@article{QiuZhangBicketal.2021, author = {Qiu, Liang and Zhang, Haoran and Bick, Thomas and Martin, Johannes and Wendler, Petra and B{\"o}ker, Alexander and Glebe, Ulrich and Xing, Chengfen}, title = {Construction of highly ordered glyco-inside nano-assemblies through RAFT dispersion polymerization of galactose-decorated monomer}, series = {Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition}, volume = {60}, journal = {Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition}, number = {20}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1433-7851}, doi = {10.1002/anie.202015692}, pages = {11098 -- 11103}, year = {2021}, abstract = {Glyco-assemblies derived from amphiphilic sugar-decorated block copolymers (ASBCs) have emerged prominently due to their wide application, for example, in biomedicine and as drug carriers. However, to efficiently construct these glyco-assemblies is still a challenge. Herein, we report an efficient technology for the synthesis of glyco-inside nano-assemblies by utilizing RAFT polymerization of a galactose-decorated methacrylate for polymerization-induced self-assembly (PISA). Using this approach, a series of highly ordered glyco-inside nano-assemblies containing intermediate morphologies were fabricated by adjusting the length of the hydrophobic glycoblock and the polymerization solids content. A specific morphology of complex vesicles was captured during the PISA process and the formation mechanism is explained by the morphology of its precursor and intermediate. Thus, this method establishes a powerful route to fabricate glyco-assemblies with tunable morphologies and variable sizes, which is significant to enable the large-scale fabrication and wide application of glyco-assemblies.}, language = {en} } @article{RanLoveHeiberetal.2018, author = {Ran, Niva A. and Love, John A. and Heiber, Michael C. and Jiao, Xuechen and Hughes, Michael P. and Karki, Akchheta and Wang, Ming and Brus, Viktor V. and Wang, Hengbin and Neher, Dieter and Ade, Harald and Bazan, Guillermo C. and Thuc-Quyen Nguyen,}, title = {Charge generation and recombination in an organic solar cell with low energetic offsets}, series = {dvanced energy materials}, volume = {8}, journal = {dvanced energy materials}, number = {5}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201701073}, pages = {12}, year = {2018}, abstract = {Organic bulk heterojunction (BHJ) solar cells require energetic offsets between the donor and acceptor to obtain high short-circuit currents (J(SC)) and fill factors (FF). However, it is necessary to reduce the energetic offsets to achieve high open-circuit voltages (V-OC). Recently, reports have highlighted BHJ blends that are pushing at the accepted limits of energetic offsets necessary for high efficiency. Unfortunately, most of these BHJs have modest FF values. How the energetic offset impacts the solar cell characteristics thus remains poorly understood. Here, a comprehensive characterization of the losses in a polymer:fullerene BHJ blend, PIPCP:phenyl-C61-butyric acid methyl ester (PC61BM), that achieves a high V-OC (0.9 V) with very low energy losses (E-loss = 0.52 eV) from the energy of absorbed photons, a respectable J(SC) (13 mA cm(-2)), but a limited FF (54\%) is reported. Despite the low energetic offset, the system does not suffer from field-dependent generation and instead it is characterized by very fast nongeminate recombination and the presence of shallow traps. The charge-carrier losses are attributed to suboptimal morphology due to high miscibility between PIPCP and PC61BM. These results hold promise that given the appropriate morphology, the J(SC), V-OC, and FF can all be improved, even with very low energetic offsets.}, language = {en} } @article{ReifegersteElinClahsen2018, author = {Reifegerste, Jana and Elin, Kirill and Clahsen, Harald}, title = {Persistent differences between native speakers and late bilinguals}, series = {Bilingualism : language and cognition}, volume = {22}, journal = {Bilingualism : language and cognition}, number = {3}, publisher = {Cambridge Univ. Press}, address = {New York}, issn = {1366-7289}, doi = {10.1017/S1366728918000615}, pages = {425 -- 440}, year = {2018}, abstract = {Previous research with younger adults has revealed differences between native (L1) and non-native late-bilingual (L2) speakers with respect to how morphologically complex words are processed. This study examines whether these L1/L2 differences persist into old age. We tested masked-priming effects for derived and inflected word forms in older L1 and L2 speakers of German and compared them to results from younger L1 and L2 speakers on the same experiment (mean ages: 62 vs. 24). We found longer overall response times paired with better accuracy scores for older (L1 and L2) participants than for younger participants. The priming patterns, however, were not affected by chronological age. While both L1 and L2 speakers showed derivational priming, only the L1 speakers demonstrated inflectional priming. We argue that general performance in both L1 and L2 is affected by aging, but that the more profound differences between native and non-native processing persist into old age.}, language = {en} } @article{SauterKratzLendlein2013, author = {Sauter, Tilman and Kratz, Karl and Lendlein, Andreas}, title = {Pore-size distribution controls shape-memory properties on the macro- and microscale of polymeric foams}, series = {Macromolecular chemistry and physics}, volume = {214}, journal = {Macromolecular chemistry and physics}, number = {11}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1352}, doi = {10.1002/macp.201300062}, pages = {1184 -- 1188}, year = {2013}, abstract = {Open porous foams with identical foam density but different pore-size distributions (bimodal or monomodal) are prepared from a shape-memory polyetherurethane (PEU) by thermally induced phase separation. The shape-memory effect of the two PEU foams is explored by cyclic thermomechanical compression tests and microstructural analysis. The obtained results reveal that the PEU foam with a bimodal pore-size distribution exhibits an increased shape-recovery under stress-free conditions, both on the macro- (foam level) as well as the microscale (pore level). While bimodal pore-size distributions induce microscale bending during compression, buckling occurs in foams with monomodal pore-size distributions, leading to both a reduced and delayed shape recovery.}, language = {en} } @article{SchubertDolfenFrischetal.2012, author = {Schubert, Marcel and Dolfen, Daniel and Frisch, Johannes and Roland, Steffen and Steyrleuthner, Robert and Stiller, Burkhard and Chen, Zhihua and Scherf, Ullrich and Koch, Norbert and Facchetti, Antonio and Neher, Dieter}, title = {Influence of aggregation on the performance of All-Polymer Solar Cells containing Low-Bandgap Naphthalenediimide Copolymers}, series = {dvanced energy materials}, volume = {2}, journal = {dvanced energy materials}, number = {3}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201100601}, pages = {369 -- 380}, year = {2012}, abstract = {The authors present efficient all-polymer solar cells comprising two different low-bandgap naphthalenediimide (NDI)-based copolymers as acceptors and regioregular P3HT as the donor. It is shown that these naphthalene copolymers have a strong tendency to preaggregate in specific organic solvents, and that preaggregation can be completely suppressed when using suitable solvents with large and highly polarizable aromatic cores. Organic solar cells prepared from such nonaggregated polymer solutions show dramatically increased power conversion efficiencies of up to 1.4\%, which is mainly due to a large increase of the short circuit current. In addition, optimized solar cells show remarkable high fill factors of up to 70\%. The analysis of the blend absorbance spectra reveals a surprising anticorrelation between the degree of polymer aggregation in the solid P3HT:NDI copolymer blends and their photovoltaic performance. Scanning near-field optical microscopy (SNOM) and atomic force microscopy (AFM) measurements reveal important information on the blend morphology. It is shown that films with high degree of aggregation and low photocurrents exhibit large-scale phase-separation into rather pure donor and acceptor domains. It is proposed that, by suppressing the aggregation of NDI copolymers at the early stage of film formation, the intermixing of the donor and acceptor component is improved, thereby allowing efficient harvesting of photogenerated excitons at the donoracceptor heterojunction.}, language = {en} } @article{SchoeneSchulzRichauetal.2014, author = {Sch{\"o}ne, Anne-Christin and Schulz, Burkhard and Richau, Klaus and Kratz, Karl and Lendlein, Andreas}, title = {Characterization of Langmuir films prepared from copolyesterurethanes based on oligo(omega-pentadecalactone) and oligo(epsilon-caprolactone)segments}, series = {Macromolecular chemistry and physics}, volume = {215}, journal = {Macromolecular chemistry and physics}, number = {24}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1352}, doi = {10.1002/macp.201400377}, pages = {2437 -- 2445}, year = {2014}, abstract = {A series of multiblock copolymers (PDLCL) synthesized from oligo(omega-pentadecalactone) diol (OPDL) and oligo(epsilon-caprolactone) diol (OCL), which are linked by 2,2(4), 4-trimethyl-hexamethylene diisocyanate (TMDI), is investigated by the Langmuir monolayer technique at the air-water interface. Brewster angle microscopy (BAM) and spectroscopic ellipsometry are employed to characterize the polymer film morphologies in situ. PDLCL containing >= 40 wt\% OCL segments form homogeneous Langmuir monofilms after spreading. The film elasticity modulus decreases with increasing amounts of OPDL segments in the copolymer. In contrast, the OCL-free polyesterurethane OPDL-TMDI cannot be spread to monomolecular films on the water surface properly, and movable slabs are observed by BAM even at low surface pressures. The results of the in situ morphological characterization clearly show that essential information concerning the reliability of Langmuir monolayer degradation (LMD) experiments cannot be obtained from the evaluation of the pi-A isotherms only. Consequently, in situ morphological characterization turns out to be indispensable for characterization of Langmuir layers before LMD experiments.}, language = {en} } @article{Skopeteas2019, author = {Skopeteas, Stavros}, title = {Splits and Birds}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43257}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-432578}, pages = {335 -- 341}, year = {2019}, language = {en} } @article{Staudacher2019, author = {Staudacher, Peter}, title = {Plato on nature (φύσις) and convention (συνθήκη)}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43319}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-433193}, pages = {395 -- 411}, year = {2019}, language = {en} } @article{Stiebels2019, author = {Stiebels, Barbara}, title = {Bienenfresserortungsversuch}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43192}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-431921}, pages = {15 -- 26}, year = {2019}, language = {en} } @article{Thiersch2019, author = {Thiersch, Craig}, title = {A note on apparent sluicing in Malagasy}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43234}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-432341}, pages = {185 -- 209}, year = {2019}, language = {en} }