TY  - JOUR
A1  - Wessig, Pablo
A1  - Gerngross, Maik
A1  - Pape, Simon
A1  - Bruhns, Philipp
A1  - Weber, Jens
T1  - Novel porous materials based on oligospiroketals (OSK)
T2  - RSC Advances
N2  - New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.
Y1  - 2014
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/38241
SN  - 2046-2069
VL  - 4
IS  - 59
SP  - 31123
EP  - 31129
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -