TY  - JOUR
A1  - Stolterfoht, Martin
A1  - Le Corre, Vincent M.
A1  - Feuerstein, Markus
A1  - Caprioglio, Pietro
A1  - Koster, Lambert Jan Anton
A1  - Neher, Dieter
T1  - Voltage-Dependent Photoluminescence and How It Correlates with the Fill Factor and Open-Circuit Voltage in Perovskite Solar Cells
T2  - Acs energy letters
N2  - Optimizing the photoluminescence (PL) yield of a solar cell has long been recognized as a key principle to maximize the power conversion efficiency. While PL measurements are routinely applied to perovskite films and solar cells under open circuit conditions (V-OC), it remains unclear how the emission depends on the applied voltage. Here, we performed PL(V) measurements on perovskite cells with different hole transport layer thicknesses and doping concentrations, resulting in remarkably different fill factors (FFs). The results reveal that PL(V) mirrors the current-voltage (JV) characteristics in the power-generating regime, which highlights an interesting correlation between radiative and nonradiative recombination losses. In particular, high FF devices show a rapid quenching of PL(V) from open-circuit to the maximum power point. We conclude that, while the PL has to be maximized at V-OC at lower biases < V-OC the PL must be rapidly quenched as charges need to be extracted prior to recombination.
Y1  - 2019
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/47739
SN  - 2380-8195
VL  - 4
IS  - 12
SP  - 2887
EP  - 2892
PB  - American Chemical Society
CY  - Washington
ER  -