TY  - JOUR
A1  - Behrendt, Felix Nicolas
A1  - Schlaad, Helmut
T1  - Metathesis polymerization of cystine-based macrocycles
T2  - Polymer Chemistry
N2  - Macrocycles based on L-cystine were synthesized by ring-closing metathesis (RCM) and subsequently polymerized by entropy-driven ring-opening metathesis polymerization (ED-ROMP). Monomer conversion reached similar to 80% in equilibrium and the produced poly (ester-amine-disulfide-alkene)s exhibited apparent molar masses (M-w(app)) of up to 80 kDa and dispersities (D) of similar to 2. The polymers can be further functionalized with acid anhydrides and degraded by reductive cleavage of the main-chain disulfide.
Y1  - 2016
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/55496
SN  - 1759-9954
SN  - 1759-9962
VL  - 8
IS  - 2
SP  - 366
EP  - 369
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -