TY  - JOUR
A1  - Sun, Y-P
A1  - Pietzsch, Annette
A1  - Hennies, Franz
A1  - Rinkevicius, Z.
A1  - Karlsson, Hans O.
A1  - Schmitt, Thorsten
A1  - Strocov, Vladimir N.
A1  - Andersson, Joakim
A1  - Kennedy, B.
A1  - Schlappa, J.
A1  - Föhlisch, Alexander
A1  - Gel'mukhanov, F.
A1  - Rubensson, Jan-Erik
T1  - Internal symmetry and selection rules in resonant inelastic soft x-ray scattering
T2  - Journal of physics : B, Atomic, molecular and optical physics
N2  - Resonant inelastic soft x-ray scattering spectra excited at the dissociative 1 sigma(g) -> 3 sigma(u) resonance in gas-phase O(2) are presented and discussed in terms of state-of-the-art molecular theory. A new selection rule due to internal spin coupling is established, facilitating a deep analysis of the valence excited final states. Furthermore, it is found that a commonly accepted symmetry selection rule due to orbital parity breaks down, as the core hole and excited electron swap parity, thereby opening the symmetry forbidden 3 sigma(g) decay channel.
Y1  - 2011
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/36674
SN  - 0953-4075
VL  - 44
IS  - 16
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  -