TY  - JOUR
A1  - Shainyan, Bagrat A.
A1  - Kirpichenko, Svetlana V.
A1  - Shlykov, Sergei A.
A1  - Keinpeter, Erich
T1  - Structure and conformational properties of 1,3,3-Trimethyl-1,3-Azasilinane gas electron diffraction, dynamic NMR, and theoretical study
T2  - The journal of physical chemistry : A, Molecules, spectroscopy, kinetics, environment & general theory
N2  - Structure and the conformational properties of 1,3,3-trimethyl-1,3-azasilinane have been studied. According to gas electron diffraction (GED), the molecule exists in a slightly distorted chair conformation with the N-Me group in equatorial position. High-level quantum chemical calculations excellently, reproduce the experimental geometry. Employing variable temperature H-1 and C-13 NMR spectroscopy down to 103 K, the conformational equilibrium could be frozen and the barrier to ring inversion determined.
Y1  - 2012
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/36200
SN  - 1089-5639
VL  - 116
IS  - 1
SP  - 784
EP  - 789
PB  - American Chemical Society
CY  - Washington
ER  -