TY  - JOUR
A1  - Liebig, Ferenc
A1  - Henning, Ricky
A1  - Sarhan, Radwan Mohamed
A1  - Prietzel, Claudia Christina
A1  - Bargheer, Matias
A1  - Koetz, Joachim
T1  - A new route to gold nanoflowers
T2  - Nanotechnology
N2  - Catanionic vesicles spontaneously formed by mixing the anionic surfactant bis(2-ethylhexyl)sulfosuccinate sodium salt with the cationic surfactant cetyltrimethylammonium bromide were used as a reducing medium to produce gold clusters, which are embedded and well-ordered into the template phase. The gold clusters can be used as seeds in the growth process that follows by adding ascorbic acid as a mild reducing component. When the ascorbic acid was added very slowly in an ice bath round-edged gold nanoflowers were produced. When the same experiments were performed at room temperature in the presence of Ag+ ions, sharp-edged nanoflowers could be synthesized. The mechanism of nanoparticle formation can be understood to be a non-diffusion-limited Ostwald ripening process of preordered gold nanoparticles embedded in catanionic vesicle fragments. Surface-enhanced Raman scattering experiments show an excellent enhancement factor of 1.7 . 10(5) for the nanoflowers deposited on a silicon wafer.
KW  - catanionic vesicles
KW  - gold cluster
KW  - gold nanoflowers
KW  - crystal growth
KW  - HRTEM
KW  - SEM
Y1  - 2018
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/52913
SN  - 0957-4484
SN  - 1361-6528
VL  - 29
IS  - 18
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  -