TY  - JOUR
A1  - Schuh, Christian
A1  - Lomadze, Nino
A1  - Rühe, Jürgen
A1  - Kopyshev, Alexey
A1  - Santer, Svetlana
T1  - Photomechanical degrafting of Azo-functionalized Poly(methacrylic acid) (PMAA) brushes
T2  - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry
N2  - We report on the preparation and characterization of photosensitive polymer brushes. The brushes are synthesized through polymer analogous attachment of azobenzene groups to surface-attached poly(methacrylic acid) (PMAA) chains. The topography of the photosensitive brushes shows a strong reaction upon irradiation with UV light. While homogeneous illumination leaves the polymer topography unchanged, irradiation of the samples with interference patterns with periodically varying light intensity leads to the formation of surface relief gratings (SRG). The height of the stripes of the grating can be controlled by adjusting the irradiation time. The SRG pattern can be erased through solvent treatment when the periodicity of the stripe pattern is less than the length of the fully stretched polymer chains. In the opposite case, photomechanical scission of receding polymer chains is observed during SRG formation, and the inscribed patterns are permanent.
Y1  - 2011
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/36608
SN  - 1520-6106
VL  - 115
IS  - 35
SP  - 10431
EP  - 10438
PB  - American Chemical Society
CY  - Washington
ER  -