055, T = 210 K.},
  language  = {en}
}
@article{MondalDeyBaburinetal.2008,
  author    = {Mondal, Suvendu Sekhar and Dey, Subarna and Baburin, Igor A. and Kelling, Alexandra and Schilde, Uwe and Janiak, Christoph and Holdt, Hans-J{\"u}rgen},
  title     = {Syntheses of two imidazolate-4-amide-5-imidate linker based hexagonal metal-organic frameworks with flexible ethoxy substituent},
  doi       = {10.1039/C3CE41632A},
  year      = {2008},
  abstract  = {A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas- sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.},
  language  = {en}
}
@article{MondalBhuniaDemeshoketal.2008,
  author    = {Mondal, Suvendu Sekhar and Bhunia, Asamanjoy and Demeshok, Serhiy and Kelling, Alexandra and Schilde, Uwe and Janiak, Christoph and Holdt, Hans-J{\"u}rgen},
  title     = {Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption ans magnetic proberties},
  year      = {2008},
  abstract  = {A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.},
  language  = {en}
}
@article{MondalBhuniaBaburinetal.2008,
  author    = {Mondal, Suvendu Sekhar and Bhunia, Asamanjoy and Baburin, Igor A. and J{\"a}ger, Christian and Kelling, Alexandra and Schilde, Uwe and Seiert, Gotthard and Janiak, Christoph and Holdt, Hans-J{\"u}rgen},
  title     = {Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity},
  doi       = {10.1039/C3CC42156B},
  year      = {2008},
  abstract  = {A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.},
  language  = {en}
}
@article{ElamparuthiLinkerKellingetal.2009,
  author    = {Elamparuthi, Elangovan and Linker, Torsten and Kelling, Alexandra and Schilde, Uwe},
  title     = {Crystal structure of methyl 3,4-di-O-benzyl-2-deoxy-2-C-nitromethyl-alpha-D-arabinopyranoside, C21H25NO6},
  issn      = {1433-7266},
  doi       = {10.1524/ncrs.2009.0027},
  year      = {2009},
  language  = {en}
}
@phdthesis{ElamparuthiLinkerKellingetal.2009,
  author    = {Elamparuthi, Elangovan and Linker, Torsten and Kelling, Alexandra and Schilde, Uwe},
  title     = {Crystal structure of methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-nitromethyl-beta-D-galactopyranoside, C29H33NO7},
  issn      = {1433-7266},
  doi       = {10.1524/ncrs.2009.0054},
  year      = {2009},
  language  = {en}
}
@article{KammerKellingBaieretal.2009,
  author    = {Kammer, Stefan and Kelling, Alexandra and Baier, Heiko and Mickler, Wulfhard and Dosche, Carsten and Rurack, Knut and Kapp, Andreas and Lisdat, Fred and Holdt, Hans-J{\"u}rgen},
  title     = {2,11-dialkylated 1,12-diazaperylene copper(I) complexes : first supramolecular column assemblies by pi-pi stacking between homoleptic tetrahedral metal complexes, exhibiting low-energy MLCT transitions},
  issn      = {1434-1948},
  doi       = {10.1002/ejic.200900695},
  year      = {2009},
  abstract  = {2,11-Dialkylated 1,12-diazaperylenes (alkyl = Me, Et, iPr) dmedap, detdap and dipdap have been synthesized by reductive cyclization of 3,3-dialkylated 1,1-biisoquinolines 3a-c, resulting in the first copper(I) complexes of a large- surface ligand. The new copper(I) complexes show low-energy MLCT absorptions unprecedented for bis(-diimin)copper(I) complexes. The solid structures of the complexes[Cu(dipdap)2]BF4·CH2Cl2·1.5H2O, [Cu(dipdap)2]OTf·CH2Cl2, [Cu(dipdap)2]I·C2H4Cl2·THF·2H2O, [Cu(dmedap)2]OTf and [Cu(dipdap)2]AQSO3·H2O (AQSO3 = sodium 9,10-dihydro-9,10-dioxo-2- anthracenesulfonate) are reported. In [Cu(dipdap)2]BF4·CH2Cl2·1.5H2O, each copper(I) complex cation interacts with two others by - stacking interactions forming a novel supramolecular column structural motif running along the crystallographic c axis. In the crystalline compound [Cu(dipdap)2]AQSO3·H2O, aggregation between two complex cations and two additional anions by - stacking interactions is observed, leading to a tetrameric assembly. Furthermore, the three complex compounds [Cu(L)2]BF4 (L = dmedap, detdap, dipdap) were tested for sensory applications in aqueous buffer solutions in electrochemical studies of the complex immobilized on glassy carbon electrodes.},
  language  = {en}
}
@article{SchmidtWernerKellingetal.2010,
  author    = {Schmidt, Bernd and Werner, Frank and Kelling, Alexandra and Schilde, Uwe},
  title     = {The reaction of 3,4-dihydro-2H-pyran with oxalyl chloride : formation and crystal structure analysis of an unexpected bicyclic product},
  issn      = {0022-152X},
  year      = {2010},
  abstract  = {3,4-Dihydro-2-H-pyran and oxalyl chloride react, depending on the conditions, to keto esters, a pyran-3- carboxylic acid or derivatives thereof, or to an hitherto unknown bicyclic acetal containing a vinyl chloride moiety. The structure of the latter product has been unambiguously elucidated by single-crystal X-ray structure analysis. A mechanism for its formation is proposed.},
  language  = {en}
}