@article{StefancuNanZhuetal.2022, author = {Stefancu, Andrei and Nan, Lin and Zhu, Li and Chis, Vasile and Bald, Ilko and Liu, Min and Leopold, Nicolae and Maier, Stefan A. and Cortes, Emiliano}, title = {Controlling plasmonic chemistry pathways through specific ion effects}, series = {Advanced optical materials}, volume = {10}, journal = {Advanced optical materials}, number = {14}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {2195-1071}, doi = {10.1002/adom.202200397}, pages = {10}, year = {2022}, abstract = {Plasmon-driven dehalogenation of brominated purines has been recently explored as a model system to understand fundamental aspects of plasmon-assisted chemical reactions. Here, it is shown that divalent Ca2+ ions strongly bridge the adsorption of bromoadenine (Br-Ade) to Ag surfaces. Such ion-mediated binding increases the molecule's adsorption energy leading to an overlap of the metal energy states and the molecular states, enabling the chemical interface damping (CID) of the plasmon modes of the Ag nanostructures (i.e., direct electron transfer from the metal to Br-Ade). Consequently, the conversion of Br-Ade to adenine almost doubles following the addition of Ca2+. These experimental results, supported by theoretical calculations of the local density of states of the Ag/Br-Ade complex, indicate a change of the charge transfer pathway driving the dehalogenation reaction, from Landau damping (in the lack of Ca2+ ions) to CID (after the addition of Ca2+). The results show that the surface dynamics of chemical species (including water molecules) play an essential role in charge transfer at plasmonic interfaces and cannot be ignored. It is envisioned that these results will help in designing more efficient nanoreactors, harnessing the full potential of plasmon-assisted chemistry.}, language = {en} } @article{DebPopovaJaffresetal.2022, author = {Deb, Marwan and Popova, Elena and Jaffr{\`e}s, Henri-Yves and Keller, Niels and Bargheer, Matias}, title = {Controlling high-frequency spin-wave dynamics using double-pulse laser excitation}, series = {Physical review applied}, volume = {18}, journal = {Physical review applied}, number = {4}, publisher = {American Physical Society}, address = {College Park}, issn = {2331-7019}, doi = {10.1103/PhysRevApplied.18.044001}, pages = {7}, year = {2022}, abstract = {Manipulating spin waves is highly required for the development of innovative data transport and processing technologies. Recently, the possibility of triggering high-frequency standing spin waves in magnetic insulators using femtosecond laser pulses was discovered, raising the question about how one can manipulate their dynamics. Here we explore this question by investigating the ultrafast magnetiza-tion and spin-wave dynamics induced by double-pulse laser excitation. We demonstrate a suppression or enhancement of the amplitudes of the standing spin waves by precisely tuning the time delay between the two pulses. The results can be understood as the constructive or destructive interference of the spin waves induced by the first and second laser pulses. Our findings open exciting perspectives towards generating single-mode standing spin waves that combine high frequency with large amplitude and low magnetic damping.}, language = {en} } @article{LorenzClemensSchroetteretal.2022, author = {Lorenz, Claas and Clemens, Vera Elisabeth and Schr{\"o}tter, Max and Schnor, Bettina}, title = {Continuous verification of network security compliance}, series = {IEEE transactions on network and service management}, volume = {19}, journal = {IEEE transactions on network and service management}, number = {2}, publisher = {Institute of Electrical and Electronics Engineers}, address = {New York}, issn = {1932-4537}, doi = {10.1109/TNSM.2021.3130290}, pages = {1729 -- 1745}, year = {2022}, abstract = {Continuous verification of network security compliance is an accepted need. Especially, the analysis of stateful packet filters plays a central role for network security in practice. But the few existing tools which support the analysis of stateful packet filters are based on general applicable formal methods like Satifiability Modulo Theories (SMT) or theorem prover and show runtimes in the order of minutes to hours making them unsuitable for continuous compliance verification. In this work, we address these challenges and present the concept of state shell interweaving to transform a stateful firewall rule set into a stateless rule set. This allows us to reuse any fast domain specific engine from the field of data plane verification tools leveraging smart, very fast, and domain specialized data structures and algorithms including Header Space Analysis (HSA). First, we introduce the formal language FPL that enables a high-level human-understandable specification of the desired state of network security. Second, we demonstrate the instantiation of a compliance process using a verification framework that analyzes the configuration of complex networks and devices - including stateful firewalls - for compliance with FPL policies. Our evaluation results show the scalability of the presented approach for the well known Internet2 and Stanford benchmarks as well as for large firewall rule sets where it outscales state-of-the-art tools by a factor of over 41.}, language = {en} } @article{GutschmannSimoesSchieweetal.2022, author = {Gutschmann, Bj{\"o}rn and Sim{\~o}es, Matilde Maldonado and Schiewe, Thomas and Schr{\"o}ter, Edith S. and M{\"u}nzberg, Marvin and Neubauer, Peter and Bockisch, Anika and Riedel, Sebastian Lothar Stefan}, title = {Continuous feeding strategy for polyhydroxyalkanoate production from solid waste animal fat at laboratory- and pilot-scale}, series = {Microbial biotechnology / Society for Applied Microbiology}, journal = {Microbial biotechnology / Society for Applied Microbiology}, publisher = {Wiley}, address = {Hoboken}, issn = {1751-7915}, doi = {10.1111/1751-7915.14104}, pages = {12}, year = {2022}, abstract = {Bioconversion of waste animal fat (WAF) to polyhydroxyalkanoates (PHAs) is an approach to lower the production costs of these plastic alternatives. However, the solid nature of WAF requires a tailor-made process development. In this study, a double-jacket feeding system was built to thermally liquefy the WAF to employ a continuous feeding strategy. During laboratory-scale cultivations with Ralstonia eutropha Re2058/pCB113, 70\% more PHA (45 g(PHA) L-1) and a 75\% higher space-time yield (0.63 g(PHA) L-1 h(-1)) were achieved compared to previously reported fermentations with solid WAF. During the development process, growth and PHA formation were monitored in real-time by in-line photon density wave spectroscopy. The process robustness was further evaluated during scale-down fermentations employing an oscillating aeration, which did not alter the PHA yield although cells encountered periods of oxygen limitation. Flow cytometry with propidium iodide staining showed that more than two-thirds of the cells were viable at the end of the cultivation and viability was even little higher in the scale-down cultivations. Application of this feeding system at 150-L pilot-scale cultivation yielded in 31.5 g(PHA) L-1, which is a promising result for the further scale-up to industrial scale.}, language = {en} } @article{NingYuMeietal.2022, author = {Ning, Jiaoyi and Yu, Hongtao and Mei, Shilin and Sch{\"u}tze, Yannik and Risse, Sebastian and Kardjilov, Nikolay and Hilger, Andr{\´e} and Manke, Ingo and Bande, Annika and Ruiz, Victor G. and Dzubiella, Joachim and Meng, Hong and Lu, Yan}, title = {Constructing binder- and carbon additive-free organosulfur cathodes based on conducting thiol-polymers through electropolymerization for lithium-sulfur batteries}, series = {ChemSusChem}, volume = {15}, journal = {ChemSusChem}, number = {14}, publisher = {Wiley}, address = {Weinheim}, issn = {1864-5631}, doi = {10.1002/cssc.202200434}, pages = {10}, year = {2022}, abstract = {Herein, the concept of constructing binder- and carbon additive-free organosulfur cathode was proved based on thiol-containing conducting polymer poly(4-(thiophene-3-yl) benzenethiol) (PTBT). The PTBT featured the polythiophene-structure main chain as a highly conducting framework and the benzenethiol side chain to copolymerize with sulfur and form a crosslinked organosulfur polymer (namely S/PTBT). Meanwhile, it could be in-situ deposited on the current collector by electro-polymerization, making it a binder-free and free-standing cathode for Li-S batteries. The S/PTBT cathode exhibited a reversible capacity of around 870 mAh g(-1) at 0.1 C and improved cycling performance compared to the physically mixed cathode (namely S\&PTBT). This multifunction cathode eliminated the influence of the additives (carbon/binder), making it suitable to be applied as a model electrode for operando analysis. Operando X-ray imaging revealed the remarkable effect in the suppression of polysulfides shuttle via introducing covalent bonds, paving the way for the study of the intrinsic mechanisms in Li-S batteries.}, language = {en} } @article{JoziNajafabadiHaberlandLeBretonetal.2022, author = {Jozi Najafabadi, Azam and Haberland, Christian and Le Breton, Eline and Handy, Mark R. and Verwater, Vincent F. and Heit, Benjamin and Weber, Michael}, title = {Constraints on crustal structure in the vicinity of the adriatic indenter (European Alps) from Vp and Vp/Vs local earthquake tomography}, series = {Journal of geophysical research : Solid earth}, volume = {127}, journal = {Journal of geophysical research : Solid earth}, number = {2}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9313}, doi = {10.1029/2021JB023160}, pages = {22}, year = {2022}, abstract = {In this study, 3-D models of P-wave velocity (Vp) and P-wave and S-wave ratio (Vp/Vs) of the crust and upper mantle in the Eastern and eastern Southern Alps (northern Italy and southern Austria) were calculated using local earthquake tomography (LET). The data set includes high-quality arrival times from well-constrained hypocenters observed by the dense, temporary seismic networks of the AlpArray AASN and SWATH-D. The resolution of the LET was checked by synthetic tests and analysis of the model resolution matrix. The small inter-station spacing (average of similar to 15 km within the SWATH-D network) allowed us to image crustal structure at unprecedented resolution across a key part of the Alps. The derived P velocity model revealed a highly heterogeneous crustal structure in the target area. One of the main findings is that the lower crust is thickened, forming a bulge at 30-50 km depth just south of and beneath the Periadriatic Fault and the Tauern Window. This indicates that the lower crust decoupled both from its mantle substratum as well as from its upper crust. The Moho, taken to be the iso-velocity contour of Vp = 7.25 km/s, agrees with the Moho depth from previous studies in the European and Adriatic forelands. It is shallower on the Adriatic side than on the European side. This is interpreted to indicate that the European Plate is subducted beneath the Adriatic Plate in the Eastern and eastern Southern Alps.}, language = {en} } @article{HuthPangTewsetal.2022, author = {Huth, Sabrina and Pang, Peter Tsun Ho and Tews, Ingo and Dietrich, Tim and Le F{\`e}vre, Arnaud and Schwenk, Achim and Trautmann, Wolfgang and Agarwal, Kshitij and Bulla, Mattia and Coughlin, Michael W. and Van den Broeck, Chris}, title = {Constraining neutron-star matter with microscopic and macroscopic collisions}, series = {Nature : the international weekly journal of science}, volume = {606}, journal = {Nature : the international weekly journal of science}, number = {7913}, publisher = {Nature Publ. Group}, address = {London [u.a.]}, issn = {0028-0836}, doi = {10.1038/s41586-022-04750-w}, pages = {276 -- 295}, year = {2022}, abstract = {Interpreting high-energy, astrophysical phenomena, such as supernova explosions or neutron-star collisions, requires a robust understanding of matter at supranuclear densities. However, our knowledge about dense matter explored in the cores of neutron stars remains limited. Fortunately, dense matter is not probed only in astrophysical observations, but also in terrestrial heavy-ion collision experiments. Here we use Bayesian inference to combine data from astrophysical multi-messenger observations of neutron stars(1-9) and from heavy-ion collisions of gold nuclei at relativistic energies(10,11) with microscopic nuclear theory calculations(12-17) to improve our understanding of dense matter. We find that the inclusion of heavy-ion collision data indicates an increase in the pressure in dense matter relative to previous analyses, shifting neutron-star radii towards larger values, consistent with recent observations by the Neutron Star Interior Composition Explorer mission(5-8,18). Our findings show that constraints from heavy-ion collision experiments show a remarkable consistency with multi-messenger observations and provide complementary information on nuclear matter at intermediate densities. This work combines nuclear theory, nuclear experiment and astrophysical observations, and shows how joint analyses can shed light on the properties of neutron-rich supranuclear matter over the density range probed in neutron stars.}, language = {en} } @article{YangGhoshRoeseretal.2022, author = {Yang, Jin and Ghosh, Samrat and Roeser, J{\´e}r{\^o}me and Acharjya, Amitava and Penschke, Christopher and Tsutsui, Yusuke and Rabeah, Jabor and Wang, Tianyi and Tameu, Simon Yves Djoko and Ye, Meng-Yang and Gr{\"u}neberg, Julia and Li, Shuang and Li, Changxia and Schomaecker, Reinhard and Van de Krol, Roel and Seki, Shu and Saalfrank, Peter and Thomas, Arne}, title = {Constitutional isomerism of the linkages in donor-acceptor covalent organic frameworks and its impact on photocatalysis}, series = {Nature Communications}, volume = {13}, journal = {Nature Communications}, number = {1}, publisher = {Nature Publishing Group UK}, address = {[London]}, issn = {2041-1723}, doi = {10.1038/s41467-022-33875-9}, pages = {10}, year = {2022}, abstract = {When new covalent organic frameworks (COFs) are designed, the main efforts are typically focused on selecting specific building blocks with certain geometries and properties to control the structure and function of the final COFs. The nature of the linkage (imine, boroxine, vinyl, etc.) between these building blocks naturally also defines their properties. However, besides the linkage type, the orientation, i.e., the constitutional isomerism of these linkages, has rarely been considered so far as an essential aspect. In this work, three pairs of constitutionally isomeric imine-linked donor-acceptor (D-A) COFs are synthesized, which are different in the orientation of the imine bonds (D-C=N-A (DCNA) and D-N=C-A (DNCA)). The constitutional isomers show substantial differences in their photophysical properties and consequently in their photocatalytic performance. Indeed, all DCNA COFs show enhanced photocatalytic H2 evolution performance than the corresponding DNCA COFs. Besides the imine COFs shown here, it can be concluded that the proposed concept of constitutional isomerism of linkages in COFs is quite universal and should be considered when designing and tuning the properties of COFs.}, language = {en} } @article{SchmandtNazziNew2022, author = {Schmandt, Silvana and Nazzi, Thierry and New, Boris}, title = {Consonant, vowel and lexical neighbourhood processing during word recognition: new evidence using the sandwich priming technique}, series = {Language, cognition and neuroscience}, volume = {37}, journal = {Language, cognition and neuroscience}, number = {9}, publisher = {Routledge, Taylor \& Francis Group}, address = {Abingdon}, issn = {2327-3798}, doi = {10.1080/23273798.2022.2046115}, pages = {1115 -- 1130}, year = {2022}, abstract = {Studies on French adults using a written lexical decision task with masked priming, in which targets were more primed by consonant- (jalu-JOLI) than vowel-related (vobi-JOLI) primes, support the proposal that consonants have more weight than vowels in lexical processing. This study examines the phonological and/or lexical nature of this consonant bias (C-bias), using a sandwich priming task in which a brief presentation of the target (pre-prime) precedes the prime-target sequence, a manipulation blocking lexical neighbourhood effects. Results from three experiments (varying pre-prime/prime durations) show consistent C-priming and no significant V-priming at earlier and later processing stages (50 or 66 ms primes). Yet, a joint analysis reveals a small V-priming, while confirming a significant consonant advantage. This demonstrates the contribution of the phonological level to the C-bias. Second, differences in performance comparing the classic versus sandwich priming task also establish a contribution of lexical neighbourhood inhibition effects to the C-bias.}, language = {en} } @article{AransonPikovskij2022, author = {Aranson, Igor S. and Pikovskij, Arkadij}, title = {Confinement and collective escape of active particles}, series = {Physical review letters}, volume = {128}, journal = {Physical review letters}, number = {10}, publisher = {American Physical Society}, address = {College Park, Md.}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.128.108001}, pages = {6}, year = {2022}, abstract = {Active matter broadly covers the dynamics of self-propelled particles. While the onset of collective behavior in homogenous active systems is relatively well understood, the effect of inhomogeneities such as obstacles and traps lacks overall clarity. Here, we study how interacting, self-propelled particles become trapped and released from a trap. We have found that captured particles aggregate into an orbiting condensate with a crystalline structure. As more particles are added, the trapped condensates escape as a whole. Our results shed light on the effects of confinement and quenched disorder in active matter.}, language = {en} }