TY  - JOUR
A1  - Holdt, Hans-Jürgen
A1  - Müller, Holger
A1  - Kelling, Alexandra
A1  - Drexler, Hans-Joachim
A1  - Müller, Thomas
A1  - Schwarze, Thomas
A1  - Schilde, Uwe
A1  - Starke, Ines
T1  - Mercury(II) chloride and iodide complexes of dithia- and tetrathiacrown ethers
N2  - The complexes [(HgCl2)(2)((ch)(2)30S(4)O(6))] (1), [HgCl,(mn21S(2)O(5))] (2), [HgCl2(ch18S(2)O(4))] (3) and [HgI(meb12S(2)O(2))](2)[Hg2I6] (4) have been synthesized, characterized and their crystal structures were determined. In [(HgCl2)(2)((ch)(2)3OS(4)O(6))] two HgCl2 units are discretely bonded within the ligand cavity of the 30-membered dichinoxaline-tetrathia-30-crown-10 ((ch)(2)30S(4)O(6)) forming a binuclear complex. HgCl2 forms I : I "in-cavity" complexes with the 21-membered maleonitrile-dithia-21-crown-7(mn21S(2)O(5)) ligand and the 18-membered chinoxaline- dithia-18-crown-6 (ch18S(2)O(4)) ligand, respectively. The 12-membered 4-methyl-benzo-dithia-12-crown-4 (meb12S(2)O(2)) ligand gave with two equivalents HgI2 the compound [HgI(meb12S(2)O(2))](2)[Hg2I6]. In the cation [HgI(meb12S(2)O(2))](+) meb12S(2)O(2) forms with the cation HgI+ a half-sandwich complex
Y1  - 2006
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/12147
UR  - http://www3.interscience.wiley.com/cgi-bin/jhome/10005159
SN  - 0044-2313
ER  -