TY  - JOUR
A1  - Schmidt, Bernd
A1  - Hauke, Sylvia
T1  - Cross metathesis of allyl alcohols how to suppress and how to promote double bond isomerization
T2  - Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry
N2  - Under standard conditions the cross metathesis of allyl alcohols and methyl acrylate is accompanied by the formation of ketones, resulting from uncontrolled and undesired double bond isomerization. By conducting the CM in the presence of phenol, the catalyst loading and the reaction time required for quantiative conversion can be reduced, and isomerization can be suppressed. On the other hand, consecutive isomerization can be deliberately promoted by evaporating excess methyl acrylate after completing cross metathesis and by adding a base or silane as chemical triggers.
Y1  - 2013
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/35357
SN  - 1477-0520
VL  - 11
IS  - 25
SP  - 4194
EP  - 4206
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -