TY  - JOUR
A1  - Wessig, Pablo
A1  - Matthes, Annika
A1  - Pick, Charlotte
T1  - The photo-dehydro-Diels-Alder (PDDA) reaction
T2  - Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry
N2  - The photo-dehydro-Diels-Alder (PDDA) reaction is a valuable extension of the classical Diels-Alder (DA) reaction. The PDDA reaction differs from the DA reaction by the replacement of one of the C-C-double bonds of the diene moiety by a C-C triple bond and by the photochemical triggering of the reaction. This entails that, in contrast to the DA reaction, the PDDA reaction proceeds according to a multistage mechanism with biradicals and cycloallenes as intermediates. The PDDA reaction provides access to a considerable variety of compound classes. For example, 1-phenylnaphthlenes, 1,1'-binaphthyls, N-heterocyclic biaryls, and naphthalenophanes could be obtained by this reaction.
Y1  - 2011
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/37219
SN  - 1477-0520
VL  - 9
IS  - 22
SP  - 7599
EP  - 7605
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -