TY  - JOUR
A1  - Schmidt, Bernd
A1  - Kunz, Oliver
T1  - Stereoselective synthesis of dienyl phosphonates via extended tethered ring-closing metathesis
T2  - Organic letters
N2  - Allylphosphonates of allylic alcohols were converted to conjugated dienyl phosphonates in a one-flask reaction, comprising a ring-closing metathesis (RCM), a base-induced ring-opening, and an alkylation. The ring-opening proceeds with very high diastereoselectivity, giving exclusively the (1Z,3E)-configured dienes. Single diastereomers and mixtures of diastereomers can be used as starting materials without noticeable effect on the diastereoselectivity of the sequence.
Y1  - 2013
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/34741
SN  - 1523-7060
SN  - 1523-7052
VL  - 15
IS  - 17
SP  - 4470
EP  - 4473
PB  - American Chemical Society
CY  - Washington
ER  -