TY  - JOUR
A1  - Pimpalpalle, Tukaram M.
A1  - Yin, Jian
A1  - Linker, Torsten
T1  - Barton radical reactions of 2-C-branched carbohydrates
T2  - Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry
N2  - Barton esters have been introduced into the side chain of carbohydrates with high yields in only a few steps from easily available glycals. Their radical reactions afford 2-C-methyl and 2-C-bromomethyl hexoses, pentoses and disaccharides in good yields in analytically pure form. Since the Barton esters have been synthesized by an oxidative radical addition and their transformations by reductive radical processes, our results demonstrate the power of such reactions in carbohydrate chemistry.
Y1  - 2012
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/36425
SN  - 1477-0520
VL  - 10
IS  - 1
SP  - 103
EP  - 109
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -