TY  - JOUR
A1  - Ochmann, Miguel
A1  - Vaz da Cruz, Vinicius
A1  - Eckert, Sebastian
A1  - Huse, Nils
A1  - Föhlisch, Alexander
T1  - R-Group stabilization in methylated formamides observed by resonant inelastic X-ray scattering
T2  - Chemical communications: ChemComm
N2  - The inherent stability of methylated formamides is traced to a stabilization of the deep-lying sigma-framework by resonant inelastic X-ray scattering at the nitrogen K-edge. Charge transfer from the amide nitrogen to the methyl groups underlie this stabilization mechanism that leaves the aldehyde group essentially unaltered and explains the stability of secondary and tertiary amides.
Y1  - 2022
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/63244
SN  - 1359-7345
SN  - 1364-548X
VL  - 58
IS  - 63
SP  - 8834
EP  - 8837
PB  - The Royal Society of Chemistry
CY  - Cambridge
ER  -