TY  - JOUR
A1  - Kreye, Oliver
A1  - Toth, Tommy
A1  - Meier, Michael A. R.
T1  - Copolymers derived from rapeseed derivatives via ADMET and thiol-ene addition
T2  - European polymer journal
N2  - Novel (co)polymers were synthesized from substances obtained from rapeseed via ADMET and thiol-ene additions. alpha,omega-Dienes derived from oleic and erucic acid were copolymerized with a ferulic acid derivative, a representative phenolic acid (p-hydroxycinnamic acid) present, for instance, in rapeseed cake. Copolymers with different ratios of these monomers were prepared via two different routes (ADMET and thiol-ene) and studied in detail. Both monomer and polymer synthesis were optimized in order to achieve high yielding synthetic procedures that meet the requirements of green chemistry. Some thermal properties of the resulting copolymer series were then studied and correlated to the co-monomer composition.
KW  - Rapeseed oil
KW  - Rapeseed cake
KW  - p-Hydroxycinnamic acids
KW  - alpha,omega-Dienes
KW  - ADMET polymerization
KW  - Thiol-ene addition
Y1  - 2011
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/36634
SN  - 0014-3057
VL  - 47
IS  - 9
SP  - 1804
EP  - 1816
PB  - Elsevier
CY  - Oxford
ER  -